Venus shares many similarities with the Earth, but concomitantly, some of its features are extremely original. This is especially true for its atmosphere, where high pressures and temperatures are found at the ground level. In these conditions, carbon dioxide, the main component of Venus' atmosphere, is a supercritical fluid. The analysis of VeGa-2 probe data has revealed the high instability of the region located in the last few kilometers above the ground level. Recent works have suggested an explanation based on the existence of a vertical gradient of molecular nitrogen abundances, around 5 ppm per meter. Our goal was then to identify which physical processes could lead to the establishment of this intriguing nitrogen gradient, in the deep atmosphere of Venus. Using an appropriate equation of state for the binary mixture CO2-N2 under supercritical conditions, and also molecular dynamics simulations, we have investigated the separation processes of N2 and CO2 in the Venusian context. Our results show that molecular diffusion is strongly inefficient, and potential phase separation is an unlikely mechanism. We have compared the quantity of CO2 required to form the proposed gradient with what could be released by a diffuse degassing from a low volcanic activity. The needed fluxes of CO2 are not so different from what can be measured over some terrestrial volcanic systems, suggesting a similar effect at work on Venus.
The composition the atmosphere of Venus results from the integration of many processes entering into play over the entire geological history of the planet. Determining the elemental abundances and isotopic ratios of noble gases (He, Ne, Ar, Kr, Xe) and stable isotopes (H, C, N, O, S) in the Venus atmosphere is a high priority scientific target since it could open a window on the origin and early evolution of the entire planet. This chapter provides an overview of the existing dataset on noble gases and stable isotopes in the Venus atmosphere. The current state of knowledge on the origin and ea…
The community commonly assumes that the Venusian atmosphere lacks organic (reduced) carbon. This is reflected in the literature, which now for almost a half a century does not mention organic carbon in connection with the Venus atmosphere. This assumption persists despite the failure of models that exclude organic carbon to account for many well-established observed features of the Venusian atmosphere. Here is presented a model summarizing reactions that almost certainly are occurring in the Venusian atmosphere. The model relies on reactions of reduced carbon compounds known to occur in concen…
Recently, phosphine was discovered in the atmosphere of Venus as a potential biosignature. This raises the question: if Venusian life exists, could it be related to terrestrial life? Based on the known rate of meteoroid impacts on Earth, we show that at least $\sim 6 \times 10^5$ asteroids have grazed Earth's atmosphere without being significantly heated and later impacted Venus, and a similar number have grazed Venus's atmosphere and later impacted the Earth, both within a period of $\sim 10^5$ years during which microbes could survive in space. Although the abundance of terrestrial life in t…
A defining characteristic of the planet Venus is its thick, CO2-dominated atmosphere. Despite over fifty years of robotic exploration, including thirteen successful atmosphere probes and landers, our knowledge of N2, the second-most-abundant compound in the atmosphere, is highly uncertain (von Zahn et al., 1983). We report the first measurement of the nitrogen content of Venus' atmosphere at altitudes between 60 and 100 km. Our result, 5.0 +/- 0.4 v% N2, is significantly higher than the value of 3.5 v% N2 reported for the lower atmosphere (<50 km altitude). We conclude that Venus' atmosphere c…
The discovery of the near infrared windows into the Venus deep atmosphere has enabled the use of remote sensing techniques to study the composition of the Venus atmosphere below the clouds. In particular, water vapor absorption lines can be observed in a number of the near-infrared windows allowing measurement of the H2O abundance at several different levels in the lower atmosphere. Accurate determination of the abundance requires a good database of spectral line parameters for the H2O absorption lines at the high temperatures (up to ~700 K) encountered in the Venus deep atmosphere. This paper…
The atmosphere of Venus is characterized by strong superrotation, in which the wind velocities at cloud heights are around 60 times faster than the surface rotation rate. The reasons for this strong superrotation are still not well understood. Motions in the atmosphere below the thick cloud deck are hard to determine remotely and in-situ measurements of the circulation below 40 km altitude are scarce. No model to date has been able to simulate superrotating winds with magnitudes comparable with those measured by entry probes, in the dense atmosphere between the surface and the clouds. However,…
The superrotation of the atmosphere of Venus requires a large torque on the up- per atmosphere. Mechanisms for providing a net balancing of this through waves or ionospheric motions to other parts of the atmosphere have been proposed but all have difficulties. Here we demonstrate that the albedo gradient from the day to night side of the cloud layer allows a gradient of light pressure that is sufficient to provide an external torque to drive this flow.
