arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1909.06408cond-mat.str-elcond-mat.mtrl-sci
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几何阻挫YBaCo4O7和DyBaCo4O7钴酸盐的结构、磁性和电极化的强度性质

Structural, magnetic and electric polarization properties of geometrically frustrated YBaCo4O7 and DyBaCo4O7 cobaltites

C. Dhanasekhar, A. K Das, A. Das, S. K. Mishra, R. Rawat, A. Venimadhav

摘要:

在RBaCo_4O_7(R = Ca,Y和稀土)钴酸盐家族中,只有CaBaCo_4O_7具有三维长程亚铁磁和自旋驱动的电极化的强度性质。在本研究中,我们已经研究了结构,磁性和电极化的强度性能在YBaCo 4 O 7和DyBaCo 4 O 7的这个家庭的成员,并得到的结果进行了比较与CaBaCo 4 O 7。化合物YBaCo_4O_7在5K以下表现出一系列与文献报道一致的磁性转变,并观察到团簇玻璃行为。DyBaCo_4O_7钴矿的粉末中子衍射研究表明其具有正交Pbn_(21)对称性和可果美层的短程120度磁关联特征,并在65 K以下表现出自旋玻璃行为。两种样品的介电测量结果表明,在高温下的频率分散和频率无关的行为在低温下没有介电异常。热释电电流的测量表明,在这两个样品中的宽峰约50 K,然而,仔细的分析涉及到热刺激去极化电流的峰值。这一研究表明,在kagome层的巨结构畸变和钴电荷有序是驱动长程磁有序和自旋驱动电极化的强度在这个钴族的关键因素。

英文摘要:

In RBaCo4O7 (R = Ca, Y and Rare earth) cobaltite family, only CaBaCo4O7 shows 3D long range ferrimagnetic and spin driven electric polarization properties. In the present study, we have investigated the structural, magnetic and electric polarization properties in YBaCo4O7 and DyBaCo4O7 members of this family and the obtained results are compared with the CaBaCo4O7. The compound YBaCo4O7 showed a series of magnetic transitions in agreement with reported literature, additionally, a cluster glass behavior below 5 K is observed. Powder neutron diffraction studies on DyBaCo4O7 cobaltite showed an orthorhombic Pbn21 symmetry and signature of short-range 120 degree magnetic correlations of kagome layer and a spin glass behavior below 65 K. Dielectric measurements on both the samples showed strong frequency dispersion at high temperature and frequency independent behavior at low temperature without dielectric anomaly. Pyroelectric current measurement has showed a broad peak around 50 K in both the samples; however, a careful analysis relates the peak to thermally stimulated depolarization current. This study signifies that the giant structural distortions and cobalt charge ordering at kagome layer are the key factors to drive both long range magnetic ordering and spin driven electric polarization in this cobaltite family.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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