We provide evidence of an extremely slow thermalization occurring in the Discrete NonLinear Schrödinger (DNLS) model. At variance with many similar processes encountered in statistical mechanics - typically ascribed to the presence of (free) energy barriers - here the slowness has a purely dynamical origin: it is due to the presence of an adiabatic invariant, which freezes the dynamics of a tall breather. Consequently, relaxation proceeds via rare events, where energy is suddenly released towards the background. We conjecture that this exponentially slow relaxation is a key ingredient contributing to the non-ergodic behavior recently observed in the negative temperature region of the DNLS equation.
Using T=0 Monte Carlo and simulated annealing simulation, we study the energy relaxation of ferromagnetic Ising and Potts models on random graphs. In addition to the expected exponential decay to a zero energy ground state, a range of connectivities for which there is power law relaxation and freezing to a metastable state is found. For some connectivities this freezing persists even using simulated annealing to find the ground state. The freezing is caused by dynamic frustration in the graphs, and is a feature of the local search-nature of the Monte Carlo dynamics used. The implications of th…
We measure the relaxation time of a square lattice Ising ferromagnet that is quenched to zero-temperature from supercritical initial conditions. We reveal an anomalous and seemingly overlooked timescale associated with the relaxation to "frozen" two-stripe states. While close to a power law of the form $\sim L^ν$ , we argue this timescale actually grows as $\sim L^{2}\ln L$, with L the linear dimension of the system. We uncover the mechanism behind this scaling form by using a synthetic initial condition that replicates the late time ordering of two-stripe states, and subsequently explain it h…
We study the quench dynamics of the $q$ Potts model on different bi/tri-dimensional lattice topologies. In particular we are interested in instantaneous quenches from $T_i \rightarrow \infty$ to $T \leq T_s$, where $T_s$ is the (pseudo)-spinodal temperature. The goal is to explain why, in the large-$q$ limit, the low-temperature dynamics freezes on some lattices while, on others, the equilibrium configuration is easily reached. The cubic ($3d$) and the triangular ($2d$) lattices are analysed in detail. We show that the dynamics blocks when lattices have acyclic \textit{unitary structures} whil…
We investigate the long-time properties of the Ising-Glauber model on a periodic cubic lattice after a quench to zero temperature. In contrast to the conventional picture from phase-ordering kinetics, we find: (i) Domains at long time are highly interpenetrating and topologically complex, with average genus growing algebraically with system size. (ii) The long-time state is almost never static, but rather contains "blinker" spins that can flip ad infinitum with no energy cost. (iii) The energy relaxation has a complex time dependence with multiple characteristic time scales, the longest of whi…
We evaluate the relaxation time to equilibrium, and especially show that it is almost independent from the system size for macroscopic isolated quantum systems. It at most polynomially depends on the system size. This estimation holds when the Hamiltonian is non-integrable, the initial deviation of the quantity of interest is of order its spectral norm, and the relaxation process is monotonic.
In this work we investigate the transient solidification of a Lennard-Jones liquid using non-equilibrium molecular dynamics simulations and continuum heat transfer theory. The simulations are performed in slab-shaped boxes, where a cold thermostat placed at the centre of the box drives the solidification of the liquid. Two well-defined solid fronts propagate outwards from the centre towards the ends of the box until solidification is completed. A continuum phase change model that accounts for the difference between the solid and the liquid densities is formulated to describe the evolution of t…
A quantum mechanical explanation of the relaxation to equilibrium is shown for macroscopic systems for nonintegrable cases and numerically verified. The macroscopic system is initially in an equilibrium state, subsequently externally perturbed during a finite time, and then isolated for a sufficiently long time. We show a quantitative explanation that the initial microcanonical state typically reaches to a state whose expectation values are well-approximated by the average over another microcanonical ensemble.
