HCN/HNC chemistry in shocks: a study of L1157-B1 with ASAI
B. Lefloch, G. Busquet, S. Viti, C. Vastel, E. Mendoza, M. Benedettini, C. Codella, L. Podio, A. Schutzer, P. R. Rivera-Ortiz, J. R. D. Lépine, R. Bachiller
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14 pages, 7 figures. Accepted for publication in MNRAS
HCN and its isomer HNC play an important role in molecular cloud chemistry and the formation of more complex molecules. We investigate here the impact of protostellar shocks on the HCN and HNC abundances from high-sensitivity IRAM 30m observations of the prototypical shock region L1157-B1 and the envelope of the associated Class 0 protostar, as a proxy for the pre-shock gas. The isotopologues H$^{12}$CN, HN$^{12}$C, H$^{13}$CN, HN$^{13}$C, HC$^{15}$N, H$^{15}$NC, DCN and DNC were all detected towards both regions. Abundances and excitation conditions were obtained from radiative transfer analysis of molecular line emission under the assumption of Local Thermodynamical Equilibrium. In the pre-shock gas, the abundances of the HCN and HNC isotopologues are similar to those encountered in dark clouds, with a HCN/HNC abundance ratio $\approx 1$ for all isotopologues. A strong D-enrichment (D/H$\approx 0.06$) is measured in the pre-shock gas. There is no evidence of $^{15}$N fractionation neither in the quiescent nor in the shocked gas. At the passage of the shock, the HCN and HNC abundances increase in the gas phase in different manners so that the HCN/HNC relative abundance ratio increases by a factor 20. The gas-grain chemical and shock model UCLCHEM allows us to reproduce the observed trends for a C-type shock with pre-shock density $n$(H)= $10^5$cm$^{-3}$ and shock velocity $V_s= 40$km/s. We conclude that the HCN/HNC variations across the shock are mainly caused by the sputtering of the grain mantle material in relation with the history of the grain ices.
ALMA Multiple-Transition Molecular Line Observations of the Ultraluminous Infrared Galaxy IRAS 20551-4250: Different HCN, HCO+, HNC Excitation and Implications for Infrared Radiative Pumping
我们提出了我们的ALMA多跃迁分子线观测结果的超亮红外星系，IRAS 20551-4250，这是已知的包含一个发光的掩埋活动星系核，并显示可检测的振动激发（v2=1f）HCN和HNC发射线。HCN、HCO+和HNC的转动J=1-0、4-3和8-7发射线在振动基态（v=0）处被清楚地检测到。振动激发（v2=1f）J=4-3的发射线被检测到的HCN和HNC，但没有HCO+。它们观测到的通量比进一步支持了我们先前基于J=3-2数据获得的建议，即（1）红外辐射泵浦在v=0处的旋转激发中起作用，至少对于HCN和HNC，以及（2）HCN丰度高于HCO+和HNC。同位素H13 CN、H13 CO+和HN 13 C J=3-2发射线的通量测量支持更高HCN丰度的情况。基于碰撞激发模型，我们约束这些线发射分子气体的物理性质，但发现更高的HNC旋转激发比HCN和HCO+是很难解释的，由于更高的有效临界密度的HNC。我们考虑了红外辐射泵浦的影响，使用现有的5-30微米的红外光谱，发现我们的观测结果很好地解释，如果辐射源位于30-100 pc的分子气体。同时覆盖的非常明亮的CO J=3-2发射线显示了一个广泛的发射翼，我们解释为由于分子外流活动的估计速度约为150 Msun/yr。
Context. The gas kinetic temperature (TK) determines the physical and chemical evolution of the Interestellar Medium (ISM). However, obtaining reliable TK estimates usually requires expensive observations including the combination of multi-line analysis and dedicated radiative transfer calculations. Aims. This work explores the use of HCN and HNC observations, and particularly its I(HCN)/I(HNC) intensity ratio of their J=1-0 lines, as direct probe of the gas kinetic temperature in the molecular ISM. Methods. We obtained a new set of large-scale observations of both HCN and HNC (1-0) lines alon…
We analyze HCN and HNC emission in the nearby starburst galaxy NGC 253 to investigate its effectiveness in tracing heating processes associated with star formation. This study uses multiple HCN and HNC rotational transitions observed using ALMA via the ALCHEMI Large Program. To understand the conditions and associated heating mechanisms within NGC 253's dense gas, we employ Bayesian nested sampling techniques applied to chemical and radiative transfer models which are constrained using our HCN and HNC measurements. We find that the volume density $n_{\text{H}_{2}}$ and cosmic ray ionization ra…
New HCN, HNC, and HCO+ measurements of 46 normal galaxies in transitions up to J=4-3 are included in a multitransition database covering HCN and HCO+ (130 galaxies) and HNC (94 galaxies). The near-linear luminosity relations are dominated by distance effects and do not reflect galaxy physical properties. Individual galaxies show significant dispersion in both their luminosity and line ratio. Line ratios do not correlate well with either luminosities or other line ratios. Only the normalized J-transition ladders of HCN and HCO+ and the J=1-0 12CO/13CO isotopologue ratio are positively correlate…
