arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 2004.08319cond-mat.mtrl-scicond-mat.str-el
收藏

错配[Ca $_2$ CoO $_3$ ] $_{0.62}$ [ CoO $_2$ ]钴酸盐的磁关联

Magnetic correlations in subsystems of the misfit [Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$] cobaltate

Abdul Ahad, K. Gautam, K. Dey, S. S. Majid, F. Rahman, S. K. Sharma, J. A. H. Coaquira, Ivan da Silva, E. Welter, D. K. Shukla

摘要:

[Ca $_2$ CoO $_3$ ] $_{0.62}$ [CoO $_2$ ]是一种二维错配金属化合物,以其丰富的温度相变、$i.e.$高温自旋态转变、中温($\sim$ 100 K)金属-绝缘体转变(MIT)和低温自旋密度波(SDW)而闻名。在低于T $_{MIT}$时进入SDW相,在27 K时变为长程。关于错配层(岩盐/Ca $_2$ CoO $_3$ \&三角形/CoO $_2$)在这些阶段中的独立作用的信息很少。通过结合一组互补的宏观(直流磁化强度和电阻率)和微观(中子衍射和X射线吸收精细结构光谱)测量纯(CCO)和Tb取代在岩盐层的CCO(CCO 1),磁相关性在这两个子系统的失配化合物解开。发现CCO表现出玻璃化,以及交换偏置(EB)的影响,而CCO 1不表现出玻璃化,虽然它显示出较弱的EB效应。通过结合扩展X射线吸收精细结构(EXAFS)光谱和中子衍射结果对CCO的局部结构调查,我们确认SDW出现在CoO $_2$层。结果表明,岩盐层的磁晶各向异性是导致电子束效应的钉扎源。Ca $_2$ CoO $_3$中的铁磁团簇影响CoO $_2$中的SDW,并最终产生玻璃化。

英文摘要:

[Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$], a two dimensional misfit metallic compound, is famous for its rich phases accessed by temperature, $i.e.$ high temperature spin-state transition, metal-insulator transition (MIT) at intermediate temperature ($\sim$ 100 K) and low temperature spin density wave (SDW). It enters into SDW phase below T$_{MIT}$ which becomes long range at 27 K. Information on the independent role of misfit layers (rocksalt/Ca$_2$CoO$_3$ \& triangular/CoO$_2$) in these phases is scarce. By combining a set of complementary macroscopic (DC magnetization and resistivity) and microscopic (neutron diffraction and X-ray absorption fine structure spectroscopy) measurements on pure (CCO) and Tb substituted in the rocksalt layer of CCO (CCO1), magnetic correlations in both subsystems of this misfit compound are unraveled. CCO is found to exhibit glassiness, as well as exchange bias (EB) effects, while CCO1 does not exhibit glassiness, albeit it shows weaker EB effect. By combining local structure investigations from extended X-ray absorption fine structure (EXAFS) spectroscopy and neutron diffraction results on CCO, we confirm that the SDW arises in the CoO$_2$ layer. Our results show that the magnetocrystalline anisotropy associated with the rocksalt layer acts as a source of pinning, which is responsible for EB effect. Ferromagnetic clusters in the Ca$_2$CoO$_3$ affects SDW in CoO$_2$ and ultimately glassiness arises.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