We propose simple protocols for performing quantum noise spectroscopy based on the method of transfer tensor maps (TTM), [Phys. Rev. Lett. 112, 110401 (2014)]. The TTM approach is a systematic way to deduce the memory kernel of a time-nonlocal quantum master equation via quantum process tomography. With access to the memory kernel it is possible to (1) assess the non-Markovianity of a quantum process, (2) reconstruct the noise spectral density beyond pure dephasing models, and (3) investigate collective decoherence in multiqubit devices. We illustrate the usefulness of TTM spectroscopy on the IBM Quantum Experience platform, and demonstrate that the qubits in the IBM device are subject to mild non-Markovian dissipation with spatial correlations.
We calculate the exact many-body time dynamics of polaritonic states supported by an optical cavity filled with organic molecules. Optical, vibrational and radiative processes are treated on an equal footing employing the Time-Dependent Variational Matrix Product States algorithm. We demonstrate signatures of non-Markovian vibronic dynamics and its fingerprints in the far-field photon emission spectrum at arbitrary light-matter interaction scales, ranging from the weak to the strong coupling regimes. We analyse both the single and many-molecule cases, showing the crucial role played by the col…
A quantum kinetic theory of the spin transfer between carriers and Mn atoms in a Mn doped diluted magnetic semiconductor is presented. It turns out that the typical memory time associated with these processes is orders of magnitude shorter than the time scale of the spin transfer. Nevertheless, Markovian rate equations, which are obtained by neglecting the memory, work well only for bulk systems. For quantum wells and wires the quantum kinetic results qualitatively deviate from the Markovian limit under certain conditions. Instead of a monotonic decay of an initially prepared excess electron s…
With continuing improvements on the quality of fabricated quantum devices, it becomes increasingly crucial to analyze noisy quantum process in greater details such as characterizing the non-Markovianity in a quantitative manner. In this work, we propose an experimental protocol, termed Spectral Transfer Tensor Maps (SpecTTM), to accurately predict the RHP non-Markovian measure of any Pauli channels without state-preparation and measurement (SPAM) errors. In fact, for Pauli channels, SpecTTM even allows the reconstruction of highly-precised noise power spectrum for qubits. At last, we also disc…
Process Tensor Approaches to Non-Markovian Quantum Dynamics
SUPA, School of Physics and Astronomy, University of St Andrews（圣安德鲁斯大学物理与天文学学院）；Center for Computational Quantum Physics, Flatiron Institute（平顿研究所计算量子物理中心）；Max-Planck-Institut für Quantenoptik（马克斯·普朗克量子光学研究所）；Munich Center for Quantum Science and Technology（慕尼黑量子科学与技术中心）；Department of Chemistry, Columbia University（哥伦比亚大学化学系）
In the path integral formulation of the evolution of an open quantum system coupled to a Gaussian, non-interacting environment, the dynamical contribution of the latter is encoded in an object called the influence functional. Here, we relate the influence functional to the process tensor -- a more general representation of a quantum stochastic process -- describing the evolution. We then use this connection to motivate a tensor network algorithm for the simulation of multi-time correlations in open systems, building on recent work where the influence functional is represented in terms of time …
We show how to learn structures of generic, non-Markovian, quantum stochastic processes using a tensor network based machine learning algorithm. We do this by representing the process as a matrix product operator (MPO) and train it with a database of local input states at different times and the corresponding time-nonlocal output state. In particular, we analyze a qubit coupled to an environment and predict output state of the system at different time, as well as reconstruct the full system process. We show how the bond dimension of the MPO, a measure of non-Markovianity, depends on the proper…
Uniform process tensor approach for the calculation of multi-time correlation functions of non-Markovian open systems
TUD Dresden University of Technology（德累斯顿工业大学）；Institute of Theoretical Physics, TUD Dresden University of Technology（德累斯顿工业大学理论物理研究所）；Institut für Physik und Astronomie, Technische Universität Berlin（柏林工业大学物理与天文学系）；Max Planck Institute for the Physics of Complex Systems（马克斯·普朗克复杂系统物理研究所）
Non-Markovian environment induced Schrödinger cat state transfer in an optical Newton's cradle
Fujian Key Laboratory of Quantum Information and Quantum Optics (Fuzhou University)（福建量子信息与量子光学重点实验室）；Department of Physics, Fuzhou University（福州大学物理系）
