We develop constitutive equations for multi-component, multi-phase, macro-scale flow in a porous medium exposed to temperature-, composition-, and pressure -gradients. The porous medium is non-deformable. We define the pressure and the composition of the representative elementary volume (REV) in terms of the volume and surface averaged pressure and the saturation, and the respective driving forces from these variables. New contributions due to varying porosity or surface tension offer explanations for non-Darcy behavior. The interaction of a thermal and mechanical driving forces give thermal osmosis. An experimental program is suggested to verify Onsager symmetry in the transport coefficients.
The long-wave dynamics of liquid films on isothermal substrates show a dynamic competition between various physical mechanisms. If the destabilizing effect of thermocapillarity overcomes the stabilizing effect of surface tension and gravity, the liquid film ruptures in finite time, through the formation of primary and secondary thermocapillary finger structures. The long-wave evolution dynamics are compared for two different substrate types: isothermal non-porous and isothermal porous for small Biot number in a zero gravity environment. The multi-time-scale dynamics is revealed through time sc…
We model the flow of a bi-viscous non-Newtonian fluid in a porous medium by a square lattice where the links obey a piece-wise linear constitutive equation. We find numerically that the flow regime where the network transitions from all links behaving according to the first linear part of the constitutive equation to all links behaving according to the second linear part of the constitutive equation, is characterized by a critical point. We measure two critical exponents associated with this critical point, one of the being the correlation length exponent. We find that both critical exponents …
We derive the entropy production for transport of multi-phase fluids in a non-deformable, porous medium exposed to differences in pressure, temperature, and chemical potentials. Thermodynamic extensive variables on the macro-scale are obtained by integrating over a representative elementary volume (REV). Using Euler homogeneity of the first order, we obtain the Gibbs equation for the REV. From this we define the intensive variables, the temperature, pressure and chemical potentials and, using the balance equations, derive the entropy production for the REV. The entropy production defines sets …
Thin liquid films on isothermal substrates, where film is flat and parallel to the substrate, succumb to thermocapillary instabilities and rupture forming local hot-spots. These instabilities are called long wavelength instabilities and are specific to aspect ratios where the liquid film mean thickness is several orders of magnitude less than the substrate characteristic dimension. In the absence of stabilizing gravitational acceleration, the growth rate of thermocapillary instabilities is further intensified, driving the film to rupture at an even earlier time. Numerical simulations of zero g…
We present a continuum (i.e., an effective) description of immiscible two-phase flow in porous media characterized by two fields, the pressure and the saturation. Gradients in these two fields are the driving forces that move the immiscible fluids around. The fluids are characterized by two seepage velocity fields, one for each fluid. Following Hansen et al.\ (Transport in Porous Media, 125, 565 (2018)), we construct a two-way transformation between the velocity couple consisting of the seepage velocity of each fluid, to a velocity couple consisting of the average seepage velocity of both flui…
The study investigates the problem of magnetohydrodynamic (MHD) free convection over a non-isothermal axisymmetric body under the action of transverse magnetic field. The body is embedded in a porous medium saturated with electrically conducting non-Newtonian power law fluid. In order to obtain similarity solution, it is assumed that the viscosity of the fluid decays exponentially with temperature. The qualitative results are illustrated for a vertical flat plate, horizontal cylinder and sphere.
