We use observations of chlorine-bearing species in molecular absorbers at intermediate redshifts to investigate chemical properties and $^{35}$Cl/$^{37}$Cl isotopic ratios in the absorbing sightlines. Chloronium (H$_2$Cl$^+$) is detected along three independent lines of sight in the z=0.89 and z=0.68 molecular absorbers located in front of the lensed quasars PKS 1830-211 and B 0218+357, respectively. Hydrogen chloride (HCl) was observed only toward PKS 1830-211, and is found to behave differently from H$_2$Cl$^+$. It is detected in one line of sight with an abundance ratio [H$_2$Cl$^+$]/[HCl] $\sim 1$, but remains undetected in the other, more diffuse, line of sight, with a ratio [H$_2$Cl$^+$]/[HCl]~$>17$. The absorption profiles of these two chlorine-bearing species are compared to other species and discussed in terms of the physical properties of the absorbing gas. Our findings are consistent with the picture emerging from chemical models where different species trace gas with different molecular hydrogen fraction. The $^{35}$Cl/$^{37}$Cl isotopic ratios are measured in the different lines of sight and are discussed in terms of stellar nucleosynthesis.
We have revisited the chemistry of chlorine-bearing species in the diffuse interstellar medium with new observations of the HCl$^+$ molecular ion and new astrochemical models. Using the GREAT instrument on board SOFIA, we observed the $^2Π_{3/2}\, J = 5/2 - 3/2$ transition of HCl$^+$ near 1444 GHz toward the bright THz continuum source W49N. We detected absorption by diffuse foreground gas unassociated with the background source, and were able to thereby measure the distribution of HCl$^+$ along the sight-line. We interpreted the observational data using an updated version of an astrochemical …
Chlorine and molecular hydrogen are known to be tightly linked together in the cold phase of the local interstellar medium through rapid chemical reactions. We present here the first systematic study of this relation at high redshifts using H$_2$-bearing damped Ly$α$ systems (DLAs) detected along quasar lines of sight. Using high-resolution spectroscopic data from VLT/UVES and Keck/HIRES, we report the detection of Cl$\,$I in 9 DLAs (including 5 new detections) out of 18 high-$z$ DLAs with $N($H$_2) \ge 10^{17.3}\,$cm$^{-2}$ (including a new H$_2$ detection at $z=3.09145$ towards J$\,$2100$-$0…
We present results from the Keck Baryonic Structure Survey (KBSS) including the first detailed measurements of the column densities, kinematics, and internal energy of metal-bearing gas within the virial radius (35-100 physical kpc) of eight ~$L^*$ galaxies at $z\sim2$. From our full sample of 130 metal-bearing absorbers, we infer that halo gas is kinematically complex when viewed in singly, doubly, and triply ionized species. Broad OVI and CIV absorbers are detected at similar velocities to the lower-ionization gas but with very different kinematic structure indicating that the circumgalactic…
We report the serendipitous detection of an H$_{2}$-bearing damped Lyman-$α$ absorber at z = 0.576 in the spectrum of the QSO J0111-0316 in the Cosmic Ultraviolet Baryon Survey. Spectroscopic observations from HST-COS in the far-ultraviolet reveal a damped absorber with log[N(HI)/cm^-2] = 20.1 +/- 0.2 and log[N(H$_{2}$)/cm^-2] = 18.97 (-0.06, +0.05). The diffuse molecular gas is found in two velocity components separated by dv = 60 km/s, with >99.9% of the total H$_{2}$ column density concentrated in one component. At a metallicity of $\approx$ 50% of solar, there is evidence for Fe enhancemen…
We report the detections of molecular hydrogen (H$_2$), vibrationally-excited H$_2$ (H$^*_2$), and neutral atomic carbon (CI), in two new afterglow spectra of GRBs\,181020A ($z=2.938$) and 190114A ($z=3.376$), observed with X-shooter at the Very Large Telescope (VLT). Both host-galaxy absorption systems are characterized by strong damped Lyman-$α$ absorbers (DLAs) and substantial amounts of molecular hydrogen with $\log N$(HI, H$_2$) = $22.20\pm 0.05,~20.40\pm 0.04$ (GRB\,181020A) and $\log N$(HI, H$_2$) = $22.15\pm 0.05,~19.44\pm 0.04$ (GRB\,190114A). The DLA metallicites, depletion levels an…
Absorption-selected galaxies offer an effective way to study low-mass galaxies at high redshift. However, the physical properties of the underlying galaxy population remains uncertain. In particular, the multiphase circum-galactic medium is thought to hold key information on gas flows into and out of galaxies that are vital for galaxy evolution models. Here we present ALMA observations of CO molecular gas in host galaxies of H_2-bearing absorbers. In our sample of six absorbers we detect molecular gas-rich galaxies in five absorber fields although we did not target high-metallicity (>50 per ce…
