The collective mode spectrum of a symmetry-breaking state, such as a superconductor, provides crucial insight into the nature of the order parameter. In this context, we present a microscopic weak-coupling theory for the collective modes of a generic multi-component time-reversal symmetry breaking superconductor, and show that fluctuations in the relative amplitude and phase of the two order parameter components are well-defined underdamped collective modes, even in the presence of nodal quasiparticles. We then demonstrate that these "generalized clapping modes" can be detected using a number of experimental techniques including ac electronic compressibility measurements, electron energy loss spectroscopy, microwave spectroscopy, and ultrafast THz spectroscopy. Finally, we discuss the implications of our work as a new form of "collective mode spectroscopy" that drastically expands the number of experimental probes capable of detecting time-reversal symmetry breaking in unconventional superconductors such as Sr$_{\text{2}}$RuO$_{\text{4}}$, UTe$_{\text{2}}$, and moiré heterostructures.
Intrinsic and symmetry protected topological states have attracted lots of interest in condensed matter physics recently. In particular, time reversal symmetry protected fermion topological insulators have been theoretically predicted and experimentally verified. However despite considerable experimental and theoretical works, definitive evidence for time reversal invariant topological superconductivity is still lacking. Here we propose that upon electron doping the hydrogenated single bilayer Bi, namely BiH, will exhibit time reversal invariant topological superconductivity. If confirmed expe…
Using functional renormalization group method, we study the favorable condition for electronic correlation driven time reversal invariant topological superconductivity in symmetry class DIII. For non-centrosymmetric systems we argue that the proximity to ferromagnetic (or small wavevector magnetic) instability can be used as a guideline for the search of this type of superconductivity. This is analogous to the appearance of singlet unconventional superconductivity in the neighborhood of antiferromagnetic instability. We show three concrete examples where ferromagnetic-like fluctuation leads to…
We propose a setup to realize time-reversal invariant topological superconductors in quantum wires, proximity coupled to conventional superconductors. We consider a model of quantum wire with strong spin-orbit coupling and proximity coupling to two s-wave superconductors. When the relative phase between the two superconductors is $ϕ=π$ a Kramers' pair of Majorana zero modes appears at each edge of the wire. We study the robustness of the phase in presence of both time-reversal invariant and time-reversal breaking perturbations. In addition, we show that the system forms a natural realization o…
It is pointed out that erroneous Bardeen-Cooper-Schrieffer model equations have been used by Haranath Ghosh in his recent treatment of time-reversal symmetry-breaking superconductivity. Consequently, his numerical results are misleading, and his conclusions are not to the point.
Time-reversal symmetry breaking superconductivity in the presence of loop-current fluctuations
School of Physics and Astronomy, Beijing Normal University(北京师范大学物理与天文学院);Key Laboratory of Multiscale Spin Physics (Beijing Normal University), Ministry of Education(教育部多尺度自旋物理重点实验室(北京师范大学));Beijing Computational Science Research Center(北京计算科学研究中心);New Cornerstone Science Laboratory, Department of Physics, School of Science, Westlake University(西湖大学理学院物理系新基石科学实验室);Institute for Theoretical Sciences, Westlake University(西湖大学理论科学研究院);Key Laboratory for Quantum Materials of Zhejiang Province, School of Science, Westlake University(西湖大学理学院浙江省量子材料重点实验室);Institute of Natural Sciences, Westlake Institute for Advanced Study(西湖高等研究院自然科学研究院)
We report muon spin relaxation measurements on the superconductor Sr2RuO4 that reveal the spontaneous appearance of an internal magnetic field below the transition temperature: the appearance of such a field indicates that the superconducting state in this material is characterized by the breaking of time-reversal symmetry. These results, combined with other symmetry considerations, suggest that superconductivity in Sr2RuO4 is of p-wave (odd-parity) type, analogous to superfluid 3He.