We present results from a study of nitrogen chemistry in Class 0/I proto-brown dwarfs (proto-BDs). We have used the IRAM 30 m telescope to observe the CN (2-1), HCN (3-2), and HNC (3-2) lines in 7 proto-BDs. All proto-BDs show a large CN/HCN abundance ratio of >20, and a HNC/HCN abundance ratio close to or larger than unity. The enhanced CN/HCN ratios can be explained by high UV flux originating from an active accretion zone in the proto-BDs. The larger than unity HNC/HCN ratio for the proto-BDs is likely caused by a combination of low temperature and high density. Both CN and HNC show a flat …
Dusty star-forming galaxies (DSFGs) at redshift z$\geq$1 are among the most vigorously star-forming galaxies in the Universe. However, their dense ($\geq$10$^5$ cm$^{-3}$ ) gas phase - typically traced by HCN(1-0) - remains almost entirely unexplored: only two DSFGs have been detected in HCN(1-0) to date. We present results of a JVLA survey of the J=1-0 transition of HCN, HCO+, and HNC(1-0) in six strongly lensed DSFGs at z = 2.5 - 3.3, effectively doubling the number of DSFGs with deep observations of these lines. We detect HCN(1-0) emission in one source (J1202+5354, 4.4$σ$), with a tentativ…
Observations of molecular clouds, prestellar cores, and protoplanetary disks have established that the HNC/HCN ratio may be a potent diagnostic of molecular gas physical conditions. The processes that govern the relative abundances of these molecules nevertheless remain poorly understood. We seek to exploit the wide range of UV irradiation strengths within the 1 pc diameter Helix planetary nebula to explore the potential role of UV radiation in driving HNC/HCN. We performed IRAM 30 m and APEX 12 m radio line observations across six positions within the Helix Nebula, making use of radiative tra…
We present the first mid-infrared (MIR) detections of HNC and H13CN in the interstellar medium, and numerous, resolved HCN rovibrational transitions. Our observations span 12.8 to 22.9 micron towards the hot core Orion IRc2, obtained with the Echelon-Cross-Echelle Spectrograph aboard the Stratospheric Observatory for Infrared Astronomy (SOFIA). Exceptional, ~5 km/s, resolution distinguishes individual rovibrational transitions of the HNC and HCN P, Q, and R branches; and the H13CN R branch. This allows direct measurement of the species' excitation temperatures, column densities, and relative a…
Quantum chemical cluster calculations show that reactions of C$^+$ with HCN or HNC embedded in the surface of an icy grain mantle can account for the formation of a recently detected molecule, glycolonitrile, which is considered to be an important precursor to ribonucleic compounds. Reactions of cations deposited on ice mantles with minimal kinetic energy have been found theoretically to result in previously unknown pathways to significant organic compounds in protostellar systems and the interstellar medium. In density functional theory cluster calculations involving up to 24H$_2$O, C$^+$ rea…
The distributions and abundances of molecules in protoplanetary disks are powerful tracers of the physical and chemical disk structures. The abundance ratios of HCN and its isomer HNC are known to be sensitive to gas temperature. Their line ratios might therefore offer a unique opportunity to probe the properties of the emitting gas. Using the 2D thermochemical code DALI, we ran a set of disk models accounting for different stellar and disk properties, with an updated chemical network for the nitrogen chemistry. These modeling results were then compared with observations, including new ALMA ob…
Certain planetary nebulae contain shells, filaments, or globules of cold gas and dust whose heating and chemistry are likely driven by UV and X-ray emission from their central stars and from wind-collision-generated shocks. We present the results of a survey of molecular line emission in the 88-236 GHz range from nine nearby (<1.5 kpc) planetary nebulae spanning a range of UV and X-ray luminosities, using the 30 m telescope of the Institut de Radioastronomie Millimetrique. Rotational transitions of thirteen molecules, including CO isotopologues and chemically important trace species, were obse…
Unmasking the physical information inherent to interstellar spectral line profiles with Machine Learning. I. Application of LTE to HCN and HNC transitions
HCN, HNC, and their isotopologues are ubiquitous molecules that can serve as chemical thermometers and evolutionary tracers to characterize star-forming regions. Despite their importance in carrying information that is vital to studies of the chemistry and evolution of star-forming regions, the collision rates of some of these molecules have not been available for rigorous studies in the past. We perform an up-to-date gas and dust chemical characterization of two different star-forming regions, TMC 1-C and NGC 1333-C7, using new collisional rates of HCN, HNC, and their isotopologues. We invest…
