Jane S. Greaves, Anita M. S. Richards, William Bains, Paul B. Rimmer, David L. Clements, Sara Seager, Janusz J. Petkowski, Clara Sousa-Silva, Sukrit Ranjan, Helen J. Fraser
备注：
Response to the Matters Arising: "No phosphine in the atmosphere of Venus" by G. Villanueva et al., preprint at arXiv:2010.14305; v2 contains updated values and additional technical details
We first respond to two points raised by Villanueva et al. We show the JCMT discovery spectrum of PH3 can not be re-attributed to SO2, as the line width is larger than observed for SO2 features, and the required abundance would be an extreme outlier. The JCMT spectrum is also consistent with our simple model, constant PH3-abundance with altitude, with no discrepancy in line profile (within data limits); reconciliation with a full photochemical model is the subject of future work. Section 2 presents initial results from re-processed ALMA data. Villanueva et al. noted an issue with bandpass calibration. They have worked on a partially re-processed subset of the ALMA data, so we note where their conclusions, and those of Greaves et al., are now superseded. To summarise: we recover PH3 in Venus' atmosphere with ALMA (~5σ confidence). Localised abundance appears to peak at ~5-10 parts-per-billion (ppb), with suggestions of spatial variation. Advanced data-products suggest a planet-averaged PH3 abundance ~1-4 ppb, lower than from the earlier ALMA processing (which indicated 7+ ppb). The ALMA data are reconcilable with the JCMT detection (~20 ppb) if there is order-of-magnitude temporal variation; more advanced processing of the JCMT data is underway to check methods. Independent PH3 measurements suggest possible altitude dependence (under ~5 ppb at 60+ km, up to ~100 ppb at 50+ km; see Section 2: Conclusions.). Given that both ALMA and JCMT were working at the limit of observatory capabilities, new spectra should be obtained. The ALMA data in-hand are no longer limited by calibration, but spectral ripples still exist, probably due to size and brightness of Venus in relation to the primary beam. Further, spatial ripples are present, potentially reducing significance of real narrow spectral features.
We propose an abiotic geological mechanism that accounts for the abundance of phosphine detected by Greaves et al., 2020. We hypothesize that trace amounts of phosphides formed in the mantle would be brought to the surface by volcanism, and then subsequently ejected into the atmosphere, where they could react with water or sulfuric acid to form phosphine. To investigate the plausibility of this hypothesis, we carry out an order of magnitude calculation. We suggest that active volcanism today could produce a rate comparable to that required to produce the phosphide-source of the phosphine. Our …
Measurements of trace-gases in planetary atmospheres help us explore chemical conditions different to those on Earth. Our nearest neighbor, Venus, has cloud decks that are temperate but hyper-acidic. We report the apparent presence of phosphine (PH3) gas in Venusian atmosphere, where any phosphorus should be in oxidized forms. Single-line millimeter-waveband spectral detections (quality up to ~15 sigma) from the JCMT and ALMA telescopes have no other plausible identification. Atmospheric PH3 at ~20 parts-per-billion abundance is inferred. The presence of phosphine is unexplained after exhausti…
The presence of phosphine (PH$_3$) in the atmosphere of Venus was reported by Greaves et al. (2021a), based on observations of the J=1-0 transition at 267 GHz using ground-based, millimeter-wave spectroscopy. This unexpected discovery presents a challenge for our understanding of Venus's atmosphere, and has led to a reappraisal of the possible sources and sinks of atmospheric phosphorous-bearing gases. Here we present results from a search for PH$_3$ on Venus using the GREAT instrument aboard the SOFIA aircraft, over three flights conducted in November 2021. Multiple PH$_3$ transitions were ta…
The detection of phosphine in the atmosphere of Venus at an abundance of $\sim 20$ ppb suggests that this gas is being generated by either indeterminate abiotic pathways or biological processes. We consider the latter possibility, and explore whether the amount of biomass required to produce the observed flux of phosphine may be reasonable. We estimate that the typical biomass densities predicted by our simple model are potentially orders of magnitude lower than the biomass density of Earth's aerial biosphere in the lower atmosphere. We briefly discuss how small spacecraft could sample the Ven…
