Thioformamide NH2CHS is a sulfur-bearing analog of formamide NH2CHO. The latter was detected in the interstellar medium back in the 1970s. Most of the sulfur-containing molecules detected in the interstellar medium are analogs of corresponding oxygen-containing compounds. Therefore, thioformamide is an interesting candidate for a search in the interstellar medium. The rotational spectrum of thioformamide was measured and analyzed in the frequency range 150 to 660 GHz using the Lille spectrometer. We searched for thioformamide toward the high-mass star-forming region Sagittarius (Sgr) B2(N) using the ReMoCA spectral line survey carried out with the Atacama Large Millimeter/submillimeter Array (ALMA). Accurate rotational constants were obtained from the analysis of the ground state of parent, 34S, 13C, and 15N singly substituted isotopic species of thioformamide. For the parent isotopolog, the lowest two excited vibrational states, v12 = 1 and v9 = 1, were analyzed using a model that takes Coriolis coupling into account. Thioformamide was not detected toward the hot cores Sgr B2(N1S) and Sgr B2(N2). The sensitive upper limits indicate that thioformamide is nearly three orders of magnitude at least less abundant than formamide. This is markedly different from methanethiol, which is only about two orders of magnitude less abundant than methanol in both sources. The different behavior shown by methanethiol versus thioformamide may be caused by the preferential formation of the latter (on grains) at late times and low temperatures, when CS abundances are depressed. This reduces the thioformamide-to-formamide ratio, because the HCS radical is not as readily available under these conditions.
The properties of molecular gas, the fuel that forms stars, inside the cavity of the circumnuclear disk (CND) are not well constrained. We present results of a velocity-resolved submillimeter scan (~480 to 1250 GHz}) and [CII]158um line observations carried out with Herschel/HIFI toward Sgr A*; these results are complemented by a ~2'x2' CO (J=3-2) map taken with the IRAM 30 m telescope at ~7'' resolution. We report the presence of high positive-velocity emission (up to about +300 km/s) detected in the wings of CO J=5-4 to 10-9 lines. This wing component is also seen in H2O (1_{1,0}-1_{0,1}) a …
We present 168 arcmin^2 spectral images of the Sgr B2 complex taken with Herschel/SPIRE-FTS. We detect ubiquitous emission from CO (up to J=12-11), H2O, [CI]492, 809 GHz, and [NII] 205 um lines. We also present maps of the SiO, N2H+, HCN, and HCO+ emission obtained with the IRAM30m telescope. The cloud environment dominates the emitted FIR (80%), H2O 752 GHz (60 %) mid-J CO (91%), and [CI] (93 %) luminosity. The region shows very extended [NII] emission (spatially correlated with the 24 and 70 um dust emission). The observed FIR luminosities imply G_0~10^3. The extended [CI] emission arises fr…
We present and analyze ALMA submillimeter observations from a multi-wavelength campaign of Sgr A* during 18 July 2019. In addition to the submillimeter, we utilize concurrent mid-IR (Spitzer) and X-ray (Chandra) observations. The submillimeter emission lags less than $δt\approx30$ minutes behind the mid-IR data. However, the entire submillimeter flare was not observed, raising the possibility that the time delay is a consequence of incomplete sampling of the light curve. The decay of the submillimeter emission is not consistent with synchrotron cooling. Therefore, we analyze these data adoptin…
The Galactic center black hole candidate Sgr A* is the best target for studies of low-luminosity accretion physics, including with near-infrared and submillimeter wavelength long baseline interferometry experiments. Here we compare images and spectra generated from a parameter survey of general relativistic MHD simulations to a set of radio to near-infrared observations of Sgr A*. Our models span the limits of weak and strong magnetization and use a range of sub-grid prescriptions for electron heating. We find two classes of scenarios can explain the broad shape of the submillimeter spectral p…