Using $HST$/COS observations of the twin quasar lines of sight Q$0107-025$A $\&$ Q$0107-025$B, we report on the physical properties, chemical abundances and transverse sizes of gas in a multiple galaxy environment at $z = 0.399$ across a transverse separation of $520$ kpc. The absorber towards Q$0107-025$B has $\log N(H I)/cm^{-2} \approx 16.8$ (partial Lyman limit) while the absorber towards the other sightline has $N(H I) \approx 2$ dex lower. The O VI along both sightlines have comparable column densities and broad $b$-values, whereas the low ionization lines are considerably narrower. The …
We report the detection of hydrogen chloride, HCl, in diffuse molecular clouds on the line of sight towards the star-forming region W31C (G10.6-0.4). The J = 1-0 lines of the two stable HCl isotopologues, H35Cl and H37Cl, are observed using the 1b receiver of the Heterodyne Instrument for the Far-Infrared (HIFI) aboard the Herschel Space Observatory. The HCl line is detected in absorption, over a wide range of velocities associated with diffuse clouds along the line of sight to W31C. The analysis of the absorption strength yields a total HCl column density of few 10^13 cm^-2, implying that HCl…
The radio galaxy NGC 1052 casts absorption features of sulfur-bearing molecules, H$_2$S, SO, SO$_2$, and CS toward the radio continuum emission from the core and jets. Using ALMA, we have measured the equivalent widths of SO absorption features in multiple transitions and determined the temperatures of $344 \pm 43$ K and $26 \pm 4$ K in sub-millimeter and millimeter wavelengths, respectively. Since sub-mm and mm continuum represents the core and jets, the high and low temperatures of the absorbers imply warm environment in the molecular torus and cooler downstream flows. The high temperature i…
We investigate the association between galaxies and metal-enriched and metal-deficient absorbers in the local universe ($z < 0.16$) using a large compilation of FUV spectra of bright AGN targets observed with the Cosmic Origins Spectrograph aboard the Hubble Space Telescope. In this homogeneous sample of 18 O VI detections at $N_{\rm O\,{VI}}\geq13.5~\mathrm{cm}^{-2}$ and 18 non-detections at $N_{\rm O\,{VI}}<13.5~\mathrm{cm}^{-2}$ using Lya absorbers with ${N_{\rm H\,{I}}\geq} 10^{14}~\mathrm{cm}^{-2}$, the maximum distance O VI extends from galaxies of various luminosities is $\sim0.6$ Mpc, …
We present results of our numerical simulation of three H2-bearing damped Lyman alpha absorbers (DLAs) in the redshift interval ~ 2-3. The systems we have modelled are the DLAs at zabs = 2.3377 towards the quasar LBQS 1232+0815, at zabs = 2.41837 towards SDSS J143912.04+111740.5 and at zabs = 2.6265 towards FBQS J081240.6+320808. We have used the spectral synthesis code CLOUDY to simulate the physical environment of these DLAs, and constrain the density, radiation field, geometry and dust-grain properties of the DLAs self-consistently based on the observed column densities of various atomic an…
We report the discovery of a massive $\log(M/M_\odot)=10.74^{+0.18}_{-0.16}$ galaxy at the same redshift as a carbon-monoxide-bearing sub-damped Lyman $α$ absorber (sub-DLA) seen in the spectrum of QSO J1439+1117. The galaxy, J1439B, is located 4\farcs7 from the QSO sightline, a projected distance of 38 physical kpc at $z=2.4189$, and exhibits broad optical emission lines ($σ_{\rm{[O III]}}=303 \pm 12$~\kms) with ratios characteristic of excitation by an active galactic nucleus (AGN). The galaxy has a factor of $\sim$9 lower star formation than is typical of star-forming galaxies of the same m…
To explore the role of titanium- and calcium-dust depletion in gas in and around galaxies we systematically study Ti/Ca abundance ratios in intervening absorption-line systems at low and high redshift. We investigate high-resolution optical spectra obtained by the UVES instrument at the Very Large Telescope and spectroscopically analyze 34 absorption-line systems at z<=0.5 to measure column densities (or limits) for CaII and TiII. We complement our UVES data set with previously published absorption-line data on Ti/Ca for redshifts up to z~3.8. Our absorber sample contains 110 absorbers (DLAs, …
