We present a succinct and intuitive derivation of a formally exact master equation for general open quantum systems, without the use of an "inverse" map which was invoked in previous works on formally exact master equations. This formalism is applicable to non-Markovian regimes. We derive a second-order equation of motion for the illustrative spin-boson model at arbitrary temperatures, observing non-exponential decoherence and relaxation. Limiting our generic derivation to zero temperature, we also reproduce the result for the special case of a vacuum bath in Phys. Rev. A 81, 042103 (2010).
We show that the exact master equation incorporating initial correlations for open quantum systems, within the Nakajima-Zwanzig operator-projection method, is a homegenous master equation for the reduced density matrix. We also derive explicitly the exact master equation for a large class of bosonic and fermionic open quantum systems incorporating initial correlations, the resulting master equation is homogenous. We find that the effects of the initial correlations can be fully embedded into the fluctuation dynamics through the exact homogenous master equation. Also a generalized nonequilibriu…
A mean field approximation is employed to derive a master equation suitable for self-interacting baths and strong system-bath coupling. Solutions of the master equation are compared with exact solutions for a central spin interacting with a spin-bath.
We provide the exact non-Markovian master equation for a two-level system interacting with a thermal bosonic bath, and we write the solution of such a master equation in terms of the Bloch vector. We show that previous approximated results are particular limits of our exact master equation. We generalize these results to more complex systems involving an arbitrary number of two-level systems coupled to different thermal baths, providing the exact master equations also for these systems. As an example of this general case we derive the master equation for the Jaynes-Cummings model.
Non-Markovian master equations describe general open quantum systems when no approximation is made. We provide the exact closed master equation for the class of Gaussian, completely positive, trace preserving, non-Markovian dynamics. This very general result allows to investigate a vast variety of physical systems. We show that the master equation for non-Markovian quantum Brownian motion is a particular case of our general result. Furthermore, we derive the master equation unraveled by a non-Markovian, dissipative stochastic Schrödinger equation, paving the way for the analysis of dissipative…
A wide class of exact master equations for a multiple qubit system can be explicitly constructed by using the corresponding exact non-Markovian quantum state diffusion equations. These exact master equations arise naturally from the quantum decoherence dynamics of qubit system as a quantum memory coupled to a collective colored noisy source. The exact master equations are also important in optimal quantum control, quantum dissipation and quantum thermodynamics. In this paper, we show that the exact non-Markovian master equation for a dissipative N-qubit system can be derived explicitly from th…
The low temperature solution of the exact master equation for an oscillator coupled to a linear passive heat bath is known to give rise to serious divergences. We now show that, even in the high temperature regime, problems also exist, notably the fact that the density matrix is not necessarily positive.
Driven two-level system is a useful model to describe many quantum objects, particularly in quantum information processing. However, the exact master equation for such a system is barely explored. Making use of the Feynman-Vernon influence functional theory, we derive an exact non-Markovian master equation for the driven two-level system and show the lost feature in the perturbative treatment for this system. The perturbative treatment leads to the time-convolutionless (TCL) and the Nakajima-Zwanzig (NZ) master equations. So to this end, we derive the time-convolutionless (TCL) and the Nakajim…
Exact master equations describing the decay of a two-state system into a structured reservoir are constructed. Employing the exact solution for the model we determine analytical expressions for the memory kernel of the Nakajima-Zwanzig master equation and for the generator of the corresponding time-convolutionless master equation. This approach allows a detailed investigation and comparison of the convergence behavior of the corresponding perturbation expansions. Moreover, we find that the structure of widely used phenomenological master equations with memory kernel may be incompatible with a …
We derive a master equation from the exact stochastic Liouville von-Neumann (SLN) equation \cite{stockburger2002,wallsbook}. The latter depends on two correlated noises and describes exactly the dynamics of an oscillator (which can be either harmonic or present an anharmonicity) coupled to an environment at thermal equilibrium. The newly derived master equation is obtained by performing analytically the average over different noise trajectories. It is found to have a complex hierarchical structure that might be helpful to explain the convergence problems occurring when performing numerically t…
We point out that the celebrated GRW master-equation is invariant under translations, reflecting the homogeneity of space, thus providing a particular realization of a general class of translation-covariant Markovian master-equations. Such master-equations are typically used for the description of decoherence due to momentum transfers between system and environment. Building on this analogy we show the exact relationship between the GRW master-equation and decoherence master-equations, further providing a collisional decoherence model formally equivalent to the GRW master-equation. This allows…
We study the non-Markovian quantum interference phenomenon of a multi-state atomic system coupled to a bosonic dissipative environment by using the exact master equations derived in this paper. Two examples involving four-level systems with or without external control fields are investigated. Our results show that non-Markovian master equations are capable of exhibiting quantum interference phenomena in a temporal domain that has not fully explored before. In particular, we show that the environmental memory is instrumental in the onset of non-Markovian quantum interference pattern in differen…
An exact quantum master equation formalism is constructed for the efficient evaluation of quantum non-Markovian dissipation beyond the weak system-bath interaction regime in the presence of time-dependent external field. A novel truncation scheme is further proposed and compared with other approaches to close the resulting hierarchically coupled equations of motion. The interplay between system-bath interaction strength, non-Markovian property, and required level of hierarchy is also demonstrated with the aid of simple spin-boson systems.