The presence of phosphine (PH$_3$) in the atmosphere of Venus was reported by Greaves et al. (2021a), based on observations of the J=1-0 transition at 267 GHz using ground-based, millimeter-wave spectroscopy. This unexpected discovery presents a challenge for our understanding of Venus's atmosphere, and has led to a reappraisal of the possible sources and sinks of atmospheric phosphorous-bearing gases. Here we present results from a search for PH$_3$ on Venus using the GREAT instrument aboard the SOFIA aircraft, over three flights conducted in November 2021. Multiple PH$_3$ transitions were ta…
In 1761, the Russian polymath Mikhail Vasilievich Lomonosov (1711-1765) discovered the atmosphere of Venus during its transit over the Sun's disc. In this paper we report on experimental reenactments of Lomonosov's discovery with antique refractors during the transit of Venus June 5-6, 2012. We conclude that Lomonosov's telescope was fully adequate to the task of detecting the arc of light around Venus off the Sun's disc during ingress or egress if proper experimental techniques as described by Lomonosov in his 1761 report are employed.
Venus's past climate evolution is uncertain. General circulation model simulations permit a habitable climate as late as ~0.7 Ga, and there is suggestive-albeit inconclusive-evidence for previous liquid water from surface geomorphology and mineralogy. However, it is unclear whether a habitable past can be reconciled with Venus's inferred atmospheric evolution. In particular, the lack of leftover atmospheric oxygen argues against recent water loss. Here, we apply a fully coupled model of Venus's atmospheric-interior-climate evolution from post-accretion magma ocean to present. The model self-co…
We propose an abiotic geological mechanism that accounts for the abundance of phosphine detected by Greaves et al., 2020. We hypothesize that trace amounts of phosphides formed in the mantle would be brought to the surface by volcanism, and then subsequently ejected into the atmosphere, where they could react with water or sulfuric acid to form phosphine. To investigate the plausibility of this hypothesis, we carry out an order of magnitude calculation. We suggest that active volcanism today could produce a rate comparable to that required to produce the phosphide-source of the phosphine. Our …
We present an effective parameterization of molecular absorption of shortwave solar radiation in Venus atmosphere. It is addressed to general circulation modeling to accelerate radiative transfer calculations in the spectral interval 125 -- 400 nm (25000 -- 80000 cm$^{-1}$ ). In F-UV and M-UV regions strong absorption of CO$_2$ ans SO$_2$ enables to parameterize gaseous absorption with only three effective cross-sections. In N-UV region absorption of SO$_2$ and the unknown UV absorber are parameterized with six effective cross-sections for each species. For treatment of Rayleigh scattering and…
Ground based observers have on 5/6th June 2012 the last opportunity of the century to watch the passage of Venus across the solar disk from Earth. Venus transits have traditionally provided unique insight into the Venus atmosphere through the refraction halo that appears at the planet outer terminator near ingress/egress. Much more recently, Venus transits have attracted renewed interest because the technique of transits is being successfully applied to the characterization of extrasolar planet atmospheres. The current work investigates theoretically the interaction of sunlight and the Venus a…
This is a white paper submitted to the Planetary Science and Astrobiology Decadal Survey. The deep atmosphere of Venus is largely unexplored and yet may harbor clues to the evolutionary pathways for a major silicate planet with implications across the solar system and beyond. In situ data is needed to resolve significant open questions related to the evolution and present-state of Venus, including questions of Venus' possibly early habitability and current volcanic outgassing. Deep atmosphere "probe-based" in situ missions carrying analytical suites of instruments are now implementable in the …
An ancient Venusian rock could constrain that planet's history, and reveal the past existence of oceans. Such samples may persist on the Moon, which lacks an atmosphere and significant geological activity. We demonstrate that if Venus' atmosphere was at any point thin and similar to Earth's, then asteroid impacts transferred potentially detectable amounts of Venusian surface material to the Lunar regolith. Venus experiences an enhanced flux relative to Earth of asteroid collisions that eject lightly-shocked ($\lesssim 40$ GPa) surface material. Initial launch conditions plus close-encounters a…
