Recent experiments on semiconductor quantum dots have demonstrated the ability to utilize a large quantum dot to mediate superexchange interactions and generate entanglement between distant spins. This opens up a possible mechanism for selectively coupling pairs of remote spins in a larger network of quantum dots. Taking advantage of this opportunity requires a deeper understanding of how to control superexchange interactions in these systems. Here, we consider a triple-dot system arranged in linear and triangular geometries. We use configuration interaction calculations to investigate the interplay of superexchange and nearest-neighbor exchange interactions as the location, detuning, and electron number of the mediating dot are varied. We show that superexchange processes strongly enhance and increase the range of the net spin-spin exchange as the dots approach a linear configuration. Furthermore, we show that the strength of the exchange interaction depends sensitively on the number of electrons in the mediator. Our results can be used as a guide to assist further experimental efforts towards scaling up to larger, two-dimensional quantum dot arrays.
We study a series-coupled double quantum dot in the Kondo regime modeled by the two-impurity Anderson model and find a new conduction-band mediated superexchange interaction that competes with Kondo physics in the strong Coulomb interaction limit. Our numerical renormalization group results, complemented with the higher-order Rayleigh-Schrödinger perturbation theory, show that the novel exchange mechanism leads to clear experimental consequences that can be checked in transport measurements through double quantum dots.
In a recent preprint arXiv:2203.15521 G. X. Chan, P. Huang, and X. Wang claim that triple-quantum dot superexchange in a (1, 0, 1) charge configuration exhibits a change of sign (going from positive to negative) as a function of middle dot detuning. Furthermore, their claim is that charge sweet-spots exist for specific values of the inter-dot detuning. Their analysis is based on the Hubbard model and something to what they refer to as the full Configuration-Interaction method. All of this findings were already reported by M. J. Rančić and G. Burkard in Ref. Phys. Rev. B 96, 201304(R) (2017) ba…
We propose the interaction of two electrons in a triple quantum dot as a minimal system to control long range superexchange transitions. These are probed by transport spectroscopy. Narrow resonances appear indicating the transfer of charge from one side of the sample to the other with the central one being occupied only virtually. We predict that two different intermediate states establish the two arms of a one dimensional interferometer. Configurations of destructive interference of the two superexchage trajectories totally block the current through the system. We emphasize the role of spin c…
Long range interaction between distant spins is an important building block for the realization of large quantum-dot network in which couplings between pairs of spins can be selectively addressed. Recent experiments on coherent logical states oscillation between remote spins facilitated by intermediate electron states has paved the first step for large scale quantum information processing. Reaching this ultimate goal requires extensive studies on the superexchange interaction on different quantum-dot spatial arrangements and electron configurations. Here, we consider a linear triple-quantum-do…
Because of their long coherence times and potential for scalability, semiconductor quantum-dot spin qubits hold great promise for quantum information processing. However, maintaining high connectivity between quantum-dot spin qubits, which favor linear arrays with nearest neighbor coupling, presents a challenge for large-scale quantum computing. In this work, we present evidence for long-distance spin-chain-mediated superexchange coupling between electron spin qubits in semiconductor quantum dots. We weakly couple two electron spins to the ends of a two-site spin chain. Depending on the spin s…
Quantum gates between spin qubits can be implemented leveraging the natural Heisenberg exchange interaction between two electrons in contact with each other. This interaction is controllable by electrically tailoring the overlap between electronic wavefunctions in quantum dot systems, as long as they occupy neighbouring dots. An alternative route is the exploration of superexchange - the coupling between remote spins mediated by a third idle electron that bridges the distance between quantum dots. We experimentally demonstrate direct exchange coupling and provide evidence for second neighbour …
We study the transport properties of a serial double quantum dot (DQD) coupled to two superconducting leads, focusing on the Josephson current through the DQD and the associated 0-$π$ transitions which result from the subtle interplay between the superconductivity, the Kondo physics, and the inter-dot superexchange interaction. We examine the competition between the superconductivity and the Kondo physics by tuning the relative strength $Δ/T_K$ of the superconducting gap $Δ$ and the Kondo temperature $T_K$, for different strengths of the superexchange coupling determined by the interdot tunnel…
Singlet-triplet states in double quantum dots are promising realizations of qubits, and capacitive coupling can be used to create entanglement between these qubits. We propose an entangling three-qubit gate of singlet-triplet qubits in a triangular setup. Our simulations using a realistic microscopic model show that a maximally entangled Greenberger-Horne-Zeilinger state can be generated as the qubits are evolved under exchange. Furthermore, our analysis for the gate operation can be used to extract the actual experimental pulse sequence needed to realize this.
