Five carbon- and nitrogen-bearing species in a hot giant planet's atmosphere
Paolo Giacobbe, Matteo Brogi, Siddharth Gandhi, Patricio E. Cubillos, Aldo S. Bonomo, Alessandro Sozzetti, Luca Fossati, Gloria Guilluy, Ilaria Carleo, Monica R… 展开作者
Paolo Giacobbe, Matteo Brogi, Siddharth Gandhi, Patricio E. Cubillos, Aldo S. Bonomo, Alessandro Sozzetti, Luca Fossati, Gloria Guilluy, Ilaria Carleo, Monica Rainer, Avet Harutyunyan, Francesco Borsa, Lorenzo Pino, Valerio Nascimbeni, Serena Benatti, Katia Biazzo, Andrea Bignamini, Katy L. Chubb, Riccardo Claudi, Rosario Cosentino, Elvira Covino, Mario Damasso, Silvano Desidera, Aldo F. M. Fiorenzano, Adriano Ghedina, Antonino F. Lanza, Giuseppe Leto, Antonio Maggio, Luca Malavolta, Jesus Maldonado, Giuseppina Micela, Emilio Molinari, Isabella Pagano, Marco Pedani, Giampaolo Piotto, Ennio Poretti, Gaetano Scandariato, Sergei N. Yurchenko, Daniela Fantinel, Alberto Galli, Marcello Lodi, Nicoletta Sanna, Andrea Tozzi
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The atmospheres of gaseous giant exoplanets orbiting close to their parent stars (hot Jupiters) have been probed for nearly two decades. They allow us to investigate the chemical and physical properties of planetary atmospheres under extreme irradiation conditions. Previous observations of hot Jupiters as they transit in front of their host stars have revealed the frequent presence of water vapour and carbon monoxide in their atmospheres; this has been studied in terms of scaled solar composition under the usual assumption of chemical equilibrium. Both molecules as well as hydrogen cyanide were found in the atmosphere of HD 209458b, a well studied hot Jupiter (with equilibrium temperature around 1,500 kelvin), whereas ammonia was tentatively detected there and subsequently refuted. Here we report observations of HD 209458b that indicate the presence of water (H2O), carbon monoxide (CO), hydrogen cyanide (HCN), methane (CH4), ammonia (NH3) and acetylene (C2H2), with statistical significance of 5.3 to 9.9 standard deviations per molecule. Atmospheric models in radiative and chemical equilibrium that account for the detected species indicate a carbon-rich chemistry with a carbon-to-oxygen ratio close to or greater than 1, higher than the solar value (0.55). According to existing models relating the atmospheric chemistry to planet formation and migration scenarios, this would suggest that HD 209458b formed far from its present location and subsequently migrated inwards. Other hot Jupiters may also show a richer chemistry than has been previously found, which would bring into question the frequently made assumption that they have solar-like and oxygen-rich compositions.
The Role of Formation Location in Shaping Sulfur-, Nitrogen-, and Carbon-Bearing Species in Super-Earth and Sub-Neptune Atmospheres
Institute for Particle Physics and Astrophysics, ETH Zurich（苏黎世联邦理工学院粒子物理与天体物理研究所）；Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles（加州大学洛杉矶分校地球、行星与空间科学系）；Observatoire de la Côte d’Azur, Université Cote d’Azur, Laboratoire Lagrange（蔚蓝海岸天文台，尼斯大学，拉格朗日实验室）；Department of Space Research and Technology, Technical University of Denmark（丹麦技术大学太空研究与技术系）
The chemical inventory of planets is determined by the physical and chemical processes that govern the early phases of star formation. The aim is to investigate N-bearing complex organic molecules towards two Class 0 protostars (B1-c and S68N) at millimetre wavelengths with ALMA. Next, the results of the detected N-bearing species are compared with those of O-bearing species for the same and other sources. ALMA observations in Band 6 ($\sim$ 1 mm) and Band 5 ($\sim$ 2 mm) are studied at $\sim$ 0.5" resolution, complemented by Band 3 ($\sim$ 3 mm) data in a $\sim$ 2.5" beam. NH2CHO, C2H5CN, HNC…
Molecular nitrogen is the most commonly assumed background gas that supports habitability on rocky planets. Despite its chemical inertness, nitrogen molecule is broken by lightning, hot volcanic vents, and bolide impacts, and can be converted into soluble nitrogen compounds and then sequestered in the ocean. The very stability of nitrogen, and that of nitrogen-based habitability, is thus called into question. Here we determine the lifetime of molecular nitrogen vis-a-vis aqueous sequestration, by developing a novel model that couples atmospheric photochemistry and oceanic chemistry. We find th…