It is known that the ideal gas equation of state is not valid in the lower atmosphere of Venus where surface pressures reach 9 MPa and surface temperatures approach 750K. Moreover, the presence of a small amount of nitrogen slightly complicates the calculation of thermodynamic properties of the real gas mixture present in the atmosphere. Previous calculations of the adiabatic lapse rate in the Venus atmosphere have used approximations to estimate the adiabatic lapse rate. Here, we calculate the adiabatic lapse rate more accurately by using multi-parameter mixture models formulated in reduced H…
The atmosphere of a transiting planet shields the stellar radiation providing us with a powerful method to estimate its size and density. In particular, because of their high ionization energy, atoms with high atomic number (Z) absorb short-wavelength radiation in the upper atmosphere, undetectable with observations in visible light. One implication is that the planet should appear larger during a primary transit observed in high energy bands than in the optical band. The last Venus transit in 2012 offered a unique opportunity to study this effect. The transit has been monitored by solar space…
The atmospheres of the terrestrial planets are known to have been modified as a consequence of the impact degassing and atmospheric erosion during the late accretion. Despite the commonality of these processes, there are distinct gaps -- roughly two orders of magnitude -- between the abundances of noble gases and nitrogen in the present-day atmospheres on Venus, Earth, and Mars. The element partitioning on planetary surfaces is thought to be significantly different between the three planets ~4 Ga: the runaway greenhouse on Venus, the carbon-silicate cycle and ocean formation on Earth, and the …
Amino acids are considered to be prime ingredients in chemistry, leading to life. Glycine is the simplest amino acid and most commonly found in animal proteins. It is a glucogenic and non-essential amino acid that is produced naturally by living bodies and plays a key role in the creation of several other important bio-compounds and proteins. We report the first spectroscopic detection of the rotational absorption lines of the simplest amino acid glycine (NH$_{2}$CH$_{2}$COOH) with confirmer I and II in the atmosphere of Venus using the archival data from the Atacama Large Millimeter/Submillim…
In this work we study in a general view slow rotating planets as Venus or Titan which present superrotating winds in their atmospheres. We are interested in understanding what mechanisms are candidates to be sources of net angular momentum to generate this kind of dynamics. In particular, in the case of Venus, in its atmosphere around an altitude of 100 Km relative to the surface, there exists winds that perform a full rotation around the planet in four terrestrial days, whereas the venusian day is equivalent to 243 terrestrial ones. This phenomenon called superrotation is known since many dec…
We use thermodynamic calculations to model atmospheric chemistry on terrestrial exoplanets that are hot enough for chemical equilibira between the atmosphere and lithosphere, as on Venus. The results of our calculations place constraints on abundances of spectroscopically observable gases, the surface temperature and pressure, and the mineralogy of the surface. These results will be useful in planning future observations of the atmospheres of terrestrial-sized exoplanets by current and proposed space observatories such as the Hubble Space Telescope (HST), Spitzer, James Webb Space Telescope (J…
The transit of Venus in 2004 offered the rare possibility to remotely sense a well-known planetary atmosphere using ground-based observations for absorption spectroscopy. Transmission spectra of Venus' atmosphere were obtained in the near infrared using the Vacuum Tower Telescope (VTT) in Tenerife. Since the instrument was designed to measure the very bright photosphere of the Sun, extracting Venus' atmosphere was challenging. CO_2 absorption lines could be identified in the upper Venus atmosphere. Moreover, the relative abundance of the three most abundant CO_2 isotopologues could be determin…