Results of calculations and high source-drain transport measurements are presented which demonstrate voltage-tunable entanglement of electron pairs in lateral quantum dots. At a fixed magnetic field, the application of a judiciously-chosen gate voltage alters the ground-state of an electron pair from an entagled spin singlet to a spin triplet.
We propose two schemes to coherently transfer arbitrary quantum states of the two-electron singlet-triplet qubit across a chain of 3 quantum dots. The schemes are based on electrical control over the detuning energy of the quantum dots. The first is a pulse-gated scheme, requiring dc pulses and engineering of inter- and intra-dot Coulomb energies. The second scheme is based on the adiabatic theorem, requiring time-dependent control of the detuning energy through avoided crossings at a rate that the system remains in the ground state. We simulate the transfer fidelity using typical experimental…
We present a theoretical proposal of a tunable charge qubit, hosted in triple quantum dots. The manipulation is solely performed by changing the heights of the two potential barriers between the three dots, while the energy of all three dots are fixed. We have found that when the relative height of the two barriers are changed, the direction of the axis of rotation in performing single-qubit gates can be varied. On the other hand, the corresponding rotation speed can be tuned by raising or lowering the two barriers at the same time. Our proposal therefore allows for tunability of both the rota…
We show that singlet-triplet superpositions of two-electron spin states in a double quantum dot undergo a phonon-induced pure dephasing which relies only on the tunnel coupling between the dots and on the Pauli exclusion principle. As such, this dephasing process is independent of spin-orbit coupling or hyperfine interactions. The physical mechanism behind the dephasing is elastic phonon scattering, which persists to much lower temperatures than real phonon-induced transitions. Quantitative calculations performed for a lateral GaAs/AlGaAs gate-defined double quantum dot yield micro-second deph…
The valley degree of freedom presents challenges and opportunities for silicon spin qubits. An important consideration for singlet-triplet states is the presence of two distinct triplets, comprised of valley vs. orbital excitations. Here we show that both of these triplets are present in the typical operating regime, but that only the valley-excited triplet offers intrinsic protection against charge noise. We further show that this protection arises naturally in dots with stronger confinement. These results reveal an inherent advantage for silicon-based multi-electron qubits.
We present a modulated microwave approach for quantum computing with qubits comprising three spins in a triple quantum dot. This approach includes single- and two-qubit gates that are protected against low-frequency electrical noise, due to an operating point with a narrowband response to high frequency electric fields. Furthermore, existing double quantum dot advances, including robust preparation and measurement via spin-to-charge conversion, are immediately applicable to the new qubit. Finally, the electric dipole terms implicit in the high frequency coupling enable strong coupling with sup…
Environmental noise usually hinders the efficiency of charge transport through coherent quantum systems; an exception is dephasing-assisted transport (DAT). We show that linear triple quantum dots in a transport configuration and subjected to pure dephasing exhibit DAT if the coupling to the drain reservoir exceeds a threshold. DAT occurs for arbitrarily weak dephasing and the enhancement can be directly controlled by the coupling to the drain. Moreover, for specific settings, the enhanced current is accompanied by a reduction in relative shot noise. We identify the quantum Zeno effect and lon…
We study theoretically the phonon-induced relaxation and decoherence of spin states of two electrons in a lateral double quantum dot in a SiGe/Si/SiGe heterostructure. We consider two types of singlet-triplet spin qubits and calculate their relaxation and decoherence times, in particular as a function of level hybridization, temperature, magnetic field, spin orbit interaction, and detuning between the quantum dots, using Bloch-Redfield theory. We show that the magnetic field gradient, which is usually applied to operate the spin qubit, may reduce the relaxation time by more than an order of ma…
The creation, coherent manipulation, and measurement of spins in nanostructures open up completely new possibilities for electronics and information processing, among them quantum computing and quantum communication. We review our theoretical proposal for using electron spins in quantum dots as quantum bits. We present single- and two qubit gate mechanisms in laterally as well as vertically coupled quantum dots and discuss the possibility to couple spins in quantum dots via superexchange. We further present the recently proposed schemes for using a single quantum dot as spin-filter and spin re…
We report electronic transport on silicon double and triple dots created with the optimized number of two gates. Using silicon nitride spacers two dots in series are created below two top gates overlapping a silicon nanowire. Coupling between dots is controlled by gate voltages. A third dot is created either by combined action of gate voltages or local doping depending on the spacers length. The main characteristics of the triple dot stability diagram are quantitatively fitted.
