arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1908.02431cond-mat.mtrl-sci
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自由二维钠片中的输运现象

Transport phenomena in a free-standing two-dimensional sodium sheet

Ajit Jena, Wu Li

摘要:

生长技术的进步为探索新的2D材料的潜在应用提供了许多可能性。借助第一性原理计算,我们表明,2D钠可以是一个新的除了家庭的晶体学稳定的2D材料的器件应用。毫不奇怪,由于半占据的$3s$轨道,2D Na具有2D电子气(2DEG)的特征。基于玻尔兹曼输运方程的精确解,研究了其输运性质。在2D材料中具有实际可调的载流子密度的情况下,电子掺杂的2D Na的本征电阻率是石墨烯的本征电阻率的$\sim$ 1.4倍,并且在450 K之前低于后者。布洛赫-格吕奈森温度几乎恒定在50 K,与载流子的类型或密度无关。在300 K时,纯2D Na的电子热导率是其体相对应物的$\sim$的1.24倍。Wiedemann-Franz定律在2D Na中很高,在室温下计算的洛伦兹数为2.41 $\times 10^{-8} V^2/deg^2$。这里提出的输运机制预计将发生在所有的Na类系统与干净的费米表面。

英文摘要:

The advances in the growth techniques provide numerous scope to explore the possibilities of new 2D materials for potential applications. With the aid of first-principle calculations we show that 2D Na can be a new addition to the family of thermodynamically stable 2D materials for device applications. Not surprisingly, due to half-occupied $3s$ orbital 2D Na possesses the features of the 2D electron gas (2DEG). The transport properties are examined based on the accurate solution of Boltzmann transport equation. With practically tunable carrier density in 2D materials, the intrinsic electrical resistivity of electron doped 2D Na is $\sim$ 1.4 times larger than that of graphene and falls below the latter 450 K onwards. The Bloch-Grüneisen temperature is almost constant at 50 K, independent of the type or density of the charge carriers. The electronic thermal conductivity of pure 2D Na is $\sim$ 1.24 times larger than that of its bulk counterpart at 300 K. The Wiedemann-Franz law stands tall in 2D Na with calculated Lorenz number 2.41 $\times 10^{-8} V^2/deg^2$ at room temperature. The transport mechanism presented here is expected to occur in all Na like systems with a clean Fermi surface.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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