A many particle Hamiltonian, where the interaction term conserves the number of particles, is considered. A master equation for the populations of the different levels is derived in an exact way. It results in a local equation with time-dependent coefficients, which can be identified with the transition probabilities in the golden rule approximation. A reinterpretation of the model as a set of coupled harmonic oscillators enables one to obtain for one of them an exact local Langevin equation, with time-dependent coefficients.
Exact solutions of the Caldeira-Leggett Master equation for the reduced density matrix for a free particle and for a harmonic oscillator system coupled to a heat bath of oscillators are obtained for arbitrary initial conditions. The solutions prove that the Fourier transform of the density matrix at time t with respect to (x + x')/2, where x and x' are the initial and final coordinates, factorizes exactly into a part depending linearly on the initial density matrix and a part independent of it. The theorem yields the exact initial state dependence of the density operator at time t and its even…
For a bosonic (fermionic) open system in a bath with many bosons (fermions) modes, we derive the exact non-Markovian master equation in which the memory effect of the bath is reflected in the time dependent decay rates. In this approach, the reduced density operator is constructed from the formal solution of the corresponding Heisenberg equations. As an application of the exact master equation, we study the active probing of non-Markovianity of the quantum dissipation of a single boson mode of electromagnetic (EM) field in a cavity QED system. The non-Markovianity of the bath of the cavity is …
For any master equation which is local in time, whether Markovian, non-Markovian, of Lindblad form or not, a general procedure is reviewed for constructing the corresponding linear map from the initial state to the state at time t, including its Kraus-type representations. Formally, this is equivalent to solving the master equation. For an N-dimensional Hilbert space it requires (i) solving a first order N^2 x N^2 matrix time evolution (to obtain the completely positive map), and (ii) diagonalising a related N^2 x N^2 matrix (to obtain a Kraus-type representation). Conversely, for a given time…
The time-convolutionless (TCL) quantum master equation provides a powerful tool to simulate reduced dynamics of a quantum system coupled to a bath. The key quantity in the TCL master equation is the so-called kernel or generator, which describes effects of the bath degrees of freedom. Since the exact TCL generators are usually hard to calculate analytically, most applications of the TCL generalized master equation have relied on approximate generators using second and fourth order perturbative expansions. By using the hierarchical equation of motion (HEOM) and extended HEOM methods, we present…
We present an exact master equation for a central spin-$1/2$ system coupled to a spin-$1/2$ bath in terms of hyperfine interaction, which provides a unified formalism for both free evolution and controlled dynamics of the central spin. The equation enables us to study controllability of dynamics processes with various degrees of non-Markovianity. We investigate the Overhauser's effect on decoherence dynamics of the central spin under different bath spectra and the system-bath coupling strengths. Nonperturbative leakage elimination approach is applied to the system to suppress decoherence in so…
The methodology of stochastic description for dissipation, a generic scheme to decouple the interaction between two subsystems, is applied to the study of dissipative dynamics in quantum optics. It is shown that the influence of the coupled thermal or vacuum field on the quantum mode can be exactly represented by the induced stochastic fields. The quantum mode thereby satisfies a stochastic differential equation and dissipation effect due to the coupling with the environment is obtained through statistical averaging. Within the framework of stochastic description, it is demonstrated how to der…
A systematic procedure for deriving the master equation of a dissipative system is reported in the framework of stochastic description. For the Caldeira-Leggett model of the harmonic-oscillator bath, a detailed and elementary derivation of the bath-induced stochastic field is presented. The dynamics of the system is thereby fully described by a stochastic differential equation and the desired master equation would be acquired with statistical averaging. It is shown that the existence of a closed-form master equation depends on the specificity of the system as well as the feature of the dissipa…
A mean field argument is used to derive a master equation for systems simultaneously interacting with external fields and coupled environmental degrees of freedom. We prove that this master equation preserves positivity of the reduced density matrix. Solutions of the master equation are compared with exact solutions for a system consisting of three spins which is manipulated with a sequence of laser pulses while interacting with a spin-bath. Exact solutions appear to converge to the master equation result as the number of bath spins increases.