We constructed a model that evolved from a non-equilibrium state to an equilibrium state. The model only needs two basic coefficients, including self-similar coefficients and non-equilibrium coefficients. The coefficients of the model can be obtained directly from real data. The model can well represent the phenomena of anomalous diffusion, non-Gaussian distribution and so on in non-equilibrium complex systems. It is important to mention that the model is a global iterative model that can exhibit statistical physical properties on multiple time scales, as well as exhibiting long-term memory pr…
We present the first analytic study of finite-size effects on critical diffusion above and below T_c of three-dimensional Ising-like systems whose order parameter is coupled to a conserved density. We also calculate the finite-size relaxation time that governs the critical order-parameter relaxation towards a metastable equilibrium state below T_c. Two new universal dynamic amplitude ratios at T_c are predicted and quantitative predictions of dynamic finite-size scaling functions are given that can be tested by Monte-Carlo simulations.
We employ Monte Carlo simulations to study the non-equilibrium relaxation of driven Ising lattice gases in two dimensions. Whereas the temporal scaling of the density auto-correlation function in the non-equilibrium steady state does not allow a precise measurement of the critical exponents, these can be accurately determined from the aging scaling of the two-time auto-correlations and the order parameter evolution following a quench to the critical point. We obtain excellent agreement with renormalization group predictions based on the standard Langevin representation of driven Ising lattice …
Nonequilibrium relaxation behaviors in the Ising model on a square lattice based on the Wolff algorithm are totally different from those based on local-update algorithms. In particular, the critical relaxation is described by the stretched-exponential decay. We propose a novel scaling procedure to connect nonequilibrium and equilibrium behaviors continuously, and find that the stretched-exponential scaling region in the Wolff algorithm is as wide as the power-law scaling region in local-update algorithms. We also find that relaxation to the spontaneous magnetization in the ordered phase is cha…
In this contribution we show that a suitably defined nonequilibrium entropy of an N-body isolated system is not a constant of the motion in general and its variation is bounded, the bounds determined by the thermodynamic entropy, i.e., the equilibrium entropy. We define the nonequilibrium entropy as a convex functional of the set of n-particle reduced distribution functions (n=0,......., N) generalizing the Gibbs fine-grained entropy formula. Additionally, as a consequence of our microscopic analysis we find that this nonequilibrium entropy behaves as a free entropic oscillator. In the approac…
The melting transition in the hard-disk system is considered. Non-equilibrium relaxation analysis of the six-fold bond-orientational order parameter has been carried out. The critical point between the hexatic and the fluid phase is determined on the basis of the dynamic scaling hypothesis. The value of the critical exponent $η$ is determined from the fluctuation of the order parameter at the criticality as $η= 0.25(2)$ which is consistent with the prediction by the Kosterlitz-Thouless-Halperin-Nelson-Young theory.
Systems with long-range interactions often relax towards statistical equilibrium over timescales that diverge with $N$, the number of particles. A recent work [S. Gupta and D. Mukamel, J. Stat. Mech.: Theory Exp. P03015 (2011)] analyzed a model system comprising $N$ globally coupled classical Heisenberg spins and evolving under classical spin dynamics. It was numerically shown to relax to equilibrium over a time that scales superlinearly with $N$. Here, we present a detailed study of the Lenard-Balescu operator that accounts at leading order for the finite-$N$ effects driving this relaxation. …
The Mpemba effect denotes an anomalous relaxation phenomenon where a system initially at a hot temperature cools faster than a system that starts at a less elevated temperature. We introduce an isothermal analog of this effect for a system prepared in a non-equilibrium steady state that then relaxes towards equilibrium. Here, the driving strength, which determines the initial non-equilibrium steady state, takes the role of the temperature in the original version. As a paradigm, we consider a particle initially driven by a non-conservative force along a one-dimensional periodic potential. We sh…
We consider the non-stationary quantum relaxation of the Ising spin chain in a transverse field of strength h. Starting from a homogeneously magnetized initial state the system approaches a stationary state by a process possessing quasi long range correlations in time and space, independent of the value of $h$. In particular the system exhibits aging (or lack of time translational invariance on intermediate time scales) although no indications of coarsening are present.
