The bond-dependent Kitaev model on the honeycomb lattice with anyonic excitations has recently attracted considerable attention. However, in solid state materials other spin interactions are present, and among such additional interactions, the off-diagonal symmetric Gamma interaction, another type of bond-dependent term, has been particularly challenging to fully understand. A minimal Kitaev-Gamma (KG) model has been investigated by various numerical techniques under a magnetic field, but definite conclusions about field-induced spin liquids remain elusive and one reason may lie in the limited sizes of the two-dimensional geometry it is possible to access numerically. We therefore focus on the KG model defined on a two-leg ladder which is much more amenable to a complete study, and determine the entire phase diagram in the presence of a magnetic field along [111]-direction. Due to the competition between the interactions and the field, an extremely rich phase diagram emerges with fifteen distinct phases. Focusing near the antiferromagnetic Kitaev region, we identify nine different phases solely within this region: several incommensurate magnetically ordered phases, spin nematic, and two chiral phases with enhanced entanglement. Of particular interest is a highly entangled phase with staggered chirality with zero-net flux occurring at intermediate field, which along with its companion phases outline a heart-shaped region of high entanglement, the heart of entanglement. We compare our results for the ladder with a C3 symmetric cluster of the two-dimensional honeycomb lattice, and offer insights into possible spin liquids in the two-dimensional limit.
Materials that realize Kitaev spin models with bond-dependent anisotropic interactions have long been searched for, as the resulting frustration effects are predicted to stabilize novel forms of magnetic order or quantum spin liquids. Here we explore the magnetism of $γ$-Li$_2$IrO$_3$, which has the topology of a 3D Kitaev lattice of inter-connected Ir honeycombs. Using resonant magnetic x-ray diffraction we find a complex, yet highly-symmetric incommensurate magnetic structure with non-coplanar and counter-rotating Ir moments. We propose a minimal Kitaev-Heisenberg Hamiltonian that naturally …
We present a theoretical study of field-induced magnetic phases in the honeycomb Kitaev-Heisenberg model, which is believed to describe the essential physics of Mott insulators with strong spin-orbit coupling such as $A_2$IrO$_3$ and $α$-RuCl$_3$. We obtain a finite temperature phase diagram based on extensive Monte Carlo simulations and analytical calculations. We show that, while Zeeman coupling favors a symmetric non-coplanar magnetic order, thermal fluctuations enhances the stability of a collinear zigzag phase that breaks the rotational symmetry of the lattice. Our large-scale simulations…
The theoretical inception of the Kitaev honeycomb model has had defining influence on the experimental hunt for quantum spin liquids, bringing unprecedented focus onto the synthesis of materials with bond-directional interactions. Numerous Kitaev materials, which are believed to harbor ground states parametrically close to the Kitaev spin liquid, have been investigated since. Yet, in these materials the Kitaev interaction often comes hand in hand with off-diagonal $Γ$ interactions -- with the competition of the two potentially giving rise to a magnetically ordered ground state. In an attempt t…
We analyze effective d-wave interactions in the two-dimensional extended Hubbard model at weak coupling and small to moderate doping. The interactions are computed from a renormalization group flow. Attractive d-wave interactions are generated via antiferromagnetic spin fluctuations in the pairing and charge channels. Above Van Hove filling, the d-wave charge interaction is maximal at incommensurate diagonal wave vectors, corresponding to nematic fluctuations with a diagonal modulation. Below Van Hove filling a modulation along the crystal axes can be favored. The nematic fluctuations are enha…
We present a theoretical study of the response of $β$-$\text{Li}_2\text{IrO}_3$ under external magnetic fields in the $ab$, $bc$ and $ac$ crystallographic planes. The results are based on the minimal nearest-neighbor $J$-$K$-$Γ$ model and reveal a rich intertwining of field-induced phases and magnetic phase transitions with distinctive signatures that can be probed directly via torque magnetometry. Most saliently, we observe: i) an unusual reentrance of the incommensurate counter-rotating order for fields in the $ab$-plane, and ii) a set of abrupt torque discontinuities which are particularly …
