We introduce a model for a periodically driven electron pump that sequentially interact with an arbitrary number of heat and particle reservoirs. Exact expressions for the thermodynamic fluxes, such as entropy production and particle flows are derived arbitrarily far from equilibrium. We use the present model to perform a comparative study of thermodynamic uncertainty relations that are valid for systems with time-periodic driving.
We present the stochastic thermodynamic analysis of a time-periodic single particle pump, including explicit results for flux, thermodynamic force, entropy production, work, heat and efficiency. These results are valid far from equilibrium. The deviations from the linear (Onsager) regime are discussed.
We derive a linear thermodynamics theory for general Markov dynamics with both steady-state and time-periodic drivings. Expressions for thermodynamic quantities, such as mechanical and chemical work, heat and entropy production are obtained in terms of equilibrium probability distribution and the drivings. The entropy production is derived as a bilinear function of thermodynamic forces and the associated fluxes. We derive explicit formulae for the Onsager coefficients and use them to verify the Onsager-Casimir reciprocal relations. Our results are illustrated on a periodically driven quantum d…
The thermodynamic uncertainty relation expresses a universal trade-off between precision and entropy production, which applies in its original formulation to current observables in steady-state systems. We generalize this relation to periodically time-dependent systems and, relatedly, to a larger class of inherently time-dependent current observables. In the context of heat engines or molecular machines, our generalization applies not only to the work performed by constant driving forces, but also to the work performed while changing energy levels. The entropic term entering the generalized un…
The theory of linear stochastic thermodynamics is developed for periodically driven systems in contact with a single reservoir. Appropriate thermodynamic forces and fluxes are identified, starting from the entropy production for a Markov process. Onsager coefficients are evaluated, the Onsager-Casimir relations are verified, and explicit expressions are given for an expansion in terms of Fourier components. The results are illustrated on a periodically modulated two level system including the optimization of the power output.
Periodic driving is used to operate machines that go from standard macroscopic engines to small non-equilibrium micro-sized systems. Two classes of such systems are small heat engines driven by periodic temperature variations and molecular pumps driven by external stimuli. Well known results that are valid for nonequilibrium steady states of systems driven by fixed thermodynamic forces, instead of an external periodic driving, have been generalized to periodically driven heat engines only recently. These results include a general expression for entropy production in terms of currents and affin…
Motivated by the recent proposed models of the information engine [D. Mandal and C. Jarzynski, Proc. Natl. Acad. Sci. 109, 11641 (2012)] and the information refrigerator [D. Mandal, H. T. Quan, and C. Jarzynski, Phys. Rev. Lett. 111, 030602 (2013)], we propose a minimal model of the information pump and the information eraser based on enzyme kinetics. This device can either pump molecules against the chemical potential gradient by consuming the information encoded in the bit stream or (partially) erase the information encoded in the bit stream by consuming the Gibbs free energy. The dynamics o…
We show that a reversible pumping mechanism operating between two states of a kinetic network can give rise to Poisson transitions between these two states. An external observer, for whom the pumping mechanism is not accessible, will observe a Markov chain satisfying local detailed balance with an emerging effective force induced by the hidden pump. Due to the reversibility of the pump, the actual entropy production turns out to be lower than the coarse grained entropy production estimated from the flows and affinities of the resulting Markov chain. Moreover, in presence of a large time scale …
We develop a unified treatment of pumping and nonequilibrium thermodynamics. We show that the pumping current generated through an adiabatic mechanical operation in equilibrium can be expressed in terms of the stationary distribution of the corresponding driven nonequilibrium system. We also show that the total transfer in pumping can be evaluated from the work imported to the driven counterpart. These findings lead us to a unified viewpoint for pumping and nonequilibrium thermodynamics.