This work reviews the long-term evolution of the atmosphere of Venus, and modulation of its composition by interior-exterior cycling. The formation and evolution of Venus's atmosphere, leading to contemporary surface conditions, remain hotly debated topics, and involve questions that tie into many disciplines. We explore these various inter-related mechanisms which shaped the evolution of the atmosphere, starting with the volatile sources and sinks. Going from the deep interior to the top of the atmosphere, we describe volcanic outgassing, surface atmosphere interactions, and atmosphere escape…
Exoplanets orbiting M-dwarfs within habitable zones are exposed to stellar environments more extreme than that terrestrial planets experience in our Solar System, which can significantly impact the atmospheres of the exoplanets and affect their habitability and sustainability. This study provides the first prediction of hot oxygen corona structure and the associated photochemical loss from a 1 bar CO2-dominated atmosphere of a Venus-like rocky exoplanet, where dissociative recombination of O2+ ions is assumed to be the major source reaction for the escape of neutral O atoms and formation of th…
The composition of an atmosphere has integrated the geological history of the entire planetary body. However, the long-term evolutions of the atmospheres of the terrestrial planets are not well documented. For Earth, there were until recently only few direct records of atmosphere's composition in the distant past, and insights came mainly from geochemical or physical proxies and/or from atmospheric models pushed back in time. Here we review innovative approaches on new terrestrial samples that led to the determination of the elemental and isotopic compositions of key geochemical tracers, namel…
Near-term studies of Venus-like atmospheres with JWST promise to advance our knowledge of terrestrial planet evolution. However, the remote study of Venus in the Solar System and the ongoing efforts to characterize gaseous exoplanets both suggest that high altitude aerosols could limit observational studies of lower atmospheres, and potentially make it challenging to recognize exoplanets as "Venus-like". To support practical approaches for exo-Venus characterization with JWST, we use Venus-like atmospheric models with self-consistent cloud formation of the seven TRAPPIST-1 exoplanets to invest…
The fate of surface water on Venus is one of the most important outstanding problems in comparative planetology. Here a new concept is proposed to explain water removal on a steam-covered proto Venus, referred to as impact-driven planetary desiccation. Since a steam atmosphere is photochemically unstable, water vapor dissociates into hydrogen and oxygen. Then, hydrogen escapes easily into space through hydrodynamic escape driven by strong extreme ultraviolet radiation from the young Sun. The focus is on the intense impact bombardment during the terminal stage of planetary accretion as generato…
The composition of meteoritic material delivered to the terrestrial planets after the end of core formation as late accretion remains contentious. Because the evolution of Venus' atmospheric composition is likely to be less intricate than the Earth's, we test implications of wet and dry late accretion compositions, using present-day Venus atmosphere measurements. Here we investigate the long-term evolution of Venus using self-consistent numerical models of global thermochemical mantle convection coupled with both an atmospheric evolution model and a late accretion N-body delivery model. Atmosp…
The discovery and characterization of Earth-sized planets that are in, or near, a tidally-locked state are of crucial importance to understanding terrestrial planet evolution, and for which Venus is a clear analog. Exoplanetary science lies at the threshold of characterizing hundreds of terrestrial planetary atmospheres, thereby providing a statistical sample far greater than the limited inventory of terrestrial planetary atmospheres within the Solar System. However, the model-based approach for characterizing exoplanet atmospheres relies on Solar System data, resulting in our limited inventor…
We propose a mechanism for the oxidation of gaseous CO into CO2 occurring on the surface mineral hematite (Fe2O3(s)) in hot, CO2-rich planetary atmospheres, such as Venus. This mechanism is likely to constitute an important source of tropospheric CO2 on Venus and could at least partly address the CO2 stability problem in Venus' stratosphere, since our results suggest that atmospheric CO2 is produced from CO oxidation via surface hematite at a rate of 0.4 Petagrammes (Pg) CO2 per (Earth) year on Venus which is about 45% of the mass loss of CO2 via photolysis in the Venusian stratosphere. We als…
