We theoretically describe a thermoelectric effect that is entirely due to Andreev processes involving the formation of Cooper pairs through the coupling of electrons and holes. The Andreev thermoelectric effect can occur in ballistic ferromagnet-superconductor junctions with a dominant superconducting proximity effect on the ferromagnet, and it is very sensitive to surface states emerging in unconventional superconductors. We consider hybrid junctions in two and three dimensions to demonstrate that the thermoelectric current is always reversed in the presence of low-energy Andreev bound states at the superconductor surface. A microscopic analysis of the proximity-induced pairing reveals that the thermoelectric effect only arises if even and odd-frequency Cooper pairs coexist in mixed singlet and triplet states. Our results are an example of the richness of emergent phenomena in systems that combine magnetism and superconductivity, and they open a pathway for exploring exotic surface states in unconventional superconductors.
Superconductors with unconventional pairings have been a fascinating subject of research, for which a central issue is to explore effects that can be used to characterize the pairing. The process of Andreev reflection--the reflection of an electron as a hole at a normal-mental-superconductor interface by transferring a Cooper pair into the superconductor--offers a basic mechanism to probe the pairing through transport. Here we predict that in Andreev reflection from unconventional superconductors, the reflected hole acquires an anomalous spatial shift normal to the plane of incidence, arising …
We develop a detailed theory describing a non-trivial interplay between non-equilibrium effects and long-range quantum coherence in superconducting hybrid nanostructures exposed to a temperature gradient. We establish a direct relation between thermoelectric and Josephson effects in such structures and demonstrate that at temperatures exceeding the Thouless energy of our device both phase-coherent thermoelectric signal and the supercurrent may be strongly enhanced due to non-equilibrium low energy quasiparticles propagating across the system without any significant phase relaxation. By applyin…
Employing quasiclassical theory of superconductivity combined with Keldysh technique we investigate large thermoelectric effect in multiterminal ballistic normal-superconducting (NS) hybrid structures. We argue that this effect is caused by electron-hole asymmetry generated by coherent Andreev reflection of quasiparticles at interfaces of two different superconductors with non-zero phase difference. Within our model we derive a general expression for thermoelectric voltages $V_{T1,2}$ induced in two different normal terminals exposed to a thermal gradient. Our results apply at any temperature …
We discuss the nonlinear Andreev current of an interacting quantum dot coupled to spin-polarized and superconducting reservoirs when voltage and temperature biases are applied across the nanostructure. Due to the particle-hole symmetry introduced by the superconducting (S) lead, the subgap spin current vanishes identically. Nevertheless, the Andreev charge current depends on the degree of polarization in the ferromagnetic (F) contact since the shift of electrostatic internal potential of the conductor depends on spin orientation of the charge carrier. This spin-dependent potential shift charac…
Superconducting spintronics is based on the creation of spin-triplet Cooper pairs in ferromagnet-superconductor (F-S) hybrid junctions. Previous proposals to manipulate spin-polarized supercurrents on-demand typically require the ability to carefully control magnetic materials. We, instead, propose a quantum heat engine that generates equal-spin Cooper pairs and drives supercurrents on-demand without manipulating magnetic components. We consider a S-F-S junction, connecting two leads at different temperatures, on top of the helical edge of a two-dimensional topological insulator. Heat and char…
We investigate the effects of Andreev bound states due to the unconventional pairing on the inverse proximity effect of ferromagnet/superconductor junctions. Utilizing quasiclassical Eilenberger theory, we obtain the magnetization penetrating into the superconductor. We show that in a wide parameter range the direction of the induced magnetization is determined by two factors: whether Andreev bound states are present at the junction interface and the sign of the spin-mixing angle. In particular, when Andreev bound states appear at the interface, the direction of the induced magnetization is op…
In noncentrosymmetric superconductors (NCSs), the conversion of a charge current into spin magnetization - the so called magnetoelectric effect - is the direct indicator of the unconventional, mixed-parity order parameter. This paper proposes a scheme to detect the magnetoelectric effect by anomalous, equal-spin Andreev tunneling in NCS/ferromagnet contacts. The proposal relies on the ability to generate spin-polarized triplet pairing by passing an electric current through an NCS. Such an induced triplet pairing bears a similarity to the paradigmatic nonunitary pairing in triplet superfluids w…
We review some recent advances in studies of phase-coherent thermoelectric effects in superconducting hybrid structures such as, e.g., Andreev interferometers. We elucidate a number of mechanisms of electron-hole symmetry breaking in such systems causing dramatic enhancement of thermoelectric effects. We demonstrate that the flux-dependent thermopower exhibits periodic dependence on the applied magnetic flux $Φ_x$ which in some limits may reduce to either odd or even functions of $Φ_x$ in accordance with experimental observations. We also show that dc Josephson current in Andreev interferomete…