Time evolution of a harmonic oscillator linearly coupled to a heat bath is compared for three classes of initial states for the bath modes - grand canonical ensemble, number states and coherent states. It is shown that for a wide class of number states the behavior of the oscillator is similar to the case of the equilibrium bath. If the bath modes are initially in coherent states, then the variances of the oscillator coordinate and momentum, as well as its entanglement to the bath, asymptotically approach the same values as for the oscillator at zero temperature and the average coordinate and …
The reduced dynamics of two interacting qubits coupled to two independent bosonic baths is investigated. The one-excitation dynamics is derived and compared with that based on the resolution of appropriate non-Markovian master equations. The Nakajima-Zwanzig and the time-convolutionless projection operator techniques are exploited to provide a description of the non-Markovian features of the dynamics of the two-qubits system. The validity of such approximate methods and their range of validity in correspondence to different choices of the parameters describing the system are brought to light.
In this paper, we generalize the quantum Brownian motion to include momentum-dependent system-environment couplings. The conventional QBM model corresponds to the spacial case $W_k = V_k$. The generalized QBM is more complicated but the generalization is necessary. This is because the particle transition and the pair production between the system and the environment represent two very different physical processes, and usually cannot have the same coupling strengths. Thus, the conventional QBM model, which is well-defined at classical level, is hardly realized in real quantum physical world. We…
We revisit the model of a quantum Brownian oscillator linearly coupled to an environment of quantum oscillators at finite temperature. By introducing a compact and particularly well-suited formulation, we give a rather quick and direct derivation of the master equation and its solutions for general spectral functions and arbitrary temperatures. The flexibility of our approach allows for an immediate generalization to cases with an external force and with an arbitrary number of Brownian oscillators. More importantly, we point out an important mathematical subtlety concerning boundary-value prob…
Stochastic Schr{ö}dinger equations for quantum trajectories offer an alternative and sometimes superior approach to the study of open quantum system dynamics. Here we show that recently established convolutionless non-Markovian stochastic Schr{ö}dinger equations may serve as a powerful tool for the derivation of convolutionless master equations for non-Markovian open quantum systems. The most interesting example is quantum Brownian motion (QBM) of a harmonic oscillator coupled to a heat bath of oscillators, one of the most-employed exactly soluble models of open system dynamics. We show explic…
We propose a new approach to study the evolution of a quantum state that is encoded in a system which is continuously subject to the operations required to implement a quantum error correcting code. In the limit of continuous error correction we introduce a Markovian master equation that includes the effects of: a) Hamiltonian evolution, b) errors caused by the interaction with an environment and c) error-correcting operations. The master equation is formally presented for all stabilizer codes and its solution is analyzed for the simplest such code.
A well-known situation in which a non-Markovian dynamics of an open quantum system $S$ arises is when this is coherently coupled to an auxiliary system $M$ in contact with a Markovian bath. In such cases, while the joint dynamics of $S$-$M$ is Markovian and obeys a standard (bipartite) Lindblad-type master equation (ME), this is in general not true for the reduced dynamics of $S$. Furthermore, there are several instances (\eg the dissipative Jaynes-Cummings model) in which a {\it closed} ME for the $S$'s state {\it cannot} even be worked out. Here, we find a class of bipartite Lindblad-type ME…
In this paper we present a method to derive an exact master equation for a bosonic system coupled to a set of other bosonic systems, which plays the role of the reservoir, under the strong coupling regime, i.e., without resorting to either the rotating-wave or secular approximations. Working with phase-space distribution functions, we verify that the dynamics are separated in the evolution of its center, which follows classical mechanics, and its shape, which becomes distorted. This is the generalization of a result by Glauber, who stated that coherent states remain coherent under certain circ…
Based on the standard transfer matrix, a formally exact quantization condition for arbitrary potentials, which outflanks and unifies the historical approaches, is derived. It can be used to find the exact bound-state energy eigenvalues of the quantum system without solving an equation of motion for the system wave functions.
