We examine square and kagome artificial spin ice for colloids confined in arrays of double-well traps. Unlike magnetic artificial spin ices, colloidal and vortex artificial spin ice realizations allow creation of doping sites through double occupation of individual traps. We find that doping square and kagome ice geometries produces opposite effects. For square ice, doping creates local excitations in the ground state configuration that produce a local melting effect as the temperature is raised. In contrast, the kagome ice ground state can absorb the doping charge without generating non-ground-state excitations, while at elevated temperatures the hopping of individual colloids is suppressed near the doping sites. These results indicate that in the square ice, doping adds degeneracy to the ordered ground state and creates local weak spots, while in the kagome ice, which has a highly degenerate ground state, doping locally decreases the degeneracy and creates local hard regions.
Using numerical simulations that mimic recent experiments on hexagonal colloidal ice, we show that colloidal hexagonal artificial spin ice exhibits an inner phase within its ice state that has not been observed previously. Under increasing colloid-colloid repulsion, the initially paramagnetic system crosses into a disordered ice-regime, then forms a topologically charge ordered state with disordered colloids, and finally reaches a three-fold degenerate, ordered ferromagnetic state. This is reminiscent of, yet distinct from, the inner phases of the magnetic kagome spin ice analog. The differenc…
Artificial particle ices are model systems of constrained, interacting particles. They have been introduced theoretically to study ice-manifolds emergent from frustration, along with domain wall and grain boundary dynamics, doping, pinning-depinning, controlled transport of topological defects, avalanches, and memory effects. Recently such particle-based ices have been experimentally realized with vortices in nano-patterned superconductors or gravitationally trapped colloids. Here we demonstrate that, although these ices are generally considered equivalent to magnetic spin ices, they can acces…
The effect of boundaries and how these can be used to influence the bulk behaviour in geometrically frustrated systems are both long-standing puzzles, often relegated to secondary role. Here we use numerical simulations and "proof of concept" experiments to demonstrate that boundaries can be engineered to control the bulk behavior in a colloidal artificial ice. We show that an antiferromagnetic frontier forces the system to rapidly reach the ground state (GS), as opposed to the commonly implemented open or periodic boundary conditions. We also show that strategically placing defects at the cor…
Artificial ice systems have been designed to replicate paradigmatic phenomena observed in frustrated spin systems. Here we present a detailed theoretical analysis based on Monte-Carlo simulations of the low energy phases in an artificial colloidal ice system, a recently introduced ice system where an ensemble of repulsive colloids are two-dimensionally confined by gravity to a lattice of double wells at a one-to-one filling. Triggered by recent results obtained by Brownian dynamics simulations [A. Libál et al, Phys. Rev. Lett. 120, 027204 (2018)], we analyze the energetics and the phase transi…
Recovery of ground-state degeneracy in two-dimensional square ice is a significant challenge in the field of geometric frustration with far-reaching fundamental implications, such as realization of vertex models and understanding the effect of dimensionality reduction. We combine experiments, theory, and numerical simulations to demonstrate that sheared square colloidal ice partially recovers the ground-state degeneracy for a wide range of field strengths and lattice shear angles. Our method opens an avenue to engineer a novel class of frustrated micro- and nano-structures based on sheared mag…
Formation mechanism of speed-dependent ice bandings in freezing colloidal suspensions, of significance in frost heaving and materials science, remains a mystery. With quantitative experiments, we propose a possible mechanism of speed-dependent ice bandings by focusing on the particle packing density and dynamic interface undercooling. The particle packing density ahead of the freezing interface decreases with increasing pulling speeds, attributed to the speed-dependent packing of particles. Through affecting the curvature undercooling of pore ices, the speed-dependent packing of particles can …
The freezing of colloidal suspensions is encountered in many natural and engineering processes such as the freezing of soils, food engineering, and cryobiology. It can also be used as a bio-inspired, versatile, and environmentally-friendly processing route for porous materials and composites. Yet, it is still a puzzling phenomenon with many unexplained features, due to the complexity of the system and the space and time scales at which the process should be investigated. We demonstrate here the interest of fast X-ray computed tomography to provide time-lapse, three-dimensional, in situ imaging…
Emergent charge crystallization and frustration in a particle anti-spin Ice
Universitat de Barcelona（巴塞罗那大学）；Institute of Complex Systems (UBICS), Universitat de Barcelona（巴塞罗那大学复杂系统研究所）；Theoretical Division, Center for NonLinear Studies, Los Alamos National Laboratory（洛斯阿拉莫斯国家实验室非线性研究理论部）
Artificial spin ices are ideal frustrated model systems in which to explore or design emergent phenomena with unprecedented characterization of the constituent degrees of freedom. In square spin ice, violations of the ice rule are topological excitations essential to the kinetics of the system, providing an ideal testbed for studying the dynamics of such defects under varied quench rates. In this work we describe the first test of the Kibble-Zurek mechanism and critical coarsening in colloidal square and colloidal hexagonal ice under quenches from a weakly interacting liquid state into a stron…