Efficient construction of time-invariant process tensors for simulating high-dimensional non-Markovian open quantum systems
Département de Physique de l’ENS Lyon, ENS de Lyon（里昂高等师范学校物理系）；SUPA, School of Physics and Astronomy, University of St Andrews（圣安德鲁斯大学物理与天文学学院）；Sorbonne Université, Institut des NanoSciences de Paris（索邦大学巴黎纳米科学研究所）；CNRS, Institut des NanoSciences de Paris（法国国家科学研究中心巴黎纳米科学研究所）
Nanoscale devices - either biological or artificial - operate in a regime where the usual assumptions of a structureless, Markovian, bath do not hold. Being able to predict and study the dynamics of such systems is crucial and is usually done by tracing out the bath degrees of freedom, which implies losing information about the environment. To go beyond these approaches we use a numerically exact method relying on a Matrix Product State representation of the quantum state of a system and its environment to keep track of the bath explicitly. This method is applied to a specific example of inter…
Efficient simulations of the dynamics of open systems is of wide importance for quantum science and tech-nology. Here, we introduce a generalization of the transfer-tensor, or discrete-time memory kernel, formalism to multi-time measurement scenarios. The transfer-tensor method sets out to compute the state of an open few-body quantum system at long times, given that only short-time system trajectories are available. Here, we showthat the transfer-tensor method can be extended to processes which include multiple interrogations (e.g. measurements) of the open system dynamics as it evolves, allo…
We utilize the novel non-Markovian quantum jump (NMQJ) approach to stochastically simulate exciton dynamics derived from a time-convolutionless master equation. For relevant parameters and time scales, the time-dependent, oscillatory decoherence rates can have negative regions, a signature of non-Markovian behavior and of the revival of coherences. This can lead to non-Markovian population beatings for a dimer system at room temperature. We show that strong exciton-phonon coupling to low frequency modes can considerably modify transport properties. We observe increased exciton transport, which…
In this paper, we investigate the non-Markovian dynamics of a model to mimic the excitation energy transfer (EET) between chromophores in photosynthesis systems. The numerical path integral method is used. This method includes the non-Markovian effects of the environmental affects and it does not need the perturbation approximation in solving the dynamics of systems of interest. It implies that the coherence helps the EET between chromophores through lasting the transfer time rather than enhances the transfer rate of the EET. In particular, the non-Markovian environment greatly increase the ef…
We study transitions of a particle between two wells, separated by a reservoir, under the condition that the particle is not detected in the reservoir. Conventional quantum trajectory theory predicts that such no-result continuous measurement would not affect these transitions. We demonstrate that it holds only for Markovian reservoirs (infinite bandwidth $Λ$). In the case of finite $Λ$, the probability of the particle's interwell transition is a function of the ratio $Λ/ν$, where $ν$ is the frequency of measurements. This scaling tells us that in the limit $ν\to\infty$, the measurement freeze…
We explore signatures of the non-Markovianity in the time-resolved energy transfer processes for quantum open systems. Focusing on typical systems such as the exact solvable damped Jaynes-Cummings model and the general spin-boson model, we establish quantitative links between the time-resolved energy current and the symmetric logarithmic derivative quantum Fisher information (SLD-QFI) flow, one of measures quantifying the non-Markovianity, within the framework of non-Markovian master equations in time-local forms. From the relationships, we find in the damped Jaynes-Cummings model that the SLD…
The weak-coupled two-level open quantum system described by non-Markovian Time-convolution-less master equation is investigated in this paper. The cut-off frequency, coupling constant and transition frequency, which impact on the system's decay rate, coherence factor and purity, are investigated. The appropriate parameters used in system simulation experiments are determined by comparing analysis results of different values of parameters for the effects of system performance. The control laws used to transfer the system states are designed on the basis of the Lyapunov stability theorem. Numeri…