To assess the strength of nematic fluctuations with a finite wave vector in a two-dimensional metal, we compute the static d-wave polarization function for tight-binding electrons on a square lattice. At Van Hove filling and zero temperature the function diverges logarithmically at q=0. Away from Van Hove filling the ground state polarization function exhibits finite peaks at finite wave vectors. A nematic instability driven by a sufficiently strong attraction in the d-wave charge channel thus leads naturally to a spatially modulated nematic state, with a modulation vector that increases in le…
The layered honeycomb magnet $α$-Li$_2$IrO$_3$ has been theoretically proposed as a candidate to display novel magnetic behaviour associated with Kitaev interactions between spin-orbit entangled $j_{\rm eff}=1/2$ magnetic moments on a honeycomb lattice. Here we report single crystal magnetic resonant x-ray diffraction combined with powder magnetic neutron diffraction to reveal an incommensurate magnetic order in the honeycomb layers with Ir magnetic moments counter-rotating on nearest-neighbour sites. This type of magnetic structure has not been reported experimentally before in honeycomb magn…
Spin liquid crystals are magnetic analogs of liquid crystals, possessing properties of both liquids and solids, a typical example of which are spin nematics. Spin nematics share many features with spin liquids, and the interplay between them is a promising, but little explored, route to uncovering new phases of matter. Here, we address this question in the context of a spin-$1$ magnet on the honeycomb lattice, by considering a model with both biquadratic interactions, favouring spin-nematic states, and Kitaev-like interactions, supporting spin liquids. Accompanying these, where dipole and quad…
The appearance of nontrivial phases in Kitaev materials exposed to an external magnetic field has recently been a subject of intensive studies. Here, we elucidate the relation between the field-induced ground states of the classical and quantum spin models proposed for such materials, by using the infinite density matrix renormalization group (iDMRG) and the linear spin wave theory (LSWT). We consider the $K ΓΓ'$ model, where $Γ$ and $Γ'$ are off-diagonal spin exchanges on top of the dominant Kitaev interaction $K$. Focusing on the magnetic field along the $[111]$ direction, we explain the ori…
Recent scattering experiments in the 3D Kitaev magnet $β$-Li$_2$IrO$_3$ have shown that a relatively weak magnetic field along the crystallographic ${\bf b}$-axis drives the system from its incommensurate counter-rotating order to a correlated paramagnet, with a significant uniform `zigzag' component superimposing the magnetization along the field. Here it is shown that the zigzag order is not emerging from its linear coupling to the field (via a staggered, off-diagonal element of the ${\bf g}$-tensor), but from its intertwining with the incommensurate order and the longitudinal magnetization.…
Motivated by growing indications for a distinct form of nematic correlations in the extremely hole doped iron pnictide compounds $A$Fe$_2$As$_2$ ($A$=K,Rb,Cs), we consider spin-driven nematic order in the general case of incommensurate magnetic fluctuations. We classify the nematic order parameters by broken mirror symmetries of the tetragonal $D_{4h}$ point group, and use this scheme to construct a general Ginzburg-Landau theory that links the nematic order to spatial pattern of magnetic fluctuations. Our analysis points to incommensurate magnetic fluctuations of wavevector $(q,q)$ as underly…
We propose a scenario of realizing the toric code phase, which can be potentially utilized for fault-tolerant quantum computation, in candidate materials of Kitaev magnets. It is demonstrated that four-body interactions among Majorana fermions in the Kitaev spin liquid state, which are induced by applied magnetic fields as well as non-Kitaev-type exchange interactions, trigger a nematic phase transition of Majorana bonds without magnetic orders, accompanying the change of the Chern number from $\pm 1$ to zero. This gapful spin liquid state with zero Chern number is nothing but the toric code p…
Recent discoveries of charge order and electronic nematic order in the iron-based superconductors and cuprates have pointed towards the possibility of nematic and charge fluctuations playing a role in the enhancement of superconductivity. The Ba1-xSrxNi2As2 system, closely related in structure to the BaFe2As2 system, has recently been shown to exhibit both types of ordering without the presence of any magnetic order. We report single crystal X-ray diffraction, resistance transport measurements, and magnetization of \BaSrLate, providing evidence that the previously reported incommensurate charg…