% context heading (optional) {Thanks to the Venus Express Mission, new data on the properties of Venus could be obtained in particular concerning its rotation.} % aims heading (mandatory) {In view of these upcoming results, the purpose of this paper is to determine and compare the major physical processes influencing the rotation of Venus, and more particularly the angular rotation rate.} % methods heading (mandatory) {Applying models already used for the Earth, the effect of the triaxiality of a rigid Venus on its period of rotation are computed. Then the variations of Venus rotation caused b…
We are of the opinion that several anomalies in the atmosphere of Venus provide evidence of yet-unknown processes and systems that are out of equilibrium. The investigation of these anomalies on Venus should be open to the wide range of explanations, including unknown biological activity. We provide an overview of two anomalies, the tentative detection of ammonia and phosphine in Venus's atmosphere. These anomalies fly in the face of the tacit assumption that the atmosphere of Venus must be in chemical redox equilibrium, an assumption connected to the belief that Venus is lifeless. We then dis…
One of the most intriguing, long-standing questions regarding Venus' atmosphere is the origin and distribution of the unknown UV-absorber, responsible for the absorption band detected at the near-UV and blue range of Venus' spectrum. In this work, we use data collected by MASCS spectrograph on board the MESSENGER mission during its second Venus flyby in June 2007 to address this issue. Spectra range from 0.3 μm to 1.5 μm including some gaseous H2O and CO2 bands, as well as part of the SO2 absorption band and the core of the UV absorption. We used the NEMESIS radiative transfer code and retriev…
The Kepler mission has revealed that Earth-sized planets are common, and dozens have been discovered to orbit in or near their host star's habitable zone. A major focus in astronomy is to determine which of these exoplanets are likely to have Earth-like properties that are amenable to follow-up with both ground- and future space-based surveys, with an ultimate goal of probing their atmospheres to look for signs of life. Venus-like atmospheres will be of particular interest in these surveys. While Earth and Venus evolved to have similar sizes and densities, it remains unclear what factors led t…
We have obtained spatially resolved near-infrared spectroscopy of the Venus nightside on 15 nights over three observing seasons. We use the depth of the CO absorption band at 2.3 microns to map the two-dimensional distribution of CO across both hemispheres. Radiative transfer models are used to relate the measured CO band depth to the volume mixing ratio of CO. The results confirm previous investigations in showing a general trend of increased CO abundances at around 60 degrees latitude north and south as compared with the equatorial regions. Observations taken over a few nights generally show…
Few spacecraft have studied the dynamics of Venus' deep atmosphere, which is needed to understand the interactions between the surface and atmosphere. Recent global simulations suggest a strong effect of the diurnal cycle of surface winds on the depth of the planetary boundary layer. We propose to use a turbulent-resolving model to characterize the Venus boundary layer and the impact of surface winds for the first time. Simulations were performed in the low plain and high terrain at the Equator and noon and midnight. A strong diurnal cycle is resolved in the high terrain, with a convective lay…
On 5-6 June 2012, Venus will be transiting the Sun for the last time before 2117. This event is an unique opportunity to assess the feasibility of the atmospheric characterisation of Earth-size exoplanets near the habitable zone with the transmission spectroscopy technique and provide an invaluable proxy for the atmosphere of such a planet. In this letter, we provide a theoretical transmission spectrum of the atmosphere of Venus that could be tested with spectroscopic observations during the 2012 transit. This is done using radiative transfer across Venus' atmosphere, with inputs from in-situ …
