The Pauli Exclusion Operator (PEO) which ensures proper symmetry of the eigenstates of multi-electron systems with respect to exchange of each pair of electrons is introduced. Once PEO is added to the Hamiltonian, no additional constraints on multi-electron wave function due to the Pauli exclusion principle are needed. For two-electron states in two dimensions ($2D$) the PEO can be expressed in a closed form in terms of momentum operators, while in the position representation PEO is a non-local operator. Generalizations of PEO for multi-electron systems is introduced. Several approximations to PEO are discussed. Examples of analytical and numerical calculations of PEO are given for isotropic and anisotropic Hooke's atom in~$2D$. Application of approximate and kernel forms of PEO for calculations of energies and states in~$2D$ Hooke's atom are analyzed. Relation of PEO to standard variational calculations with the use of Slater determinant is discussed.
The Pauli exclusion principle can be stated as inequality $<ψ|ρ|ψ>\le 1$ for the electron density matrix $ρ$. Nowadays it is replaced by skew symmetry of the multi-electron wave function. The replacement leads to numerous additional constraints on $ρ$, which are discussed in this letter together with their physical implications, in particular for spin magnetic moment of a multi-electron system.
"What are the consequences ... that Fermi particles cannot get into the same state ... " R. P. Feynman wrote of the Pauli exclusion principle, "In fact, almost all the peculiarities of the material world hinge on this wonderful fact." In 1972 Borland and Dennis showed that there exist powerful constraints beyond the Pauli exclusion principle on the orbital occupations of Fermi particles, providing important restrictions on quantum correlation and entanglement. Here we use computations on quantum computers to experimentally verify the existence of these additional constraints. Quantum many-ferm…
The Pauli Exclusion Principle is a basic principle of Quantum Mechanics, and its validity has never been seriously challenged. However, given its fundamental standing, it is very important to check it as thoroughly as possible. Here we describe the VIP (VIolation of the Pauli exclusion principle) experiment, an improved version of the Ramberg and Snow experiment (E. Ramberg and G. Snow, {\it Phys. Lett. B} {\bf 238}, 438 (1990)); VIP has just completed the installation at the Gran Sasso underground laboratory, and aims to test the Pauli Exclusion Principle for electrons with unprecedented accu…
Pauli's exclusion principle has a strong impact on the properties of most fermionic quantum systems. Remarkably, the fermionic exchange symmetry implies further constraints on the one-particle picture. By exploiting those generalized Pauli constraints we derive a measure which quantifies the influence of the exchange symmetry beyond Pauli's exclusion principle. It is based on a geometric hierarchy induced by the exclusion principle constraints. We provide a proof of principle by applying our measure to a simple model. In that way, we conclusively confirm the physical relevance of the generaliz…
The Pauli Exclusion Principle is one of the basic principles of modern physics and is at the very basis of our understanding of matter: thus it is fundamental importance to test the limits of its validity. Here we present the VIP (Violation of the Pauli Exclusion Principle) experiment, where we search for anomalous X-rays emitted by copper atoms in a conductor: any detection of these anomalous X-rays would mark a Pauli-forbidden transition. ] VIP is currently taking data at the Gran Sasso underground laboratories, and its scientific goal is to improve by at least four orders of magnitude the p…
Bell's inequality has been traditionally used to explore the relationship between hidden variables and the Copenhagen interpretation of quantum mechanics. In this paper, another use is found. Bell's inequality is used to derive a coupling principle for elementary particles and to give a deeper understanding of baryonic structure. We also give a derivation of the Pauli exclusion principle from the coupling principle. Pacs: 14.20-c, 12.90+b, 3.65.Bz, 12.40.Ee
The validity of the Pauli Exclusion Principle, a building block of Quantum Mechanics, is tested for electrons. The VIP (VIolation of Pauli exclusion principle) and its follow-up VIP-2 experiments at the Laboratori Nazionali del Gran Sasso search for x-rays from copper atomic transition that are prohibited by the Pauli Exclusion Principle. The candidate events, if they exist, originate from the transition of a $2p$ orbit electron to the ground state which is already occupied by two electrons. The present limit on the probability for Pauli Exclusion Principle violation for electrons set by the V…
