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arXiv 2004.13584cond-mat.mtrl-sci
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新型磁拓扑绝缘体FeBi2Te4的晶体生长与表征

Crystal Growth and characterization of possible New Magnetic Topological Insulators FeBi2Te4

Ankush Saxena, Poonam Rani, S. Patnaik, Vipin Nagpal, I. Felner, V. P. S. Awana

摘要:

本文报道了采用真空封装自熔法成功地生长了新型磁性拓扑绝缘体FeBi_2 Te_4单晶。粉末XRD数据的详细Rietveld分析表明,生长的MTI晶体主要由FeBi 2 Te 4相以及Bi 2 Te 3和FeTe的少数相主导。扫描电子显微镜(SEM)图像显示生长的MTI单晶的形态为层状型层状结构。该晶体的拉曼光谱在65、110和132 cm-1处显示出三种不同的声子模式,以及在90和144 cm-1处的两个分裂二级模式。二次分裂模是FeTe嵌入Bi_2Te_3晶胞的结果。在200 K、20 K和2 K三种温度下,外加磁场高达12 T,测量了Bi 2 Te 3晶体的磁电阻。直流磁化强度测量的温度依赖性表明,FeBi 2 Te 4晶体主要是铁磁(FM)或亚铁磁性的性质高于295 K,虽然二次弱磁转变被视为在54- 46 K以及。详细的等温磁化强度(MH)结果表明,在295 K时FM饱和磁矩为0.00213emu/g,直到400 K基本保持不变。总之,我们已经生长了MTI FeBi_2 Te_4单晶,它可能是室温或更高温度下量子反常霍尔(QAH)效应的可能进入者。

英文摘要:

Here we report successful single crystal growth of new possible magnetic topological insulator (MTI) FeBi2Te4 by self-flux method via vacuum encapsulation process. The detailed Rietveld analysis of Powder XRD data shows the as grown MTI crystal to be mainly dominated by FeBi2Te4 phase along with minority phases of Bi2Te3 and FeTe. Scanning electron microscope (SEM) image shows the morphology of as grown MTI single crystal to be of layered type laminar structure. Raman spectroscopy of the crystal exhibited three distinct phonon modes at 65, 110, and 132 cm-1 along with two split secondary modes at 90, and 144cm-1. The secondary split modes are result of FeTe intercalation in Bi2Te3 unit cell. Magneto-resistance measurement has been performed at different temperatures i.e. 200K, 20K and 2K in applied magnetic fields up to 12 Tesla, which showed very low MR in comparison to pure Bi2Te3 crystal. Temperature dependence of DC magnetization measurements show the FeBi2Te4 crystal to be mainly of ferromagnetic (FM) or ferri-magnetic nature above 295 K, albeit a secondary weak magnetic transition is seen at 54-46K as well. Detailed isothermal magnetization (MH) results showed that FM saturation moment at 295K is 0.00213emu/g, which is nearly invariant till 400 K. Summary, we had grown an MTI FeBi2Te4 single crystal, which may be a possible entrant for Quantum Anomalous Hall (QAH) effect at room temperature or above.

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