It is shown that the standard quantum Brownian equation (QBE) can violate positivity not only past the thermal correlation time, but at arbitrarily long times at high system frequencies. In an effort to improve the standard QBE, exact operator solutions are provided for a class of non-autonomous master equations. These exact solutions are used to derive sufficient positivity conditions for the coefficients of the master equations.
A Lindblad master equation for a harmonic oscillator, which describes the dynamics of an open system, is formally solved. The solution yields the spectral resolution of the Liouvillian, that is, all eigenvalues and eigenprojections are obtained. This spectral resolution is discussed in depth in the context of the biorthogonal system and the rigged Hilbert space, and the contribution of each eigenprojection to expectation values of physical quantities is revealed. We also construct the ladder operators of the Liouvillian, which clarify the structure of the spectral resolution.
We perform a first- principles derivation of the general master equation to study the non-Markovian dynamics of a two-level atom (2LA) interacting with an electromagnetic field (EMF). We use the influence functional method which can incorporate the full backreaction of the field on the atom, while adopting Grassmannian variables for the 2LA and the coherent state representation for the EMF. We find exact master equations for the cases of a free quantum field and a cavity field in the vacuum. In response to the search for mechanisms to preserve maximal coherence in quantum computations in ion t…
Quantum operations are usually defined as completely positive (CP), trace preserving (TP) maps on quantum states, and can be represented by operator-sum or Kraus representations. In this paper, we calculate operator-sum representation and master equation of an exactly solvable dynamic of one-qubit open system in layered environment . On the other hand, we obtain exact Nakajima-Zwanzig (NZ) and time-convolutionless (TCL) master equation from the maps. Finally, we study a simple example to consider the relation between CP maps and initial quantum correlation and show that vanishing initial quant…
The Hu-Paz-Zhang equation is a master equation for an oscillator coupled to a linear passive bath. It is exact within the assumption that the oscillator and bath are initially uncoupled . Here an exact general solution is obtained in the form of an expression for the Wigner function at time t in terms of the initial Wigner function. The result is applied to the motion of a Gaussian wave packet and to that of a pair of such wave packets. A serious divergence arising from the assumption of an initially uncoupled state is found to be due to the zero-point oscillations of the bath and not removed …
The exact fermion master equation previously obtained in [Phys. Rev. B \textbf{78}, 235311 (2008); New J. Phys. \textbf{12}, 083013 (2010)] describes the dynamics of quantum states of a principal system of fermionic particles under the influences of external fermion reservoirs (e.g. nanoelectronic systems). Here, we present the general solution to this exact fermion master equation. The solution is analytically expressed in the most intuitive particle number representation. It is applicable to an arbitrary number of orbitals in the principal system prepared at arbitrary initial states. We demo…
We derive the exact time-evolution for a general quantum system under the influence of pure phase-noise and demonstrate that for a Gaussian initial state of the bath, the exact result can be obtained also within a perturbative time-local master equation approach already in second order of the system-bath coupling strength. We reveal that this equivalence holds if the initial state of the bath can be mapped to a Gaussian phase-space distribution function. Moreover, we discuss the relation to the standard Bloch-Redfield approach.
Using the exact path integral solution for the damped harmonic oscillator it is shown that in general there does not exist an exact dissipative Liouville operator describing the dynamics of the oscillator for arbitrary initial bath preparations. Exact non-stationary Liouville operators can be found only for particular preparations. Three physically meaningful examples are examined. An exact new master equation is derived for thermal initial conditions. Second, the Liouville operator governing the time-evolution of equilibrium correlations is obtained. Third, factorizing initial conditions are …
We discuss recent findings about properties of quantum nonequilibrium steady states. In particular we focus on transport properties. It is shown that the time dependent density matrix renormalization method can be used successfully to find a stationary solution of Lindblad master equation. Furthermore, for a specific model an exact solution is presented.