In petroleum reservoir simulation, the industry standard preconditioner, the constrained pressure residual method (CPR), is a two-stage process which involves solving a restricted pressure system with Algebraic Multigrid (AMG). Initially designed for isothermal models, this approach is often used in the thermal case. However, it does not have a specific treatment of the additional energy conservation equation and temperature variable. We seek to develop preconditioners which better capture thermal effects such as heat diffusion. In order to study the effects of both pressure and temperature on…
For both isothermal and thermal petroleum reservoir simulation, the Constrained Pressure Residual (CPR) method is the industry-standard preconditioner. This method is a two-stage process involving the solution of a restricted pressure system. While initially designed for the isothermal case, CPR is also the standard for thermal cases. However, its treatment of the energy conservation equation does not incorporate heat diffusion, which is often dominant in thermal cases. In this paper, we present an extension of CPR: the Constrained Pressure-Temperature Residual (CPTR) method, where a restricte…
The classical Lorentz reciprocal theorem (LRT) was originally derived for slow viscous flows of incompressible Newtonian fluids under the isothermal condition. In the present work, we extend the LRT from simple to complex fluids with open or moving boundaries that maintain non-equilibrium stationary states. In complex fluids, the hydrodynamic flow is coupled with the evolution of internal degrees of freedom such as the solute concentration in two-phase binary fluids and the spin in micropolar fluids. The dynamics of complex fluids can be described by local conservation laws supplemented with l…
Modelling Material Injection Into Porous Structures Under Non-isothermal Conditions
University of Stuttgart（斯图加特大学）；Institute for Modelling and Simulation of Biomechanical Systems, University of Stuttgart（斯图加特大学生物力学系统建模与仿真研究所）；Institute of Structural Mechanics and Dynamics of Aerospace Structures, University of Stuttgart（斯图加特大学航空航天结构结构力学与动力学研究所）；Ansbach University of Applied Sciences（安斯巴赫应用科学大学）；Stuttgart Center for Simulation Science (SC SimTech), University of Stuttgart（斯图加特大学斯图加特模拟科学中心）
Darcy's law for porous media transport is given a new local thermodynamic basis in terms of the grand potential of confined fluids. The local effective pressure gradient is determined using non-equilibrium molecular dynamics, and the hydraulic conductivity and permeability are investigated. The transport coefficients are determined for single-phase flow in face-centered cubic lattices of solid spheres. The porosity changed from that in the closest packing of spheres to near unity in a pure fluid, while the fluid mass density varied from that of a dilute gas to a dense liquid. The permeability …
Based on thermodynamic considerations we derive a set of equations relating the seepage velocities of the fluid components in immiscible and incompressible two-phase flow in porous media. They necessitate the introduction of a new velocity function, the co-moving velocity. This velocity function is a characteristic of the porous medium. Together with a constitutive relation between the velocities and the driving forces, such as the pressure gradient, these equations form a closed set. We solve four versions of the capillary tube model analytically using this theory. We test the theory numerica…
In this paper, a pore-scale network modeling method, based on the flow continuity residual in conjunction with a Newton-Raphson non-linear iterative solving technique, is proposed and used to obtain the pressure and flow fields in a network of interconnected distensible ducts representing, for instance, blood vasculature or deformable porous media. A previously derived analytical expression correlating boundary pressures to volumetric flow rate in compliant tubes for a pressure-area constitutive elastic relation has been used to represent the underlying flow model. Comparison to a preceding eq…
Convection heat transfer in porous media is a universal phenomenon in nature, and it is also frequently encountered in scientific and engineering fields. An in-depth understanding of the fundamental mechanism of convection heat transfer in porous media requires efficient and powerful numerical tools. In this paper, a cascaded lattice Boltzmann (CLB) method for convection heat transfer in porous media at the representative elementary volume (REV) scale is presented. In the CLB method, the flow field is solved by an isothermal CLB model with the D2Q9 lattice based on the generalized non-Darcy mo…
We perform direct numerical simulations of the flow through a model of a deformable porous medium. Our model is a two-dimensional hexagonal lattice, with defects, of soft elastic cylindrical pillars, with elastic shear modulus $G$, immersed in a liquid. We use a two-phase approach: the liquid phase is a viscous fluid and the solid phase is modeled as an incompressible viscoelastic material, whose complete nonlinear structural response is considered. We observe that the Darcy flux ($q$) is a nonlinear function -- steeper than linear -- of the pressure-difference ($ΔP$) across the medium. Furthe…