Time-reversal-invariant topological superconductors have a full paring gap in the bulk and gapless Majorana states at the edge or on the surface. Here, we theoretically propose topological superconductivity in a doped quantum spin Hall insulator. We study the pairing symmetry of doped Sn$X$ film within a two-orbital model, and show that it realizes a topological superconductor when the intraorbital attractive interaction is stronger than the interorbital interaction, which is generic for a doped quantum spin Hall insulator with strong spin-orbit coupling. Edge channels are studied in a tight-b…
The traditional symmetries that protect superconductivity are time-reversal and inversion. Here, we examine the minimal symmetries protecting superconductivity in two dimensions and find that time-reversal symmetry and inversion symmetry are not required, and having a combination of either symmetry with a mirror operation on the basal plane is sufficient. We classify superconducting states stabilized by these two symmetries, when time-reversal and inversion symmetries are not present, and provide realistic minimal models as examples. Interestingly, several experimentally realized systems, such…
We consider a model for a one-dimensional quantum wire with Rashba spin-orbit coupling and repulsive interactions, proximity coupled to a conventional s-wave superconductor. Using a combination of Hartree-Fock and density matrix renormalization group calculations, we show that for sufficiently strong interactions in the wire, a time-reversal invariant topological superconducting phase can be stabilized in the absence of an external magnetic field. This phase supports two zero-energy Majorana bound states at each end, which are protected by time-reversal symmetry. The mechanism for the formatio…
We analyze the possible interaction-induced superconducting instabilities in noncentrosymmetric systems based on symmetries of the normal state. It is proven that pure electron-phonon coupling will always lead to a fully gapped superconductor that does not break time-reversal symmetry and is topologically trivial. We show that topologically nontrivial behavior can be induced by magnetic doping without gapping out the resulting Kramers pair of Majorana edge modes. In case of superconductivity arising from the particle-hole fluctuations associated with a competing instability, the properties of …
Vortex phase in a singlet superconductor in the absence of impurities is shown to be absolutely unstable with respect to the appearance of a triplet component which breaks both inversion and time-reversal symmetries of Cooper pairs. Symmetry breaking paramagnetic effects are demonstrated to be of the order of unity if the orbital upper critical field, Hc2(0), is of the order of Clogston paramagnetic limiting field, Hp. We suggest a generic phase diagram of such type-IV superconductor, which is singlet one at H=0 and characterized by mixed singlet-triplet order parameter with broken time-revers…
We propose a new type of non-uniform condensate state in the presence of time-reversal symmetry. The underlying platform of this state is a corrugated honeycomb lattice which exhibits an inhomogeneous pseudo magnetic field. Using the self-consistent tight-binding Bogoliubov-de Gennes formalism, we show that an s-wave pairing of chiral carriers in the presence of an inhomogeneous pseudo magnetic field results in a spatially modulated order parameter with the half wavelength of the corrugation. The manner of modulation depends on the fundamental directions of the honeycomb lattice, the zigzag an…
We establish quasi-two-dimensional thin films of iron-based superconductors (FeSCs) as a new high-temperature platform for hosting intrinsic time-reversal-invariant helical topological superconductivity (TSC). Based on the combination of Dirac surface state and bulk extended $s$-wave pairing, our theory should be directly applicable to a large class of experimentally established FeSCs, opening a new TSC paradigm. In particular, an applied electric field serves as a "topological switch" for helical Majorana edge modes in FeSC thin films, allowing for an experimentally feasible design of gate-co…
We report on muon spin relaxation measurements of the 4f^2-based heavy-fermion superconductor filled-skutterudite PrOs4Sb12. The results reveal the spontaneous appearance of static internal magnetic fields below the superconducting transition temperature, providing unambiguous evidence for the breaking of time-reversal symmetry in the superconducting state. A discussion is made on which of the spin or orbital component of Cooper pairs carries a nonzero momentum.
We study time reversal symmetry breaking superconductivity with $Δ_k = Δ_{x^2-y^2} (k) +e^{iθ} Δ_α$ ($α= s$ or $d_{xy}$) symmetries. It is shown that the behavior of such superconductors could be {\em qualitatively} different depending on the minor components ($α$) and its phase at lower temperatures. It is argued that such {\em qualitatively different} behaviors in thermal as well as in angular dependencies could be a {\em source} of consequences in transport and Josephson physics. Orthorhombicity is found to be a strong mechanism for mixed phase (in case of $α= s$). We show that due to elect…
We investigate the superconducting gap function of topological superconductor PbTaSe$_2$. Temperature, magnetic field, and three-dimensional (3D) field-angle dependences of the specific heat prove that the superconductivity of PbTaSe$_2$ is fully-gapped, with two isotropic $s$-wave gaps. The pair-breaking effect is probed by systematically increasing non-magnetic disorders through H$^+$-irradiations. The superconducting transition temperature, $T_{\rm{c}}$, is found to be robust against disorders, which suggests that the pairing should be sign-preserved rather than sign-reversed.