Incommensurate spiral order is a common occurrence in frustrated magnetic insulators. Typically, all magnetic moments rotate uniformly, through the same wavevector. However the honeycomb iridates family Li2IrO3 shows an incommensurate order where spirals on neighboring sublattices are counter-rotating, giving each moment a different local environment. Theoretically describing its spin dynamics has remained a challenge: the Kitaev interactions proposed to stabilize this state, which arise from strong spin-orbit effects, induce magnon umklapp scattering processes in spin-wave theory. Here we pro…
The layered honeycomb iridate $α$-Li$_2$IrO$_3$ displays an incommensurate magnetic structure with counterrotating moments on nearest-neighbor sites, proposed to be stabilized by strongly-frustrated anisotropic Kitaev interactions between spin-orbit entangled Ir$^{4+}$ magnetic moments. Here we report powder inelastic neutron scattering measurements that observe sharply dispersive low-energy magnetic excitations centered at the magnetic ordering wavevector, attributed to Goldstone excitations of the incommensurate order, as well as an additional intense mode above a gap $Δ\simeq2.3$ meV. Zero-…
Nematic phase transitions in high-temperature superconductors have a strong impact on the electronic properties of these systems. BaFe$_2$As$_2$,\@ with an established nematic transition around 137 K induced by magnetic fluctuations, and BaNi$_2$As$_2$,\@ a non-magnetic analog of BaFe$_2$As$_2$ with a structural transition in the same temperature range,\@ share a common tetragonal aristotype crystal structure with space-group type $I4/mmm$.\@ In contrast to BaFe$_2$As$_2$ where collinear stripe magnetic order is found for the orthorhombic low-$T$ phase, a unidirectional charge density wave tog…
The Kitaev model is a remarkable spin model with gapped and gapless spin liquid phases, which are potentially realized in iridates and $α$-RuCl$_3$. In the recent experiment of $α$-RuCl$_3$, the signature of a nematic transition to the gapped toric code phase, which breaks the $C_3$ symmetry of the system, has been observed through the angle dependence of the heat capacity. We here propose a mechanism by which the nematic transition can be detected electrically. This is seemingly impossible because $J_\textrm{eff}=1/2$ spins do not have an electric quadrupole moment (EQM). However, in the seco…
We study bond energy correlation functions in an exactly solvable quantum spin model of Kitaev type on the kagome lattice with stable Fermi surface of partons proposed recently by Chua et al, Ref.\[arXiv:1010.1035]. Even though any spin correlations are ultra-short ranged, we find that the bond energy correlations have power law behavior with a $1/|{\bm r}|^3$ envelope and oscillations at incommensurate wavevectors. We determine the corresponding singular surfaces in momentum space, which provide a gauge-invariant characterization of this gapless spin liquid.
We study classical two-dimensional frustrated Heisenberg models with generically incommensurate groundstates. A new theory for the spin-nematic "order by disorder" transition is developed based on the self-consistent determination of the effective exchange coupling bonds. In our approach, fluctuations of the constraint field imposing conservation of the local magnetic moment drive nematicity at low temperatures. The critical temperature is found to be highly sensitive to the peak helimagnetic wavevector, and vanishes continuously when approaching rotation symmetric Lifshitz points. Transitions…
We revisit the problem of electrons on a square lattice below half filling close to an Ising-nematic quantum critical point. For Fermi surfaces with sufficiently strong antinodal nesting, the static nematic susceptibility is maximal at the antinodal nesting wave vector within a simple RPA calculation. We present a detailed analysis of the nematic susceptibility within Eliashberg theory and show that the strong interaction between Fermions in the antinodal regions shifts the maximum of the nematic susceptibility to slightly larger wave vectors. The corresponding order is akin to the incommensur…
