Jane S. Greaves, Anita M. S. Richards, William Bains, Paul B. Rimmer, David L. Clements, Sara Seager, Janusz J. Petkowski, Clara Sousa-Silva, Sukrit Ranjan, Helen J. Fraser
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Revised and updated re-analysis of the phosphine spectra in Venus' clouds; Submitted to Nature Astronomy "Matters Arising" on Apr/19/2021
We recover PH3 in the atmosphere of Venus in data taken with ALMA, using three different calibration methods. The whole-planet signal is recovered with 5.4σ confidence using Venus bandpass self-calibration, and two simpler approaches are shown to yield example 4.5-4.8σ detections of the equatorial belt. Non-recovery by Villanueva et al. is attributable to (a) including areas of the planet with high spectral-artefacts and (b) retaining all antenna baselines which raises the noise by a factor ~2.5. We release a data-processing script that enables our whole-planet result to be reproduced. The JCMT detection of PH3 remains robust, with the alternative SO2 attribution proposed by Villanueva et al. appearing inconsistent both in line-velocity and with millimetre-wavelength SO2 monitoring. SO2 contamination of the ALMA PH3-line is minimal. Net abundances for PH3, in the gas column above ~55 km, are up to ~20 ppb planet-wide with JCMT, and ~7 ppb with ALMA (but with signal-loss possible on scales approaching planetary size). Derived abundances will differ if PH3 occupies restricted altitudes - molecules in the clouds will contribute significantly less absorption at line-centre than equivalent numbers of mesospheric molecules - but in the latter zone, PH3 lifetime is expected to be short. Given we recover phosphine, we suggest possible solutions (requiring substantial further testing): a small collisional broadening coefficient could give narrow lines from lower altitude, or a high eddy diffusion coefficient could allow molecules to survive longer at higher altitudes. Alternatively, PH3 could be actively produced by an unknown mechanism in the mesosphere, but this would need to be in addition to cloud-level PH3 detected retrospectively by Pioneer-Venus.
The detection of phosphine in the atmosphere of Venus at an abundance of $\sim 20$ ppb suggests that this gas is being generated by either indeterminate abiotic pathways or biological processes. We consider the latter possibility, and explore whether the amount of biomass required to produce the observed flux of phosphine may be reasonable. We estimate that the typical biomass densities predicted by our simple model are potentially orders of magnitude lower than the biomass density of Earth's aerial biosphere in the lower atmosphere. We briefly discuss how small spacecraft could sample the Ven…
In the light of the recent announcement of the discovery of the potential biosignature phosphine in the atmosphere of Venus I present an independent reanalysis of the original JCMT data to assess the statistical reliability of the detection. Two line detection methods are explored, low order polynomial fits and higher order multiple polynomial fits. A non-parametric bootstrap analysis reveals that neither line detection method is able to recover a statistically significant detection. Similar to the results of other reanalyses of ALMA Venus spectra, the polynomial fitting process results in fal…
We are of the opinion that several anomalies in the atmosphere of Venus provide evidence of yet-unknown processes and systems that are out of equilibrium. The investigation of these anomalies on Venus should be open to the wide range of explanations, including unknown biological activity. We provide an overview of two anomalies, the tentative detection of ammonia and phosphine in Venus's atmosphere. These anomalies fly in the face of the tacit assumption that the atmosphere of Venus must be in chemical redox equilibrium, an assumption connected to the belief that Venus is lifeless. We then dis…
The potential detection of ppb levels phosphine (PH3) in the clouds of Venus through millimeter-wavelength astronomical observations is extremely surprising as PH3 is an unexpected component of an oxidized environment of Venus. A thorough analysis of potential sources suggests that no known process in the consensus model of Venus' atmosphere or geology could produce PH3 at anywhere near the observed abundance. Therefore, if the presence of PH3 in Venus' atmosphere is confirmed, it is highly likely to be the result of a process not previously considered plausible for Venusian conditions. The so…
New analysis is presented of the 1.1 mm wavelength absorption lines in Venus' atmosphere that suggested the presence of phosphine. We retrieve a sulphur dioxide observation from the JCMT archive that was simultaneous within a few days of the PH3 1-0 spectrum obtained in June 2017, and demonstrate via a radiative transfer calculation that contamination of PH3 by SO2 was ~10 per cent. We also present ALMA 2019 spectra of PH3 1-0 and an SO2 transition acquired simultaneously, and infer that SO2 line-contamination was ~2 percent (for the least-noisy half of the planetary disc). The contamination-s…