In the light of the recent announcement of the discovery of the potential biosignature phosphine in the atmosphere of Venus I present an independent reanalysis of the original JCMT data to assess the statistical reliability of the detection. Two line detection methods are explored, low order polynomial fits and higher order multiple polynomial fits. A non-parametric bootstrap analysis reveals that neither line detection method is able to recover a statistically significant detection. Similar to the results of other reanalyses of ALMA Venus spectra, the polynomial fitting process results in fal…
Context: ALMA observations of Venus at 267 GHz have been presented in the literature that show the apparent presence of phosphine (PH3) in its atmosphere. Phosphine has currently no evident production routes on the planet's surface or in its atmosphere. Aims: The aim of this work is to assess the statistical reliability of the line detection by independent re-analysis of the ALMA data. Methods: The ALMA data were reduced as in the published study, following the provided scripts. First the spectral analysis presented in the study was reproduced and assessed. Subsequently, the spectrum was stati…
The recent candidate detection of ~1 ppb of phosphine in the middle atmosphere of Venus is so unexpected that it requires an exhaustive search for explanations of its origin. Phosphorus-containing species have not been modelled for Venus' atmosphere before and our work represents the first attempt to model phosphorus species in the Venusian atmosphere. We thoroughly explore the potential pathways of formation of phosphine in a Venusian environment, including in the planet's atmosphere, cloud and haze layers, surface, and subsurface. We investigate gas reactions, geochemical reactions, photoche…
We are of the opinion that several anomalies in the atmosphere of Venus provide evidence of yet-unknown processes and systems that are out of equilibrium. The investigation of these anomalies on Venus should be open to the wide range of explanations, including unknown biological activity. We provide an overview of two anomalies, the tentative detection of ammonia and phosphine in Venus's atmosphere. These anomalies fly in the face of the tacit assumption that the atmosphere of Venus must be in chemical redox equilibrium, an assumption connected to the belief that Venus is lifeless. We then dis…
On 14th September 2020, the Royal Astronomical Society made an official statement coupled with a webminar on the discovery of phosphine on Venus. Single-line millimetre-waveband spectral detections of phosphine (with a signal-to-noise ratio of $\approx$ 15$σ$) from the JCMT and ALMA telescopes indicated a phosphine abundance of 20 ppb (parts per billion), 1000 times more than that on the Earth. Phosphine is an important biomarker and immediate speculation in the media about indicators of life being found on Venus followed. This article presents an analysis of the study and the results on the o…
The search for life elsewhere in the universe is one of the central aims of science in the 21st century. While most of this work is aimed at planets orbiting other stars, the search for life in our own Solar System is an important part of this endeavour. Venus is often thought to have too harsh an environment for life, but it may have been a more hospitable place in the distant past. If life evolved there in the past then the cloud decks of Venus are the only remaining niche where life as we know it might survive today. The discovery of the molecule phosphine, PH$_3$, in these clouds has reinv…
The potential detection of ppb levels phosphine (PH3) in the clouds of Venus through millimeter-wavelength astronomical observations is extremely surprising as PH3 is an unexpected component of an oxidized environment of Venus. A thorough analysis of potential sources suggests that no known process in the consensus model of Venus' atmosphere or geology could produce PH3 at anywhere near the observed abundance. Therefore, if the presence of PH3 in Venus' atmosphere is confirmed, it is highly likely to be the result of a process not previously considered plausible for Venusian conditions. The so…