Due to the combination of a substantial spin-orbit coupling and correlation effects, iridium oxides hold a prominent place in the search for novel quantum states of matter, including, e.g., Kitaev spin liquids and topological Weyl states. We establish the promise of the very recently synthesized hyper-honeycomb iridate $β$-Li2IrO3 in this regard. A detailed theoretical analysis reveals the presence of large ferromagnetic first-neighbor Kitaev interactions, while a second-neighbor antiferromagnetic Heisenberg exchange drives the ground state from ferro to zigzag order via a three-dimensional Ki…
Electronic nematicity, the breaking of the crystal lattice rotational symmetry by the electronic fluid, is a fascinating quantum state of matter. Recently, BaNi$_2$As$_2$ has emerged as a promising candidate for a novel type of nematicity triggered by charge fluctuations. In this work, we scrutinize the electronic nematicity of BaNi$_2$(As$_{1-x}$P$_x$)$_2$ with $0 \leq x \leq 0.10$ using electronic transport measurements under strain. We report a large $B_{1g}$ elastoresistance coefficient that is maximized at a temperature slightly higher than the first-order triclinic transition, and that c…
We study an extended Kitaev-Heisenberg model including additional anisotropic couplings by using two-dimensional density-matrix renormalization group method. Calculating the gound-state energy, entanglement entropy, and spin-spin correlation functions, we make a phase diagram of the extended Kitaev-Heisenberg model around spin-liquid phase. We find a zigzag antiferromagnetic phase, a ferromagnetic phase, a 120-degree antiferromagnetic phase, and two kinds of incommensurate phases around the Kitaev spin-liquid phase. Furthermore, we study the entanglement spectrum of the model and find that ent…
Recently, realizations of Kitaev physics have been sought in the A2IrO3 family of honeycomb iridates, originating from oxygen-mediated exchange through edge-shared octahedra. However, for the j = 1/2 Mott insulator in these materials exchange from direct d-orbital overlap is relevant, and it was proposed that a Heisenberg term should be added to the Kitaev model. Here we provide the generic nearest-neighbour spin Hamiltonian when both oxygen-mediated and direct overlap are present, containing a bond dependent off-diagonal exchange in addition to Heisenberg and Kitaev terms. We analyze this com…
We develop a low-energy effective theory for spin-1/2 frustrated two-leg Heisenberg spin ladders. We obtain a new type of interchain coupling that breaks parity symmetry. In the presence of an XXZ-type anisotropy, this interaction gives rise to a novel ground state, characterized by incommensurate correlations. In the case of a single ladder, this state corresponds to a spin nematic phase. For a frustrated quasi-one-dimensional system of infinitely many weakly coupled chains, this state develops true three dimensional spiral order. We apply our theory to recent neutron scattering experiments o…
We show that the mesoscopic incommensurate $\mathbb{Z}_2$ vortex crystals proposed for layered triangular anisotropic magnets can be most saliently identified by two distinctive signatures in dynamical spin response experiments: The presence of pseudo-Goldstone `phonon' modes at low frequencies $ω$, associated with the collective vibrations of the vortex cores, and a characteristic multi-scattered intensity profile at higher $ω$, arising from a large number of Bragg reflections and magnon bandgaps. These are direct fingerprints of the large vortex sizes and magnetic unit cells and the solitoni…
We report the existence of a phase transition at high temperature in the 3D Kitaev candidate material, $β$-Li$_2$IrO$_3$. We show that the transition is bulk, intrinsic and orders a tiny magnetic moment with a spatially anisotropic saturation moment. We show that even though this transition is global, it does not freeze the local Ir moments, which order at much lower temperatures into an incommensurate state. Rather, the ordered moment has an orbital origin that is coupled to spin correlations, likely of a Kitaev origin. The separate ordering of spin-correlated orbital moments and of local Ir …
Anyon polarons as a window into the competing phases of the Kitaev-Gamma-Gamma-prime model
School of Physical Science and Technology, Lanzhou University（兰州大学物理科学与技术学院）；Lanzhou Center for Theoretical Physics, Key Laboratory of Quantum Theory and Applications of MoE, Key Laboratory of Theoretical Physics of Gansu Province, Gansu Provincial Research Center for Basic Disciplines of Quantum Physics, Lanzhou University（兰州大学理论物理中心，教育部量子理论及应用重点实验室，甘肃省理论物理重点实验室，甘肃省量子物理基础学科研究中心，兰州大学）；Institut für Theoretische Physik, Universität Leipzig（莱比锡大学理论物理研究所）