We study a symmetric exclusion process in which the hopping rates at two chosen adjacent sites vary periodically in time and have a relative phase difference. This mimics a colloidal suspension subjected to external space and time dependent modulation of the diffusion constant. The two special sites act as a classical pump by generating an oscillatory current with a nonzero ${\cal DC}$ value whose direction depends on the applied phase difference. We analyze various features in this model through simulations and obtain an expression for the $\cal{DC}$ current via a novel perturbative treatment…
We aim to give a pedagogic presentation of the open system dynamics of a periodically driven qubit in contact with a temperature bath. We are specifically interested in the thermodynamics of the qubit. It is well known that by combining the Markovian approximation with Floquet theory it is possible to derive a stochastic Schrödinger equation in $\mathbb{C}^2$ for the state of the qubit. We follow here a different approach. We use Floquet theory to embed the time-non autonomous qubit dynamics into time-autonomous yet infinite dimensional dynamics. We refer to the resulting infinite dimensional …
Small nonequelibrium systems driven by an external periodic protocol can be described by Markov processes with time-periodic transition rates. In general, current fluctuations in such small systems are large and may play a crucial role. We develop a theoretical formalism to evaluate the rate of such large deviations in periodically driven systems. We show that the scaled cumulant generating function that characterizes current fluctuations is given by a maximal Floquet exponent. Comparing deterministic protocols with stochastic protocols, we show that, with respect to large deviations, systems …
Periodically driven coherent conductors provide a universal platform for the development of quantum transport devices. Here, we lay down a comprehensive theory to describe the thermodynamics of these systems. We first focus on moderate thermo-electrical biases and low driving frequencies. For this linear response regime, we establish generalized Onsager-Casimir relations and an extended fluctuation-dissipation theorem. Furthermore, we derive a family of thermodynamic bounds proving that any local matter or heat current puts a non-trivial lower limit on the overall dissipation rate of a coheren…
Scattering theory is a standard tool for the description of transport phenomena in mesoscopic systems. Here, we provide a detailed derivation of this method for nano-scale conductors that are driven by oscillating electric or magnetic fields. Our approach is based on an extension of the conventional Lippmann-Schwinger formalism to systems with a periodically time dependent Hamiltonian. As a key result, we obtain a systematic perturbation scheme for the Floquet scattering amplitudes that describe the transition of a transport carrier through a periodically driven sample. Within a general multi-…
For periodically driven systems, we derive a family of inequalities that relate entropy production with experimentally accessible data for the mean, its dependence on driving frequency, and the variance of a large class of observables. With one of these relations, overall entropy production can be bounded by just observing the time spent in a set of states. Among further consequences, the thermodynamic efficiency both of isothermal cyclic engines like molecular motors under a periodic load and of cyclic heat engines can be bounded using experimental data without requiring knowledge of the spec…
We consider a harmonic oscillator under periodic driving and coupled to two harmonic-oscillator heat baths at different temperatures. We use the thermofield transformation with chain mapping for this setup, which allows us to study the unitary evolution of the system and the baths up to a time when the periodic steady state emerges in the system. We characterize this periodic steady state, and we show that, by tuning the system and the bath parameters, one can turn this system from an engine to an accelerator or even to a heater. The possibility to study the unitary evolution of the system and…
Theoretical treatments of periodically-driven quantum thermal machines (PD-QTMs) are largely focused on the limit-cycle stage of operation characterized by a periodic state of the system. Yet, this regime is not immediately accessible for experimental verification. Here, we present a general thermodynamic framework that can handle the performance of PD-QTMs both before and during the limit-cycle stage of operation. It is achieved by observing that periodicity may break down at the ensemble average level, even in the limit-cycle phase. With this observation, and using conventional thermodynamic…
Small nonequilibrium systems in contact with a heat bath can be analyzed with the framework of stochastic thermodynamics. In such systems, fluctuations, which are not negligible, follow universal relations such as the fluctuation theorem. More recently, it has been found that, for nonequilibrium stationary states, the full spectrum of fluctuations of any thermodynamic current is bounded by the average rate of entropy production and the average current. However, this bound does not apply to periodically driven systems, such as heat engines driven by periodic variation of the temperature and art…
According to the second law of thermodynamics the total entropy of a system is increased during almost any dynamical process. The positivity of the specific heat implies that the entropy increase is associated with heating. This is generally true both at the single particle level, like in the Fermi acceleration mechanism of charged particles reflected by magnetic mirrors, and for complex systems in everyday devices. Notable exceptions are known in noninteracting systems of particles moving in periodic potentials. Here the phenomenon of dynamical localization can prevent heating beyond certain …
Classically, the power generated by an ideal thermal machine cannot be larger than the Carnot limit. This profound result is rooted in the second law of thermodynamics. A hot question is whether this bound is still valid for microengines operating far from equilibrium. Here, we demonstrate that a quantum chiral conductor driven by AC voltage can indeed work with efficiencies much larger than the Carnot bound. The system also extracts work from common temperature baths, violating Kelvin-Planck statement. Nonetheless, with the proper definition, entropy production is always positive and the seco…
We derive general relations between maximum power, maximum efficiency, and minimum dissipation regimes from linear irreversible thermodynamics. The relations simplify further in the presence of a particular symmetry of the Onsager matrix, which can be derived from detailed balance. The results are illustrated on a periodically driven system and a three terminal device subject to an external magnetic field.
