There is a tacit assumption that multiband superconductors are essentially the same as multigap superconductors. More precisely, it is usually assumed that the number of excitation gaps in the single-particle energy spectrum of a uniform superconductor determines the number of contributing bands in the corresponding superconducting model. Here we demonstrate that contrary to this widely accepted viewpoint, the superconducting magnetic properties are sensitive to the number of contributing bands even when the corresponding excitation gaps are degenerate and cannot be distinguished. In particular, we find that the crossover between superconductivity types I and II - the intertype regime - is strongly affected by difference between characteristic lengths of multiple contributing condensates. The reason for this is that condensates with diverse characteristic lengths coexisting in one system interfere constructively or destructively, which results in multi-condensate magnetic phenomena regardless of the presence/absence of the multigap structure in the single-particle excitation spectrum.
We present results of in field directional point contact spectroscopy (DPCS) study in the quaternary borocarbide superconductor YNi2B2C, which is characterized by a highly anisotropic superconducting gap function. For I||a, the superconducting energy gap (D), decreases linearly with magnetic field and vanishes around 3.25T which is well below the upper critical field (Hc2~6T) measured at the same temperature (2.2K). For I||c, on the other hand, D decreases weakly with magnetic field but the broadening parameter (G) increases rapidly with magnetic field with the absence of any resolvable featur…
Recently, a test for a sign-changing gap function in a candidate multiband unconventional superconductor involving quasiparticle interference data was proposed. The test was based on the antisymmetric, Fourier transformed conductance maps integrated over a range of momenta $\bf q$ corresponding to interband processes, which was argued to display a particular resonant form, provided the gaps changed sign between the Fermi surface sheets connected by $\bf q$. The calculation was performed for a single impurity, however, raising the question of how robust this measure is as a test of sign-changin…
I solved the Eliashberg equations for multiband non-phononic $s\pm$ wave spin glass superconductor and I calculated the temperature dependence of the gaps and superfluid density that reveals unusual behavior as non monotonic temperature dependence and reentrant superconductivity. For particular values of input parameters the phase diagram is still more complex with two different ranges of temperature where the superconductivity appears.
We report a detailed low-temperature thermodynamic investigation (heat capacity and magnetization) of the superconducting state of KFe2As2 for H || c axis. Our measurements reveal that the properties of KFe2As2 are dominated by a relatively large nodeless energy gap (Delta?0 = 1.9 kBTc) which excludes dx2-y2 symmetry. We prove the existence of several additional extremely small gaps (?Delta0 < 1.0 kBTc) that have a profound impact on the low-temperature and low-field behavior, similar to MgB2, CeCoIn5 and PrOs4Sb12. The zero-field heat capacity is analyzed in a realistic self-consistent 4-band…
A theory of the proximity effect in normal metal - multiband superconductor hybrid structures is formulated within the quasiclassical Green's function formalism. It is shown that the existence of multiple superconducting bands manifests itself as the occurence of additional peaks in the density of states in the structure. The interplay between the proximity effect and the interband coupling influences the magnitudes of the gaps in a superconductor in a non-trivial way. The developed theory is applied to the calculation of supercurrent in multiband Superconductor - Normal metal - Superconductor…
We study the dependence of the superconducting gaps on both the disorder and the temperature within the two-band model for iron-based materials. In the clean limit, the system is in the $s_\pm$ state with the sign-changing gaps. Scattering by nonmagnetic impurities leads to the change of sign of the smaller gap thus resulting in a transition from the $s_{\pm}$ to the $s_{++}$ state with the sign-preserving gaps. We show here that the transition is temperature-dependent, thus, there is a line of $s_\pm \to s_{++}$ transition in the temperature-disorder phase diagram. There exists a narrow range…
This article reviews theoretical and experimental work on the novel physics in multiband superconductors. Multiband superconductors are characterized by multiple superconducting energy gaps in different bands with interaction between Cooper pairs in these bands. The discovery of prominent multiband superconductors $\mathrm{MgB_2}$ and later iron-based superconductors has triggered enormous interests in multiband superconductors. Most recently discovered superconductors exhibit multiband features. The multiband superconductors possess novel properties that are not shared by their single-band co…
We examine the effect of a single, non-magnetic impurity in a multiband, extended s-wave superconductor allowing for anisotropy of the gaps on the Fermi surfaces. We derive analytic expressions for the Green's functions in the continuum and analyse the conditions for the existence of sharp impurity-induced resonant states. Underlying band structure is more relevant for the multiband than for single band case, and mismatch between the bands generically makes the formation of the impurity states less likely in the physical regime of parameters. We confirm these conclusions by numerically solving…
We investigate how hybridization (single-quasiparticle scattering) between two superconducting bands induces odd-frequency superconductivity in a multiband superconductor. An explicit derivation of the odd-frequency pairing correlation and its full frequency dependence is given. We find that the density of states is modified, from the sum of the two BCS spectra, at higher energies by additional hybridization gaps with strong coherence peaks when odd-frequency pairing is present.