The initial reports of the presence of phosphine in the cloud decks of Venus has led to the suggestion that volcanism was the source of phosphine, through volcanic phosphides ejected into the clouds. Here we examine the idea that mantle plume volcanism, bringing material from the deep mantle to the surface, could generate observed amounts of phosphine through interaction of explosively erupted phosphide with sulfuric acid clouds. Direct eruption of deep mantle phosphide is unphysical, but shallower material could contain traces of phosphide, and could be erupted to the surface. Explosive erupt…
New analysis is presented of the 1.1 mm wavelength absorption lines in Venus' atmosphere that suggested the presence of phosphine. We retrieve a sulphur dioxide observation from the JCMT archive that was simultaneous within a few days of the PH3 1-0 spectrum obtained in June 2017, and demonstrate via a radiative transfer calculation that contamination of PH3 by SO2 was ~10 per cent. We also present ALMA 2019 spectra of PH3 1-0 and an SO2 transition acquired simultaneously, and infer that SO2 line-contamination was ~2 percent (for the least-noisy half of the planetary disc). The contamination-s…
We present a re-examination of mass spectral data obtained from the Pioneer Venus Large Probe Neutral Mass Spectrometer. Our interpretations of differing trace chemical species are suggestive of redox disequilibria in Venus' middle clouds. Assignments to the data (at 51.3 km) include phosphine, hydrogen sulfide, nitrous acid, nitric acid, carbon monoxide, hydrochloric acid, hydrogen cyanide, ethane, and potentially ammonia, chlorous acid, and several tentative PxOy species. All parent ions were predicated upon assignment of corresponding fragmentation products, isotopologues, and atomic specie…
We published spectra of phosphine molecules in Venus' clouds, following open-science principles in releasing data and scripts (with community input leading to ALMA re-processing, now benefiting multiple projects). Some misconceptions about de-trending of spectral baselines have also emerged, which we address here. Using the JCMT PH3-discovery data, we show that mathematically-correct polynomial fitting of periodic ripples does not lead to "fake lines" (probability < ~1%). We then show that the ripples can be characterised in a non-subjective manner via Fourier transforms. A 20 ppb PH3 feature …
Recently published ALMA observations suggest the presence of 20 ppb PH$_3$ in the upper clouds of Venus. This is an unexpected result, as PH$_3$ does not have a readily apparent source and should be rapidly photochemically destroyed according to our current understanding of Venus atmospheric chemistry. While the reported PH$_3$ spectral line at 266.94 GHz is nearly co-located with an SO$_2$ spectral line, the non-detection of stronger SO$_2$ lines in the wideband ALMA data is used to rule out SO$_2$ as the origin of the feature. We present a reassessment of wideband and narrowband datasets der…
The detection of phosphine (PH3) in the atmosphere of Venus has been recently reported based on millimeter-wave radio observations (Greaves et al. 2020), and its re-analyses (Greaves et al. 2021a/b). In this Matters Arising we perform an independent reanalysis, identifying several issues in the interpretation of the spectroscopic data. As a result, we determine sensitive upper-limits for PH3 in Venus' atmosphere (>75 km, above the cloud decks) that are discrepant with the findings in G2020 and G2021a/b. The measurements target the fundamental first rotational transition of PH3 (J=1-0) at 266.9…
We recover PH3 in the atmosphere of Venus in data taken with ALMA, using three different calibration methods. The whole-planet signal is recovered with 5.4σ confidence using Venus bandpass self-calibration, and two simpler approaches are shown to yield example 4.5-4.8σ detections of the equatorial belt. Non-recovery by Villanueva et al. is attributable to (a) including areas of the planet with high spectral-artefacts and (b) retaining all antenna baselines which raises the noise by a factor ~2.5. We release a data-processing script that enables our whole-planet result to be reproduced. The JCM…