The Pauli Exclusion Principle (PEP) is one of the basic principles of modern physics and, even if there are no compelling reasons to doubt its validity, it is still debated today because an intuitive, elementary explanation is still missing, and because of its unique stand among the basic symmetries of physics. The present paper reports a new limit on the probability that PEP is violated by electrons, in a search for a shifted K$_α$ line in copper: the presence of this line in the soft X-ray copper fluorescence would signal a transition to a ground state already occupied by 2 electrons. The ob…
The VIolation of Pauli exclusion principle -2 experiment, or VIP-2 experiment, at the Laboratori Nazionali del Gran Sasso searches for x-rays from copper atomic transition that are prohibited by the Pauli Exclusion Principle. Candidate direct violation events come from the transition of a $2p$ electron to the ground state that is already occupied by two electrons. From the first data taking campaign in 2016 of VIP-2 experiment, we determined a best upper limit of 3.4 $\times$ 10$^{-29}$ for the probability that such a violation exists. Significant improvement in the control of the experimental…
The Pauli exclusion principle (PEP) represents one of the basic principles of modern physics and, even if there are no compelling reasons to doubt its validity, it still spurs a lively debate, because an intuitive, elementary explanation is still missing, and because of its unique stand among the basic symmetries of physics. A new limit on the probability that PEP is violated by electrons was estabilished by the VIP (VIolation of the Pauli exclusion principle) Collaboration, using the method of searching for PEP forbidden atomic transitions in copper. The preliminary value, ${1/2}β^{2} \textle…
We are experimentally investigating possible violations of standard quantum mechanics predictions in the Gran Sasso underground laboratory in Italy. We test with high precision the Pauli Exclusion Principle and the collapse of the wave function (collapse models). We present our method of searching for possible small violations of the Pauli Exclusion Principle (PEP) for electrons, through the search for anomalous X-ray transitions in copper atoms. These transitions are produced by new electrons (brought inside the copper bar by circulating current) which can have the possibility to undergo Paul…
The VIP2 (VIolation of the Pauli Exclusion Principle) experiment at the Gran Sasso underground laboratory (LNGS) is searching for possible violations of standard quantum mechanics predictions in atoms at very high sensitivity. We investigate atomic transitions with precision X-ray spectroscopy in order to test the Pauli Exclusion Principle (PEP) and therefore the related spin-statistics theorem. We will present our experimental method for the search for "anomalous" (i.e. Pauli-forbidden) X-ray transitions in copper atoms, produced by "new" electrons, which could have tiny probability to underg…
The Pauli Exclusion Principle is one of the most fundamental rules of nature and represents a pillar of modern physics. According to many observations the Pauli Exclusion Principle must be extremely well fulfilled. Nevertheless, numerous experimental investigations were performed to search for a small violation of this principle. The VIP experiment at the Gran Sasso underground laboratory searched for Pauli-forbidden X-ray transitions in copper atoms using the Ramberg-Snow method and obtained the best limit so far. The follow-up experiment VIP2 is designed to reach even higher sensitivity. It …
In this article, the rotational invariance of entangled quantum states is investigated as a possible cause of the Pauli exclusion principle. First, it is shown that a certain class of rotationally invariant states can only occur in pairs. This will be referred to as the coupling principle. This in turn suggests a natural classification of quantum systems into those containing coupled states and those that do not. Surprisingly, it would seem that Fermi-Dirac statistics follows as a consequence of this coupling while the Bose-Einstein follows by breaking it. Finally, the experimental evidence to…
The VIP (Violation of Pauli exclusion principle) experiment and its follow-up experiment VIP-2 at the Laboratori Nazionali del Gran Sasso (LNGS) search for X-rays from Cu atomic states that are prohibited by the Pauli Exclusion Principle (PEP). The candidate events, if they exist, will originate from the transition of a $2p$ orbit electron to the ground state which is already occupied by two electrons. The present limit on the probability for PEP violation for electron is 4.7 $\times10^{-29}$ set by the VIP experiment. With upgraded detectors for high precision X-ray spectroscopy, the VIP-2 ex…
We examine the influence of the Pauli exclusion principle on the scattering properties of composite bosons (cobosons) made of two fermions, such as the exciton quasiparticle. The scattering process incorporates boson-phonon interactions that arise due to lattice vibrations. Composite boson scattering rates increase with the entanglement between the two fermionic constituents, which comes with a larger number of available single-fermion states. An important role is played by probabilities associated with accommodating an incoming boson among the remaining unoccupied Schmidt modes in the initial…