In this paper general dynamic equations describing the time evolution of isothermal quasi-incompressible multicomponent liquids are derived in the framework of the classical Ginzburg-Landau theory of first order phase transformations. Based on the fundamental {equations of continuum mechanics}, a general convection-diffusion dynamics is set up first for compressible liquids. The constitutive relations for the diffusion fluxes and the capillary stress are determined in the framework of gradient theories. {Next the general definition of incompressibility is given}, which is taken into account {i…
The present paper develops an isothermal model for fast (high Deborah number) contraction flows of polymers from a reservoir to a die of circular or rectangular cross-sections. Two components of composite flow models in different regions of the flow domain are connected in succession with the use of asymptotic matching boundary conditions. These components are inhomogeneous elongation and a modified unsteady shearing. It is constructed based on a stable and descriptive set of viscoelastic constitutive equations with the specified material parameters. The present model demonstrates a reasonable…
We consider the propagation of nonlinear plane waves in porous media within the framework of the Biot-Coussy biphasic mixture theory. The tortuosity effect is included in the model, and both constituents are assumed incompressible (Yeoh-type elastic skeleton, and saturating fluid). In this case, the linear dispersive waves governed by Biot's theory are either of compression or shear-wave type, and nonlinear waves can be classified in a similar way. In the special case of a neo-Hookean skeleton, we derive the explicit expressions for the characteristic wave speeds, leading to the hyperbolicity …
Capillary energy barriers have important consequences for immiscible fluid flow in porous media. We derive time-and-space averaging theory to account for non-equilibrium behavior and understand the role of athermal capillary fluctuations in the context of their relationship to larger scale phenomenological equations. The formulation resolves several key challenges associated with two-fluid flow in porous media: (1) geometric and thermodynamic quantities are constructed as smooth functions of time based on time-and space averages; (2) averaged thermodynamics are developed for films; (3) multi-s…
We study numerically two-dimensional creeping viscoelastic flow past a biperiodic square array of cylinders within the Oldroyd B, FENE-CR and FENE-P constitutive models of dilute polymer solutions. Our results capture the initial mild decrease then dramatic upturn ('thickening') seen experimentally in the drag coefficient as a function of increasing Weissenberg number. By systematically varying the porosity of the flow geometry, we demonstrate two qualitatively different mechanisms underpinning this thickening effect: one that operates in the highly porous case of widely spaced obstacles, and …
We study the effect of spatially-correlated heterogeneity on isothermal drying of porous media. We combine a minimal pore-scale model with microfluidic experiments with the same pore geometry. Our simulated drying behavior compare favorably with experiments, considering the large sensitivity of the emergent behavior to the uncertainty associated with even small manufacturing errors. We show that increasing the correlation length in particle sizes promotes preferential drying of clusters of large pores, prolonging liquid connectivity and surface wetness and thus higher drying rates for longer p…
Models that describe two-fluid flow in porous media suffer from a widely-recognized problem that the constitutive relationships used to predict capillary pressure as a function of the fluid saturation are non-unique, thus requiring a hysteretic description. As an alternative to the traditional perspec- tive, we consider a geometrical description of the capillary pressure, which relates the average mean curvature, the fluid saturation, the interfacial area between fluids, and the Euler characteristic. The state equation is formulated using notions from algebraic topology and cast in terms of me…
The Navier-Stokes-Korteweg (NSK) system is a classical diffuse interface model which is based on van der Waals theory of capillarity. Diffuse interface methods have gained much interest to model two-phase flow in porous media. However, for the numerical solution of the NSK equations two major challenges have to be faced. First, an extended numerical stencil is required due to a third-order term in the linear momentum and the total energy equations. In addition, the dispersive contribution in the linear momentum equations prevents the straightforward use of contact angle boundary conditions. Se…