We use thermochemical equilibrium calculations to model iron, magnesium, and silicon chemistry in the atmospheres of giant planets, brown dwarfs, extrasolar giant planets (EGPs), and low-mass stars. The behavior of individual Fe-, Mg-, and Si-bearing gases and condensates is determined as a function of temperature, pressure, and metallicity. Our results are thus independent of any particular model atmosphere. The condensation of Fe metal strongly affects iron chemistry by efficiently removing Fe-bearing species from the gas phase. Monatomic Fe is the most abundant Fe-bearing gas throughout the…
Understanding the atmosphere's composition during the Archean eon is a fundamental issue to unravel ancient environmental conditions. We show from the analysis of nitrogen and argon isotopes in fluid inclusions trapped in 3.0-3.5 Ga hydrothermal quartz that the PN2 of the Archean atmosphere was lower than 1.1 bar, possibly as low as 0.5 bar, and had a nitrogen isotopic composition comparable to the present-day one. These results imply that dinitrogen did not play a significant role in the thermal budget of the ancient Earth and that the Archean PCO2 was probably lower than 0.7 bar.
Several clues indicate that Titan's atmosphere has been depleted in methane during some period of its history, possibly as recently as 0.5-1 billion years ago. It could also happen in the future. Under these conditions, the atmosphere becomes only composed of nitrogen with a range of temperature and pressure allowing liquid or solid nitrogen to condense. Here, we explore these exotic climates throughout Titan's history with a 3D Global Climate Model (GCM) including the nitrogen cycle and the radiative effect of nitrogen clouds. We show that for the last billion years, only small polar nitrogen…
Nitrogen- and nitrogen-oxygen-bearing organic molecules in comet 67P/Churyumov-Gerasimenko: An untargeted investigation
University of Bern（伯尔尼大学）；Institut d’Astrophysique Spatiale, Université Paris-Saclay, CNRS（巴黎南天体物理研究所，巴黎萨克雷大学，法国国家科学研究中心）；Department of Climate and Space Sciences and Engineering, University of Michigan（密歇根大学气候与空间科学与工程系）；Southwest Research Institute（西南研究院）；Department of Physics and Astronomy, The University of Texas at San Antonio（德克萨斯大学圣安东尼奥分校物理与天文系）；Royal Belgian Institute for Space Aeronomy, BIRA-IASB（比利时皇家空间气象学研究所）；Center for Space and Habitability, University of Bern（伯尔尼大学太空与宜居性中心）
A major motivation of spectroscopic observations of giant exoplanets is to unveil planet formation processes from atmospheric compositions. Several recent studies suggested that atmospheric nitrogen, like carbon and oxygen, can provide important constrains on planetary formation environments. Since nitrogen chemistry can be far from thermochemical equilibrium in warm atmospheres, we extensively investigate under what conditions, and with what assumptions, the observable NH3 abundances can diagnose an atmosphere's bulk nitrogen abundance. In the first paper of this series, we investigate atmosp…
Atmospheric nitrogen may be a necessary ingredient for the habitability of a planet since its presence helps to prevent water loss from a planet. The present day nitrogen isotopic ratio, $^{15}$N/$^{14}$N, in the Earth's atmosphere is a combination of the primitive Earth's ratio and the ratio that might have been delivered in comets and asteroids. Asteroids have a nitrogen isotopic ratio that is close to the Earth's. This indicates either a similar formation environment to the Earth or that the main source of nitrogen was delivery by asteroids. However, according to geological records, the Ear…
Kuiper belt object (KBO) Eris is exceptionally bright with a greater visible geometric albedo than any other known KBO. Its infrared reflectance spectrum is dominated by methane, which should form tholins that darken the surface on timescales much shorter than the age of the Solar System. Thus one or more ongoing processes probably maintain its brightness. Eris is predicted to have a primarily nitrogen atmosphere that is in vapor pressure equilibrium with nitrogen-ice and is collisional (not ballistic). Eris's eccentric orbit is expected to result in two atmospheric regimes: (1) a period near …
We show that in extremely irradiated atmospheres of hot super-Earths shortwave absorption of CN can cause strong temperature inversions. We base this study on previous observations of 55 Cancri e, which lead us to believe that ultra-short-period super-Earths can sustain volatile atmospheres, rich in nitrogen and/or carbon. We compute our model atmospheres in a radiative-convective equilibrium for a variety of nitrogen-rich cases and orbital parameters. We demonstrate the effects caused by thermal inversions on the chemistry and compute low resolution synthetic emission spectra for a range of 0…