We report the magnetic and superconducting properties of locally noncentrosymmetric SrPtAs obtained by muon-spin-rotation/relaxation (muSR) measurements. Zero-field muSR reveals the occurrence of small spontaneous static magnetic fields with the onset of superconductivity. This finding suggests that the superconducting state of SrPtAs breaks time-reversal symmetry. The superfluid density as determined by transverse field muSR is nearly flat approaching T = 0 K proving the absence of extended nodes in the gap function. By symmetry, several superconducting states supporting time-reversal symmetr…
We argue that superconductivity in the coexistence region with spin-density-wave (SDW) order in weakly doped Fe-pnictides differs qualitatively from the ordinary $s^{+-}$ state outside the coexistence region, as it develops an additional gap component which is a mixture of intra-pocket singlet ($s^{++}$) and inter-pocket spin-triplet pairings (the $t-$state). The coupling constant for the $t-$channel is proportional to the SDW order and involves interactions that do not contribute to superconductivity outside of the SDW region. We argue that the $s^{+-}$ and $t-$type superconducting orders coe…
We study the possibility of complex tensor ($d$-wave) superconducting order in three-dimensional semimetals with chiral spin-1/2 triple-point fermions, which have an effective orbital angular momentum of $L=1$ arising from a crossing of three bands. Retaining the first three lowest order terms in momentum and assuming rotational symmetry we show that the resulting mean-field $d$-wave ground state breaks time reversal symmetry, and depends crucially on the coefficients of the two quadratic terms in the Hamiltonian. The phase diagram at a finite chemical potential displays both the "cyclic" and …
Bulk TiSe$_2$ is an intrinsically layered transition metal dichalcogenide (TMD) hosting both superconducting and charge density wave (CDW) ordering. Motivated by the recent progress in preparing two-dimensional TMDs, we study these frustrated orderings in {\it single} trilayer of TiSe$_2$ within a renormalization group approach. We establish that a novel state with time-reversal symmetry broken chiral superconductivity can emerge from the strong competition between CDW formation and superconductivity. Its stability depends on the precise strength and screening of the electron-electron interact…
Superconductivity is associated with spontaneously broken gauge symmetry. In some exotic superconductors the time-reversal symmetry is broken as well, accompanied with internal magnetic field. A time-reversal symmetry broken (TRSB) superconductivity without internal magnetic field involved can be induced by frustrated inter-component couplings, which becomes a realistic issue recently due to the discovery of iron-pnictide superconductors. Here we derive stability condition for this novel TRSB state using the Ginzburg-Landau (GL) theory. We find that there are multiple divergent coherence lengt…
Time-reversal symmetry breaking superconductivity with electronic glass in nickelate (La, Pr, Sm)3Ni2O7 films
Peking University(北京大学);Southern University of Science and Technology(南方科技大学);Renmin University of China(中国人民大学);ShanghaiTech University(上海科技大学);Boston College(波士顿学院);Tsinghua University(清华大学)
Sr$_{2}$RuO$_{4}$ is one of the most promising candidates of a topological superconductor with broken time-reversal symmetry, because a number of experiments have revealed evidences for a spin-triplet chiral $p$-wave superconductivity. In order to clarify the time-reversal symmetry of Sr$_{2}$RuO$_{4}$, we introduce a novel test that examines the invariance of the Josephson critical current under the inversion of both the current and magnetic fields, in contrast to the detection of a spontaneous magnetic field employed in past experiments. Analyses of the transport properties of the planar and…
We report point contact Andreev Reflection (PCAR) measurements on a high-quality single crystal of the non-centrosymmetric superconductor Re6Zr. We observe that the PCAR spectra can be fitted by taking two isotropic superconducting gaps with Delta_1 ~ 0.79 meV and Delta_2 ~ 0.22 meV respectively, suggesting that there are at least two bands which contribute to superconductivity. Combined with the observation of time reversal symmetry breaking at the superconducting transition from muon spin relaxation measurements (Phys. Rev. Lett. 112, 107002 (2014)), our results imply an unconventional super…
Time-reversal symmetry breaking (TRSB) with a Bardeen-Cooper-Schrieffer (BCS) -like superconductivity occurs in a small, but growing number of noncentrosymmetric (NCS) materials, although the mechanism is poorly understood. We present heat capacity, magnetization, resistivity, and muon spin resonance/relaxation ($μ$SR) measurements on polycrystalline samples of NCS La$_{7}$Pd$_{3}$. Transverse-field $μ$SR and heat capacity data show La$_{7}$Pd$_{3}$ is a type-II superconductor with a BCS-like gap structure, while zero-field $μ$SR results provide evidence of TRSB. We discuss the implications of…