We further investigate a class of time-reversal-invariant two-band s-wave topological superconductors introduced in Phys. Rev. Lett. 108, 036803 (2012). We show how, in the presence of time-reversal symmetry, Z_2 invariants that distinguish between trivial and non-trivial quantum phases can be constructed by considering only one of the Kramers' sectors in which the Hamiltonian decouples into. We find that the main features identified in our original 2D setting remain qualitatively unchanged in 1D and 3D, with non-trivial topological superconducting phases supporting an odd number of Kramers' p…
We report point contact Andreev Reflection (PCAR) measurements on a high-quality single crystal of the non-centrosymmetric superconductor Re6Zr. We observe that the PCAR spectra can be fitted by taking two isotropic superconducting gaps with Delta_1 ~ 0.79 meV and Delta_2 ~ 0.22 meV respectively, suggesting that there are at least two bands which contribute to superconductivity. Combined with the observation of time reversal symmetry breaking at the superconducting transition from muon spin relaxation measurements (Phys. Rev. Lett. 112, 107002 (2014)), our results imply an unconventional super…
In this article we review recent progress in the understanding of multiband superconductivity and its relationship to odd-frequency pairing. We begin our discussion by reviewing the emergence of odd-frequency pairing in a simple two-band model, providing a brief pedagogical overview of the formalism. We then examine several examples of multiband superconducting systems in each case describing, both, the origin of the band degree of freedom and the nature of the odd-frequency pairing. Throughout, we attempt to convey a unified picture of how odd-frequency pairing emerges in these materials and …
We present measurements of the specific heat coefficient γ(= C/T) in the low temperature limit as a function of an applied magnetic field for the Fe-based superconductor BaFe$_2$(As$_{0.7}$P$_{0.3}$)$_2$. We find both a linear regime at higher fields and a limiting square root $H$ behavior at very low fields. The crossover from a Volovik-like $\sqrt{H}$ to a linear field dependence can be understood from a multiband calculation in the quasiclassical approximation assuming gaps with different momentum dependence on the hole- and electron-like Fermi surface sheets.