Many experiments investigated the violation of the Pauli Exclusion Principle (PEP) since its discovery in 1925. The VIP (VIolation of the Pauli Principle) experiment tested the PEP by measuring the probability for an external electron to be captured and undergo a 2p to 1s transition during its cascading process, where the 1s state is already occupied by two electrons. This transition is forbidden by the Pauli Exclusion Principle. The VIP experiment resulted in a preliminary upper limit for the probability of the violation of the PEP of 4.7 x 10^{-29}. Currently a setup for the follow-up experi…
The theory of Fermion oscillators has two essential ingredients: zero-point energy and Pauli exclusion principle. We devlop the theory of the statistical mechanics of generalized q-deformed Fermion oscillator algebra with inclusion principle (i.e., without the exclusion principle), which corresponds to ordinary fermions with Pauli exclusion principle in the classical limit $q \to 1$. Some of the remarkable properties of this theory play a crucial role in the understanding of the q-deformed Fermions. We show that if we insist on the weak exclusion principle, then the theory has the expected low…
High-precision experiments have been done to test the Pauli exclusion principle (PEP) for electrons by searching for anomalous $K$-series X-rays from a Cu target supplied with electric current. With the highest sensitivity, the VIP (VIolation of Pauli Exclusion Principle) experiment set an upper limit at the level of $10^{-29}$ for the probability that an external electron captured by a Cu atom can make the transition from the 2$p$ state to a 1$s$ state already occupied by two electrons. In a follow-up experiment at Gran Sasso, we aim to increase the sensitivity by two orders of magnitude. We …
The development of mathematically complete and consistent models solving the so-called "measurement problem", strongly renewed the interest of the scientific community for the foundations of quantum mechanics, among these the Dynamical Reduction Models posses the unique characteristic to be experimentally testable. In the first part of the paper an upper limit on the reduction rate parameter of such models will be obtained, based on the analysis of the X-ray spectrum emitted by an isolated slab of germanium and measured by the IGEX experiment. The second part of the paper is devoted to present…
Under continuous-wave laser excitation in an InGaAs multi-quantum-well (MQW) structure, the carrier temperature extracted from photoluminescence rises faster for 405 nm excitation compared with 980 nm excitation, as the injected carrier density increases. Ensemble Monte Carlo simulation of the carrier dynamics in the MQW system shows that this carrier temperature rise is dominated by nonequilibrium LO phonon effects, with the Pauli exclusion having a significant effect at high carrier densities. Further, we find a significant fraction of carriers reside in the satellite L-valleys for 405 nm ex…
We propose and work out a reduced density matrix functional theory (RDMFT) for calculating energies of eigenstates of interacting many-electron systems beyond the ground state. Various obstacles which historically have doomed such an approach to be unfeasible are overcome. First, we resort to a generalization of the Ritz variational principle to ensemble states with fixed weights. This in combination with the constrained search formalism allows us to establish a universal functional of the one-particle reduced density matrix. Second, we employ tools from convex analysis to circumvent the too i…
Equal-spin and opposite-spin density-density correlations in the BCS-BEC crossover: Gauge Symmetry, Pauli Exclusion Principle, Wick's Theorem and Experiments
Rhineland-Palatinate Technical University Kaiserslautern-Landau（莱茵兰-普法尔茨凯泽斯劳滕-兰道理工大学）；Georgia Institute of Technology（佐治亚理工学院）
An intuitive, generic, physical model, or conceptual paradigm for pilot wave steerage of particle beams based on Stochastic Electrodynamics is presented. The utility of this model for understanding the Pauli Exclusion Principle is briefly considered, and a possible experimental verification for the underlying concepts is proposed. \\[7mm] Key words: Quantum Mechanics, Pilot Wave, Pauli Exclusion Principle, Stochastic Electrodynamics
By the Pauli exclusion principle no quantum state can be occupied by more than one electron. One can put it as a constraint on the electron density matrix that bounds its eigenvalues by 1. Shortly after its discovery the Pauli principle has been replaced by skew symmetry of a multi-electron wave function. In this paper we solve a longstanding problem about the impact of this replacement on the electron density matrix, that goes far beyond the original Pauli principle.