The ratio of nitrogen isotopes in the Martian atmosphere is a key constraint on the planet's atmospheric evolution. However, enrichment of the heavy isotope expected due to atmospheric loss from sputtering and photochemical processes is greater than measurements. A massive, multi-bar early CO2-dominated atmosphere and recent volcanic outgassing have been proposed to explain this discrepancy, and many previous models have assumed atmospheric nitrogen rapidly reached a steady state where loss to space balanced volcanic outgassing. Here we show using time-dependent models that the abundance and i…
Inferences of molecular compositions of exoplanetary atmospheres have generally focused on C, H, and O-bearing molecules. Recently, additional absorption in HST WFC3 transmission spectra around 1.55$μ$m has been attributed to nitrogen-bearing chemical species: NH$_3$ or HCN. These species, if present in significant abundance, would be strong indicators of disequilibrium chemical processes -- e.g. vertical mixing and photochemistry. The derived N abundance, in turn, could also place important constraints on planetary formation mechanisms. Here, we examine the detectability of nitrogen chemistry…
The Earth's N2-dominated atmosphere is a very special feature. Firstly, N2 as main gas is unique on the terrestrial planets in the inner solar system and gives a hint for tectonic activity. Studying the origins of atmospheric nitrogen and its stability provides insights into the uniqueness of the Earth's habitat. Secondly, the coexistence of N2 and O2 within an atmosphere is unequaled in the entire solar system. Such a combination is strongly linked to the existence of aerobic lifeforms. The availability of nitrogen on the surface, in the ocean, and within the atmosphere can enable or prevent …
Hydrogen cyanide (HCN) is a key feedstock molecule for the production of life's building blocks. The formation of HCN in an N$_2$-rich atmospheres requires first that the triple bond between N$\equiv$N be severed, and then that the atomic nitrogen find a carbon atom. These two tasks can be accomplished via photochemistry, lightning, impacts, or volcanism. The key requirements for producing appreciable amounts of HCN are the free availability of N$_2$ and a local carbon to oxygen ratio of C/O $\geq 1$. We discuss the chemical mechanisms by which HCN can be formed and destroyed on rocky exoplane…
This brief review will discuss the current knowledge on the origin and evolution of the nitrogen atmospheres of the icy bodies in the solar system, particularly of Titan, Triton and Pluto. An important tool to analyse and understand the origin and evolution of these atmospheres can be found in the different isotopic signatures of their atmospheric constituents. The $^{14}$N/$^{15}$N ratio of the N$_2$-dominated atmospheres of these bodies serve as a footprint of the building blocks from which Titan, Triton and Pluto originated and of the diverse fractionation processes that shaped these atmosp…
An important source of opacity in exoplanet atmospheres at short visible and near-UV wavelengths is Rayleigh scattering of light on molecules. It is accompanied by a related, albeit weaker process -- Raman scattering. We analyze the signatures of Raman scattering imprinted in the reflected light and the geometric albedo of exoplanets, which could provide information about atmospheric properties. Raman scattering affects the geometric albedo spectra of planets in following ways. Firstly, it causes filling-in of strong absorption lines in the incident radiation, thus producing sharp peaks in the…
In this chapter we describe the remote sensing measurement of nitrogen-bearing species in Titan's atmosphere by the Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft. This instrument, which detects the thermal infrared spectrum from 10-1500 cm-1 (1000-7 microns) is sensitive to vibrational emissions of gases and condensates in Titan's stratosphere and lower mesosphere, permitting the measurement of ambient temperature and the abundances of gases and particulates. Three N-bearing species are firmly detected: HCN, HC3N and C2N2, and their vertical and latitudinal distributions hav…
The composition of an atmosphere has integrated the geological history of the entire planetary body. However, the long-term evolutions of the atmospheres of the terrestrial planets are not well documented. For Earth, there were until recently only few direct records of atmosphere's composition in the distant past, and insights came mainly from geochemical or physical proxies and/or from atmospheric models pushed back in time. Here we review innovative approaches on new terrestrial samples that led to the determination of the elemental and isotopic compositions of key geochemical tracers, namel…