Resonances in the superconducting properties, in a regime of crossover from BCS to mixed Bose-Fermi superconductivity, are investigated in a two-band superconductor where the chemical potential is tuned near the band edge of the second mini-band generated by quantum confinement effects. The shape resonances at T=0 in the superconducting gaps (belonging to the class of Feshbach-like resonances) is manifested by interference effects in the superconducting gap at the first large Fermi surface when the chemical potential is in the proximity of the band edge of the second mini-band. The case of a s…
The recently discovered multiband superconductors have created a new class of novel superconductors. In these materials multiple superconducting gaps arise due to the formation of Cooper pairs on different sheets of the Fermi surfaces. An important feature of these superconductors is the interband couplings, which not only change the individual gap properties, but also create new collective modes. Here we investigate the effect of the interband couplings in the Ginzburg-Landau theory. We produce a general $τ^{(2n+1)/2}$ expansion ($τ= 1-T/T_c$) and show that this expansion has unexpected behav…
We present very low temperature scanning tunneling microscopy (STM) experiments on single crystalline samples of the superconductor $β$-Bi$_2$Pd. We find a single fully isotropic superconducting gap. However, the magnetic field dependence of the intervortex density of states is higher than the one expected in a single gap superconductor, and the hexagonal vortex lattice is locked to the square atomic lattice. Such increase in the intervortex density of states and vortex lattice locking have been found in superconductors with multiple superconducting gaps and anisotropic Fermi surfaces. We comp…
We consider the effect of isotropic impurity scattering on the exotic superconducting states that arise from the usual BCS mechanism in substances of cubic and hexagonal symmetry where the Fermi surface contains inequivalent but degenerate pockets (e.g. around several points of high symmetry). As examples we look at CeCo$_2$, CeRu$_2$, and LaB$_6$; all of which have such Fermi surface topologies and the former exhibits unconventional superconducting behavior. We find that while these non s-wave states are suppressed by non-magnetic impurities, the suppression is much weaker than would be expec…
The thermal conductivity of the layered s-wave superconductor NbSe_2 was measured down to T_c/100 throughout the vortex state. With increasing field, we identify two regimes: one with localized states at fields very near H_c1 and one with highly delocalized quasiparticle excitations at higher fields. The two associated length scales are most naturally explained as multi-band superconductivity, with distinct small and large superconducting gaps on different sheets of the Fermi surface.
The superconductivity of a kagome superconductor CsV3Sb5 is studied by scanning tunneling microscopy / spectroscopy at an ultralow temperature with high resolution. Two kinds of superconducting gaps with multiple sets of coherent peaks and residual zero-energy density of states are observed on both half-Cs and Sb surfaces, implying multiband superconductivity with gap nodes. Sixfold star-shaped magnetic vortex is observed with conventional Caroli-de Gennes-Matricon bound states inside. Magnetic impurities suppress the superconductivity, while nonmagnetic impurities do not, suggesting the absen…
We report 31P-NMR and specific heat measurements on an iron (Fe)-based superconductor SrFe2(As0.65P0.35)2 with Tc=26 K, which have revealed the development of antiferromagnetic correlations in the normal state and the unconventional superconductivity(SC) with nodal gap dominated by the gapless low-lying quasiparticle excitations. The results are consistently argued with an unconventional multiband SC state with the gap-size ratio of different bands being significantly large; the large full gaps in s\pm-wave state keep Tc high, whereas a small gap with a nodal-structure causes gapless feature u…
The in-plane thermal conductivity of iron-based superconductor Ca$_{10}$(Pt$_{4-δ}$As$_8$)((Fe$_{1-x}$Pt$_{x}$)$_2$As$_2$)$_5$ single crystal (``10-4-8", $T_c$ = 22 K) was measured down to 80 mK. In zero field, the residual linear term $κ_0/T$ is negligible, suggesting nodeless superconducting gaps in this multiband compound. In magnetic fields, $κ_0/T$ increases rapidly, which mimics those of multiband superconductor NbSe$_2$ and LuNi$_2$B$_2$C with highly anisotropic gap. Such a field dependence of $κ_0/T$ is an evidence for multiple superconducting gaps with quite different magnitudes or hi…
