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arXiv 1602.05293cond-mat.softcond-mat.dis-nncond-mat.stat-mech
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静止液体固有结构中的长程应力关联

Long Range Stress Correlations in the Inherent Structures of Liquids at Rest

Sadrul Chowdhury, Sneha Abraham, Toby Hudson, Peter Harrowell

摘要:

模拟研究了二维和三维二元液体混合物中局部势能极小值(固有结构)的原子剪切应力。这些固有的结构应力是过冷液体中缓慢的应力松弛和高粘度的基础。我们发现,原子剪切应力的固有结构(IS)的两种液体在休息表现出缓慢衰减的各向异性的相关性。我们发现,应力相关性的IS配置的总剪应力的方差显着贡献,并考虑应力相关性的各向异性和空间范围的起源。

英文摘要:

Simulation studies of the atomic shear stress in the local potential energy minima (inherent structures) are reported for binary liquid mixtures in 2D and 3D. These inherent structure stresses are fundamental to slow stress relaxation and high viscosity in supercooled liquids. We find that the atomic shear stress in the inherent structures (IS) of both liquids at rest exhibits slowly decaying anisotropic correlations. We show that the stress correlations contributes significantly to the variance of the total shear stress of the IS configurations and consider the origins of the anisotropy and spatial extent of the stress correlations.

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