Single organic molecules for photonic quantum technologies
C. Toninelli, I. Gerhardt, A. S. Clark, A. Reserbat-Plantey, S. Götzinger, Z. Ristanovic, M. Colautti, P. Lombardi, K. D. Major, I. Deperasińska, W. H. Pernice,… 展开作者
C. Toninelli, I. Gerhardt, A. S. Clark, A. Reserbat-Plantey, S. Götzinger, Z. Ristanovic, M. Colautti, P. Lombardi, K. D. Major, I. Deperasińska, W. H. Pernice, F. H. L. Koppens, B. Kozankiewicz, A. Gourdon, V. Sandoghdar, M. Orrit
Isolating single molecules in the solid state has allowed fundamental experiments in basic and applied sciences. When cooled down to liquid helium temperature, certain molecules show transition lines, that are tens of megahertz wide, limited only by the excited state lifetime. The extreme flexibility in the synthesis of organic materials provides, at low costs, a wide palette of emission wavelengths and supporting matrices for such single chromophores. In the last decades, the controlled coupling to photonic structures has led to an optimized interaction efficiency with light. Molecules can hence be operated as single photon sources and as non-linear elements with competitive performance in terms of coherence, scalability and compatibility with diverse integrated platforms. Moreover, they can be used as transducers for the optical read-out of fields and material properties, with the promise of single-quanta resolution in the sensing of charges and motion. We show that quantum emitters based on single molecules hold promise to play a key role in the development of quantum science and technologies.
Generations of technologies with fundamentally new information processing capabilities will emerge if microscopic physical systems can be controlled to encode, transmit, and process quantum information, at scale and with high fidelity. In the decade after its 2008 inception, the technology of integrated quantum photonics enabled the generation, processing, and detection of quantum states of light, at a steadily increasing scale and level of complexity. Using both established and advanced fabrication techniques, the field progressed from the demonstrations of fixed circuits comprising few compo…
Current proposals for scalable photonic quantum technologies require on-demand sources of indistinguishable single photons with very high efficiency (having unheralded loss below $1\%$). Even with recent progress in the field there is still a significant gap between the requirements and state of the art performance. Here, we propose an on-chip source of multiplexed, heralded photons. Using quantum feedback control on a photon storage cavity with an optimized driving protocol, we estimate an on-demand efficiency of $99\%$ and unheralded loss of order $1\%$, assuming high efficiency detectors an…
Large-scale quantum technologies require exquisite control over many individual quantum systems. Typically, such systems are very sensitive to environmental fluctuations, and diagnosing errors via measurements causes unavoidable perturbations. In this work we present an in situ frequency locking technique that monitors and corrects frequency variations in single photon sources based on microring resonators. By using the same classical laser fields required for photon generation as a probe to diagnose variations in the resonator frequency, our protocol applies feedback control to correct photon…
A major roadblock for large-scale photonic quantum technologies is the lack of practical reliable certification tools. We introduce an experimentally friendly - yet mathematically rigorous - certification test for experimental preparations of arbitrary m-mode pure Gaussian states, pure non-Gaussian states generated by linear-optical circuits with n-boson Fock-basis states as inputs, and states of these two classes subsequently post-selected with local measurements on ancillary modes. The protocol is efficient in m and the inverse post-selection success probability for all Gaussian states and a…
The first quantum technology, which harnesses uniquely quantum mechanical effects for its core operation, has arrived in the form of commercially available quantum key distribution systems that achieve enhanced security by encoding information in photons such that information gained by an eavesdropper can be detected. Anticipated future quantum technologies include large-scale secure networks, enhanced measurement and lithography, and quantum information processors, promising exponentially greater computation power for particular tasks. Photonics is destined for a central role in such technolo…
Single organic molecules offer great promise as bright, reliable sources of identical single photons on demand, capable of integration into solid-state devices. It has been proposed that such molecules in a crystalline organic matrix might be placed close to an optical waveguide for this purpose, but so far there have been no demonstrations of sufficiently thin crystals, with a controlled concentration of suitable dopant molecules. Here we present a method for growing very thin anthracene crystals from super-saturated vapour, which produces crystals of extreme flatness and controlled thickness…
Integrated photonics offers great potential for quantum communication devices in terms of complexity, robustness and scalability. Silicon photonics in particular is a leading platform for quantum photonic technologies, with further benefits of miniaturisation, cost-effective device manufacture and compatibility with CMOS microelectronics. However, effective techniques for high-speed modulation of quantum states in standard silicon photonic platforms have been limited. Here we overcome this limitation and demonstrate high-speed low-error quantum key distribution modulation with silicon photonic…
Exquisite quantum control has now been achieved in small ion traps, in nitrogen-vacancy centres and in superconducting qubit clusters. We can regard such a system as a universal cell with diverse technological uses from communication to large-scale computing, provided that the cell is able to network with others and overcome any noise in the interlinks. Here we show that loss-tolerant entanglement purification makes quantum computing feasible with the noisy and lossy links that are realistic today: With a modestly complex cell design, and using a surface code protocol with a network noise thre…