Left-handedness with three zero-absorption windows tuned by the incoherent pumping field and inter-dot tunnelings in a GaAs/AlGaAs triple quantum dots system
We theoretically investigate the quantum transport properties of a triangular triple quantum dot (TTQD) ring connected with two reservoirs by means of analytical derivation and accurate hierarchical-equations-of-motion calculation. A bias-induced chiral current in the absence of magnetic field is firstly demonstrated, which results from that the coupling between spin gauge field and spin current in the nonequilibrium TTQD induces a scalar spin chirality that lifts the chiral degeneracy and thus the time inversion symmetry. The chiral current is proved to oscillate with bias within the Coulomb …
We study double quantum dots in a Ge/SiGe heterostructure and test their maturity towards singlet-triplet ($S-T_0$) qubits. We demonstrate a large range of tunability, from two single quantum dots to a double quantum dot. We measure Pauli spin blockade and study the anisotropy of the $g$-factor. We use an adjacent quantum dot for sensing charge transitions in the double quantum dot at interest. In conclusion, Ge/SiGe possesses all ingredients necessary for building a singlet-triplet qubit.
It is demonstrated that parallel weakly coupled quantum dots exhibit non-equilibrium blockade regimes caused by a full occupation in the spin triplet state, in analogy to the Pauli spin blockade in serially weakly coupled quantum dots. Charge tends to accumulate in the two-electron triplet for bias voltages that support transitions between the singlet and three-electron states.
We present a scheme for correcting for crosstalk- and noise-induced errors in exchange-coupled singlet-triplet semiconductor double quantum dot qubits. While exchange coupling allows the coupling strength to be controlled independently of the intraqubit exchange couplings, there is also the problem of leakage, which must be addressed. We show that, if a large magnetic field difference is present between the two qubits, leakage is suppressed. We then develop pulse sequences that correct for crosstalk- and noise-induced errors and present parameters describing them for the 24 Clifford gates. We …
We study the triplet-singlet relaxation in two-electron semiconductor quantum dots. Both single dots and vertically coupled double dots are discussed. In our work, the electron-electron Coulomb interaction, which plays an important role in the electronic structure, is included. The spin mixing is caused by spin-orbit coupling which is the key to the triplet-singlet relaxation. We show that the selection rule widely used in the literature is incorrect unless near the crossing/anticrossing point in single quantum dots. The triplet/singlet relaxation in double quantum dots can be markedly changed…
The fluctuation behavior of triple quantum dots (TQDs) has, so far, largely focused on current cumulants in the long-time limit via full counting statistics. Given that (TQDs) are non-trivial open quantum systems with many interesting features, such as Aharonov-Bohm interference and coherent population blocking, new fluctuating-time statistics, such as the waiting time distribution (WTD), may provide more information than just the current cumulants alone. In this paper, we use a Born-Markov master equation to calculate the standard and higher-order WTDs for coherentlycoupled TQDs arrayed in tr…
Weakly coupled quantum dots in the Pauli spin blockade regime are considered with respect to spin-dependent transport. By attaching one half-metallic and one non-magnetic lead, the Pauli spin blockade if formed by a pure triplet state with spin moment $S_z=1$ or -1. Furthermore, additional spin blockade regimes emerge because of full occupation in states with opposite spin to that of the half-metallic lead.
We apply an elementary measurement scheme to calculate the electronic triplet-singlet transition mediated by hyperfine interaction in a double quantum dot. We show how the local character of the hyperfine interaction and the nuclear back-action process (flip-flop) are crucial to cancel destructive interferences of the triplet-singlet transition probability. It is precisely this cancellation which differentiates the hyperfine interaction from an anisotropic magnetic field which mixes the triplet and the singlet eigenstates.