In this work, the relaxation process of the spin-3/2 Blume-Capel model with quenched random crystal field on a two dimensional square lattice has been investigated by a method which combines the statistical equilibrium theory and the thermodynamic of linear irreversible processes. Generalized force and flux have been defined in irreversible thermodynamics limit. The kinetic equation for the magnetization has been obtained by using linear response theory. In order to understand effect of the first-order phase transition on the relaxation process, low temperature regions have been analyzed. And …
For a model long-range interacting system of classical Heisenberg spins, we study how fluctuations, such as those arising from having a finite system size or through interaction with the environment, affect the dynamical process of relaxation to Boltzmann-Gibbs equilibrium. Under deterministic spin precessional dynamics, we unveil the full range of quasistationary behavior observed during relaxation to equilibrium, whereby the system is trapped in nonequilibrium states for times that diverge with the system size. The corresponding stochastic dynamics, modeling interaction with the environment …
We investigate the evolution of a system composed of $N$ non-interacting point particles of mass $m$ in a container divided into two chambers by a movable adiabatic piston of mass $M\gg m$. Using a two-time-scale perturbation approach in terms of the small parameter $α=2m/(M+m)$, we show that the evolution towards thermal equilibrium proceeds in two stages. The first stage is a fast, deterministic, adiabatic relaxation towards mechanical equilibrium. The second stage, which takes place at times ${\cal O}(M)$, is a slow fluctuation-driven, diathermic relaxation towards thermal equilibrium. A ve…
Paper in honour of Freeman Dyson on the occasion of his 80th birthday. Normal N-body systems relax to equilibrium distributions in which classical kinetic energy components are 1/2 kT, but, when inter-particle forces are an inverse cubic repulsion together with a linear (simple harmonic) attraction, the system pulsates for ever. In spite of this pulsation in scale, r(t), other degrees of freedom relax to an ever-changing Maxwellian distribution. With a new time, tau, defined so that r^2d/dt =d/d tau it is shown that the remaining degrees of freedom evolve with an unchanging reduced Hamiltonian…
Using the recently derived Dissipation Theorem and a corollary of the Transient Fluctuation Theorem (TFT), namely the Second Law Inequality, we derive the unique time independent, equilibrium phase space distribution function for an ergodic Hamiltonian system in contact with a remote heat bath. We prove under very general conditions that any deviation from this equilibrium distribution breaks the time independence of the distribution. Provided temporal correlations decay, and the system is ergodic, we show that any nonequilibrium distribution that is an even function of the momenta, eventually…
In the present paper the problem of the relaxation of magnetization to equilibrium (i.e., with no magnetization) is investigated numerically for a variant of the well-known model introduced by Bohr to study the diamagnetism of electrons in metals. Such a model is mathematically equivalent to a billiard with obstacles in a magnetic field. We show that it is not guaranteed that equilibrium is attained within the typical time scales of microscopic dynamics. Indeed, considering an out of equilibrium state produced by an adiabatic switching on of a magnetic field, we show that, depending on the val…
A classical long-range-interacting $N$-particle system relaxes to thermal equilibrium on time scales growing with $N$; in the limit $N\to \infty$ such a relaxation time diverges. However, a completely non-collisional relaxation process, known as violent relaxation, takes place on a much shorter time scale independent of $N$ and brings the system towards a non-thermal quasi-stationary state. A finite system will eventually reach thermal equilibrium, while an infinite system will remain trapped in the quasi-stationary state forever. For times smaller than the relaxation time the distribution fun…
Relaxation of the thermal Casimir or van der Waals force for a model dielectric medium is investigated. We start with a model of interacting polarization fields with a dynamics that leads to a frequency dependent dielectric constant of the Debye form. In the static limit the usual zero frequency Matsubara mode component of the Casimir force is recovered. We then consider the out of equilibrium relaxation of the van der Waals force to its equilibrium value when two initially uncorrelated dielectric bodies are brought into sudden proximity. It is found that the spatial dependence of the out of e…
We examine the question of the criteria of the relaxation to the equilibrium in the hard disk dynamics. In the Event-Chain Monte Carlo, we check the displacement distributions which follows to the exponential law.
