Magnetic nanoparticles are useful biological probes as well as therapeutic agents. There have been several approaches used to model nanoparticle magnetization dynamics for both Brownian as well as Néel rotation. The magnetizations are often of interest and can be compared with experimental results. Here we summarize these approaches including the Stoner-Wohlfarth approach, and stochastic approaches including thermal fluctuations. Non-equilibrium related temperature effects can be described by a distribution function approach (Fokker-Planck equation) or a stochastic differential equation (Langevin equation). Approximate models in several regimes can be derived from these general approaches to simplify implementation.
Assemblies of magnetic nanoparticles show a great potential for application in biomedicine, in particular, in magnetic hyperthermia. However, to achieve desired therapeutic effect in magnetic hyperthermia the assembly of nanoparticles should have a sufficiently high specific absorption rate in alternating magnetic field of moderate amplitude and frequency.
Remote sensing of magnetic nanoparticles has exciting applications for magnetic nanoparticle hyperthermia and molecular detection. We introduce, simulate, and experimentally demonstrate an innovation---a sensing coil that is geometrically decoupled from the excitation field---for magnetic nanoparticle spectroscopy that increases the flexibility and capabilities of remote detection. The decoupling enhances the sensitivity absolutely; to small amounts of nanoparticles, and relatively; to small changes in the nanoparticle dynamics. We adapt a previous spectroscopic method that measures the relaxa…
Measurements of magnetic hysteresis loops in single Co nanoparticles at dilution refrigerator temperatures are presented. The nanoparticles are in electric contact with bulk Al leads via tunnel junctions. The tunnel current versus magnetic field displays a magnetic hysteresis loop. The magnetic switching field is reduced by current, and the magnetization of the nanoparticle can be switched by applying a voltage pulse, demonstrating that the magnetic stability of the nanoparticle is diminished by electron transport. Additional transitions and random switches of magnetization can be driven by la…
Recent work [1] demonstrated high coercivity and magnetic moment in cobalt carbide nanoparticle assemblies and explained the high coercivity from first principles in terms of the high magnetocrystalline anisotropy of the cobalt carbide nanoparticles. In this work, we comprehensively model the interaction between the nanoparticles comprising the assembly and systematically understand the effect of particle size, distribution of the orientations of the nanoparticles' magnetocrystalline anisotropy axis with respect to the applied magnetic field, and dipole coupling between nanoparticles on the te…
The complex permittivity and permeability of superparamagnetic iron-oxide nanoparticles has been quantified using a circular waveguide assembly with a static magnetic field to align the nanoparticle's magnetization. The high sensitivity of the measurement provides the precise resonant feature of nanoparticles. The complex permeability in the vicinity of ferromagnetic resonance (FMR) is in agreement with the nanoparticle's measured magnetization via conventional magnetometry. A rigorous and self-consistent measure of complex permittivities and permeabilities of nanoparticles is crucial to ascer…
We present a systematic numerical modeling investigation of magnetization dynamics and thermal magnetic moment fluctuations of single magnetic domain nanoparticles in a configuration applicable to enhancing inductive magnetic resonance detection signal to noise ratio (SNR). Previous proposals for oriented anisotropic single magnetic domain nanoparticle amplification of magnetic flux in MRI coil focused only on the coil pick-up voltage signal enhancement. Here we extend the analysis to the numerical evaluation of the SNR by modeling the inherent thermal magnetic noise introduced into the detect…
The influence of the crystal structure inhomogeneities on the magnetic properties of cobalt nanoparticles with different aspect ratio and spherical nanoparticles of chromium dioxide, cobalt ferrite and magnetite has been studied by means of numerical simulation. The polycrystalline nanoparticles are modeled by means of subdivision of the nanoparticle volume into tightly bound single-crystal granules with randomly distributed directions of the easy anisotropy axes. The probability of appearance of quasi uniform and vortex states in sufficiently large assemblies of polycrystalline nanoparticles …
Magnetization of nanoparticles of NiO are measured and analyzed taking into account a distribution in particle magnetic moment. We find that disregarding this distribution in the analysis is the reason for the many anomalous observations reported on this system in the literature.
We report evidence of the magnetization reversal in nanoparticles by surface acoustic waves (SAWs). The experimental system consists of isolated magnetite nanoparticles dispersed on a piezoelectric substrate. Magnetic relaxation from a saturated state becomes significantly enhanced in the presence of the SAW at a constant temperature of the substrate. The dependence of the relaxation on SAW power and frequency has been investigated. The effect is explained by the effective ac magnetic field generated by the SAW in the nanoparticles.