A fundamental question in quantum transport is how quantum coherence influences charge transfer through nanostructures. We address this issue for linear triple quantum dots by comparison of a Lindblad density matrix description with a Pauli rate equation approach and analyze the corresponding zero-frequency counting statistics for coherent and sequential charge tunneling, respectively. The impact of decaying coherences of the density matrix due to dephasing is also studied. Our findings reveal that the sensitivity to coherence shown by shot noise and skewness, in particular in the limit of lar…
We estimate the triplet-singlet relaxation rate due to spin-orbit coupling assisted by phonon emission in weakly-confined quantum dots. Our results for two and four electrons show that the different triplet-singlet relaxation trends observed in recent experiments under magnetic fields can be understood within a unified theoretical description, as the result of the competition between spin-orbit coupling and phonon emission efficiency. Moreover, we show that both effects are greatly affected by the strength of the confinement and the external magnetic field, which may give access to very long-l…
Graphene is a nonmagnetic semimetal and cannot be directly used as electronic or spintronic devices. We demonstrate that graphene quantum dots (GQDs) can exhibit strong edge magnetism and tunable energy gaps due to the presence of localized edge states. By using large-scale first principle density functional theory (DFT) calculations and detailed analysis based on model Hamiltonians, we can show that the zigzag edge states in GQDs become much stronger and more localized as the system size increases. The enhanced edge states induce strong electron-electron interactions along the edges of GQDs, …
An important requirement for spin-based quantum information processing is reliable and fast readout of electron spin states, allowing for feedback and error correction. However, common readout techniques often require additional gate structures hindering device scaling or impose stringent constraints on the tuning configuration of the sensed quantum dots. Here, we operate an in-line charge sensor within a triple quantum dot, where one of the dots is coupled to a microwave cavity and used to readout the charge states of the other two dots. Owing to the proximity of the charge sensor, we observe…
Electronic transport through a triple quantum dot system, with only a single dot coupled directly to external leads, is considered theoretically. The model includes Coulomb correlations in the central dot, while such correlations in the two side-coupled dots are omitted. The infinite-U mean-field slave-boson approach is used to obtain basic transport characteristics in the Kondo regime. When tuning position of the side-coupled dots' levels, transition from subradiant to superradiant like mode (and vice versa) has been found in the spectral function, in analogy to the Dicke effect in atomic phy…
We consider a quantum dot embedded in a three-dimensional nanowire with tunable aspect ratio a. A configuration interaction theory is developed to calculate the energy spectra of the finite 1D quantum dot systems charged with two electrons in the presence of magnetic fields B along the wire axis. Fruitful singlet-triplet transition behaviors are revealed and explained in terms of the competing exchange interaction, correlation interaction, and spin Zeeman energy. In the high aspect ratio regime, the singlet-triplet transitions are shown designable by tuning the parameters a and B. The transiti…
We analyze transport through both a double quantum dot and a triple quantum dot with inhomogeneous Zeeman splittings in the presence of crossed dc and ac magnetic fields. We find that strongly spin-polarized current can be achieved by tuning the relative energies of the Zeeman-split levels of the dots, by means of electric gate voltages: depending on the energy level detuning, the double quantum dot works either as spin-up or spin-down filter. We show that a triple quantum dot in series under crossed dc and ac magnetic fields can act not only as spin-filter but also as spin-inverter.
