Quantum dynamics of driven open systems should be compatible with both quantum mechanic and thermodynamic principles. By formulating the thermodynamic principles in terms of a set of postulates we obtain a thermodynamically consistent master equation. Following an axiomatic approach, we base the analysis on an autonomous description, incorporating the drive as a large transient control quantum system. In the appropriate physical limit, we derive the semi-classical description, where the control is incorporated as a time-dependent term in the system Hamiltonian. The transition to the semi-classical description reflects the conservation of global coherence and highlights the crucial role of coherence in the initial control state. We demonstrate the theory by analyzing a qubit controlled by a single bosonic mode in a coherent state.
We consider the dynamical properties of dissipative continuous-time quantum walks on directed graphs. Using a large-deviation approach we construct a thermodynamic formalism allowing us to define a dynamical order parameter, and to identify transitions between dynamical regimes. For a particular class of dissipative quantum walks we propose a quantum generalization of the the classical PageRank vector, used to rank the importance of nodes in a directed graph. We also provide an example where one can characterize the dynamical transition from an effective classical random walk to a dissipative …
We study the fundamental limitations of cooling to absolute zero for a qubit, interacting with a single mode of the electromagnetic field. Our results show that the dynamical Casimir effect, which is unavoidable in any finite-time thermodynamic cycle, forbids the attainability of the absolute zero of temperature, even in the limit of an infinite number of cycles.
High-precision low-temperature thermometry is a challenge for experimental quantum physics and quantum sensing. Here we consider a thermometer modelled by a dynamically-controlled multilevel quantum probe in contact with a bath. Dynamical control in the form of periodic modulation of the energy-level spacings of the quantum probe can dramatically increase the maximum accuracy bound of low-temperatures estimation, by maximizing the relevant quantum Fisher information. As opposed to the diverging relative error bound at low temperatures in conventional quantum thermometry, periodic modulation of…
We introduce a generalized approach to characterize the non-Markovianity of quantum dynamical maps via breakdown of monotonicity of thermodynamic functions. By adopting an entropy-based formulation of quantum thermodynamics, we use the relationship between heat and entropy to propose a measure of non-Markovianity based on the heat flow for single-qubit quantum evolutions. This measure can be applied for unital dynamical maps that do not invert the sign of the internal energy. Under certain conditions, it can also be extended for other thermodynamic functions, such as internal energy and work f…
We study the thermodynamic properties of a superconductor/normal metal/superconductor Josephson junction {in the short limit}. Owing to the proximity effect, such a junction constitutes a thermodynamic system where {phase difference}, supercurrent, temperature and entropy are thermodynamical variables connected by equations of state. These allow conceiving quasi-static processes that we characterize in terms of heat and work exchanged. Finally, we combine such processes to construct a Josephson-based Otto and Stirling cycles. We study the related performance in both engine and refrigerator ope…
We study non-equilibrium stationary states of a cavity system consisting of many atoms interacting with a quantized cavity field mode, under a driving field in a dissipative environment. We derive a quantum master equation which is suitable for treating systems with a strong driving field and a strong atom-photon interaction. We do this by making use of the fact that the mean-field dynamics are exact in the thermodynamic limit thanks to a uniform coupling between atoms and photons. We find ordered states with symmetry-broken components of the photon field and atomic excitation driven by the ex…
A scheme for improving the sensitivity of quantum thermometry is proposed where the sensing quantum system used to recover the temperature of an external bath is dynamically coupled with an external ancilla (a meter) via a Hamiltonian term $\hat{H}_I$. At variance with previous approaches, our scheme relies neither on the presence of initial entanglement between the sensor and the meter, nor on the possibility of performing joint measurements on the two systems. The advantages we report arise from the fact that the presence of $\hat{H}_I$ interferes with the bath-sensor interaction, transformi…
Assigning the variations of internal energy into heat or work contributions is a challenging task due to the fact that these properties are trajectory dependent. A number of proposals have been put forward for open quantum systems following an arbitrary dynamics. We here focus on non-equilibrium thermodynamics of a two-level system and explore, in addition to the conventional approach, two definitions motivated by either classical work or heat, in which the driving Hamiltonian or the trajectory itself are respectively used to set up a reference basis. We first give the thermodynamic properties…
We investigate the energy distribution and quantum thermodynamics in periodically driven polaritonic systems in the stationary state at room temperature. Specifically, we consider an exciton strongly coupled to a harmonic oscillator and quantify the energy reorganization between these two systems and their interaction as a function of coupling strength, driving force, and detuning. After deriving the quantum master equation for the polariton density matrix with weak environment interactions, we obtain the dissipative time propagator and the long-time evolution of an equilibrium initial state. …
We aim to give a pedagogic presentation of the open system dynamics of a periodically driven qubit in contact with a temperature bath. We are specifically interested in the thermodynamics of the qubit. It is well known that by combining the Markovian approximation with Floquet theory it is possible to derive a stochastic Schrödinger equation in $\mathbb{C}^2$ for the state of the qubit. We follow here a different approach. We use Floquet theory to embed the time-non autonomous qubit dynamics into time-autonomous yet infinite dimensional dynamics. We refer to the resulting infinite dimensional …
While it is well known that complete positivity guarantees the fulfilment of the second law of thermodynamics, its possible violations have never been proposed as a check of the complete positivity of a given open quantum dynamics. We hereby consider an open quantum micro-circuit, effectively describable as a two-level open quantum system, whose asymptotic current might be experimentally accessible. This latter could indeed be used to discriminate between its possible non-completely positive Redfield dynamics and a completely positive one obtained by standard weak-coupling limit techniques, at…
We provide a dynamical proof of the second law of thermodynamics, along the lines of an argument of Penrose and Gibbs, making crucial use of the upper semicontinuity of the mean entropy proved by Robinson and Ruelle and Lanford and Robinson. An example is provided by a class of models of quantum spin systems introduced by Emch and Radin. Consequences regarding irreversibility and the time arrow, as well as possible extensions to quantum continuous systems are discussed.