One of the key goals of exoplanet science is the atmospheric characterisation of super-Earths. Atmospheric abundances provide insight on the formation and evolution of those planets and help to put our own rocky planets in context. Observations on 55 Cancri e point towards a N-dominated atmosphere. In this paper we explore this possibility, showing which will be the most abundant gases and observable species in emission and transmission spectroscopy of such an atmosphere. We use analytical arguments and observed parameters to estimate the possible thermal profile of the atmosphere and test thr…
We explore the chemistry and observability of nitrogen dominated atmospheres for ultra-short-period super-Earths. We base the assumption, that super-Earths could have nitrogen filled atmospheres, on observations of 55 Cnc e that favour a scenario with a high-mean-molecular-weight atmosphere. We take Titan's elemental budget as our starting point and using chemical kinetics compute a large range of possible compositions for a hot super-Earth. We use analytical temperature profiles and explore a parameter space spanning orders of magnitude in C/O \& N/O ratios, while always keeping nitrogen the …
We predict that cyanoacetylene (HC$_3$N) is produced photochemically in the atmosphere of GJ 1132 b in abundances detectable by the James Webb Space Telescope (JWST), assuming that the atmosphere is hydrogen dominated and rich in molecular nitrogen (N$_2$), methane (CH$_4$) and hydrogen cyanide (HCN), as described by Swain et al. (2021). First, we construct line list and cross-sections for HC$_3$N. Then we apply these cross-sections and the model atmosphere of Swain et al. (2021) to a radiative transfer model in order to simulate the transmission spectrum of GJ 1132 b as it would be seen by JW…
We examine the history of the loss and replenishment of the Martian atmosphere using elemental and isotopic compositions of nitrogen and noble gases. The evolution of the atmosphere is calculated by taking into consideration various processes: impact erosion and replenishment by asteroids and comets, atmospheric escape induced by solar radiation and wind, volcanic degassing, and gas deposition by interplanetary dust particles. Our model reproduces the elemental and isotopic compositions of N and noble gases (except for Xe) in the Martian atmosphere, as inferred from exploration missions and an…
We study the influence of the turbulent transport on ice chemistry in protoplanetary disks, focusing on carbon and nitrogen bearing molecules. Chemical rate equations are solved with the diffusion term, mimicking the turbulent mixing in the vertical direction. Turbulence can bring ice-coated dust grains from the midplane to the warm irradiated disk surface, and the ice mantles are reprocessed by photoreactions, thermal desorption, and surface reactions. The upward transport decreases the abundance of methanol and ammonia ices at r < 30 AU, because warm dust temperature prohibits their reformat…
Thanks to the \textit{Cassini} spacecraft onboard instruments, it has been known that Titan's ionospheric chemistry is complex and the molecular growth is initiated through the photolysis of the most abundant species directly in the upper atmosphere. Among the pool of chemical compounds formed by the photolysis, N-bearing species are involved in the haze formation but the chemical incorporation pathways need to be better constrained.}\\ In this work, we performed low-pressure EUV photochemical laboratory experiments. The APSIS reactor was filled with a N$_2$/CH$_4$ (90/10\%) gas mixture releva…
We apply a 1D upper atmosphere model to study thermal escape of nitrogen over Titan's history. Significant thermal escape should have occurred very early for solar EUV fluxes 100 to 400 times higher than today with escape rates as high as $\approx 1.5\times 10^{28}$ s$^{-1}$ and $\approx 4.5\times 10^{29}$ s$^{-1}$, respectively, while today it is $\approx 7.5\times 10^{17}$ s$^{-1}$. Depending on whether the Sun originated as a slow, moderate or fast rotator, thermal escape was the dominant escape process for the first 100 to 1000 Myr after the formation of the solar system. If Titan's atmosp…
Context. The chemical building blocks of life contain a large proportion of nitrogen, an essential element. Titan, the largest moon of Saturn, with its dense atmosphere of molecular nitrogen and methane, offers an exceptional opportunity to explore how this element is incorporated into carbon chains through atmospheric chemistry in our Solar System. A brownish dense haze is consistently produced in the atmosphere and accumulates on the surface on the moon. This solid material is nitrogen-rich and may contain prebiotic molecules carrying nitrogen. Aims. To date, our knowledge of the processes l…