We analyze coherent spin phenomena in triple quantum dots in triangular configuration under crossed DC and AC magnetic fields. In particular, we discuss the interplay between Aharonov-Bohm current oscillations, coherent electron trapping and spin blockade under electron spin resonance conditions. We demonstrate that, for certain field frequencies, AC magnetic fields induce an antiresonant behavior in the current, allowing for both removal and restoration of entangled spin blockaded states by tuning the AC field frequency. Our theoretical predictions indicate how to manipulate spin qubits in a …
Charged impurities in semiconductor quantum dots comprise one of the main obstacles to achieving scalable fabrication and manipulation of singlet-triplet spin qubits. We theoretically show that using dots that contain several electrons each can help to overcome this problem through the screening of the rough and noisy impurity potential by the excess electrons. We demonstrate how the desired screening properties turn on as the number of electrons is increased, and we characterize the properties of a double quantum dot singlet-triplet qubit for small odd numbers of electrons per dot. We show th…
Preparation and transfer of quantum states is a fundamental task in quantum information. We propose a protocol to prepare a state in the left and center quantum dots of a triple dot array and transfer it directly to the center and right dots. Initially the state in the left and center dots is prepared combining the exchange interaction and magnetic field gradients. Once in the desired state, ac gate voltages in the outer dots are switched on, allowing to select a given photoassisted long-range path and to transfer the prepared state directly from one edge to the other with high fidelity. We in…
The singlet-triplet relaxation in nanowire-based quantum dots induced by confined phonons is investigated theoretically. Due to the quasi-one-dimensional nature of the confined phonons, the singlet-triplet relaxation rates exhibit multi-peaks as function of magnetic field and the relaxation rate between the singlet and the spin up triplet state is found to be enhanced at the vicinity of the singlet-triplet anti-crossing. We compare the effect of the deformation-potential coupling and the piezoelectric coupling and find that the deformation-potential coupling dominates the relaxation rates in m…
Coherent interactions at a distance provide a powerful tool for quantum simulation and computation. The most common approach to realize an effective long-distance coupling 'on-chip' is to use a quantum mediator, as has been demonstrated for superconducting qubits and trapped ions. For quantum dot arrays, which combine a high degree of tunability with extremely long coherence times, the experimental demonstration of coherent spin-spin coupling via an intermediary system remains an important outstanding goal. Here, we use a linear triple-quantum-dot array to demonstrate a first working example o…
Tunneling in a quantum coherent structure is not restricted to only nearest neighbours. Hopping between distant sites is possible via the virtual occupation of otherwise avoided intermediate states. Here we report the observation of long range transitions in the transport through three quantum dots coupled in series. A single electron is delocalized between the left and right quantum dots while the centre one remains always empty. Superpositions are formed and both charge and spin are exchanged between the outermost dots. Detection of the process is achieved via the observation of narrow reson…
We report highly tunable control of holes in Ge/Si core/shell nanowires (NWs). We demonstrate the ability to create single quantum dots (QDs) of various sizes, with low hole occupation numbers and clearly observable excited states. For the smallest dot size we observe indications of single-hole occupation. Moreover, we create double and triple tunnel-coupled quantum dot arrays. In the double quantum dot configuration we observe Pauli spin blockade (PSB). These results open the way to perform hole spin qubit experiments in these devices.
A spin qubit in semiconductor quantum dots holds promise for quantum information processing for scalability and long coherence time. An important semiconductor qubit system is a double quantum dot trapping two electrons or holes, whose spin states encode either a singlet-triplet qubit or two single-spin qubits coupled by exchange interaction. In this article, we report progress on spin dephasing of two exchange-coupled spins in a double quantum dot. We first discuss the schemes of two-qubit gates and qubit encodings in gate-defined quantum dots or donor atoms based on the exchange interaction.…
We show that spin-orbit coupling in a quantum dot molecule allows for coherent manipulation of two electron spin states using Raman transitions. Such two-electron spin states defined by the singlet and triplet states of two exchange coupled quantum dots can have favorable coherence properties. In addition, two of the four metastable ground states in this system can be used as auxiliary states that could facilitate implementation of tasks such as mapping of spin states to that of a single propagating photon. We find that even weak spin-orbit effects -- manifesting themselves as slightly differe…
Although individual spins in quantum dots have been studied extensively as qubits, their investigation under strong resonant driving in the scope of accessing Mollow physics is still an open question. Here, we have grown high quality positively charged quantum dots embedded in a planar microcavity that enable enhanced light-matter interactions. Under a strong magnetic field in the Voigt configuration, individual positively charged quantum dots provide a double-lambda level structure. Using a combination of above-band and resonant excitation, we observe the formation of Mollow triplets on all o…