Deterministic generation of large-scale photonic GHZ states utilizing spin echo in a solid-state quantum light source
The Physics Department and the Solid State Institute, Technion-Israel Institute of Technology（以色列理工学院物理系与固体研究所）；Quantum Science Center of Guangdong-Hong Kong-Macao Greater Bay Area（粤港澳大湾区量子科学中心）；State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics, Sun Yat-sen University（中山大学物理学院光电材料与技术国家重点实验室）；Guangdong Technion-Israel Institute of Technology（广东以色列理工学院）
Optically-addressable solid-state spin defects are promising candidates for storing and manipulating quantum information using their long coherence ground state manifold; individual defects can be entangled using photon-photon interactions, offering a path toward large scale quantum photonic networks. Quantum computing protocols place strict limits on the acceptable photon losses in the system. These low-loss requirements cannot be achieved without photonic engineering, but are attainable if combined with state-of-the-art nanophotonic technologies. However, most materials that host spin defect…
Several emerging quantum technologies, including quantum networks, modular and fusion-based quantum computing, rely crucially on the ability to perform photonic Bell state measurements. Therefore, photon losses and the 50\% success probablity upper bound of Bell state measurements pose a critical limitation to photonic quantum technologies. Here, we develop protocols that overcome these two key challenges through logical encoding of photonic qubits. Our approach uses a tree graph state logical encoding, which can be produced deterministically with a few quantum emitters, and achieves near-dete…
Graph codes play an important role in photonic quantum technologies as they provide significant protection against qubit loss, a dominant noise mechanism. Here, we develop methods to analyse and optimise measurement-based tolerance to qubit loss and computational errors for arbitrary graph codes. Using these tools we identify optimised codes with up to 12 qubits and asymptotically-large modular constructions. The developed methods enable significant benefits for various photonic quantum technologies, as we illustrate with novel all-photonic quantum repeater states for quantum communication and…
Rare-earth ions are promising solid state systems to build light-matter interfaces at the quantum level. This relies on their potential to show narrow optical homogeneous linewidths or, equivalently, long-lived optical quantum states. In this letter, we report on europium molecular crystals that exhibit linewidths in the 10s of kHz range, orders of magnitude narrower than other molecular centers. We harness this property to demonstrate efficient optical spin initialization, coherent storage of light using an atomic frequency comb, and optical control of ion-ion interactions towards implementat…
The modeling of physical processes is an integral part of scientific and technical research. In this area, the Extendible C++ Application in Quantum Technologies (ECAQT) package provides the numerical simulations and modeling of complex quantum systems in the presence of decoherence with wide applications in photonics. It allows creating models of interacting complex systems and simulates their time evolution with a number of available time-evolution drivers. Physical simulations involving massive amounts of calculations are often executed on distributed computing infrastructures. It is often …
Quantum technologies, such as quantum communication, sensing and imaging, need a platform which is flexible, miniaturizable and works at room temperature. Integrated photonics is a promising and fast-developing platform. This requires to develop the right tools to design and fabricate arbitrary photonic quantum devices. Here we present an algorithm which, starting from a $n$-mode transformation $U$, designs a photonic device implementing $U$. Using this method we design integrated photonic devices which implement quantum gates with high fidelity. Apart from quantum computation, future applicat…
Integrated photonics has enabled much progress towards quantum technologies. Many applications, including quantum communication, sensing, and distributed and cloud quantum computing, will require coherent photonic interconnection between separate chip-based sub-systems. Large-scale quantum computing systems and architectures may ultimately require quantum interconnects to enable scaling beyond the limits of a single wafer and towards "multi-chip" systems. However, coherently interconnecting separate chips is challenging due to the fragility of these quantum states and the demanding challenges …
Integrated optical components on lithium niobate play a major role in standard high-speed communication systems. Over the last two decades, after the birth and positioning of quantum information science, lithium niobate waveguide architectures have emerged as one of the key platforms for enabling photonics quantum technologies. Due to mature technological processes for waveguide structure integration, as well as inherent and efficient properties for nonlinear optical effects, lithium niobate devices are nowadays at the heart of many photon-pair or triplet sources, single-photon detectors, cohe…
Scalable photonic quantum technologies are based on multiple nested interferometers. To realize this architecture, integrated optical structures are needed to ensure stable, controllable, and repeatable operation. Here we show a key proof-of-principle demonstration of an externally-controlled photonic quantum circuit based upon UV-written waveguide technology. In particular, we present non-classical interference of photon pairs in a Mach-Zehnder interferometer constructed with X couplers in an integrated optical circuit with a thermo-optic phase shifter in one of the interferometer arms.