We consider a molecular aggregate consisting of $N$ identical monomers. Each monomer comprises two electronic levels and a single harmonic mode. The monomers interact with each other via dipole-dipole forces. The monomer vibrational modes are bilinearly coupled to a bath of harmonic oscillators. This is a prototypical model for the description of coherent exciton transport, from quantum dots to photosynthetic antennae. We derive an exact quantum master equation for such systems. Computationally, the master equation may be useful for the testing of various approximations employed in theories of…
In this paper, we derive the exact master equation to investigate the decoherence dynamics of Majorana zero modes in the Kitaev model, a 1D $p\,$-wave spinless topological superconducting chain (TSC), that is disturbed by charge fluctuations through gate controls. The exact master equation is derived by extending Feynman-Vernon influence functional approach to fermionic open systems involving pairing excitations. We obtain the exact master equations for the zero-energy bogoliubon in the TSC, and then transfer it into the master equation for Majorana zero modes. Within this exact master equatio…
We present a first-principles derivation of the Markovian semi-group master equation without invoking the rotating wave approximation (RWA). Instead we use a time coarse-graining approach which leaves us with a free timescale parameter, which we can optimize. Comparing this approach to the standard RWA-based Markovian master equation, we find that significantly better agreement is possible using the coarse-graining approach, for a three-level model coupled to a bath of oscillators, whose exact dynamics we can solve for at zero temperature. The model has the important feature that the RWA has a…
We define an ensemble of projection operators, each of which has an exact associated Nakajima-Zwanzig master equation for quantum open system evolution. A mean field approximation for the memory kernels is introduced that yields, for an optimally chosen projection operator, a completely determined inhomogeneous master equation. Previous proofs of positivity and equilibration are extended to these new inhomogeneous non-Markovian master equations. We study a nitrogen vacancy center in diamond interacting with 13C impurities to illustrate the method.
Based on the recent experiments on the hybrid quantum system of a superconducting microwave cavity coupling strongly to an inhomogeneous broadening spin ensemble under an external driving field, we use the exact master equation approach to investigate its non-Markovian decoherence dynamics. Here the spin ensemble is made by negatively charged nitrogen-vacancy (NV) defects in diamond. Our exact master equation theory for open systems depicts the experimental decoherence results and reveals the mechanism how the decoherence induced by the inhomogeneous broadening is suppressed in the strong-coup…
Given a multilevel system coupled to a bath, we use a Feshbach P,Q partitioning technique to derive an exact trace-nonpreserving master equation for a subspace $\mathcal{S}_{i}$ of the system. The resultant equation properly treats the leakage effect from $\mathcal{S}_{i}$ into the remainder of the system space. Focusing on a second-order approximation, we show that a one-dimensional master equation is sufficient to study problems of quantum state storage and is a good approximation, or exact, for several analytical models. It allows a natural definition of a leakage function and its control, …
A method of exactly solving the master equation is presented in this letter. The explicit form of the solution is determined by the time evolution of a composite system including an auxiliary system and the open system in question. The effective Hamiltonian governing the time evolution of the composed system are derived from the master equation. Two examples, the dissipative two-level system and the damped harmonic oscillator, are presented to illustrate the solving procedure. PACS number(s): 05.30.-d, 05.40.+j, 42.50.Ct
Hu, Paz and Zhang [ B.L. Hu, J.P. Paz and Y. Zhang, Phys. Rev. D {\bf 45} (1992) 2843] have derived an exact master equation for quantum Brownian motion in a general environment via path integral techniques. Their master equation provides a very useful tool to study the decoherence of a quantum system due to the interaction with its environment. In this paper, we give an alternative and elementary derivation of the Hu-Paz-Zhang master equation, which involves tracing the evolution equation for the Wigner function. We also discuss the master equation in some special cases.
In this paper we discuss a master equation applied to the two level system of an atom and derive an exact solution to it in an abstract manner. We also present a problem and a conjecture based on the three level system. Our results may give a small hint to understand the huge transition from Quantum World to Classical World. To the best of our knowledge this is the finest method up to the present.
We show that open quantum systems of two-level atoms symmetrically coupled to a single-mode photon field can be efficiently simulated by applying a SU(4) group theory to quantum master equations. This is important since many foundational examples in quantum optics fall into this class. We demonstrate the method by finding exact solutions for many-atom open quantum systems such as lasing and steady state superradiance.
Master equations are a useful tool to describe the evolution of open quantum systems. In order to characterize the mathematical features and the physical origin of the dynamics, it is often useful to consider different kinds of master equations for the same system. Here, we derive an exact connection between the time-local and the integro-differential descriptions, focusing on the class of commutative dynamics. The use of the damping-basis formalism allows us to devise a general procedure to go from one master equation to the other and vice-versa, by working with functions of time and their La…
When dealing with system-reservoir interactions in an open quantum system, such as a photosynthetic light-harvesting complex, approximations are usually made to obtain the dynamics of the system. One question immediately arises: how good are these approximations, and in what ways can we evaluate them? Here, we propose to use entanglement and a measure of non-Markovianity as benchmarks for the deviation of approximate methods from exact results. We apply two frequently-used perturbative but non-Markovian approximations to a photosynthetic dimer model and compare their results with that of the n…
