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arXiv 2109.02697cond-mat.soft
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退火无序对流体混合物相分离动力学和老化现象的影响

Effect of Annealed Disorder on Phase Separation Kinetics and Aging Phenomena in Fluid Mixtures

Rounak Bhattacharyya, Bhaskar Sen Gupta

摘要:

我们使用最先进的分子动力学模拟,研究退火无序的影响相分离动力学和老化现象的二元流体混合物。在无序的存在下,我们观察到一个戏剧性的相分离动力学减慢。磁畴生长遵循幂律,指数依赖于无序。由于能量上有利的位置,畴边界变粗糙,这将关联函数和结构因子修改为非Porod行为。关联函数和结构因子提供了明确的证据,证明超普适性在我们的系统中不成立。通过计算二次序参量自相关函数,定性地研究了退火无序对非平衡时效动力学的作用。关联函数的衰减随无序度显著减慢。这个量表现出的比例律相对于在观察时间和年龄的系统的域长度的比率。我们发现标度律适用于无序系统,因此对这种分离的流体混合物具有鲁棒性和通用性。

英文摘要:

We use state-of-the-art molecular dynamics simulations to study the effects of annealed disorder on the phase separating kinetics and aging phenomena of a segregating binary fluid mixture. In the presence of disorder, we observe a dramatic slowing down in the phase separation dynamics. The domain growth follows the power-law with a disorder-dependent exponent. Due to the energetically favorable positions, the domain boundary roughens which modifies the correlation function and structure factor to a non-Porod behavior. The correlation function and structure factor provide clear evidence that the superuniversality does not hold in our system. The role of annealed disorder on the non-equilibrium aging dynamics is studied qualitatively by computing the two-time order parameter autocorrelation function. The decay of the correlation function slows down significantly with the disorder. This quantity exhibits scaling laws with respect to the ratio of the domain length at the observation time and the age of the system. We find the scaling laws hold good for the disordered system and therefore, robust and generic to such segregating fluid mixtures.

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