Perfectly incompressible materials do not exist in nature but are a useful approximation of several media which can be deformed in non-isothermal processes but undergo very small volume variation. In this paper the linear analysis of the Darcy-Bénard problem is performed in the class of extended-quasi-thermal-incompressible fluids, introducing a factor $β$ which describes the compressibility of the fluid and plays an essential role in the instability results. In particular, in the Oberbeck-Boussinesq approximation, a more realistic constitutive equation for the fluid density is employed in ord…
Selective heating of a microparticle surface had been observed to cause its autonomous movement in a fluid medium due to self-generated temperature gradients. In this work, we theoretically investigate the response of such an auto-thermophoretic particle near a planar wall which is held isothermal. We derive an exact solution of the energy equation and employ the Reynolds reciprocal theorem to obtain the translational and rotational swimming velocities in the creeping flow limit. Subsequently, we analyse the trajectories of the micromotor for different thermo-physical and configurational param…
We derive a homogenized macroscopic model for fluid flows over ordered homogeneous porous surfaces. The unconfined free-flow is described by the Navier-Stokes equation, and the Darcy equation governs the seepage flow within the porous domain. Boundary conditions that accurately capture mass and momentum transport at the contact surface between these two domains are derived using the multiscale homogenization technique. In addition to obtaining the generalized version of the widely used Beavers-Joseph slip condition for tangential velocities, the present work provides an accurate formulation fo…
We study non-isothermal diffusive transport of a weakly-soluble two-component substance in a liquid-saturated porous medium being in contact with the reservoir of this substance. Particular attention is given to the example case of infiltration of nitrogen and oxygen from the atmosphere under the annual temperature oscillation. The surface temperature of the porous medium half-space oscillates in time, which results in a decaying solubility wave propagating deep into the porous medium. In such a system, the zones of saturated solution and nondissolved phase coexist with the zones of undersatur…
In the above paper by Bechtel, Cai, Rooney and Wang, Physics of Fluids, 2004, 16, 3955-3974 six different theories of a Newtonian viscous fluid are investigated and compared, namely, the theory of a compressible Newtonian fluid, and five constitutive limits of this theory: the incompressible theory, the limit where density changes only due to changes in temperature, the limit where density changes only with changes in entropy, the limit where pressure is a function only of temperature, and the limit of pressure a function only of entropy. The six theories are compared through their ability to …
Continuum models of porous media use macroscopic parameters and state variables to capture essential features of pore-scale physics. We propose a macroscopic property "accessivity" ($α$) to characterize the network connectivity of different sized pores in a porous medium, and macroscopic state descriptors "radius-resolved saturations" ($ψ_w(F),ψ_n(F)$) to characterize the distribution of fluid phases within. Small accessivity ($α\to0$) implies serial connections between different sized pores, while large accessivity ($α\to1$) corresponds to more parallel arrangements, as the classical capillar…
The radially outward flow of fluid through a porous medium occurs in many practical problems, from transport across vascular walls to the pressurisation of boreholes in the subsurface. When the driving pressure is non-negligible relative to the stiffness of the solid structure, the poromechanical coupling between the fluid and the solid can control both the steady-state and the transient mechanics of the system. Very large pressures or very soft materials lead to large deformations of the solid skeleton, which introduce kinematic and constitutive nonlinearity that can have a nontrivial impact …
Multi-phase reactive transport processes are ubiquitous in igneous systems. A challenging aspect of modelling igneous phenomena is that they range from solid-dominated porous to liquid-dominated suspension flows and therefore entail a wide spectrum of rheological conditions, flow speeds, and length scales. Most previous models have been restricted to the two-phase limits of porous melt transport in deforming, partially molten rock and crystal settling in convecting magma bodies. The goal of this paper is to develop a framework that can capture igneous system from source to surface at all phase…
The radially outward flow of fluid into a porous medium occurs in many practical problems, from transport across vascular walls to the pressurisation of boreholes. As the driving pressure becomes non-negligible relative to the stiffness of the solid structure, the poromechanical coupling between the fluid and the solid has an increasingly strong impact on the flow. For very large pressures or very soft materials, as is the case for hydraulic fracturing and arterial flows, this coupling can lead to large deformations and, hence, to strong deviations from a classical, linear-poroelastic response…