We propose an abiotic geological mechanism that accounts for the abundance of phosphine detected by Greaves et al., 2020. We hypothesize that trace amounts of phosphides formed in the mantle would be brought to the surface by volcanism, and then subsequently ejected into the atmosphere, where they could react with water or sulfuric acid to form phosphine. To investigate the plausibility of this hypothesis, we carry out an order of magnitude calculation. We suggest that active volcanism today could produce a rate comparable to that required to produce the phosphide-source of the phosphine. Our …
We published spectra of phosphine molecules in Venus' clouds, following open-science principles in releasing data and scripts (with community input leading to ALMA re-processing, now benefiting multiple projects). Some misconceptions about de-trending of spectral baselines have also emerged, which we address here. Using the JCMT PH3-discovery data, we show that mathematically-correct polynomial fitting of periodic ripples does not lead to "fake lines" (probability < ~1%). We then show that the ripples can be characterised in a non-subjective manner via Fourier transforms. A 20 ppb PH3 feature …
The recent candidate detection of ~1 ppb of phosphine in the middle atmosphere of Venus is so unexpected that it requires an exhaustive search for explanations of its origin. Phosphorus-containing species have not been modelled for Venus' atmosphere before and our work represents the first attempt to model phosphorus species in the Venusian atmosphere. We thoroughly explore the potential pathways of formation of phosphine in a Venusian environment, including in the planet's atmosphere, cloud and haze layers, surface, and subsurface. We investigate gas reactions, geochemical reactions, photoche…
Measurements of trace-gases in planetary atmospheres help us explore chemical conditions different to those on Earth. Our nearest neighbor, Venus, has cloud decks that are temperate but hyper-acidic. We report the apparent presence of phosphine (PH3) gas in Venusian atmosphere, where any phosphorus should be in oxidized forms. Single-line millimeter-waveband spectral detections (quality up to ~15 sigma) from the JCMT and ALMA telescopes have no other plausible identification. Atmospheric PH3 at ~20 parts-per-billion abundance is inferred. The presence of phosphine is unexplained after exhausti…
Recently published ALMA observations suggest the presence of 20 ppb PH$_3$ in the upper clouds of Venus. This is an unexpected result, as PH$_3$ does not have a readily apparent source and should be rapidly photochemically destroyed according to our current understanding of Venus atmospheric chemistry. While the reported PH$_3$ spectral line at 266.94 GHz is nearly co-located with an SO$_2$ spectral line, the non-detection of stronger SO$_2$ lines in the wideband ALMA data is used to rule out SO$_2$ as the origin of the feature. We present a reassessment of wideband and narrowband datasets der…
The detection of phosphine (PH3) in the atmosphere of Venus has been recently reported based on millimeter-wave radio observations (Greaves et al. 2020), and its re-analyses (Greaves et al. 2021a/b). In this Matters Arising we perform an independent reanalysis, identifying several issues in the interpretation of the spectroscopic data. As a result, we determine sensitive upper-limits for PH3 in Venus' atmosphere (>75 km, above the cloud decks) that are discrepant with the findings in G2020 and G2021a/b. The measurements target the fundamental first rotational transition of PH3 (J=1-0) at 266.9…
The search for life elsewhere in the universe is one of the central aims of science in the 21st century. While most of this work is aimed at planets orbiting other stars, the search for life in our own Solar System is an important part of this endeavour. Venus is often thought to have too harsh an environment for life, but it may have been a more hospitable place in the distant past. If life evolved there in the past then the cloud decks of Venus are the only remaining niche where life as we know it might survive today. The discovery of the molecule phosphine, PH$_3$, in these clouds has reinv…
On 14th September 2020, the Royal Astronomical Society made an official statement coupled with a webminar on the discovery of phosphine on Venus. Single-line millimetre-waveband spectral detections of phosphine (with a signal-to-noise ratio of $\approx$ 15$σ$) from the JCMT and ALMA telescopes indicated a phosphine abundance of 20 ppb (parts per billion), 1000 times more than that on the Earth. Phosphine is an important biomarker and immediate speculation in the media about indicators of life being found on Venus followed. This article presents an analysis of the study and the results on the o…