Our aim is to characterize the polarized continuum emission properties including intensity, polarization position angle, and polarization percentage of Sgr A* at $\sim$100 (3.0 mm), $\sim$230 (1.3 mm), $\sim$345 (0.87 mm), $\sim$500 (0.6 mm), and $\sim$700 GHz (0.43 mm). We report continuum emission properties of Sgr A* at the above frequency bands, based on the Atacama Large Millimeter Array (ALMA) observations. We measured flux densities of Sgr A* from ALMA single pointing and mosaic observations. We performed sinusoidal fittings to the observed (XX-YY)/I intensity ratios, to derive the pola…
In 2019, Sgr A* - the supermassive black hole in the Galactic Center - underwent unprecedented flaring activity in the near infrared (NIR), brightening by up to a factor of 100 compared to quiescent values. Here we report ALMA observations of Sgr A*'s continuum variability at 1.3 mm (230 GHz) - a tracer of the accretion rate - conducted one month after the brightest detected NIR flare and in the middle of the flaring activity of 2019. We develop an innovative light curve extraction technique which (together with ALMA's excellent sensitivity) allows us to obtain the light curves which are simul…
We have extended the pure rotational investigation of the two isomers syn and anti vinyl mercaptan to the millimeter domain using a frequency-multiplication spectrometer. The species were produced by a radiofrequency discharge in 1,2-ethanedithiol. Additional transitions have been re-measured in the centimeter band using Fourier-transform microwave spectroscopy to better determine rest frequencies of transitions with low-$J$ and low-$K_a$ values. Experimental investigations were supported by quantum chemical calculations on the energetics of both the [C$_2$,H$_4$,S] and [C$_2$,H$_4$,O] isomeri…
A radio source at the Galactic center Sgr A* is a prime supermassive black hole candidate and therefore key to developing our understanding of them. Time variations in the 230 GHz band flux of Sgr A* have been found with the Atacama Large Millimeter/submillimeter Array (ALMA) Cycle 5 observations. Measuring the flux density of Sgr A* in 1 min snapshots at 217.5, 219.5, and 234.0 GHz, we obtained light curves for ten 70 min periods. The light curves show variations at a few tens of minutes and hourly scales. The shorter timescale is similar to the orbital period of the innermost stable circular…
For all the amides detected in the interstellar medium (ISM), the corresponding nitriles or isonitriles have also been detected in the ISM, some of which have relatively high abundances. Among the abundant nitriles for which the corresponding amide has not yet been detected is cyanoacetylene (HCCCN), whose amide counterpart is propiolamide (HCCC(O)NH$_2$). With the aim of supporting searches for this amide in the ISM, we provide a complete rotational study of propiolamide from 6 GHz to 440 GHz using rotational spectroscopic techniques in the frequency and time domain. We identified and measure…
Up to now, mostly relatively simple molecules have been detected in interstellar diffuse molecular clouds in our galaxy, but more complex species have been reported in the diffuse/translucent medium of a z = 0.89 spiral galaxy. We aim at searching for complex organic molecules (COMs) in diffuse molecular clouds along the line of sight to Sgr B2(N), taking advantage of the high sensitivity and angular resolution of the Atacama Large Millimeter/submillimeter Array (ALMA). We use data acquired as part of the EMoCA survey performed with ALMA. To analyse the absorption features of the molecules det…
Short timescale variation in the submillimeter flux of Sagittarius A*
National Astronomical Observatory of Japan（日本国立天文台）；Japan Meteorological Agency（日本气象厅）；Joint ALMA Observatory（ALMA联合 observatory）；The Graduate University for Advanced Studies (SOKENDAI)（高级研究院 (SOKENDAI)）；Meisei University（明海大学）；The University of Tokyo（东京大学）；Keio University（庆应义塾大学）
We report serendipitous detections of line emission with the Atacama Large Millimeter/submillimeter Array (ALMA) in band 3, 6, and 7 in the central parsec down to within 1" around Sgr A* at an up to now highest resolution (<0.5") view of the Galactic Center (GC) in the sub-millimeter (sub-mm) domain. From the 100 GHz continuum and the H39αemission we obtain a uniform electron temperature around 6000 K for the minispiral. The spectral index of Sgr A* is ~ 0.5 at 100 - 250 GHz and ~ 0.0 at 230 - 340 GHz. The bright sources in the center show spectral indices around -0.1 implying Bremsstrahlung e…