Formation of nitriles and isonitriles by the heavy-ion irradiation of propionitrile in N2-rich astrophysical ices
Centre de Recherche sur les Ions, les Matériaux et la Photonique (CIMAP), Université Caen Normandie（离子、材料与光子研究中心，诺曼底大学）；Departamento de Física, Centro Federal de Educação Tecnológica Celso Suckow da Fonseca (CEFET/RJ)（物理系，塞尔索·苏克瓦·达丰塞卡联邦技术学院）
We modeled the transit signatures in the Lya line of a putative Earth-sized planet orbiting in the HZ of the M dwarf GJ436. We estimated the transit depth in the Lya line for an exo-Earth with three types of atmospheres: a hydrogen-dominated atmosphere, a nitrogen-dominated atmosphere, and a nitrogen-dominated atmosphere with an amount of hydrogen equal to that of the Earth. We calculated the in-transit absorption they would produce in the Lya line. We applied it to the out-of-transit Lya observations of GJ 436 obtained by the HST and compared the calculated in-transit absorption with observat…
N2 is abundant in Pluto's atmosphere and on its surface, but the supply is depleted by prodigious atmospheric escape. We demonstrate that cometary impacts could not have delivered enough N mass to resupply Pluto's N2 atmospheric escape over time; thus Pluto's N2 is likely endogenous, and therefore was either acquired early in its history or created by chemistry inside/on Pluto. We find that cratering could excavate a considerable amount of N2 to resupply the atmosphere against escape if the near-surface N2 reservoir is deep. However, we find that this process likely falls short of that necessa…
Nitrogen is the most common element in Earth's atmosphere and also appears to be present in significant amounts in the mantle. However, its long-term cycling between these two reservoirs remains poorly understood. Here a range of biotic and abiotic mechanisms are evaluated that could have caused nitrogen exchange between Earth's surface and interior over time. In the Archean, biological nitrogen fixation was likely strongly limited by nutrient and/or electron acceptor constraints. Abiotic fixation of dinitrogen becomes efficient in strongly reducing atmospheres, but only once temperatures exce…
The chemical abundances of exoplanet atmospheres may provide valuable information about the bulk compositions, formation pathways, and evolutionary histories of planets. Exoplanets with large, relatively cloud-free atmospheres, and which orbit bright stars provide the best opportunities for accurate abundance measurements. For this reason, we measured the transmission spectrum of the bright (V~10.2), large (1.37 R$_{J}$), sub-Saturn mass (0.19 M$_{J}$) exoplanet WASP-127b across the near-UV to near-infrared wavelength range (0.3 - 5 $μ$m), using the Hubble and Spitzer Space Telescopes. Our res…
The formation of organic compounds is generally assumed to result from abiotic processes in the Solar System, with the exception of biogenic organics on Earth. Nitrogen-bearing organics are of particular interest, notably for prebiotic perspectives but also for overall comprehension of organic formation in the young solar system and in planetary atmospheres. We have investigated abiotic synthesis of organics upon plasma discharge, with special attention to N isotope fractionation. Organic aerosols were synthesized from N2-CH4 and N2-CO gaseous mixtures using low-pressure plasma discharge exper…
Since the Archean, N2 has been a major atmospheric constituent in Earth's atmosphere. Nitrogen is an essential element in the building blocks of life, therefore the geobiological nitrogen cycle is a fundamental factor in the long term evolution of both Earth and Earth-like exoplanets. We discuss the development of the Earth's N2 atmosphere since the planet's formation and its relation with the geobiological cycle. Then we suggest atmospheric evolution scenarios and their possible interaction with life forms: firstly, for a stagnant-lid anoxic world, secondly for a tectonically active anoxic wo…
We have searched for the presence of simple P and S-bearing molecules in Titan's atmosphere, by looking for the characteristic signatures of phosphine and hydrogen sulfide in infrared spectra obtained by Cassini CIRS. As a result we have placed the first upper limits on the stratospheric abundances, which are 1 ppb (PH3) and 330 ppb (H2S), at the 2-sigma significance level.