Relaxation to equilibrium after strong and collective excitation is studied, by using a Hamiltonian dynamical system of one dimensional XY model. After an excitation of a domain of $K$ elements, the excitation is concentrated to fewer elements, which are made farther away from equilibrium, and the excitation intensity increases logarithmically with $K$. Equilibrium is reached only after taking this ``roundabout'' route, with the time for relaxation diverging asymptotically as $K^γ$ with $γ\approx 4.2$.
Starting from the second law of thermodynamics applied to an isolated system consisting of the system surrounded by an extremely large medium, we formulate a general non-equilibrium thermodynamic description of the system when it is out of equilibrium. We then apply it to study the structural relaxation in glasses and establish the phenomenology behind the concept of the fictive temperature and of the empirical Tool-Narayanaswamy equation on firmer theoretical foundation.
Ferromagnetic transition in double-exchange systems is studied by non-equilibrium relaxation technique combined with Monte Carlo calculations. Critical temperature and critical exponents are estimated from relaxation of the magnetic moment. The results are consistent with the previous Monte Carlo results in thermal equilibrium. The exponents estimated by these independent techniques suggest that the universality class of this transition is the same as that of short-range interaction models but is different from the mean-field one.
We present a dynamical description of slow relaxation processes based on the extension of Onsager's fluctuation theory to systems in local quasi-equilibrium. A non-Markovian Fokker-Planck equation for the conditional probability density is derived and from it we obtain the relaxation equation for the moments. We show that the fluctuation-dissipation theorem can be formulated in terms of the temperature of the system at local quasi-equilibrium. Our theory may be applied to a wide variety of systems undergoing slow relaxation. We discuss in particular slow dynamics in glassy systems and Brownian…
It has recently been shown that relaxation of the rotational energy of hot non-equlibrium photofragments (i) slows down significantly with the increase of their initial rotational temperature and (ii) differs dramatically from the relaxation of the equilibrium rotational energy correlation function, manifesting thereby breakdown of the linear response description [Science 311, 1907 (2006)]. We demonstrate that this phenomenon may be caused by the angular momentum dependence of rotational friction. We have developed the generalized Fokker-Planck equation whose rotational friction depends upon a…
We examine the problem of how excited populations of electrons relax after they have been excited by a pump. We include three of the most important relaxation processes: (i) impurity scattering; (ii) Coulomb scattering; and (iii) electron-phonon scattering. The relaxation of an excited population of electrons is one of the most fundamental processes measured in pump/probe experiments, but its interpretation remains under debate. We show how several common assumptions about non-equilibrium relaxation that are pervasive in the field may not hold under quite general conditions. The analysis shows…
This letter reports experimental and numerical results on particle dynamics in an out-of-equilibrium granular medium. We observed two distinct types of grain motion: the well known cage motion, during which a grain is always surrounded by the same neighbors, and low probability "jumps", during which a grain moves significantly more relative to the others. These observations are similar to the results obtained for other out-of-equilibrium systems (glasses, colloidal systems, etc.). Although such jumps are extremely rare, by inhibiting them in numerical simulations we demonstrate that they play …
Fluctuation theorems are a generalization of thermodynamics on small scales and provide the tools to characterize the fluctuations of thermodynamic quantities in non-equilibrium nanoscale systems. They are particularly important for understanding irreversibility and the second law in fundamental chemical and biological processes that are actively driven, thus operating far from thermal equilibrium. Here, we apply the framework of fluctuation theorems to investigate the important case of a system relaxing from a non-equilibrium state towards equilibrium. Using a vacuum-trapped nanoparticle, we …
The concept of a non-equilibrium interfacial tension, defined via the work required to deform the system such that the interfacial area is changed while the volume is conserved, is investigated theoretically in the context of the relaxation of an initial perturbation of a colloidal fluid towards the equilibrium state. The corresponding general formalism is derived for systems with planar symmetry and applied to fluid models of colloidal suspensions and polymer solutions. It is shown that the non-equilibrium interfacial tension is not necessarily positive, that negative non-equilibrium interfac…
Systems far from equilibrium approach stability slowly due to "anti-mixing" characterized by regions of the phase-space that remain disconnected after prolonged action of the flow. We introduce the Optimal Growth Mode (OGM) to capture this slow initial relaxation. The OGM is calculated from Markov matrices approximating the action of the Fokker-Planck operator onto the phase space. It is obtained as the mode having the largest growth in energy before decay. Important nuances between the OGM and the more traditional slowest decaying mode are detailed in the case of the Lorenz 63 model. The impl…
We study thermal relaxation in ordered arrays of coupled nonlinear elements with external driving. We find, that our model exhibits dynamic self-organization manifested in a universal stretched-exponential form of relaxation. We identify two types of self-organization, cooperative and anti-cooperative, which lead to fast and slow relaxation, respectively. We give a qualitative explanation for the behavior of the stretched exponent in different parameter ranges. We emphasize that this is a system exhibiting stretched-exponential relaxation without explicit disorder or frustration.