Recently observed Pauli crystals are structures formed by trapped ultracold atoms with the Fermi statistics. Interactions between these atoms are switched off, so their relative positions are determined by joined action of the trapping potential and the Pauli exclusion principle. Numericalmodeling is used in this paper to find the Pauli crystals in a two-dimensional isotropic harmonic trap, three-dimensional harmonic trap, and a two-dimensional square well trap. The Pauli crystals do not have the symmetry of the trap -- the symmetry is broken by the measurement of positions and, in many cases,…
The modern state of the Pauli Exclusion Principle (PEP) is discussed. PEP can be considered from two viewpoints. On the one hand, it asserts that particles with half-integer spin (fermions) are described by antisymmetric wave functions, and particles with integer spin (bosons) are described by symmetric wave functions. This is the so-called spin-statistics connection (SSC). As we will discuss, the physical reasons why SSC exists are still unknown. On the other hand, according to PEP, the permutation symmetry of the total wave functions can be only of two types: symmetric or antisymmetric, both…
It is important that any dynamics method approaches the correct population distribution at long times. In this paper, we derive a one-body reduced density matrix dynamics for electrons in energetic contact with a bath. We obtain a remarkable equation of motion which shows that in order to reach equilibrium properly, rates of electron transitions depend on the density matrix. Even though the bath drives the electrons towards a Boltzmann distribution, hole blocking factors in our equation of motion cause the electronic populations to relax to a Fermi-Dirac distribution. These factors are an old …
In a first historical part I shall give a detailed description of how Pauli discovered --before the advent of the new quantum mechanics -- his exclusion principle. The second part is devoted to the insight and results that have been obtained in more recent times in our understanding of the stability of matter in bulk, both for ordinary matter (like stones) and self-gravitating bodies.
In Dirac's hole theory (HT) the vacuum state is generally believed to be the state of minimum energy due to the assumption that the Pauli Exclusion Principle prevents the decay of positive energy electrons into occupied negative energy states. However recently papers have appeared that claim to show that there exist states with less energy than that of the vacuum[4][5][6]. Here we will consider a simple model of HT consisting of zero mass electrons in 1-1D space-time. It will be shown that for this model there are states with less energy than the HT vacuum state and that the Pauli Principle is…
The Pauli exclusion principle is a fundamental law underpinning the structure of matter. Due to their anti-symmetric wave function, no two fermions can occupy the same quantum state. Here, we report on the direct observation of the Pauli principle in a continuous system of up to six particles in the ground state of a two-dimensional harmonic oscillator. To this end, we sample the full many-body wavefunction by applying a single atom resolved imaging scheme in momentum space. We find so-called Pauli crystals as a manifestation of higher order correlations. In contrast to true crystalline phases…
Spontaneous emission by an excited fermionic atom can be suppressed due to the Pauli exclusion principle if the relevant final states after the decay are already occupied by identical atoms in the ground state. Here we discuss a setup where a single atom is prepared in the first excited state on a single site of an optical lattice under conditions of very tight trapping. We investigate these phenomena in the context of two experimental realizations: (1) with alkali atoms, where the decay rate of the excited state is large and (2) with alkaline earth-like atoms, where the decay rate from metast…
The Pauli Exclusion Principle (PEP) is a basic principle of Quantum Mechanics, and its validity has never been seriously challenged. However, given its importance, it is very important to check it as thoroughly as possible. Here we describe the VIP (Violation of PEP) experiment, an improved version of the Ramberg and Snow experiment (Ramberg and Snow, Phys. Lett. B238 (1990) 438); VIP shall be performed at the Gran Sasso underground laboratories, and aims to test the Pauli Exclusion Principle for electrons with unprecedented accuracy, down to $\frac{β^2}{2} \sim 10^{-30}$