We aim at assessing what are the most dominant dust species or types, including silicate and iron oxide grains present in the ISM, by using recent observations of dust depletion of galaxies at various evolutionary stages. We use the observed elemental abundances in dust of several metals (O, S, Si, Mg, and Fe) in different environments, considering systems with different metallicities and dust content, namely damped Lyman-α absorbers (DLAs) towards quasars and the Galaxy. We derive a possible dust composition by computationally finding the statistically expected elemental abundances in dust as…
While molecular quasar absorption systems provide unique probes of the physical and chemical properties of the gas as well as original constraints on fundamental physics and cosmology, their detection remains challenging. Here we present the results from a complete survey for molecular gas in thirty-nine absorption systems selected solely upon the detection of neutral carbon lines in SDSS spectra, without any prior knowledge of the atomic or molecular gas content. H2 is found in all twelve systems (including seven new detections) where the corresponding lines are covered by the instrument setu…
The gamma-ray burst (GRB) afterglows provide an unique opportunity to study the interstellar medium (ISM) of star-forming galaxies at high-redshift. The GRB-DLAs (damped Lyman-$α$ absorbers) contain a large neutral hydrogen column density, N(H I), and are observed against the GRB afterglow. A large fraction of GRB-DLAs show presence of molecular hydrogen (H$_2$) which is an indicator of star-formation. Hence it is important to study those GRB-DLAs which have H$_2$ lines to decipher and understand their physical conditions. The GRB-DLAs 121024A and 120815A, situated at redshift 2.30 and 2.36 re…
We present UV to NIR spectroscopic observations of the quasar J0015+1842 and its proximate molecular absorber at z=2.631. The [OIII] emission line of the quasar is composed of a broad (FWHM~1600 km/s), spatially-unresolved component, blueshifted by ~600 km/s from a narrow, spatially-resolved component (FWHM~650 km/s). The wide, blueshifted, unresolved component is consistent with the presence of outflowing gas in the nuclear region. The narrow component can be further decomposed into a blue and a red blob with velocity width of several hundred km/s each, seen ~5 pkpc on opposite spatial locati…
Although they are only minor constituents of the interstellar medium, halogen-containing molecules are of special interest because of their unique thermochemistry. Here, we present a theoretical study of the chemistry of interstellar molecules containing the halogen elements chlorine and fluorine. We have modeled both diffuse and dense molecular clouds, making use of updated estimates for the rates of several key chemical processes. We present predictions for the abundances of the three halogen molecules that have been detected to date in the interstellar medium: HF, CF+ and HCl. As in our pre…
We investigate the composition of interstellar grains along the line of sight toward Zeta Ophiuchi, a well-studied environment near the diffuse-dense cloud transition. A spectral decomposition analysis of the solid-state absorbers is performed using archival spectroscopic observations from the Spitzer Space Telescope and Infrared Space Observatory. We find strong evidence for the presence of sub-micron-sized amorphous silicate grains, principally comprised of olivine-like composition, with no convincing evidence of H2O ice mantles. However, tentative evidence for thick H2O ice mantles on large…
We perform detailed spectroscopic analysis and numerical modelling of an H2-bearing damped Lyman-alpha absorber (DLA) at zabs = 2.05 towards the quasar FBQS J2340-0053. Metal absorption features arise from fourteen components spread over $Δv_{90}$ = 114 km s$^{-1}$, seven of which harbour H2. Column densities of atomic and molecular species are derived through Voigt profile analysis of their absorption lines. We measure total N(H I), N(H2) and N(HD) to be 20.35+/-0.05, 17.99+/-0.05 and 14.28+/-0.08 (log cm$^{-2}$) respectively. H2 is detected in the lowest six rotational levels of the ground v…
We present a high-resolution (R=140,000) spectrum of the bright quasar HE0001-2340 (z=2.26), obtained with ESPRESSO at the Very Large Telescope. We analyse three systems at z=0.45, z=1.65, and z=2.19 using multiple-component Voigt-profile fitting. We also compare our spectrum with those obtained with VLT/UVES, covering a total period of 17 years. We disentangle turbulent and thermal broadening in many components spread over about 400 km/s in the z~2.19 sub-DLA system. We derive an average temperature of 16000+/-1300 K, i.e., about twice the canonical value of the warm neutral medium in the Gal…