In multiband superconductors, multiple collective modes exist associated with the multiple order parameters. Oscillations of the amplitude and the relative phase of the order parameters are called Higgs and Leggett modes, respectively. Recently, it has been suggested that nonmagnetic impurity scattering would enhance nonlinear coupling between the Higgs mode and an electromagnetic wave with a frequency located in the superconducting gap region, while its effect on the Leggett mode is still unresolved. Here, we theoretically investigated the nonlinear optical response of multiband Bardeen-Coope…
We develop a theory of the quasiparticle interference (QPI) in multiband superconductors based on strong-coupling Eliashberg approach within the Born approximation. In the framework of this theory, we study dependencies of the QPI response function in the multiband superconductors with nodeless s-wave superconductive order parameter. We pay a special attention to the difference of the quasiparticle scattering between the bands having the same and opposite signs of the order parameter. We show that, at the momentum values close to the momentum transfer between two bands, the energy dependence o…
We study multigap superconductivity, with strong angular variations of one of the gaps, as appropriate for certain iron-based high-temperature superconductors. We solve the gap equations of this model and find that the nodes or zeroes in the gap function present at Tc - although purely accidental -- typically survive down to T=0. Based on this result, we investigate the line of quantum transitions at which gap zeroes first appear. The peculiar "zero-point" critical scaling emanating from this line dominates quasiparticle thermodynamics and transport properties over much of the phase diagram, a…
We study the nonequilibrium dynamics of multiband BCS superconductors subjected to ultrashort pump pulses. Using density-matrix theory, the time evolution of the Bogoliubov quasiparticle densities and the superconducting order parameters are computed as a function of pump pulse frequency, duration, and intensity. Focusing on two-band superconductors, we consider two different model systems. The first one, relevant for iron-based superconductors, describes two-band superconductors with a repulsive interband interaction $V_{12}$ which is much larger than the intraband pairing terms. The second m…
Experimental support is found for the multiband model of the superconductivity in the recently discovered system MgB2 with the transition temperature Tc = 39 K. By means of Andreev reflection evidence is obtained for two distinct superconducting energy gaps. The sizes of the two gaps (Delta_S = 2.8 meV and Delta_L = 7 meV) are respectively smaller and larger than the expected weak coupling value. Due to the temperature smearing of the spectra the two gaps are hardly distinguishable at elevated temperatures but when a magnetic field is applied the presence of two gaps can be demonstrated close …
We argue that a multiband superconductor with sign-changing gaps may have multiple spin resonances. We calculate the RPA-based spin resonance spectra of a pnictide superconductor by using the five band tight-binding model or angle-resolved photoemission spectroscopy (ARPES) Fermi surface (FS) and experimental values of superconducting (SC) gaps. The resonance spectra split in both energy and momenta due to the effects of multiband and multiple gaps in $s^{\pm}-$pairing; the higher energy peak appears around the commensurate momenta due to scattering between $α-$FS to $γ/δ-$FS pockets. The seco…
We discuss the shape resonance in the superconducting gaps of a two band superconductor by tuning the chemical potential at a Lifshitz transition for Femi surface neck collapsing and for spot appearing. The high temperature superconducting scenario for complex matter shows the coexistence of a first BCS condensate made of Cooper pairs in the first band and a second boson-like condensate made of bosons like bipolarons, in the second band where the chemical potential is tuned near a Lifshitz transition. The interband coupling controls the shape resonance in the pair exchange between the two cond…
Nb doped SrTiO3, the first discovered two-gap superconductor, is shown to be the most unconventional one of the known multiband superconductors, since the smaller of the two superconducting gaps follows a non BCS temperature dependence. Such a behavior stems from two cooperating effects: an extreme anisotropy in the frequency dependent interactions, involving one very soft mode and an almost vanishing interband interaction. In contrast to all other multiband superconductors, the temperature dependence of the superfluid density of Nb doped SrTiO3 is predicted to exhibit an inflection point clos…