Many proposals to generate a time-reversal invariant topological superconducting phase are based on imposing a $π$ phase difference between the superconducting leads proximitizing a nanostructure. We show that this phase can be induced on a thin film of a topological insulator like Bi$_2$Se$_3$ in proximity to a single s-wave superconductor. In our analysis we take into account the parity degree of freedom of the electronic states which is not included in effective Dirac-like surface theories. We find that the topological phase can be reached when the induced interparity pairing dominates over…
Superconductors with broken time-reversal symmetry represent arguably one of the most promising venues for realizing highly sought-after topological superconductivity that is vital to fault-tolerant quantum computation. Here, by using extensive muon-spin relaxation and rotation measurements, we report that the isostructural silicide superconductors (Ta, Nb)OsSi spontaneously break time-reversal symmetry at the superconducting transition while surprisingly showing a fully-gapped superconductivity characteristic of conventional superconductors. The first-principles calculations show that (Ta, Nb…
We propose a feasible route to engineer one and two dimensional time reversal invariant (TRI) topological superconductors (SC) via proximity effects between nodeless extended s wave iron-based SC and semiconductors with large Rashba spin-orbit interactions. At the boundary of a TRI topological SC, there emerges a Kramers pair of Majorana edge (bound) states. For a Josephson pi-junction we predict a Majorana quartet that is protected by mirror symmetry and leads to a mirror fractional Josephson effect. We analyze the evolution of Majorana pair in Zeeman fields, as the SC undergoes a symmetry cl…
A topological superconductor is characterized by having a pairing gap in the bulk and gapless self-hermitian Majorana modes at its boundary. In one dimension, these are zero-energy modes bound to the ends, while in two dimensions these are chiral gapless modes traveling along the edge. Majorana modes have attracted a lot of interest due to their exotic properties, which include non-abelian exchange statistics. Progress in realizing topological superconductivity has been made by combining spin-orbit coupling, conventional superconductivity, and magnetism. The existence of protected Majorana mod…
The noncentrosymmetric superconductor Re$_{24}$Ti$_{5}$, a time-reversal symmetry (TRS) breaking candidate with $T_c = 6$\,K, was studied by means of muon-spin rotation/relaxation ($μ$SR) and tunnel-diode oscillator (TDO) techniques. At a macroscopic level, its bulk superconductivity was investigated via electrical resistivity, magnetic susceptibility, and heat capacity measurements. The low-temperature penetration depth, superfluid density and electronic heat capacity all evidence an $s$-wave coupling with an enhanced superconducting gap. The spontaneous magnetic fields revealed by zero-field…
FeSe is a unique member of the family of iron-based superconductors, not only because of the high values of $T_{c}$ in FeSe monolayer, but also because in bulk FeSe superconductivity emerges inside a nematic phase without competing with long-range magnetic order. Near $T_{c}$, superconducting order necessarily has $s+d$ symmetry, because nematic order couples linearly the $s$-wave and $d$-wave harmonics of the superconducting order parameter. Here we argue that the near-degeneracy between $s$-wave and $d$-wave pairing instabilities in FeSe, combined with the sign-change of the nematic order pa…
We investigate pairing states realized at the (001) interface of a spin-triplet superconductor Sr$_2$RuO$_4$ on the basis of microscopic calculations. Because of a Rashba-type spin-orbit interaction induced at the interface, strong parity-mixing of Cooper pairs between a spin-singlet state and a spin-triplet state occurs in this system. There are also strong inter-band pair correlations between the spin-orbit split bands, in spite of the considerably large spin-orbit splitting. This is due to frustration between the spin-orbit interaction and pairing interactions. In this pairing state, time-r…
For Josephson junctions based on s-wave superconductors, time-reversal symmetry is known to allow for powerful relations between the normal-state junction properties, the excitation spectrum, and the Josephson current. Here we provide analogous relations for Josephson junctions involving one-dimensional time-reversal-invariant topological superconductors supporting Majorana-Kramers pairs, considering both topological-topological and s-wave-topological junctions. Working in the regime where the junction is much shorter than the superconducting coherence length, we obtain a number of analytical …