We study at the single-photon level the nonreciprocal excitation transfer between emitters coupled with a common waveguide. Non-Markovian retarded effects are taken into account due to the large separation distance between different emitter-waveguide coupling ports. It is shown that the excitation transfer between the emitters of a small-atom dimer can be obviously nonreciprocal by introducing between them a coherent coupling channel with nontrivial coupling phase. We prove that for dimer models the nonreciprocity cannot coexist with the decoherence-free giant-atom structure although the latte…
There has long been interest to control the transfer of population between specified quantum states. Recent work has optimized the control law for closed system population transfer by using a gradient ascent pulse engineer- ing algorithm [1]. Here, a spin-boson model consisting of two-level atoms which interact with the dissipative environment, is investigated. With opti- mal control, the quantum system can invert the populations of the quantum logic states. The temperature plays an important role in controlling popula- tion transfer. At low temperatures the control has active performance, whi…
Excitation energy transfer (EET) and electron transfer (ET) are crucially involved in photosynthetic processes. In reality, the photosynthetic reaction center constitutes an open quantum system of EET and ET, which manifests an interplay of pigments, solar light and phonon baths. So far theoretical studies have been mainly based on master equation approaches in the Markovian condition. The non-Markovian environmental effect, which may play a crucial role, has not been sufficiently considered. In this work, we propose a mixed dynamic approach to investigate this open system. The influence of ph…
A Markov assumption considers a physical system memoryless to simplify its dynamics. Whereas memory effect or the non-Markovian phenomenon is more general in nature. In the quantum regime, it is challenging to define or quantify the non-Markovianity because the measurement of a quantum system often interferes with it. We simulate the open quantum dynamics in a superconducting processor, then characterize and quantify the non-Markovian process. With the complete set of intervening projections and the final measurement of the qubit, a restricted process tensor can be determined to account for th…
Based on tensor network realizations of path integrals reducing exponential memory scaling to polynomial efficiency and a Liouville space implementation of a time-discrete quantum memory, we investigate a quantum system simultaneously exposed to two structured reservoirs. For this purpose, we employ a numerically exact quasi-2D tensor network combining both diagonal and off-diagonal system-reservoir interactions with a twofold memory for continuous and discrete retardation effects. As a possible example, we study the non-Markovian dynamical interplay between discrete photonic feedback and stru…
We analyze efficiency of excitation energy transfer in photosynthetic complexes in transient and stationary setting. In the transient setting the absorption process is modeled as an individual event resulting in a subsequent relaxation dynamics. In the stationary setting the absorption is a continuous stationary process, leading to the nonequilibrium steady state. We show that, as far as the efficiency is concerned, both settings can be considered to be the same, as they result in almost identical efficiency. We also show that non-Markovianity has no effect on the resulting efficiency, i.e., c…
Directional transfer from coherence to longitudinal polarization and algebraic storage in a transmon with Markovian dephasing and a glassy environment: A non-Markovian fractional renewal model
Dokuz Eylul University（德格埃尤尔大学）；Izmir Institute of Technology（伊兹密尔理工学院）
The initial stages of the evolution of an open quantum system encode the key information of its underlying dynamical correlations, which in turn can predict the trajectory at later stages. We propose a general approach based on non-Markovian dynamical maps to extract this information from the initial trajectories and compress it into non-Markovian transfer tensors. Assuming time-translational invariance, the tensors can be used to accurately and efficiently propagate the state of the system to arbitrarily long timescales. The non-Markovian Transfer Tensor Method (TTM) demonstrates the coherent…
In the classical domain, it is well-known that divisibility does not imply that a stochastic process is Markovian. However, for quantum processes, divisibility is often considered to be synonymous with Markovianity. We show that completely positive (CP) divisible quantum processes can still involve non-Markovian temporal correlations, that we then fully classify using the recently developed process tensor formalism, which generalizes the theory of stochastic processes to the quantum domain.