The presence of phosphine (PH$_3$) in the atmosphere of Venus was reported by Greaves et al. (2021a), based on observations of the J=1-0 transition at 267 GHz using ground-based, millimeter-wave spectroscopy. This unexpected discovery presents a challenge for our understanding of Venus's atmosphere, and has led to a reappraisal of the possible sources and sinks of atmospheric phosphorous-bearing gases. Here we present results from a search for PH$_3$ on Venus using the GREAT instrument aboard the SOFIA aircraft, over three flights conducted in November 2021. Multiple PH$_3$ transitions were ta…
Context: ALMA observations of Venus at 267 GHz have been presented in the literature that show the apparent presence of phosphine (PH3) in its atmosphere. Phosphine has currently no evident production routes on the planet's surface or in its atmosphere. Aims: The aim of this work is to assess the statistical reliability of the line detection by independent re-analysis of the ALMA data. Methods: The ALMA data were reduced as in the published study, following the provided scripts. First the spectral analysis presented in the study was reproduced and assessed. Subsequently, the spectrum was stati…
The initial reports of the presence of phosphine in the cloud decks of Venus has led to the suggestion that volcanism was the source of phosphine, through volcanic phosphides ejected into the clouds. Here we examine the idea that mantle plume volcanism, bringing material from the deep mantle to the surface, could generate observed amounts of phosphine through interaction of explosively erupted phosphide with sulfuric acid clouds. Direct eruption of deep mantle phosphide is unphysical, but shallower material could contain traces of phosphide, and could be erupted to the surface. Explosive erupt…
We present a re-examination of mass spectral data obtained from the Pioneer Venus Large Probe Neutral Mass Spectrometer. Our interpretations of differing trace chemical species are suggestive of redox disequilibria in Venus' middle clouds. Assignments to the data (at 51.3 km) include phosphine, hydrogen sulfide, nitrous acid, nitric acid, carbon monoxide, hydrochloric acid, hydrogen cyanide, ethane, and potentially ammonia, chlorous acid, and several tentative PxOy species. All parent ions were predicated upon assignment of corresponding fragmentation products, isotopologues, and atomic specie…
We first respond to two points raised by Villanueva et al. We show the JCMT discovery spectrum of PH3 can not be re-attributed to SO2, as the line width is larger than observed for SO2 features, and the required abundance would be an extreme outlier. The JCMT spectrum is also consistent with our simple model, constant PH3-abundance with altitude, with no discrepancy in line profile (within data limits); reconciliation with a full photochemical model is the subject of future work. Section 2 presents initial results from re-processed ALMA data. Villanueva et al. noted an issue with bandpass cali…
Recently, phosphine was discovered in the atmosphere of Venus as a potential biosignature. This raises the question: if Venusian life exists, could it be related to terrestrial life? Based on the known rate of meteoroid impacts on Earth, we show that at least $\sim 6 \times 10^5$ asteroids have grazed Earth's atmosphere without being significantly heated and later impacted Venus, and a similar number have grazed Venus's atmosphere and later impacted the Earth, both within a period of $\sim 10^5$ years during which microbes could survive in space. Although the abundance of terrestrial life in t…
Phosphine could be a key molecule in the understanding of exotic chemistry happening in (exo)planetary atmospheres. While it has been detected in the Solar System's giant planets, it has not been observed in exoplanets yet. In the exoplanetary context however it has been theorized as a potential biosignature molecule. The goal of our study is to identify which illustrative science cases for PH3 chemistry are observable with a space-based mid-infrared nulling interferometric observatory like the LIFE (Large Interferometer For Exoplanets) concept. We identified a representative set of scenarios …
Following the announcement of the detection of phosphine (PH$_3$) in the cloud deck of Venus at millimeter wavelengths, we have searched for other possible signatures of this molecule in the infrared range. Since 2012, we have been observing Venus in the thermal infrared at various wavelengths to monitor the behavior of SO$_2$ and H$_2$O at the cloud top. We have identified a spectral interval recorded in March 2015 around 950 cm$^{-1}$ where a PH$_3$ transition is present. From the absence of any feature at this frequency, we derive, on the disk-integrated spectrum, a 3-$σ$ upper limit of 5 p…
The potential detection of phosphine in the atmosphere of Venus has reignited interest in the possibility of life aloft in this environment. If the cloud decks of Venus are indeed an abode of life, it should reside in the "habitable zone" between ~ 50-60 km altitude, roughly coincident with the middle cloud deck, where the temperature and pressure (but not the atmospheric composition) are similar to conditions at the Earth's surface. We map out a precursor astrobiological mission to search for such putative lifeforms in situ with instrument balloons, which could be delivered to Venus via launc…