We propose the implementation of a quantum heat pump with ultracold atoms. It is based on two periodically driven coherently coupled quantum dots using ultracold atoms. Each dot possesses two relevant quantum states and is coupled to a fermionic reservoir. The working principle is based on energy-selective driving-induced resonant tunneling processes, where a particle that tunnels from one dot to the other either absorbs or emits the energy quantum $\hbarω$ associated with the driving frequency, depending on its energy. We characterize the device using Floquet theory and compare simple analyti…
Motivated to understand the asymptotic behavior of periodically driven thermodynamic systems, we study the prototypical example of Brownian particle, overdamped and underdamped, in harmonic potentials subjected to periodic driving. The harmonic strength and the coefficients of drift and diffusion are all taken to be $T$-periodic. We obtain the asymptotic distributions almost exactly treating driving nonperturbatively. In the underdamped case, we exploit the underlying $SL_2$ symmetry to obtain the asymptotic state, and study the dynamics and fluctuations of energies and entropy. We further obt…
We consider topological phases in periodically driven (Floquet) systems exhibiting many-body localization, protected by a symmetry $G$. We argue for a general correspondence between such phases and topological phases of undriven systems protected by symmetry $\mathbb{Z} \rtimes G$, where the additional $\mathbb{Z}$ accounts for the discrete time translation symmetry. Thus, for example, the bosonic phases in $d$ spatial dimensions without intrinsic topological order (SPT phases) are classified by the cohomology group $H^{d+1}(\mathbb{Z} \rtimes G, \mathrm{U}(1))$. For unitary symmetries, we int…
A 1D Josephson junction loop, doped with a spin-flipper and attached to two thermal reservoirs, operates as a heat engine or a refrigerator, a Joule pump, or even a cold pump. When operating as a quantum heat engine, the efficiency of this device exceeds that of some recent Josephson heat engine proposals. Further, as a quantum refrigerator, the coefficient of performance of this device is much higher than previously proposed Josephson junction-based refrigerators. In addition, this device can be tuned from engine mode to refrigerator mode or any other mode, i.e., Joule pump or cold pump, by e…
This work explores a fundamental dynamical structure for a wide range of many-body quantum systems under periodic driving. Generically, in the thermodynamic limit, such systems are known to heat up to infinite temperature states after infinite-time evolution, irrespective of dynamical details. In the present study, instead of considering infinitely long-time scale, we aim to provide a framework to understand the long but finite time behavior, namely the transient dynamics. In the analysis, we focus on the Floquet-Magnus (FM) expansion that gives a formal expression of the effective Hamiltonian…
The investigation of optimal processes has a long history in the field of thermodynamics. It is well known that finite-time processes that minimize dissipation often exhibit discontinuities. We use a combination of numerical and analytical approaches to study the driving cycle that maximizes the output in a simple model of a stochastic pump: a system driven out of equilibrium by a cyclic variation of external parameters. We find that this optimal solution is singular, with an infinite rate of switching between sets of parameters. The appearance of such singular solutions in thermodynamic proce…
We study heating rates in strongly interacting quantum lattice systems in the thermodynamic limit. Using a numerical linked cluster expansion, we calculate the energy as a function of the driving time and find a robust exponential regime. The heating rates are shown to be in excellent agreement with Fermi's golden rule. We discuss the relationship between heating rates and, within the eigenstate thermalization hypothesis, the smooth function that characterizes the off-diagonal matrix elements of the drive operator in the eigenbasis of the static Hamiltonian. We show that such a function, in no…