We study the interplay between charge and spin ordering in electronic liquid crystalline states with a particular emphasis on fluctuating spin stripe phenomena observed in recent neutron scattering experiments\cite{Hinkov2008, Haug2009}. Based on a phenomenological model, we propose that charge nematic ordering is indeed behind the formation of temperature dependent incommensurate inelastic peaks near wavevector $(π,π)$ in the dynamic structure factor of YBa$_2$Cu$_3$O$_{6+y}$. We strengthen this claim by providing a compelling fit to the experimental data which cannot be reproduced by a numbe…
Mechanism of Incommensurate Magnetic Order in $\mathrm{BaCo_2(AsO_4)_2}$: Interplay of Frustrated Further-Neighbor Exchanges and Bond-Directional Anisotropy
Qom University of Technology（库姆理工大学）；University of Toronto（多伦多大学）；Shahrekord University（沙赫里克尔德大学）
Anisotropic Kitaev Spin Glass in Li$_{2}$Ru$_{x}$Ir$_{1-x}$O$_{3}$
University of California, San Diego（加州大学圣迭戈分校）；Institute of Science and Technology Austria（奥地利科学技术研究所）；TRIUMF（特利昂夫实验室）；Argonne National Laboratory（阿贡国家实验室）；Brookhaven National Laboratory（布鲁克海文国家实验室）；Lawrence Berkeley National Laboratory（劳伦斯伯克利国家实验室）；Brigham Young University（杨百翰大学）；University of California, Berkeley（加州大学伯克利分校）
We study quantum disordered ground states of the two dimensional Heisenberg-Kitaev model on the triangular lattice using a Schwinger boson approach. Our aim is to identify and characterize potential gapped quantum spin liquid phases that are stabilized by anisotropic Kitaev interactions. For antiferromagnetic Heisenberg- and Kitaev couplings and sufficiently small spin $S$ we find three different symmetric $Z_2$ spin liquid phases, separated by two continuous quantum phase transitions. Interestingly, the gap of elementary excitations remains finite throughout the transitions. The first spin li…
Renormalization group analysis for bosonization coefficients in half-odd-integer Kitaev spin chains
School of Physics, Nankai University（南开大学物理学院）；Kavli Institute for Theoretical Sciences, University of Chinese Academy of Sciences（中国科学院大学 Kavli理论科学研究所）
Superconductivity is significantly enhanced in monolayer FeSe grown on SrTiO3, but not for multilayer films, in which large strength of nematicity develops. However, the link between the high-transition temperature superconductivity in monolayer and the correlation related nematicity in multilayer FeSe films is not well understood. Here, we use low-temperature scanning tunneling microscopy to study few-layer FeSe thin films grown by molecular beam epitaxy. We observe an incommensurate long-range smectic phase, which solely appears in bilayer FeSe films. The smectic order still locally exists a…
Nematic order has manifested itself in a variety of materials in the cuprate family. We propose an effective field theory of a layered system with incommensurate, intertwined spin- and charge-density wave (SDW and CDW) orders, each of which consists of two components related by $C_4$ rotations. Using a variational method (which is exact in a large $N$ limit), we study the development of nematicity from partially melting those density waves by either increasing temperature or adding quenched disorder. As temperature decreases we first find a transition to a nematic phase, but depending on the r…
A minimal Kitaev-Gamma model has been recently investigated to understand various Kitaev systems. In the one-dimensional Kitaev-Gamma chain, an emergent SU(2)$_1$ phase and a rank-1 spin ordered phase with $O_h\rightarrow D_4$ symmetry breaking were identified using non-Abelian bosonization and numerical techniques. However, puzzles near the antiferromagnetic Kitaev region with finite Gamma interaction remained unresolved. Here we focus on this parameter region and find that there are two new phases, namely, a rank-1 ordered phase with an $O_h\rightarrow D_3$ symmetry breaking, and a peculiar …
Electronic-liquid-crystal phases, in which part of the spatial symmetries are broken spontaneously, are considered to play a vital role in interpreting the structure-property relation in strongly-correlated materials. Although electronic-liquid-crystal phases have been inferred in studies of a wide range of materials, the nature of the transition between such phases has received little experimental attention. Here we report the direct observation of an electronic smectic-nematic phase transition in a doped manganite utilizing transmission electron microscopic techniques. We show that, in this …
The recently-synthesized iridate $β$-Li$_2$IrO$_3$ has been proposed as a candidate to display novel magnetic behavior stabilized by frustration effects from bond-dependent, anisotropic interactions (Kitaev model) on a three-dimensional "hyperhoneycomb" lattice. Here we report a combined study using neutron powder diffraction and magnetic resonant x-ray diffraction to solve the complete magnetic structure. We find a complex, incommensurate magnetic order with non-coplanar and counter-rotating Ir moments, which surprisingly shares many of its features with the related structural polytype "strip…