Thermomagnetic measurements are used to obtain the size distribution and anisotropy of magnetic nanoparticles. An analytical transformation method is described which utilizes temperature-dependent zero-field cooling (ZFC) magnetization data to provide a quantitative measurement of the average diameter and relative abundance of superparamagnetic nanoparticles. Applying this method to self-assembled MnAs nanoparticles in MnAs-GaAs composite films reveals a log-normal size distribution and reduced anisotropy for nanoparticles compared to bulk materials. This analytical technique holds promise for…
We present Vinamax, a simulation tool for nanoparticles that aims at simulating magnetization dynamics on very large timescales. To this end, each in dividual nanoparticle is approximated by a macrospin. Vinamax numerically solves the Landau-Lifshitz equation by adopting a dipole approximation method, while temperature effects can be taken into account with two stochastic methods. It describes the influence of demagnetizing and anisotropy fields on magnetic nanoparticles at finite temperatures in a space and time-dependent externally applied field. Vinamax can be used in biomedical research wh…
Superparamagnetic nanoparticles containing hundreds and thousands of coupled electron spins are on the boundary between classical and quantum behavior, and demonstrate features which are typical for paramagnetic spins and absent in macroscopic ferromagnetic systems. In order to better understand the evolution of magnetization dynamics from quantum to classical behavior with the increase in the system size, we study the electron magnetic resonance signal in suspensions of iron oxide nanoparticles as the function of the particle size. The experimental data are compared with numerical simulations…
We investigate the magnetization dynamics of a conducting magnetic nanoparticle weakly coupled to source and drain electrodes, under the assumption that all relaxation comes from exchange of electrons with the electrodes. The magnetization dynamics is characterized by a relaxation time $t_1$, which strongly depends on temperature, bias voltage, and gate voltage. While a direct measure of a nanoparticle magnetization might be difficult, we find that $t_1$ can be determined through a time resolved transport measurement. For a suitable choice of gate voltage and bias voltage, the magnetization pe…
We have carried out in ferritin the Field-Cooling method and data analysis proposed by Mamiya et al. (Phys. Rev. Lett. 88, 67202 (2002) at T = 5 K in order to check the time magnetic relaxation of these antiferromagnetic nanoparticles as a function of the magnetic field. We found that relaxation at T = 5 K in ferritin is faster in the absence of magnetic field, in good agreement with the zero-field Resonant Spin Quantum Tunneling observed previously in ferritin (Phys. Rev. Lett. 79, 1754 (1997).
We report studies on temperature, field and time dependence of magnetization on cupric oxide nanoparticles of sizes 9 nm, 13 nm and 16 nm. The nanoparticles show unusual features in comparison to other antiferromagnetic nanoparticle systems. The field cooled (FC) and zero field cooled (ZFC) magnetization curves bifurcate well above the Néel temperature and the usual peak in the ZFC magnetization curve is absent. The system does not show any memory effects which is in sharp contrast to the usual behavior shown by other antiferromagnetic nanoparticles. It turns out that the non-equilibrium behav…
The performance characteristics of magnetic nanoparticles towards application, e.g. in medicine, imaging, or as sensors, is directly determined by their magnetization relaxation and total magnetic moment. In the commonly assumed picture, nanoparticles have a constant overall magnetic moment originating from the magnetization of the single-domain particle core surrounded by a surface region hosting spin disorder. In contrast, this work demonstrates the significant increase of the magnetic moment of ferrite nanoparticles with applied magnetic field. At low magnetic field, the homogeneously magne…
We address the theory of the coupled lattice and magnetization dynamics of freely suspended single-domain nanoparticles. Magnetic anisotropy generates low-frequency satellite peaks in the microwave absorption spectrum and a blueshift of the ferromagnetic resonance (FMR) frequency. The low-frequency resonances are very sharp with maxima exceeding that of the FMR, because their magnetic and mechanical precessions are locked, thereby suppressing Gilbert damping. Magnetic nanoparticles can operate as nearly ideal motors that convert electromagnetic into mechanical energy. The Barnett/Einstein-de H…