Organic microcavities are photonic nanostructures that strongly confine the electromagnetic field, allowing exotic quantum regimes of light-matter interaction with disordered organic semiconductors. The unambiguous interpretation of the spectra of organic microcavities has been a long-standing challenge due to several competing effects involving electrons, vibrations and cavity photons. Here we present a theoretical framework that is able to describe the main spectroscopic features of organic microcavities consistently. We introduce a class of light-matter excitations called dark vibronic pola…
Quantum computers require technologies that offer both sufficient control over coherent quantum phenomena and minimal spurious interactions with the environment. We show, that photons confined to photonic crystals, and in particular to highly efficient waveguides formed from linear chains of defects doped with atoms can generate strong non-linear interactions which allow to implement both single and two qubit quantum gates. The simplicity of the gate switching mechanism, the experimental feasibility of fabricating two dimensional photonic crystal structures and integrability of this device wit…
Integrated quantum photonics devices in diamond have tremendous potential for many quantum applications, including long-distance quantum communication, quantum information processing, and quantum sensing. These devices benefit from diamond's combination of exceptional thermal, optical, and mechanical properties. Its wide electronic bandgap makes diamond an ideal host for a variety of optical active spin qubits that are key building blocks for quantum technologies. In landmark experiments, diamond spin qubits have enabled demonstrations of remote entanglement, memory-enhanced quantum communicat…
Photons for quantum technologies have been identified early on as a very good candidate for carrying quantum information encoded onto them, either by polarization encoding, time encoding or spatial encoding. Quantum cryptography, quantum communications, quantum networks in general and quantum computing are some of the applications targeted by what is now called quantum photonics. Nevertheless, it was pretty clear at an early stage that bulk optics for handling quantum states of light with photons would not be able to deliver what is needed for these technologies. More recently, single photons,…
Recent breakthroughs in solid-state photonic quantum technologies enable generating and detecting single photons with near-unity efficiency as required for a range of photonic quantum technologies. The lack of methods to simultaneously generate and control photons within the same chip, however, has formed a main obstacle to achieving efficient multi-qubit gates and to harness the advantages of chip-scale quantum photonics. Here we propose and demonstrate an integrated voltage-controlled phase shifter based on the electro-optic effect in suspended photonic waveguides with embedded quantum emitt…
Rare-earth ions in crystals are a proven solid-state platform for quantum technologies in the ensemble regime and attractive for new opportunities at the single ion level. Among the trivalent rare earths, ${}^{171}\mathrm{Yb}^{3+}$ is unique in that it possesses a single 4f excited-state manifold and is the only paramagnetic isotope with a nuclear spin of 1/2. In this work, we present measurements of the optical and spin properties of $^{171}$Yb$^{3+}$:YVO$_4$ to assess whether this distinct energy level structure can be harnessed for quantum interfaces. The material was found to possess large…
Single molecules in solid-state matrices have been proposed as sources of single-photon Fock states back 20 years ago. Their success in quantum optics and in many other research fields stems from the simple recipes used in the preparation of samples, with hundreds of nominally identical and isolated molecules. Main challenges as of today for their application in photonic quantum technologies are the optimization of light extraction and the on-demand emission of indistinguishable photons. We here present Hong-Ou-Mandel experiments with photons emitted by a single molecule of dibenzoterrylene in…
Several years ago, it was shown that strong coupling between an electronic transition in organic molecules and a resonant photonic structure can modify the electronic landscape of the molecules and affect their chemical behavior. Since then, this new concept has evolved into a new field known as polaritonic chemistry, which employs strong coupling as a new tool for controlling material properties and molecular chemistry. An important ingredient in the progress of this field was the recent demonstration of strong coupling of molecular vibrations to mid-infrared resonators, which enabled the mod…
Microwave photonics is a remarkably powerful system for quantum simulation and technologies, but its integration in superconducting circuits, superior in many aspects, is constrained by the long wavelengths and impedance mismatches in this platform. We introduce a solution to these difficulties via compact networks of high-kinetic inductance microstrip waveguides and coupling wires with strongly reduced phase velocities. We demonstrate broadband capabilities for superconducting microwave photonics in terms of routing, emulation and generalized linear and nonlinear networks.
The shot-noise spectrum of a quantum dot p-i-n junction embedded inside a three-dimensional photonic crystal is investigated. Radiative decay properties of quantum dot excitons can be obtained from the observation of the current noise. The characteristic of the photonic band gap is revealed in the current noise with discontinuous behavior. Applications of such a device in entanglement generation and emission of single photons are pointed out, and may be achieved with current technologies.