Following the announcement of the detection of phosphine (PH$_3$) in the cloud deck of Venus at millimeter wavelengths, we have searched for other possible signatures of this molecule in the infrared range. Since 2012, we have been observing Venus in the thermal infrared at various wavelengths to monitor the behavior of SO$_2$ and H$_2$O at the cloud top. We have identified a spectral interval recorded in March 2015 around 950 cm$^{-1}$ where a PH$_3$ transition is present. From the absence of any feature at this frequency, we derive, on the disk-integrated spectrum, a 3-$σ$ upper limit of 5 p…
The Venusian clouds originate from the binary condensation of H$_{2}$SO$_{4}$ and H$_{2}$O. The two components strongly interact with each other via chemistry and cloud formation. Previous works adopted sophisticated microphysical approaches to understand the clouds. Here we show that the observed vapor and cloud distributions on Venus can be well explained by a semi-analytical model. Our model assumes local thermodynamical equilibrium for water vapor but not for sulfuric acid vapor, and includes the feedback of cloud condensation and acidity to vapor distributions. The model predicts strong s…
Context images for Venus Express radio occultation measurements: A search for a correlation between temperature structure and UV contrasts in the clouds of Venus
We report a model study on the effects of clouds on emission spectra of super-Venus planets. Our goal is to assess possible ways to identify characteristic spectral features due to clouds. We show that it is possible to distinguish an impact of H2SO4 clouds on the CO2 absorption band at 4.8 micron for temperature profiles with and without a thermal inversion. The thermal inversion can help to distinguish the signal from high altitude clouds (85 km, ~1 mbar). Featureless emission spectra are found for high altitude clouds (85 km, ~1 mbar) with temperature profile without thermal inversion. More…
The atmosphere of Venus is characterized by strong superrotation, in which the wind velocities at cloud heights are around 60 times faster than the surface rotation rate. The reasons for this strong superrotation are still not well understood. Motions in the atmosphere below the thick cloud deck are hard to determine remotely and in-situ measurements of the circulation below 40 km altitude are scarce. No model to date has been able to simulate superrotating winds with magnitudes comparable with those measured by entry probes, in the dense atmosphere between the surface and the clouds. However,…
Compared to the diversity seen in exoplanets, Venus is a veritable astrophysical twin of the Earth, however its global cloud layer truncates features in transmission spectroscopy, masking its non-Earth-like nature. Observational indicators that can distinguish an exo-Venus from an exo-Earth must therefore survive above the cloud layer. The above-cloud atmosphere is dominated by photochemistry, which depends on the spectrum of the host star and therefore changes between stellar systems. We explore the systematic changes in photochemistry above the clouds of Venus-like exoplanets orbiting K-Dwar…
Near-term studies of Venus-like atmospheres with JWST promise to advance our knowledge of terrestrial planet evolution. However, the remote study of Venus in the Solar System and the ongoing efforts to characterize gaseous exoplanets both suggest that high altitude aerosols could limit observational studies of lower atmospheres, and potentially make it challenging to recognize exoplanets as "Venus-like". To support practical approaches for exo-Venus characterization with JWST, we use Venus-like atmospheric models with self-consistent cloud formation of the seven TRAPPIST-1 exoplanets to invest…
Solar light gets scattered at cloud top level in Venus' atmosphere, in the visible range, which corresponds to the altitude of 67 km. We present Doppler velocity measurements performed with the high resolution spectrometer MTR of the Solar telescope THEMIS (Teide Observatory, Canary Island) on the sodium D2 solar line (5890 Å). Observations lasted only 49 min because of cloudy weather. However, we could assess the instrumental velocity sensitivity, 31 m/s per pixel of 1 arcsec, and give a value of the amplitude of zonal wind at equator at 151 +/- 16 m/s.