We demonstrate that superconductors which break time-reversal symmetry can exhibit thermoelectric properties, which are entirely different from the Ginzburg mechanism. As an example, we show that in the $s+is$ superconducting state there is a reversible contribution to thermally induced supercurrent, whose direction is not invariant under time-reversal operation. Moreover in contrast to Ginzburg's mechanism it has a singular behavior near the time-reversal symmetry breaking phase transition. The effect can be used to confirm or rule out the $s+is$ state, which is widely expected to be realized…
In an unconventional superconductor, the interplay of scattering off impurities and Andreev processes may lead to different scattering times for electronlike and holelike quasiparticles. Such electron-hole asymmetry appears when the impurity scattering phase shift is intermediate between the Born and unitary limits and leads to an expectation for large thermoelectric effects. Here, we examine the thermoelectric response of a $d$-wave superconductor connected to normal-metal reservoirs under a temperature bias using a fully self-consistent quasiclassical theory. The thermoelectrically induced q…
We discuss the nonlinear current of an interacting quantum dot coupled to normal and superconducting reservoirs with applied voltage and temperature differences. Due to the particle-hole symmetry introduced by the superconducting lead, the pure (subgap) thermoelectric response vanishes. However, we show that the Andreev bound states shift as the thermal gradient increases. As a consequence, the $I$--$V$ characteristic can be tuned with a temperature bias if the system is simultaneously voltage biased. This is a cross effect that occurs beyond linear response only. Furthermore, we emphasize the…
The order parameter of bulk two-dimensional superconductors is classified as nodal, if it vanishes for a direction in momentum space, or gapful if it does not. Each class can be topologically nontrivial if Andreev bound states are formed at the edges of the superconductor. Non-magnetic impurities in the superconductor affect the formation of Andreev bound states and can drastically change the tunneling spectra for small voltages. Here, we investigate the mean current and its fluctuations for two-dimensional tunnel junctions between a normal-metal and unconventional superconductors by solving t…
Many of the properties of superconductors related to quantum coherence are revealed when the superconducting state is forced to vary in space - in response to an external magnetic field, a proximity contact, an interface to a ferromagnet, or to impurities embedded in the superconductor. Among the earliest examples is Andreev reflection of an electron into a retro-reflected hole at a normal-superconducting interface. In regions of strong inhomogeneity multiple Andreev reflection leads to the formation of sub-gap states, Andreev bound states, with excitation energies below the superconducting ga…
The formation of electron pairs is a prerequisite of superconductivity. The fermionic nature of electrons yields four classes of superconducting correlations with definite symmetry in spin, space and time. Here, we suggest double quantum dots coupled to conventional s-wave superconductors in the presence of inhomogeneous magnetic fields as a model system exhibiting unconventional pairing. Due to their small number of degrees of freedom, tunable by gate voltages, quantum-dot systems provide an ideal tool to gain fundamental insight in unconventional pairing. We propose two detection schemes for…
We study the surface Andreev bound states (SABSs) and quasiparticle tunneling spectroscopy of three-dimensional (3D) chiral superconductor by changing the surface (interface) misorientation angle of chiral superconductors. We obtain analytical formula of the energy dispersion of SABS for general pair potential when an original 4$\times$4 BdG Hamiltonian can be reduced to be two 2$\times$2 blocks. The resulting SABS for 3D chiral superconductors with pair potential given by $k_z(k_x + ik_y)^ν$ $(ν = 1, 2)$ has a complicated energy dispersion due to the coexistence of both point and line nodes. …
A detailed investigation of the non-equilibrium steady-state electric and thermoelectric transport properties of a quantum dot coupled to the normal metallic and s-wave superconducting reservoirs (N-QD-S) are provided within the Coulomb blockade regime. Using non-equilibrium Keldysh Green's function formalism, initially, various model parameter dependence of thermoelectric transport properties are analysed within the linear response regime. It is observed that the single-particle tunnelling close to the superconducting gap edge can generate a relatively large thermopower and figure of merit. M…
We investigate the nonlocal thermoelectric transport in a Cooper-pair splitter based on a double-quantum-dot-superconductor three-terminal hybrid structure. We find that the nonlocal coupling between the superconductor and the quantum dots gives rise to nonlocal thermoelectric effects which originate from the nonlocal particle-hole breaking of the system. We show that Cooper-pair splitting induces the generation of a thermo-current in the superconducting lead without any transfer of charge between the two normal metal leads. Conversely, we show that a nonlocal heat exchange between the normal …