Geometric phases, generated by cyclic evolutions of quantum systems, offer an inspiring playground for advancing fundamental physics and technologies, alike. Intriguingly, the exotic statistics of anyons realised in physical systems can be interpreted as a topological version of geometric phases. However, non-Abelian statistics has not yet been demonstrated in the laboratory. Here we employ an all optical quantum system that simulates the statistical evolution of Majorana fermions. As a result we experimentally realise non-Abelian Berry phases with the topological characteristic that they are …
FPGA Based Feedforward System for Photonic Quantum Computing Applications
Q.ANT GmbH（Q.ANT有限公司）；Center for Macroscopic Quantum States (Big Q), Department of Physics, Technical University of Denmark（丹麦技术大学物理系宏观量子态中心（Big Q））；Ingenieurbüro Filgis（Filgis工程事务所）
We point out that individual organic dye molecules, deposited close to optical waveguides on a photonic chip, can act as single photon sources and can also provide localised, giant optical nonlinearities. This new atom-photon interface may be used as a resource for processing quantum information.
Solid state quantum emitters are between the most promising candidates for single photon generation in quantum technologies. However, they suffer from decoherence effects which limit their efficiency and indistinguishability. For instance, the radiation emitted in the zero phonon line (ZPL) of most color centers is on the order of a few percent (e.g. $NV^-$ centers in Diamond, $V_{Si}V_{C}$ in SiC) limiting the emission rate of single photons as well as the efficiency. At the same time, reliable interfacing with photons in an integrated manner still remains a challenge on both diamond and SiC …
With high integration density and excellent optical properties, silicon photonics is becoming a promising platform for complete integration and large-scale optical quantum information processing. Scalable quantum information applications need photon generation and detection to be integrated on the same chip, and we have seen that various devices on the silicon photonic chip have been developed for this goal. This paper reviews the relevant research results and state-of-the-art technologies on the silicon photonic chip for scalable quantum applications. Despite the shortcomings, properties of s…
Achieving the regime of single-photon nonlinearities in photonic devices just exploiting the intrinsic high-order susceptibilities of conventional materials would open the door to practical semiconductor-based quantum photonic technologies. Here we show that this regime can be achieved in a triply resonant integrated photonic device made of two coupled ring resonators, without necessarily requiring low volume confinement, in a material platform displaying an intrinsic third-order nonlinearity. By strongly driving one of the three resonances of the system, a weak coherent probe at one of the ot…
Donor impurity spins in silicon-28 are highly competitive qubits for upcoming solid-state quantum technologies, yet a proven scalable strategy for multi-qubit devices remains conspicuously absent. These CMOS-compatible, atomically identical qubits offer significant advantages including 3-hour coherence ($T_2$) lifetimes, as well as simultaneous qubit initialization, manipulation and readout fidelities near $\sim\!99.9\%$. These properties meet the requirements for many modern quantum error correction protocols, which are essential for constructing large-scale universal quantum technologies. Ho…
Quantum photonics plays a crucial role in the development of novel communication and sensing technologies. Color centers hosted in silicon carbide and diamond offer single photon emission and long coherence spins that can be scalably implemented in quantum networks. We develop systems that integrate these color centers with photonic devices that modify their emission properties through electromagnetically tailored light and matter interaction.
The recent progress in nanotechnology [1,2] and single-molecule spectroscopy [3-5] paves the way for cost-effective organic quantum optical technologies emergent with a promise to real-life devices operating at ambient conditions. In this letter, we harness $π$-conjugated segments of an organic ladder-type polymer strongly coupled to a microcavity forming correlated collective dressed states of light, so-called of exciton-polariton condensates. We explore an efficient way for all-optical ultra-fast control over the macroscopic condensate wavefunction via a single photon. Obeying Bose statistic…
Low-loss fiber optic links have the potential to connect superconducting quantum processors together over long distances to form large scale quantum networks. A key component of these future networks is a quantum transducer that coherently and bidirectionally converts photons from microwave frequencies to optical frequencies. We present a platform for electro-optic photon conversion based on silicon-organic hybrid photonics. Our device combines high quality factor microwave and optical resonators with an electro-optic polymer cladding to perform microwave-to-optical photon conversion from 6.7 …
Quantum technologies could largely benefit from the control of quantum emitters in sub-micrometric size crystals. These are naturally prone to the integration in hybrid devices, including heterostructures and complex photonic devices. Currently available quantum emitters sculpted in nanocrystals suffer from spectral instability, preventing their use as single photon sources e.g., for most quantum optics operations. In this work we report on unprecedented performances of single-photon emission from organic nanocrystals (average size of hundreds \SI{}{\nano\meter}), made of anthracene (Ac) and d…