We present results of an investigation into the formation of nitrogen-bearing molecules in the atmosphere of Titan. We extend a previous model (Li et al. 2015, 2016) to cover the region below the tropopause, so the new model treats the atmosphere from Titan's surface to an altitude of 1500 km. We consider the effects of condensation and sublimation using a continuous, numerically stable method. This is coupled with parameterized treatments of the sedimentation of the aerosols and their condensates, and the formation of haze particles. These processes affect the abundances of heavier species su…
We have developed 1-D photochemical and thermochemical kinetics and diffusion models for the transiting exoplanets HD 189733b and HD 209458b to study the effects of disequilibrium chemistry on the atmospheric composition of "hot Jupiters." Here we investigate the coupled chemistry of neutral carbon, hydrogen, oxygen, and nitrogen species, and we compare the model results with existing transit and eclipse observations. We find that the vertical profiles of molecular constituents are significantly affected by transport-induced quenching and photochemistry, particularly on cooler HD 189733b; howe…
Interpretations of exoplanetary transmission spectra have been undermined by apparent obscuration due to clouds/hazes. Debate rages on whether weak H$_2$O features seen in exoplanet spectra are due to clouds or inherently depleted oxygen. Assertions of solar H$_2$O abundances have relied on making a priori model assumptions, e.g. chemical/radiative equilibrium. In this work, we attempt to address this problem with a new retrieval paradigm for transmission spectra. We introduce POSEIDON, a two-dimensional atmospheric retrieval algorithm including generalised inhomogeneous clouds. We demonstrate…
Deciphering the role of clouds is central to our understanding of exoplanet atmospheres, as they have a direct impact on the temperature and pressure structure, and observational properties of the planet. Super-hot Jupiters occupy a temperature regime similar to low mass M-dwarfs, where minimal cloud condensation is expected. However, observations of exoplanets such as WASP-12b (Teq ~ 2500 K) result in a transmission spectrum indicative of a cloudy atmosphere. We re-examine the temperature and pressure space occupied by these super-hot Jupiter atmospheres, to explore the role of the initial Al…
Volatile molecules containing hydrogen, carbon, and nitrogen are key components of planetary atmospheres. In the pebble accretion model for rocky planet formation, these volatile species are accreted during the main planetary formation phase. For this study, we modelled the partitioning of volatiles within a growing planet and the outgassing to the surface. The core stores more than 90\% of the hydrogen and carbon budgets of Earth for realistic values of the partition coefficients of H and C between metal and silicate melts. The magma oceans of Earth and Venus are sufficiently deep to undergo …
The Earth was born in violence. Many giant collisions of protoplanets are thought to have occurred during the terrestrial planet formation. Here we investigated the giant impact stage by using a hybrid code that consistently deals with the orbital evolution of protoplanets around the Sun and the details of processes during giant impacts between two protoplanets. A significant amount of materials (up to several tens of percent of the total mass of the protoplanets) is ejected by giant impacts. We call these ejected fragments the giant-impact fragments (GIFs). In some of the erosive hit-and-run …
Nitrogen is a biosignature gas that cannot be maintained in its Earth-like ratio with CO$_2$ under abiotic conditions. It has also proven to be notoriously hard to detect at optical and infrared wavelengths. Fortunately, the ultraviolet region, which has only recently started being explored for terrestrial exoplanets, may provide new opportunities to characterise exoplanetary atmospheric nitrogen. In this work, the future prospects for detecting atomic nitrogen absorption lines in the transmission spectrum of an Earth-like planet orbiting in the habitable zone of a Sun-like star with LUVOIR ar…
Ocean-atmosphere chemistry on Earth has undergone dramatic evolutionary changes through its long history, with potentially significant ramifications for the emergence and long-term stability of atmospheric biosignatures. Though a great deal of work has centered on refining our understanding of false positives for remote life detection, much less attention has been paid to the possibility of false negatives, that is, cryptical biospheres that are widespread and active on a planet's surface but are ultimately undetectable or difficult to detect in the composition of a planet's atmosphere. Here, …
Venus shares many similarities with the Earth, but concomitantly, some of its features are extremely original. This is especially true for its atmosphere, where high pressures and temperatures are found at the ground level. In these conditions, carbon dioxide, the main component of Venus' atmosphere, is a supercritical fluid. The analysis of VeGa-2 probe data has revealed the high instability of the region located in the last few kilometers above the ground level. Recent works have suggested an explanation based on the existence of a vertical gradient of molecular nitrogen abundances, around 5…