Recently, in certain flat band lattice systems at commensurate fillings, fractional quantum Hall states have been found -- which have anyonic excitations. We study such systems away from commensuration, i.e. the ground state of an anyon gas in such a system. The presence of the underlying lattice allows access to an entirely new regime where the anyon kinetic energy can be larger than their interaction energy. Within the flux-attachment approach, using mean-field then adding fluctuations, we find several possible superfluid states. Two have intrinsic topological order, i.e. fractionalized quas…
Strong-coupling approach to temperature dependence of competing orders of superconductivity: Possible time-reversal symmetry breaking and nontrivial topology
Recently, compounds with noncentrosymmetric crystal structure have attracted much attention for providing a rich playground in search for unconventional superconductivity. NbIr$_2$B$_2$ is a new member to this class of materials harboring superconductivity below $T_{\rm c} = 7.3(2)$~K and very high upper critical field that exceeds Pauli limit. Here we report on muon spin rotation ($μ$SR) experiments probing the temperature and field dependence of effective magnetic penetration depth in this compound. Our transverse-field -$μ$SR results suggest a fully gaped $s$-wave superconductvity. Further,…
We investigate the nature of the time-reversal breaking pairing state in the hole-doped monolayer MoS$_{2}$ on the basis of the realistic three-orbital attractive Hubbard-like model with the atomic spin-orbit coupling. Due to the multi-band features arising from the Mo $d$ orbitals in the noncentrosymmetric crystal structure, the Lifshitz transition takes place upon hole doping. Across the Lifshitz transition point, the sign of the relative phase between the Cooper-pair components drastically changes, leading to the emergence of the time-reversal breaking phase with complex gap functions. It i…
The competition between Kitaev and Heisenberg interactions away from half filling is studied for the the hole-doped Kitaev-Heisenberg $t$-$J_K$-$J_H$ model on a honeycomb lattice. While the isotropic Heisenberg coupling supports a time-reversal violating d-wave singlet state, we find that the Kitaev interaction favors a time-reversal invariant p-wave superconducting phase, which obeys the rotational symmetries of the microscopic model, and is robust for $J_H<J_K/2$. Within the p-wave superconducting phase, a critical chemical potential $μ_c \approx t$ separates a topologically trivial phase fo…
Time-reversal symmetry breaking superconductors are exotic phases of matter with fascinating properties, which are, however, encountered rather sparsely. Here we identify the possibility of realizing such a superconducting ground state that exhibits an $f+is$ pairing symmetry in strained graphene. Although the underlying attractive interactions need to be sufficiently strong and comparable in pristine graphene to support such pairing state, we argue that strain can be conducive for its formation even for weak interactions. We show that quantum-critical behavior near the transition is controlle…
We discuss superconductivity in a model on a cubic lattice for a $Γ_3$ non-Kramers system. In previous studies, it is revealed that $d$-wave superconductivity with $E_g$ symmetry occurs in a wide parameter range in a $Γ_3$ system. Such anisotropic superconductivity can break the cubic symmetry of the lattice. In a $Γ_3$ system, the quadrupole degrees of freedom are active and the effect of the cubic symmetry breaking should be important. Here, we investigate the coexisting states of the $d$-wave superconductivity and quadrupole order by a mean-field theory. In particular, we discuss possible c…
Time-reversal invariant topological superconductors are a new state of matter which have a bulk superconducting gap and robust Majorana fermion surface states. These have not yet been realized in solid state systems. In this paper, we propose that this state can be realized in doped Weyl semimetals or Weyl metals. The Fermi surfaces of a Weyl metal carry Chern numbers, which is a required ingredient for such a topological superconductor. By applying the fluctuation-exchange approach to a generic model of time-reversal invariant Dirac and Weyl semimetals, we investigate what microscopic interac…