We present a theoretical study of the static and dynamical properties of the Kitaev magnet $β$-Li$_2$IrO$_3$ based on the minimal $J$-$K$-$Γ$ model. We argue that the incommensurate magnetic order of $β$-Li$_2$IrO$_3$ can be qualitatively understood in terms of a long-wavelength twisting of a nearby commensurate, period-3 state, that shares the same symmetry, propagation vector, counter-rotation of the two spin sublattices, and non-coplanarity. This period-3 state shows very different structure when either the Kitaev interaction $K$ or the off-diagonal exchange anisotropy $Γ$ is dominant, feat…
Tuning the magnetic properties of Kitaev materials via the antiferromagnetic proximity effect: Novel phases and application to an $α$-RuCl$_3$/MnPS$_3$ bilayer
We report the magnetic structure and electronic properties of the honeycomb antiferromagnet $\rm NaNi_2BiO_{5.66}$. We find magnetic order with moments along the $c$ axis for temperatures below $T_{c1}=6.3(1)\>{\rm K}$ and then in the honeycomb plane for $T < T_{c2}=4.8(1)\>{\rm K}$ with a counterrotating pattern and an ordering wave vector ${\bf q}=(\frac{1}{3},\> \frac{1}{3},\> 0.15(1))$. Density functional theory and electron spin resonance indicate this is high-spin Ni$^{3+}$ magnetism near a high to low spin transition. The ordering wave vector, in-plane magnetic correlations, missing ent…
We investigate the quantum phases of the frustrated spin-$\frac{1}{2}$ $J_1$-$J_2$-$J_3$ Heisenberg model on the square lattice with ferromagnetic $J_1$ and antiferromagnetic $J_2$ and $J_3$ interactions. Using the pseudo-fermion functional renormalization group technique, we find an intermediate paramagnetic phase located between classically ordered ferromagnetic, stripy antiferromagnetic, and incommensurate spiral phases. We observe that quantum fluctuations lead to significant shifts of the spiral pitch angles compared to the classical limit. By computing the response of the system with res…
Recently, the family of rare-earth chalcohalides were proposed as candidate compounds to realize the Kitaev spin liquid (KSL). In the present work, we firstly propose an effective spin Hamiltonian consistents with the symmetry group of the crystal structure. Then we apply classical Monte Carlo simulations to preliminarily study the model and establish a phase diagram. When approaching to the low temperature limit, several magnetic long range orders are observed, including the stripe, the zigzag, the antiferromagnetic (AFM), the ferromagnetic (FM), the incommensurate spiral (IS), the Multi-$\pm…
We study the extended Kitaev model called the K$Γ$ model, using a perturbative expansion combined with a well-controlled mean-field approximation and a cutting-edge exact diagonalization. In the phase diagram, we discover a nematic Kitaev spin liquid and a Kekulé Kitaev spin liquid. The former potentially explains the high-field nematic state with zero Chern number experimentally observed in $α$-RuCl$_3$, even for sufficiently small values of $Γ/|K|$. The latter has a Majorana zero mode in its $Z_3$ vortex core, which can be potentially controlled by the domain wall motion. This opens a possib…
The ground state of the spin$-1/2$ kagome antiferromagnet remains uncertain despite decades of active research. Here we step aside from this debated question to address the ground-state nature of a related, and potentially just as rich, system made of corner-sharing triangles: the square-kagome lattice (SKL). Our work is motivated by the recent synthesis of a distorted SKL compound mentioned in [Morita & Tohyama, J. Phys. Soc. Japan 87, 043704 (2018)]. We have studied its spin$-1/2$ $J_{1}$-$J_{2}$ phase diagram with an unrestricted Schwinger boson mean-field theory (SBMFT). We show that, in a…
We develop a microscopic theory of finite-temperature spin-nematic orderings in three-dimensional spatially anisotropic magnets consisting of weakly-coupled frustrated spin-1/2 chains with nearest-neighbor and next-nearest-neighbor couplings in a magnetic field. Combining a field theoretical technique with density-matrix renormalization group results, we complete finite-temperature phase diagrams in a wide magnetic-field range that possess spin-bond-nematic and incommensurate spin-density-wave ordered phases. The effects of a four-spin interaction are also studied. The relevance of our results…