A scalable flow-based approach to mitigate topological freezing
Albert Einstein Center for Fundamental Physics, Institute for Theoretical Physics, University of Bern（阿尔伯特·爱因斯坦基础物理学研究中心，理论物理学研究所，伯尔尼大学）；Higgs Centre for Theoretical Physics, School of Physics and Astronomy, The University of Edinburgh（希格斯理论物理学中心，物理与天文学学院，爱丁堡大学）；Centre for Mathematical Sciences, University of Plymouth（数学科学中心，普利茅斯大学）
We study the non--equilibrium motion of an elastic string in a two dimensional pinning landscape using Langevin dynamics simulations. The relaxation of a line, initially flat, is characterized by a growing length, $L(t)$, separating the equilibrated short length scales from the flat long distance geometry that keep memory of the initial condition. We show that, in the long time limit, $L(t)$ has a non--algebraic growth with a universal distribution function. The distribution function of waiting times is also calculated, and related to the previous distribution. The barrier distribution is narr…
We study instabilities and relaxation to equilibrium in a long-range extension of the Fermi-Pasta-Ulam-Tsingou (FPU) oscillator chain by exciting initially the lowest Fourier mode. Localization in mode space is stronger for the long-range FPU model. This allows us to uncover the sporadic nature of instabilities, i.e., by varying initially the excitation amplitude of the lowest mode, which is the control parameter, instabilities occur in narrow amplitude intervals. Only for sufficiently large values of the amplitude, the system enters a permanently unstable regime. These findings also clarify t…
The long-time behaviour of spin-spin correlators in the slow relaxation of systems undergoing phase-ordering kinetics is studied in geometries of finite size. A phenomenological finite-size scaling ansatz is formulated and tested through the exact solution of the kinetic spherical model, quenched to below the critical temperature, in $2<d<4$ dimensions.
So far, only the energy thresholds of single discrete breathers in nonlinear Hamiltonian systems have been analytically obtained. In this work, the energy thresholds of discrete breathers in thermal equilibrium and the energy thresholds of long-lived discrete breathers which can remain after a long time relaxation are analytically estimated for nonlinear chains. These energy thresholds are size dependent. The energy thresholds of discrete breathers in thermal equilibrium are same as the previous analytical results for single discrete breathers. The energy thresholds of long-lived discrete brea…
We review in details some recently proposed kinetic models of opinion dynamics. We discuss the several variants including a generalised model. We provide mean field estimates for the critical points, which are numerically supported with reasonable accuracy. Using non-equilibrium relaxation techniques, we also investigate the nature of phase transitions observed in these models. We study the nature of correlations as the critical points are approached, and comment on the universality of the phase transitions observed.
We study the out-of-equilibrium dynamics of the quantum cellular automaton Rule 54 using a time-channel approach. We exhibit a family of (non-equilibrium) product states for which we are able to describe exactly the full relaxation dynamics. We use this to prove that finite subsystems relax to a one-parameter family of Gibbs states. We also consider inhomogeneous quenches. Specifically, we show that when the two halves of the system are prepared in two different solvable states, finite subsystems at finite distance from the centre eventually relax to the non-equilibrium steady state (NESS) pre…