The Th$_{7}$Fe$_{3}$ family of superconductors provides a rich playground for unconventional superconductivity. La$_7$Ni$_3$ is the latest member of this family, which we here investigate by means of thermodynamic and muon spin rotation and relaxation measurements. Our specific heat data provides evidence for two distinct and approximately isotropic superconducting gaps. The larger gap has a value slightly higher than that of weak-coupling BCS theory, indicating the presence of significant correlations. These observations are confirmed by transverse-field muon-rotation measurements. Furthermor…
We consider mixed symmetry superconducting phases in Dirac materials in the odd parity channel, where pseudoscalar and vector order parameters can coexist due to their similar critical temperatures when attractive interactions are of finite range. We show that the coupling of these order parameters to unordered magnetic dopants favors the condensation of novel time-reversal symmetry breaking (TRSB) phases, characterized by a condensate magnetization, rotation symmetry breaking, and simultaneous ordering of the dopant moments. We find a rich phase diagram of mixed TRSB phases characterized by p…
In general, magnetism and superconductivity are antagonistic to each other. However, there are several families of superconductors, in which superconductivity may coexist with magnetism, and only a few examples are known, when superconductivity itself induces spontaneous magnetism. The most known compounds are Sr$_2$RuO$_4$ and some noncentrosymmetric superconductors. Here, we report the finding of a narrow dome of a novel $s+is'$ superconducting (SC) phase with broken time-reversal symmetry (BTRS) inside the broad $s$-wave SC region of the centrosymmetric multiband superconductor Ba$_{\rm 1-x…
We consider a model of multiband superconductivity, inspired by iron pnictides, in which three bands are connected via repulsive pair-scattering terms. Generically, three distinct superconducting states arise within such a model. Two of them are straightforward generalizations of the two-gap order parameter while the third one corresponds to a time-reversal symmetry breaking order parameter, altogether absent within the two-band model. Potential observation of such a genuinely frustrated state would be a particularly vivid manifestation of the repulsive interactions being at the root of iron-b…
We study possible applications of high critical temperature nodal superconductors for the search for Majorana bound states in the DIII class. We propose a microscopic analysis of the proximity effect induced by d-wave superconductors on a semiconductor wire with strong spin-orbit coupling. We characterize the induced superconductivity on the wire employing a numerical self-consistent tight-binding Bogoliubov-de Gennes approach, and analytical considerations on the Green's function. The order parameter induced on the wire, the pair correlation function, and the renormalization of the Fermi poin…
Time-reversal symmetric topological superconductivity in Machida-Shibata lattices
I. Institute for Theoretical Physics, University of Hamburg(汉堡大学第一理论物理研究所);Centre for Ultrafast Imaging(超快成像中心);RIKEN Interdisciplinary Theoretical and Mathematical Sciences (iTHEMS)(理化学研究所交叉理论与数学科学(iTHEMS))
The iron-based superconductors are an ideal platform to reveal the enigma of the unconventional superconductivity and potential topological superconductivity. Among them, the monolayer Fe(Se,Te)/SrTiO3(001), which is proposed to be topological nontrivial, shows interface-enhanced high-temperature superconductivity in the two dimensional limit. However, the experimental studies on the superconducting pairing mechanism of monolayer Fe(Se,Te) films are still limited. Here, by measuring quasiparticle interference in monolayer Fe(Se,Te)/SrTiO3(001), we report the observation of the anisotropic stru…
The kagome metal CsV$_{3}$Sb$_{5}$ features an unusual competition between the charge-density-wave (CDW) order and superconductivity. Evidence for time-reversal symmetry breaking (TRSB) inside the CDW phase has been accumulating. Hence, the superconductivity in CsV$_{3}$Sb$_{5}$ emerges from a TRSB normal state, potentially resulting in an exotic superconducting state. To reveal the pairing symmetry, we first investigate the effect of nonmagnetic impurity. Our results show that the superconducting critical temperature is insensitive to disorder, pointing to conventional $s$-wave superconductiv…
Epitaxial bilayer films of Bi(110) and Ni host a time-reversal symmetry (TRS) breaking superconducting order with an unexpectedly high transition temperature $T_c = 4.1$ K. Using time-domain THz spectroscopy, we measure the low energy electrodynamic response of a Bi/Ni bilayer thin film from $0.2$ THz to $2$ THz as a function of temperature and magnetic field. We analyze the data in the context of a BCS-like superconductor with a finite normal-state scattering rate. In zero magnetic field, all states in the film become fully gapped, providing important constraints into possible pairing symmetr…