We present extensive Scanning Tunneling Spectroscopy (STM/S) measurements at low temperatures in the multiband superconductor MgB$_2$. We find a similar behavior in single crystalline samples and in single grains, which clearly shows the partial superconducting density of states of both the $π$ and $σ$ bands of this material. The superconducting gaps corresponding to both bands are not single valued. Instead, we find a distribution of superconducting gaps centered around 1.9mV and 7.5mV, corresponding respectively to each set of bands. Interband scattering effects, leading to a single gap stru…
The detailed optical properties of the multiband iron-chalcogenide superconductor FeTe$_{0.55}$Se$_{0.45}$ have been reexamined for a large number of temperatures above and below the critical temperature $T_c=14$ K for light polarized in the a-b planes. Instead of the simple Drude model that assumes a single band, above $T_c$ the normal-state optical properties are best described by the two-Drude model that considers two separate electronic subsystems; we observe a weak response ($ω_{p,D;1}\simeq 3000$ cm$^{-1}$) where the scattering rate has a strong temperature dependence ($1/τ_{D,1}\simeq 3…
I calculated the effect of magnetic impurities on the normal and superconductive properties of a multiband s-wave superconductor by direct solution of the two-band Eliashberg equations. In this way I determined the critical temperature, the values of the superconductive gaps, the shape of the superconductive density of states and other physical quantities that depend on the concentration of magnetic impurities. I found that the gaps and the penetration lengths display an unusual behaviour as a function of temperature. I examine the possibility that the presence of a negative induced gap raises…
We study the spin resonance in superconducting state of iron-based materials within multiband models with two unequal gaps, $Δ_L$ and $Δ_S$, on different Fermi surface pockets. We show that due to the indirect nature of the gap entering the spin susceptibility at the nesting wave vector $\mathbf{Q}$ the total gap $\tildeΔ$ in the bare susceptibility is determined by the sum of gaps on two different Fermi surface sheets connected by $\mathbf{Q}$. For the Fermi surface geometry characteristic to the most of iron pnictides and chalcogenides, the indirect gap is either $\tildeΔ= Δ_L + Δ_S$ or $\ti…
High Tc superconductivity in FeAs-based multilayers (pnictides), evading temperature decoherence effects in a quantum condensate, is assigned to a Feshbach resonance (called also shape resonance) in the exchange-like interband pairing. The resonance is switched on by tuning the chemical potential at an electronic topological transition (ETT) near a band edge, where the Fermi surface topology of one of the subbands changes from 1D to 2D topology. We show that the tuning is realized by changing i) the misfit strain between the superconducting planes and the spacers ii) the charge density and iii…
Recent angle-resolved photoemission spectroscopy measurements of Co-doped LiFeAs report a large and robust superconducting gap on the $Γ$-centered hole band that lies 8 meV below the Fermi level. We show that, unlike a conventional superconductor described by BCS theory, a multiband system with strong interband Coulomb interactions can explain these observations. We model LiFeAs with a five-band model in which the shallow hole band is coupled with the other bands by only Coulomb interactions. Using Eliashberg theory, we find reasonable interaction parameters that reproduce the $T_c$ and all fi…
Intermetallic R$_3$T$_4$X$_{13}$ series consists of cage like structure and have been in focus due to their unconventional electronic ground states. In this work, we report the normal and superconducting state properties of a high quality single crystal of Lu$_3$Os$_4$Ge$_{13}$. Lu$_3$Os$_4$Ge$_{13}$ belongs to the above mentioned series and crystallizes in a cubic crystal structure with the space group $\it{Pm\bar{3}n}$. Using electrical transport, magnetization and heat capacity measurements, we show that Lu$_3$Os$_4$Ge$_{13}$ is a type-II multi-band superconductor ($T{_c} =3.1$~K) with unus…
Survival of the metallic state in a single-hole multiband $p$-orbital molecular system