We present the detection and characterisation of mesoscale waves on the lower clouds of Venus using images from the Visible Infrared Thermal Imaging Spectrometer onboard the European Venus Express space mission and from the 2 $μ$m camera (IR2) instrument onboard the Japanese space mission Akatsuki. We used image navigation and processing techniques based on contrast enhancement and geometrical projections to characterise morphological properties of the detected waves, such as horizontal wavelength and the relative optical thickness drop between crests and troughs. Additionally, we performed ph…
One of the striking features about Venus atmosphere is its temporal variability and dynamics, with a chaotic polar vortex, large-scale atmospheric waves, sheared features, and variable winds that depend on local time and possibly orographic features. The aim of this research is to combine data accumulated over several years and obtain a global mean state of the atmosphere focusing in the global structure of the clouds using the cloud opacity and upper cloud temperatures. We have first produced global maps using the integrated radiance through the infrared atmospheric windows centred around 1.7…
Life in the clouds of Venus, if present in sufficiently high abundance, must be affecting the atmospheric chemistry. It has been proposed that abundant Venusian life could obtain energy from its environment using three possible sulfur energy-metabolisms. These metabolisms raise the possibility of Venus's enigmatic cloud-layer SO$_2$-depletion being caused by life. We here couple each proposed energy-metabolism to a photochemical-kinetics code and self-consistently predict the composition of Venus's atmosphere under the scenario that life produces the observed SO$_2$-depletion. Using this photo…
Longwave Infrared Camera (LIR) onboard Akatsuki first revealed the global structure of the thermal tides in the upper cloud layer of Venus. The data were acquired over three Venusian years, and the analysis was done over the areas from the equator to the mid-latitudes in both hemispheres and over the whole local time. Thermal tides at two vertical levels were analyzed by comparing data at two different emission angles. Dynamical wave modes consisting of tides were identified; the diurnal tide consisted mainly of Rossby-wave and gravity-wave modes, while the semidiurnal tide predominantly consi…
The current Venus climate is largely regulated by globally-covered concentrated sulfuric acid clouds from binary condensation of sulfuric acid (H2SO4) and water (H2O). To understand this complicated H2SO4-H2O gas-cloud system, previous theoretical studies either adopted complicated microphysical calculations or assumed that both H2SO4 and H2O vapor follow their saturation vapor pressure. In this study, we developed a simple one-dimensional cloud condensation model including condensation, diffusion and sedimentation of H2SO4 and H2O but without detailed microphysics. Our model is able to explai…
One of the most intriguing, long-standing questions regarding Venus' atmosphere is the origin and distribution of the unknown UV-absorber, responsible for the absorption band detected at the near-UV and blue range of Venus' spectrum. In this work, we use data collected by MASCS spectrograph on board the MESSENGER mission during its second Venus flyby in June 2007 to address this issue. Spectra range from 0.3 μm to 1.5 μm including some gaseous H2O and CO2 bands, as well as part of the SO2 absorption band and the core of the UV absorption. We used the NEMESIS radiative transfer code and retriev…
Altered Cosmic Organics as Venus' Ultraviolet Absorbers
California State Polytechnic University, Pomona（加州州立理工大学波莫纳分校）；Blue Marble Space（蓝色大理石空间研究所）；Arizona State University（亚利桑那州立大学）；NASA Goddard Institute for Space Studies（美国宇航局戈达德太空研究所）；Uppsala University（乌普萨拉大学）；University of Wisconsin, Madison（威斯康星大学麦迪逊分校）
The depletion of SO$_2$ and H$_2$O in and above the clouds of Venus (45 -- 65 km) cannot be explained by known gas-phase chemistry and the observed composition of the atmosphere. We apply a full-atmosphere model of Venus to investigate three potential explanations for the SO$_2$ and H$_2$O depletion: (1) varying the below-cloud water vapor (H$_2$O), (2) varying the below-cloud sulfur dioxide (SO$_2$), and (3) the incorporation of chemical reactions inside the sulfuric acid cloud droplets. We find that increasing the below-cloud H$_2$O to explain the SO$_2$ depletion results in a cloud top that…
Phosphine could be a key molecule in the understanding of exotic chemistry happening in (exo)planetary atmospheres. While it has been detected in the Solar System's giant planets, it has not been observed in exoplanets yet. In the exoplanetary context however it has been theorized as a potential biosignature molecule. The goal of our study is to identify which illustrative science cases for PH3 chemistry are observable with a space-based mid-infrared nulling interferometric observatory like the LIFE (Large Interferometer For Exoplanets) concept. We identified a representative set of scenarios …