Enabled by rapidly developing quantum technologies, it is possible to network quantum systems at a much larger scale in the near future. To deal with non-Markovian dynamics that is prevalent in solid-state devices, we propose a general transfer function based framework for modeling linear quantum networks, in which signal flow graphs are applied to characterize the network topology by flow of quantum signals. We define a noncommutative ring $\mathbb{D}$ and use its elements to construct Hamiltonians, transformations and transfer functions for both active and passive systems. The signal flow gr…
In quantum communication and distributed quantum computing, one-dimensional waveguides provide directional transfer of quantum information. A single-mode waveguide has a density-of-states singularity at the lower cut-off frequency, which resembles sharp resonances of a cavity but with non-Markovian dynamics. Thus we put forward schemes of coupling atomic transitions and a waveguide continuum edge. We first present a scheme of spin-photon quantum interface operating in the non-Markovian regime for a $Λ$-type three-level system coupled to a waveguide. Then we show that strong coupling between at…
Tracing out the environmental degrees of freedom is a necessary procedure when simulating open quantum systems. While being an essential step in deriving a tractable master equation it represents a loss of information. In situations where there is strong interplay between the system and environmental degrees of freedom this loss makes understanding the dynamics challenging. These dynamics, when viewed in isolation, have no time-local description: they are non-Markovian and memory effects induce complex features that are difficult to interpret. To address this problem, we here show how to use s…
Relying on an exact time evolution scheme, we identify a novel transient energy transfer phe- nomenon in an exactly-solvable quantum microscopic model consisting of a three-level system coupled to two non-Markovian zero-temperature bosonic baths through two separable quantum channels. The dynamics of this model can be solved exactly using the quantum-state-diffusion equation formalism, demonstrating finite intervals of unidirectional energy flow across the system, typically, from the non-Markovian environment towards the more Markovian bath. Furthermore, when introducing a spatial asymmetry in…
In this study, we explore optimal environments for efficient EET between end sites in a number of dimer and trimer model pigment-protein molecular aggregates when the EET dynamics is modeled by the HEOM-method. For these optimal environmental parameters, we further quantify the non-Markovianity by the BLP-measure to elucidate its possible connection to efficient EET. We also quantify coherence in the pigment systems by means of the measure l1-norm of coherence to analyze its interplay with environmental effects when EET efficiency is maximal. Our aim is to investigate possible environmental de…
We consider population transfer in open quantum systems, which are described by quantum dynamical semigroups (QDS). Using second order perturbation theory of the Lindblad equation, we show that it depends on a weak external field only through the field's autocorrelation function (ACF), which is phase independent. Therefore, for leading order in perturbation, QDS cannot support dependence of the population transfer on the phase properties of weak fields. We examine an example of weak-field phase-dependent population transfer, and show that the phase-dependence comes from the next order in the p…
We theoretically investigate an exciton-coupled electron transfer (XCET) process that is conversion of an exciton into a charge transfer state. This conversion happens in an exciton transfer (XT) process, and the electron moves away in an electron transfer(ET) process in multiple environments (baths). This XCET process plays an essential role in the harvesting of solar energy in biological and photovoltaic materials. We develop a practical theoretical model to study the efficiency of XCET process that occurs either in consecutive or concerted processes under the influence of non-Markovian bath…
Capturing non-Markovian dynamics of open quantum systems is generally a challenging problem, especially for strongly-interacting many-body systems. In this work, we combine recently developed non-Markovian quantum state diffusion techniques with tensor network methods to address this challenge. As a first example, we explore a Hubbard-Holstein model with dissipative phonon modes, where this new approach allows us to quantitatively assess how correlations spread in the presence of non-Markovian dissipation in a 1D many-body system. We find regimes where correlation growth can be enhanced by the…
The non-Markovianity of an arbitrary open quantum system is analyzed in reference to the multi-time statistics given by its monitoring at discrete times. On the one hand, we exploit the hierarchy of inhomogeneous transfer tensors, which provides us with relevant information about the role of correlations between the system and the environment in the dynamics. The connection between the transfer-tensor hierarchy and the CP-divisibility property is then investigated, by showing to what extent quantum Markovianity can be linked to a description of the open-system dynamics by means of the composit…
An exact solution to the interaction between two emitters mediated by Förster resonance energy transfer is presented. The system is comprised of a one-dimensional optical waveguide with two embedded two-level systems and is analyzed using a recently developed quantum-field theoretical approach. This exactly solvable model features several competing mechanisms that lead to a rich physical behavior such as, for instance, the possibility to change from an attractive to a repulsive interaction. Our nonperturbative analysis allows on very general grounds to describe the interaction as a truly non-M…
Understanding heat transfer between a quantum system and its environment is of undisputed importance if reliable quantum devices are to be constructed. Here, we investigate the heat transfer between system and bath in non-Markovian open systems in the process of adiabatic speedup. Using the quantum state diffusion equation method, the heat current, energy current, and power are calculated during free evolution and under external control of the system. While the heat current increases with increasing system-bath coupling strength and bath temperature, it can be restricted by the non-Markovian n…