Osaka Metropolitan University（大阪公立大学）；University of California, Berkeley（加州大学伯克利分校）；National Institute of Standards and Technology (NIST)（美国国家标准与技术研究院）；Aristotle University of Thessaloniki（塞萨洛尼基亚里士多德大学）；Institute “Jožef Stefan”（约泽夫史丹福研究所）；Japan Synchrotron Radiation Research Institute (JASRI)（日本同步辐射研究机构）；RIKEN SPring-8 Center（理化学研究所SPring-8中心）；National Synchrotron Radiation Research Center（国家同步辐射研究中心）；Oak Ridge National Laboratory（橡树岭国家实验室）；University of Ljubljana（卢布尔雅那大学）
Although the pairing mechanism of the Fe-based superconductors (FeSCs) has not yet been settled with a consensus, as to the pairing symmetry and the superconducting (SC) gap function, the abundant majority of experiments are supporting for the spin-singlet sign-changing s-wave SC gaps on multibands ($s^{\pm}$-wave state). This multiband $s^{\pm}$-wave state is a very unique gap state {\it per se} and displays numerous unexpected novel SC properties such as a strong reduction of the coherence peak, non-trivial impurity effects, nodal-gap-like nuclear magnetic resonance (NMR) signals, various Vo…
Recent discovery of superconductivity in YbRh$_2$Si$_2$ has raised particular interest in its pairing mechanism and gap symmetry. Here we propose a phenomenological theory of its superconductivity and investigate possible gap structures by solving the multiband Eliashberg equations combining realistic Fermi surfaces from first-principles calculations and a quantum critical form of magnetic pairing interactions. The resulting gap symmetry shows sensitive dependence on the in-plane propagation wave vector of the quantum critical fluctuations, suggesting that superconductivity in YbRh$_2$Si$_2$ i…
The physical origin of cuprate high-temperature superconductor pseudogaps remains debatable. We point out that the indication of such excitation is hidden in the usual expression for the quasiparticle energy. It can be realized on a suitable multiband spectrum with an interband pairing channel. The band components bearing the chemical potential manifest superconducting gaps. A band with the Fermi energy outside creates a pseudogap type excitation. The latter does not characterize the pairing strength. On a doping-driven spectral arrangement the nature of low-energy excitations changes with dop…
An orbitally degenerate two-band Hubbard model is analyzed with inclusion of the Hund's rule induced spin-triplet paired states and their coexistence with magnetic ordering. The so-called statistically consistent Gutzwiller approximation (SGA) has been applied to the case of a square lattice. The superconducting gaps, the magnetic moment, and the free energy are analyzed as a function of the Hund's rule coupling strength and the band filling. Also, the influence of the intersite hybridization on the stability of paired phases is discussed. In order to examine the effect of correlations the res…
We show that electronic Raman scattering affords a window into the essential properties of the pairing potential $V_{\mathbf{k},\mathbf{k^{\prime}}}$ of iron-based superconductors. In Ba$_{0.6}$K$_{0.4}$Fe$_2$As$_2$ we observe band dependent energy gaps along with excitonic Bardasis-Schrieffer modes characterizing, respectively, the dominant and subdominant pairing channel. The $d_{x^2-y^2}$ symmetry of all excitons allows us to identify the subdominant channel to originate from the interaction between the electron bands. Consequently, the dominant channel driving superconductivity results fro…
To probe manifestations of multiband superconductivity in oxypnictides, we measured the angular dependence of magnetic torque $τ(θ)$ in the mixed state of SmO$_{0.8}$F$_{0.2}$FeAs single crystals as functions of temperature $T$ and high magnetic field $H$ up to 30 T. We show that the effective mass anisotropy parameter $γ$ extracted from $τ(θ)$, can be greatly overestimated if the strong paramagnetism of Sm or Fe ions is not properly taken into account. The correctly extracted $γ$ depends on both $T$ and $H$, saturating at $γ\simeq 9$ at lower temperatures. Neither the London penetration depth…
We demonstrate that a Weyl point, widely examined in 3D Weyl semimetals and superfluids, can develop a pair of non-degenerate gapless spheres. Such a bouquet of two spheres is characterized by three distinct topological invariants of manifolds with full energy gaps, i.e., the Chern number of a 0D point inside one developed sphere, the winding number of a 1D loop around the original Weyl point, and the Chern number of a 2D surface enclosing the whole bouquet. We show that such structured Weyl points can be realized in the superfluid quasiparticle spectrum of a 3D degenerate Fermi gas subject to…