An unknown absorber near the cloud top level of Venus generates a broad absorption feature from the ultraviolet (UV) to visible, peaking around 360 nm, and therefore plays a critical role in the solar energy absorption. We present a quantitative study on the variability of the cloud albedo at 365 nm and its impact on Venus' solar heating rates based on an analysis of Venus Express and Akatsuki's UV images, and Hubble Space Telescope and MESSENGER's UV spectral data; in this analysis the calibration correction factor of the UV images of Venus Express (VMC) is updated relative to the Hubble and …
We report Venus image observations around the two maximum elongations of the planet at June and October 2015. From these images we describe the global atmospheric dynamics and cloud morphology in the planet before the arrival of JAXA Akatsuki mission on December the 7th. The majority of the images were acquired at ultraviolet wavelengths (380-410 nm) using small telescopes. The Venus dayside was also observed with narrow band filters at other wavelengths (890 nm, 725-950 nm, 1.435 μm CO2 band) using the instrument PlanetCam-UPV/EHU at the 2.2m telescope in Calar Alto Observatory. In all cases,…
Imaging Venus' surface at night in the near-IR from above its clouds: New analytical models for the effective spatial resolution, illustrated with new Parker Solar Probe data
On the estimation of Sulfuric Acid Vapor concentrations below the Venus cloud deck using the Akatsuki Radio Science Experiment
Space Physics Laboratory, VSSC（空间物理实验室，VSSC）；Research Centre, University of Kerala（喀拉拉大学研究中心）；Graduate School of Frontier Sciences, The University of Tokyo（东京大学前沿科学研究生院）；Faculty of Science, Kyoto Sangyo University（京都产业大学理学部）
The potential detection of phosphine in the atmosphere of Venus has reignited interest in the possibility of life aloft in this environment. If the cloud decks of Venus are indeed an abode of life, it should reside in the "habitable zone" between ~ 50-60 km altitude, roughly coincident with the middle cloud deck, where the temperature and pressure (but not the atmospheric composition) are similar to conditions at the Earth's surface. We map out a precursor astrobiological mission to search for such putative lifeforms in situ with instrument balloons, which could be delivered to Venus via launc…
Venus clouds host a convective layer between roughly 50 and 60 km that mixes heat, momentum, and chemical species. Observations and numerical modelling have helped to understand the complexity of this region. However, the impact on chemistry is still not known. Here, we use for the first time a three-dimensional convection-resolving model with passive tracers to mimic SO$_2$ and H$_2$O for two latitudinal cases. The tracers are relaxed towards a vertical profile in agreement with measured values, with a timescale varying over several orders of magnitude. The vertical mixing is quantified, it i…
Context. Reflected light from a spatially unresolved planet yields unique insight into the overall optical properties of the planet cover. Glories are optical phenomena caused by light that is backscattered within spherical droplets following a narrow distribution of sizes; they are well known on Earth as localised features above liquid clouds. Aims. Here we report the first evidence for a glory in the disk-integrated photometry of Venus and, in turn, of any planet. Methods. We used previously published phase curves of the planet that were reproduced over the full range of phase angles with mo…
The so-called unknown absorber in the clouds of Venus is an important absorber of solar energy, but its vertical distribution remains poorly quantified. We analyze the 283 and 365-nm phase curves of the disk-integrated albedo measured by Akatsuki. Based on our models, we find that the unknown absorber can exist either well-mixed over the entire upper cloud or within a thin layer. The necessary condition to explain the 365-nm phase curve is that the unknown absorber must absorb efficiently within the cloud scale height immediately below the cloud top. Using this constraint, we attempt to extrac…
The upper haze (UH) of Venus is variable on the order of days and it is populated by two particle modes. We use a 1D microphysics and vertical transport model based on the Community Aerosol and Radiation Model for Atmospheres to evaluate whether interaction of upwelled cloud particles and sulfuric acid particles nucleated in situ on meteoric dust are able to generate the two size modes and whether their observed variability are due to cloud top vertical transient winds. Nucleation of photochemically produced sulfuric acid onto polysulfur condensation nuclei generates mode 1 cloud droplets that…
The atmosphere of Venus remains mysterious, with many outstanding chemical connundra. These include: the unexpected presence of ~10 ppm O2 in the cloud layers; an unknown composition of large particles in the lower cloud layers; and hard to explain measured vertical abundance profiles of SO2 and H2O. We propose a new hypothesis for the chemistry in the clouds that largely addresses all of the above anomalies. We include ammonia (NH3), a key component that has been tentatively detected both by the Venera 8 and Pioneer Venus probes. NH3 dissolves in some of the sulfuric acid cloud droplets, effe…