Tunneling across superconducting junctions proceeds by a rich variety of processes, which transfer single electrons, Cooper pairs, or even larger numbers of electrons by multiple Andreev reflections. Photon-assisted tunneling combined with the venerable Tien-Gordon model has long been a powerful tool to identify tunneling processes between superconductors. Here, we probe superconducting tunnel junctions including an impurity-induced Yu-Shiba-Rusinov (YSR) state by exposing a scanning tunneling microscope with a superconducting tip to microwave radiation. We find that a simple Tien-Gordon descr…
Non-centrosymmetric superconductors exhibit the magnetoelectric effect which manifests itself in the appearance of the magnetic spin polarization in response to a dissipationless electric current (supercurrent). While much attention has been dedicated to the thermodynamic version of this phenomenon (Edelstein effect), non-equilibrium transport magnetoelectric effects have not been explored yet. We propose the magnetoelectric Andreev effect (MAE) which consists in the generation of spin-polarized triplet Andreev conductance by an electric supercurrent. The MAE stems from the spin polarization o…
We study unconventional superconductivity in thin exfoliated single crystals of a promising 3D topological superconductor candidate, Nb-doped Bi$_2$Se$_3$ through Andreev reflection spectroscopy and magneto-transport. Measurements of Andreev reflection in low and high resistance samples both show enhanced conductance around zero bias and conductance dips at the superconducting energy gap. Such behavior is inconsistent with conventional Blonder-Tinkham-Klapwijk theory of Andreev reflection. We discuss how our results are consistent with $p$-wave pairing symmetry, supporting the possibility of t…
We study a singlet-triplet Josephson junction between a conventional s-wave superconductor and an unconventional p$_{\rm x}$-wave superconductor. The Andreev spectrum of the junction yields a spontaneous magnetization in equilibrium. This allows manipulating the occupation of the Andreev levels using an ac Zeeman field. The induced Rabi oscillations manifest themselves as a resonance in the current-phase relation. For a circularly polarized magnetic field, we find a spin selection rule, yielding Rabi oscillations only in a certain interval of the superconducting phase difference.
The two-dimensional nature of graphene makes it an ideal platform to explore proximity-induced unconventional planar superconductivity and the possibility of topological superconductivity. Using Green's functions techniques, we study the transport properties of a finite size ballistic graphene layer placed between a normal state electrode and a graphene lead with proximity-induced unconventional superconductivity. Our microscopic description of such a junction allows us to consider the effect of edge states in the graphene layer and the imperfect coupling to the electrodes. The tunnel conducta…
Quasiparticle excitations provide viable information on the physics of unconventional superconductors. Higgs and Leggett modes are some of the classic examples. Another important bosonic excitation is the spin exciton originating from the sign-changing superconducting gap structure. Here we report a direct observation of the temperature-dependent spin exciton in the Andreev spectra of iron-based superconductors. Combined with the other experimental evidence, our observation confirms the extended $s$-wave ($s_\pm$) order parameter symmetry and indirectly proves the spin-fluctuation mechanism of…
We present a theory of superconductivity in magic-angle twisted bilayer graphene and analyze the superconducting phase diagram in presence of the magnetic field. Namely, we consider a model of a granular array hosting localized states, which are hybridized via the delocalized fermions in the inter-grain regions. We study a strong coupling situation when the interactions lead to an incoherent state with preformed Cooper pairs inside the grains. The Andreev scattering among different grains manifests itself through the global phase-coherent superconducting state at lower temperatures. We demonst…
Herewith, we review the available experimental data of thermoelectric transport properties of iron-based superconductors and parent compounds. We discuss possible physical mechanisms into play in determining the Seebeck effect, from whence one can extract information about Fermi surface reconstruction and Lifshitz transitions, multiband character, coupling of charge carriers with spin excitations and its relevance in the unconventional superconducting pairing mechanism, nematicity, quantum critical fluctuations close to the optimal doping for superconductivity, correlation. Additional informat…
A Strongly Anisotropic Superconducting Gap in the Kagome Superconductor CsV$_3$Sb$_5$: A Study of Directional Point-Contact Andreev Reflection Spectroscopy
We study the influence of non-magnetic impurity scatterings on the tunneling conductance of a junction consisting of a normal metal and a disordered unconventional superconductor by solving the quasiclassical Eilenberger equation self-consistently. We find that the impurity scatterings in both the Born and unitary limits affect the formation of the Andreev bound states and modify strongly the tunneling spectra around zero bias. Our results are interpreted well by the appearance of odd-frequency Cooper pairs near the interface and by the divergent behavior of the impurity self-energy. The prese…