In the VIP2 (VIolation of the Pauli Exlusion Principle) experiment at the Gran Sasso underground laboratory (LNGS) we are searching for possible violations of standard quantum mechanics predictions. With high precision we investigate the Pauli Exclusion Principle and the collapse of the wave function (collapse models). We will present our experimental method of searching for possible small violations of the Pauli Exclusion Principle for electrons, via the search for "anomalous" X-ray transitions in copper atoms, produced by "new" electrons (brought inside a copper bar by circulating current) w…
From a geometric point of view, Pauli's exclusion principle defines a hypersimplex. This convex polytope describes the compatibility of $1$-fermion and $N$-fermion density matrices, therefore it coincides with the convex hull of the pure $N$-representable $1$-fermion density matrices. Consequently, the description of ground state physics through $1$-fermion density matrices may not necessitate the intricate pure state generalized Pauli constraints. In this article, we study the generalization of the $1$-body $N$-representability problem to ensemble states with fixed spectrum $\mathbf{w}$, in o…
Polymer self-consistent field theory techniques are used to find radial electron densities and total binding energies for isolated atoms. Quantum particles are modelled as Gaussian threads with ring-polymer architecture in a four dimensional thermal-space, and a Pauli potential is postulated based on classical excluded volume implemented in the thermal-space using Edwards/Flory-Huggins interactions in a mean-field approximation. Other approximations include a Fermi-Amaldi correction for electron-electron self-interactions, a spherical averaging approximation to reduce the dimensionality of the…
We are experimentally investigating possible violations of standard quantum mechanics predictions in the Gran Sasso underground laboratory in Italy. We test with high precision the Pauli Exclusion Principle and the collapse of the wave function (collapse models). We present our method of searching for possible small violations of the Pauli Exclusion Principle (PEP) for electrons, through the search for anomalous X-ray transitions in copper atoms, produced by fresh electrons (brought inside the copper bar by circulating current) which can have the probability to undergo Pauli-forbidden transiti…
The Schrödinger-Pauli theory of electrons in the presence of a static electromagnetic field can be described from the perspective of the individual electron via its equation of motion or `Quantal Newtonian' first law. The law is in terms of `classical' fields whose sources are quantum-mechanical expectation values of Hermitian operators taken with respect to the wave function. The law states that the sum of the external and internal fields experienced by each electron vanishes. The external field is the sum of the binding electrostatic and Lorentz fields. The internal field is the sum of field…
Fermionic natural occupation numbers do not only obey Pauli's exclusion principle but are even stronger restricted by so-called generalized Pauli constraints. Whenever given natural occupation numbers lie on the boundary of the allowed region the corresponding $N$-fermion quantum state has a significantly simpler structure. We recall the recently proposed natural extension of the Hartree-Fock ansatz based on this structural simplification. This variational ansatz is tested for the lithium atom. Intriguingly, the underlying mathematical structure yields universal geometrical bounds on the corre…
The Pauli exclusion principle gives an upper bound of 1 on the natural occupation numbers. Recently there has been an intriguing amount of theoretical evidence that there is a plethora of additional generalized Pauli restrictions or (in)equalities, of kinematic nature, satisfied by these numbers. Here for the first time a numerical analysis of the nature of such constraints is effected in real atoms. The inequalities are nearly saturated, or quasi-pinned. For rank-six and rank-seven approximations for lithium, the deviation from saturation is smaller than the lowest occupancy number. For a ran…
The question of whether given density operators for subsystems of a multipartite quantum system are compatible to one common total density operator is known as the quantum marginal problem. We briefly review the solution of a subclass of such problems found just recently. In particular, this provides the solution of the $1$-body $N$-representability problem. Its solution, the so-called generalized Pauli constraints, restrict the set of mathematically possible fermionic occupation numbers significantly, and strengthens Pauli's exclusion principle. Moreover, we review the study of a concrete phy…