VAPOLA - A multiyear, multiband polarization survey of AGNs and Sgr A* at millimeter wavelengths with ALMA II. Spectropolarimetric properties and their evolution from 2017 to 2023
Universidade de São Paulo（圣保罗大学）；INAF – Istituto di Radioastronomia（意大利国家天体物理研究所射电天文研究所）；Università degli Studi di Cagliari（卡利亚里大学）；INFN, Sezione di Cagliari（意大利国家核物理研究所卡利亚里分部）；University of Balearic Islands（巴利阿里群岛大学）；Institute of the Balearic Islands (IAIB)（巴利阿里群岛研究所）；Health Research Institute of the Balearic Islands (IdISBa)（巴利阿里群岛健康研究所）；Max-P（马克斯·普朗克）
Methyl mercaptan (CH$_3$SH) is an important sulfur-bearing species in the interstellar medium, terrestrial environment, and potentially in planetary atmospheres. The aim of the present study is to provide accurate spectroscopic parameters for the most abundant minor isotopolog CH$_3$$^{34}$SH to support radio astronomical observations at millimeter and submillimeter wavelengths. The rotational spectrum of CH$_3$$^{34}$SH, which is complicated by the large-amplitude internal rotation of the CH$_3$ group versus the $^{34}$SH frame, was investigated in the 49$-$510 GHz and 1.1$-$1.5 THz frequency…
We report on the first pulsar and transient survey of the Galactic Center (GC) with the Atacama Large Millimeter/submillimeter Array (ALMA). The observations were conducted during the Global Millimeter VLBI Array campaign in 2017 and 2018. We carry out searches using timeseries of both total intensity and other polarization components in the form of Stokes parameters. We incorporate acceleration and its derivative in the pulsar search, and also search in segments of the entire observation to compensate for potential orbital motion of the pulsar. While no new pulsar is found, our observations y…
VAPOLA -- A multi-year, multi-band polarization survey of AGN and Sgr A* at mm wavelengths with ALMA I. Survey Overview and Science-Ready Archival Products
Università degli Studi di Cagliari（卡利亚里大学）；INAF - Osservatorio Astronomico di Cagliari（意大利国家天体物理研究所卡利亚里天文台）；University of Balearic Islands（巴利阿里群岛大学）；Institute of the Balearic Islands (IAIB)（巴利阿里群岛研究所）；Health Research Institute of the Balearic Islands (IdISBa)（巴利阿里群岛健康研究所）；Universidade São Paulo, Instituto de Astronomia, Geofísica e Ciéencias Atmosféricas（圣保罗大学天文、地球物理与大气科学研究所）；INAF-Istituto di Radioastronomia（意大利国家天体物理研究所射电天文学研究所）；INAF–Italian Centre for Astronomical Archive（意大利天体物理研究所意大利天文档案中心）
In recent times, large organic molecules of exceptional complexity have been found in diverse regions of the interstellar medium. In this context, we aim to provide accurate frequencies of the ground vibrational state of two key aliphatic aldehydes, n-butanal and its branched-chain isomer, i-butanal, to enable their eventual detection in the interstellar medium. We employ a frequency modulation millimeter-wave absorption spectrometer to measure the rotational features of n- and i-butanal. We use the spectral line survey ReMoCA performed with the Atacama Large Millimeter/submillimeter Array to …
The molecule studied in this work, 2-hydroxyprop-2-enal, is among the candidates to be searched for in the interstellar medium (ISM), as it is a dehydration product of C3 sugars and contains structural motifs typical for some interstellar molecules. The aim of this work is to deepen knowledge about the millimetre-wave spectrum of 2-hydroxyprop-2-enal in the region enabling its search towards astronomical objects. We target the solar-type protostar IRAS16293-2422 and star-forming region Sagittarius (Sgr) B2(N). The rotational spectrum of 2-hydroxyprop-2-enal was measured and analysed in the fre…
Up to date, only 6 imines have been detected in the interstellar medium. The 3-carbon imine, 2-propanimine ((CH$_3$)$_2$C=NH), is predicted to be the structural isomer with the lowest energy in the C$_3$H$_7$N group, and appears to be a good candidate for astronomical searches. Unexpectedly, no microwave or millimeter wave spectrum is available for 2-propanimine. In this work, we provide the first high resolution millimeter wave spectrum of 2-propanimine and its analysis. With the guide of this laboratory measurement, we aim to search for 2-propanimine in two molecule-rich sources Sgr B2(N) an…