The recent advancement of quantum computer hardware offers the potential to simulate quantum many-body systems beyond the capability of its classical counterparts. However, most current works focus on simulating the ground-state properties or pure-state quantum dynamics of quantum systems. Finite-temperature physics are much less explored, and existing literature mainly consider equilibrium properties. Here we present a variational quantum simulation protocol based on the thermofield dynamics formalism to simulate the dynamical and non-equilibrium finite-temperature properties of quantum syste…
For a quantum (many-body) system with dynamical symmetry described by a given Lie group, we study the trace of exponential operators with complex coefficients in one of the irreducible subspaces in terms of the boson realization. By using this approach, for compact groups, we obtain the result of the trace that is consistent with the well-known Weyl character formula. For non-compact groups (with SU(1,1) as an application), convergent condition of the trace is also obtained. This approach may be a powerful tool to study the thermodynamics of quantum (many-body) systems in equilibrium state or …
We postulate a principle stating that the initial condition of a physical system is typically algorithmically independent of the dynamical law. We argue that this links thermodynamics and causal inference. On the one hand, it entails behaviour that is similar to the usual arrow of time. On the other hand, it motivates a statistical asymmetry between cause and effect that has recently postulated in the field of causal inference, namely, that the probability distribution P(cause) contains no information about the conditional distribution P(effect|cause) and vice versa, while P(effect) may contai…
Redfield theory provides a closed kinetic description of a quantum system in weak contact with a very dense reservoir. Landau-Zener theory does the same for a time-dependent driven system in contact with a sparse reservoir. Using a simple model, we analyze the validity of these two theories by comparing their predictions with exact numerical results. We show that despite their a priori different range of validity, these two descriptions can give rise to an identical quantum master equation. Both theories can be used for a nonequilibrium thermodynamic description which we show is consistent wit…
Periodically driven coherent conductors provide a universal platform for the development of quantum transport devices. Here, we lay down a comprehensive theory to describe the thermodynamics of these systems. We first focus on moderate thermo-electrical biases and low driving frequencies. For this linear response regime, we establish generalized Onsager-Casimir relations and an extended fluctuation-dissipation theorem. Furthermore, we derive a family of thermodynamic bounds proving that any local matter or heat current puts a non-trivial lower limit on the overall dissipation rate of a coheren…
We determine the quasistationary distribution of Floquet-state occupation probabilities for a parametrically driven harmonic oscillator coupled to a thermal bath. Since the system exhibits detailed balance, and the canonical representatives of its quasienergies are equidistant, these probabilities are given by a geometrical Boltzmann distribution, but its quasitemperature differs from the actual temperature of the bath, being affected by the functional form of the latter's spectral density. We provide two examples of quasithermal engineering, i.e., of deliberate manipulation of the quasistatio…
In classical Markov jump processes, current fluctuations can only be reduced at the cost of increased dissipation. To explore how quantum effects influence this trade-off, we analyze the uncertainty of steady-state currents in Markovian open quantum systems. We first consider three instructive examples and then systematically minimize the product of uncertainty and entropy production for small open quantum systems. As our main result, we find that the thermodynamic cost of reducing fluctuations can be lowered below the classical bound by coherence. We conjecture that this cost can be made arbi…
It is shown that a macroscopic superposition state of radiation, strongly interacting with an ensemble of two-level atoms, is removed generating a coherent state describing a classical radiation field, when the thermodynamic limit is taken on the unitary evolution obtained by the Schroedinger equation. Decoherence appears as a dynamical effect in agreement with a recent proposal [M. Frasca, Phys. Lett. A 283, 271 (2001)]. To prove that this effect is quite general, we show that this same behavior appears when a superposition of two Fock number states is also considered. Higher order correction…