Strong electron and spin correlations are studied in parallel-coupled double quantum dots with interdot spin superexchange $J$. In the Kondo regime with {\it}{degenerate} dot energy levels, a coherent transport occurs at zero temperature, where two entangled (bonding and antibonding) resonances are formed near the Fermi energy. When increasing $J$ or the dot-lead parallel-coupling \QTR{it}{asymmetry} ratio $Γ_{2}/Γ_{1}$, a swap between two entangled resonances occurs and the line shapes of the linear conductance are interchanged. The zero-bias differential conductance shows a peak at the criti…
We study electron-phonon interaction induced decoherence between two-electron singlet and triplet states in a semiconductor double quantum dot using a spin-boson model. We investigate the onset and time evolution of this dephasing, and study its dependence on quantum dot parameters such as dot size and double dot separations, as well as the host materials (GaAs and Si). At the short time limit, electron-phonon interaction only causes an incomplete initial Gaussian decay of the off-diagonal density matrix element in the singlet-triplet Hilbert space. A complete long-time exponential decay due t…
We consider the transport through a system of three coupled quantum dots in a perpendicular magnetic field. At zero field, destructive interference can trap an electron in a dark state -- a coherent superposition of dot states that completely blocks current flow. The magnetic field can disrupt this interference giving rise to oscillations in the current and its higher-order statistics as the field is increased. These oscillations have a period of either the flux-quantum or half the flux-quantum, depending on the dot geometry. We give results for the stationary current and for the shotnoise and…
We investigate the Josephson effect in one triple-terminal junction with embedded parallel-coupled double quantum dots. It is found that the inter-superconductor supercurrent has opportunities to oscillate in $4π$ period, with the adjustment of the phase differences among the superconductors. What is notable is that such a result is robust and independent of fermion parities, intradot Coulomb strength, and the dot-superconductor coupling manner. By introducing the concept of spinful many-particle Majorana modes, we present the analytical definition of the Majorana operator via superposing elec…
We calculate, via spin density functional theory (SDFT) and exact diagonalization, the eigenstates for electrons in a variety of external potentials, including double and triple dots. The SDFT calculations employ realistic wafer profiles and gate geometries and also serve as the basis for the exact diagonalization calculations. The exchange interaction J between electrons is the difference between singlet and triplet ground state energies and reflects competition between tunneling and the exchange matrix element, both of which result from overlap in the barrier. For double dots, a characterist…
Spin qubits involving individual spins in single quantum dots or coupled spins in double quantum dots have emerged as potential building blocks for quantum information processing applications. It has been suggested that triple quantum dots may provide additional tools and functionalities. These include the encoding of information to either obtain protection from decoherence or to permit all-electrical operation, efficient spin busing across a quantum circuit, and to enable quantum error correction utilizing the three-spin Greenberger-Horn-Zeilinger quantum state. Towards these goals we demonst…
In the semi-conductor double quantum dot singlet-triplet qubit architecture, the decoherence caused by the qubit's charge environment poses a serious obstacle in the way towards large scale quantum computing. The effects of the charge decoherence can be mitigated by operating the qubit in the so called sweet spot regions where it is insensitive to electrical noise. In this paper, we propose singlet-triplet qubits based on two quantum dots of different sizes. Such asymmetric double dot systems allow the implementation of exchange gates with controllable exchange splitting $J$ operated in the do…
We present a theory of quantum circuits based on logical qubits encoded in chirality of electron spin complexes in lateral gated semiconductor triple quantum dot molecules with one electron spin in each dot. Using microscopic Hamiltonian we show how to initialize, coherently control and measure the quantum state of a chirality based coded qubit using static in-plane magnetic field and voltage tuning of individual dots. The microscopic model of two interacting coded qubits is established and mapped to an Ising Hamiltonian, resulting in conditional two-qubit phase gate.
The effect of long distance coherent tunneling (LDCT) on the charge and heat currents in serially coupled triple quantum dots (TQDs) connected to electrodes is illustrated by using a combination of the extended Hurbbard model and Anderson model. The charge and heat currents are calculated with a closed-form Landauer expression for the transmission coefficient suitable for the Coulomb blockade regime. The physical parameters including bias-dependent quantum dot energy levels, electron Coulomb interactions, and electron hopping strengths are calculated in the framework of effective mass theory f…
Orbital modeling of two electron spins confined in a double quantum dot is revisited. We develop an extended Hund Mulliken approach that includes excited orbitals, allowing for a triplet configuration with both electrons residing in a single dot. This model improves the reliability and applicability of the standard Hund Mulliken approximation, while remaining largely analytical, thus it enables us to identify the mechanisms behind the exchange coupling dynamics that we find. In particular, our calculations are in close agreement with exchange values that were recently measured at a high interd…
Few-electron quantum dots are investigated in the regime of strong tunneling to the leads. Inelastic cotunneling is used to measure the two-electron singlet-triplet splitting above and below a magnetic field driven singlet-triplet transition. Evidence for a non-equilibrium two-electron singlet-triplet Kondo effect is presented. Cotunneling allows orbital correlations and parameters characterizing entanglement of the two-electron singlet ground state to be extracted from dc transport.