This {\it supplement} paper presents the maps of HCN $J$=4-3, HNC $J$=1-0, $\mathrm{H^{13}CN}$ $J$=1-0, and HC$_3$N $J$=10-9 for the Galactic central molecular zone (CMZ), which have been obtained using the Atacama Submillimeter Telescope Experiment and Nobeyama Radio Observatory 45-m telescope. Three-dimensional maps (2-D in space and 1-D in velocity) of the gas kinetic temperature ($T_\mathrm{kin}$), hydrogen volume density ($n_\mathrm{H_2}$), and fractional abundances of eight molecules (HCN, HNC, $\mathrm{HC_3N}$, HCO$^+$, $\mathrm{H_2CO}$, SiO, CS, and $\mathrm{N_2H^+}$) have been constru…
SMA Observations Reveal Abundant HNC Chemistry in Transition Disks
University of Virginia（弗吉尼亚大学）；University of Texas San Antonio（德克萨斯大学圣安东尼奥分校）；Southwest Research Institute（西南研究院）；University of Arizona（亚利桑那大学）；The University of Tokyo（东京大学）；University of California, Berkeley（加州大学伯克利分校）；Université Grenoble Alpes（格勒诺布尔阿尔卑斯大学）
We report a statistical analysis exploring the origin of the overall low star formation efficiency (SFE) of the Galactic central molecular zone (CMZ) and the SFE diversity among the CMZ clouds using a wide-field HCN $J$=4-3 map, whose optically thin critical density ($\sim10^7\,\mathrm{cm}^{-3}$) is the highest among the tracers ever used in CMZ surveys. Logistic regression is performed to empirically formulate star formation probability of 195 HCN clumps, 13 of which contain star formation signatures. The explanatory parameters in the best-fit model are reduced into the virial parameter $α_{\…
Quantum and Structural Effects Captured via a Statistical Method: the SACM Applied to HCN and HNC Colliding with CO
Univ. Rennes, CNRS, IPR (Institut de Physique de Rennes), UMR 6251（雷恩大学）；Department of Chemistry, Missouri University of Science and Technology（密苏里科技大学）
We present 3 mm and 2 mm band simultaneously spectroscopic observations of HCN 1-0, HCO$^{+}$ 1-0, HNC 1-0, and CS 3-2 with the IRAM 30 meter telescope, toward a sample of 70 sources as nearby galaxies with infrared luminosities ranging from several 10$^{5}L_{\odot}$ to more than 10$^{12}L_{\odot}$. After combining HCN 1-0, HCO$^{+}$ 1-0 and HNC 1-0 data from literature with our detections, relations between luminosities of dense gas tracers (HCN 1-0, HCO$^{+}$ 1-0 and HNC 1-0) and infrared luminosities are derived, with tight linear correlations for all tracers. Luminosities of CS 3-2 with on…
6.7 GHz methanol masers are the brightest of class II methanol masers that are regarded as excellent signposts in the formation of young massive stars. We present here a molecular line study of 68 6.7 GHz methanol maser hosts chosen from the MMB catalogue, that have MALT90 data available. We performed (1) pixel-by-pixel study of 9 methanol maser sources that have high signal-to-noise ratio and (2) statistical study taking into account the entire 68 sources. We estimated the molecular column densities and abundances of N$_2$H$^+$(1-0), HCO$^+$(1-0), HCN(1-0) and HNC(1-0) lines. The derived abun…
We selected 90 massive star-forming clumps with strong N2H+, HCO+, HCN, and HNC emission from the Millimetre Astronomy Legacy Team 90 GHz survey. We obtained Herschel data for all 90 sources and NRAO VLA Sky Survey data for 51 of them. We convolved and regridded all images to the same resolution and pixel size and derived the temperature, H2 column density, molecules' abundances and abundance, and ratios of each pixel. Our analysis yields three main conclusions. First, the abundances of N2H+, HCO+, HCN, and HNC increase when the column density decreases and the temperature increases, with spat…
We present ALMA, NOEMA, and IRAM-30m/EMIR observations of the high-density tracer molecules HCN, HCO+, and HNC in three of the brightest lensed dusty star-forming galaxies at z~3-3.5, part of the Planck's Dusty GEMS sample, to probe the gas reservoirs closely associated with their exceptional levels of star formation. We obtain robust detections of ten emission lines between J_up=4 and 6, as well as several additional flux upper limits. In PLCK_G244.8+54.9, the brightest source at z=3.0, the HNC(5-4) line emission at 0.1" resolution, together with other spatially-integrated line profiles, sugg…
Isotopologue abundance ratios are important to understand the evolution of astrophysical objects and ultimately the origins of a planetary system like our own. Being nitrogen a fundamental ingredient of pre-biotic material, understanding its chemistry and inheritance is of fundamental importance to understand the formation of the building blocks of life. We present here single-dish observations of the ground state rotational transitions of the $^{13}$C and $^{15}$N isotopologues of HCN, HNC and CN with the IRAM 30m telescope. We analyse their column densities and compute the $^{14}$N/$^{15}$N …