Measurements of trace-gases in planetary atmospheres help us explore chemical conditions different to those on Earth. Our nearest neighbor, Venus, has cloud decks that are temperate but hyper-acidic. We report the apparent presence of phosphine (PH3) gas in Venusian atmosphere, where any phosphorus should be in oxidized forms. Single-line millimeter-waveband spectral detections (quality up to ~15 sigma) from the JCMT and ALMA telescopes have no other plausible identification. Atmospheric PH3 at ~20 parts-per-billion abundance is inferred. The presence of phosphine is unexplained after exhausti…
We study the interaction between the atmospheres of Venus-like, non-magnetized exoplanets orbiting an M-dwarf star, and the stellar wind using a multi-species Magnetohydrodynaic (MHD) model. We focus our investigation on the effect of enhanced stellar wind and enhanced EUV flux as the planetary distance from the star decreases. Our simulations reveal different topologies of the planetary space environment for sub- and super-Alfvenic stellar wind conditions, which could lead to dynamic energy deposition in to the atmosphere during the transition along the planetary orbit. We find that the stell…
The Akatsuki instrument LIR measured an unprecedented wave feature at the top of Venusian cloud layer. Stationary bow-shape waves of thousands of kilometers large lasting several Earth days have been observed over the main equatorial mountains. Here we use for the first time a mesoscale model of the Venus's atmosphere with high-resolution topography and fully coupled interactive radiative transfer computations. Mountain waves resolved by the model form large-scale bow shape waves with an amplitude of about 1.5 K and a size up to several decades of latitude similar to the ones measured by the A…
The similarity of Venus and Earth in bulk properties make Venus an appealing target for future colonization. Several proposals have been put forward for colonizing and even terraforming Venus despite the extreme conditions on the planet's surface. Such a terraforming project would face large challenges centered around removing Venus's massive carbon dioxide atmosphere and replacing it with a habitable environment. I review past proposals and propose a new method for terraforming Venus by building an artificial surface in the much more hospitable upper atmosphere where the temperature and press…
Recent miniaturization of electronics in very small, low-cost and low-power configurations suitable for use in spacecraft have inspired innovative small-scale satellite concepts, such as ChipSats, centimeter-scale satellites with a mass of a few grams. These extremely small spacecraft have the potential to usher in a new age of space science accessibility. Due to their low ballistic coefficient, ChipSats can potentially be used in a swarm constellation for extended surveys of planetary atmospheres, providing large amounts of data with high reliability and redundancy. We present a preliminary f…
Altered Cosmic Organics as Venus' Ultraviolet Absorbers
California State Polytechnic University, Pomona（加州州立理工大学波莫纳分校）；Blue Marble Space（蓝色大理石空间研究所）；Arizona State University（亚利桑那州立大学）；NASA Goddard Institute for Space Studies（美国宇航局戈达德太空研究所）；Uppsala University（乌普萨拉大学）；University of Wisconsin, Madison（威斯康星大学麦迪逊分校）
The recent candidate detection of ~1 ppb of phosphine in the middle atmosphere of Venus is so unexpected that it requires an exhaustive search for explanations of its origin. Phosphorus-containing species have not been modelled for Venus' atmosphere before and our work represents the first attempt to model phosphorus species in the Venusian atmosphere. We thoroughly explore the potential pathways of formation of phosphine in a Venusian environment, including in the planet's atmosphere, cloud and haze layers, surface, and subsurface. We investigate gas reactions, geochemical reactions, photoche…
The Deep Atmosphere Venus Investigation of Noble gases, Chemistry, and Imaging (DAVINCI) mission described herein has been selected for flight to Venus as part of the NASA Discovery Program. DAVINCI will be the first mission to Venus to incorporate science-driven flybys and an instrumented descent sphere into a unified architecture. The anticipated scientific outcome will be a new understanding of the atmosphere, surface, and evolutionary path of Venus as a possibly once-habitable planet and analog to hot terrestrial exoplanets. The primary mission design for DAVINCI as selected features a pre…