Magnetic vortices existing in soft magnetic nanoparticles with sizes larger than the single-domain diameter can be efficient nano-heaters in biomedical applications. Using micromagnetic numerical simulation we prove that in the optimal range of particle diameters the magnetization reversal of the vortices in spherical iron and magnetite nanoparticles is possible for moderate amplitudes of external alternating magnetic field. In contrast to the case of superparamagnetic nanoparticles, for the vortex configuration the hysteresis loop area increases as a function of frequency. So that high values…
We present a study by ferromagnetic resonance at microwave Q band of two sheets of cobalt nanoparticles obtained by annealing SiO2 layers implanted with cobalt ions. This ex- perimental study is performed as a function of the applied magnetic field orientation, tempera- ture, and dose of implanted cobalt ions. We demonstrate that each of those magnetic sheet of cobalt nanoparticles can be well modelled by a nearly two dimensional ferromagnetic sheet hav- ing a reduced effective saturation magnetization, compared to a regular thin film of cobalt. The nanoparticles are found superparamagnetic ab…
High fraction of the surface atoms considerably enhances the influence of size and shape on the magnetic and electronic properties of nanoparticles. Shape effects in ferromagnetic nanoparticles are well understood and allow to set and control the parameters of a sample that affect its magnetic anisotropy during production. In the present paper we study the shape effects in the other widely used magnetic materials -- antiferromagnets, -- which possess vanishingly small or zero macroscopic magnetization. We take into account the difference between the surface and bulk magnetic anisotropy of a na…
We demonstrate the quantitative measurement of the magnetization of individual magnetic nanoparticles (MNP) using a magnetic force microscope (MFM). The quantitative measurement is realized by calibration of the MFM signal using an MNP reference sample with traceably determined magnetization. A resolution of the magnetic moment of the order of 10^(-18) Am^2 under ambient conditions is demonstrated which is presently limited by the tip's magnetic moment and the noise level of the instrument. The calibration scheme can be applied to practically any MFM and tip thus allowing a wide range of futur…
Highly sophisticated synthesis methods and experimental techniques allow for precise measurements of magnetic properties of nanoparticles that can be reliably reproduced using theoretical models. Here, we investigate the magnetic properties of ferrite nanoparticles by using theoretical techniques based on Monte Carlo methods. We introduce three stages of sophistication in the macromagnetic model. First, by using tailor-made hamiltonians we study single nanoparticles. In a second stage, the internal structure of the nanoparticle is taken into consideration by defining an internal (core) and ext…
Magnetic skyrmions formed at temperatures around room temperature in square-based parallelepiped magnetic FePt nanoparticles with perpendicular magnetocrystalline anisotropy (MCA) were studied during the magnetization reversal using micromagnetic simulations. Finite Differences (FD) method were used for the solution of the Landau-Lifshitz-Gilbert equation. Magnetic configurations exhibiting Néel skyrmionic formations were detected. The magnetic skyrmions can be created in different systems generated by the variation of external field, side length and width of the squared-based parallelepiped m…
We show that by capping Co nanoparticles with small amounts of Pt strong changes of the magnetic properties can be induced. The Co nanoparticles have a mean diameter of 2.7 nm. From magnetometry measurements we find that for zero and for small amounts of Pt (nominal thickness t(Pt) < 0.7 nm) the nanoparticles behave superparamagnetic like. With increasing t(Pt) the blocking temperature is enhanced from 16 up to 108 K. Capping with Pd yields comparable results. However, for values t(Pt) > 1 nm a strongly coupled state is encountered resembling a ferromagnet with a T_c approx. 400 K
We report detailed studies on non-equilibrium magnetic behavior of antiferromagnetic Co_3O_4 nanoparticles. Temperature and field dependence of magnetization, wait time dependence of magnetic relaxation (aging), memory effects and temperature dependence of specific heat have been investigated to understand the magnetic behavior of these particles. We find that the system shows some features characteristic of nanoparticle magnetism such as bifurcation of field cooled (FC) and zero field cooled (ZFC) susceptibilities and a slow relaxation of magnetization. However, strangely, the temperature at …
We argue that for some species of magnetic nanoparticles the macrospin can have a nonvanishing moment of inertia and then an orbital angular momentum. We represent such nanoparticles by two interacting rigid rotors one of which has a large spin attached to the body, namely by a Two Rotor Model with spin. By this model we can describe in a unified way the cases of nanoparticles free and stuck in an elastic or rigid matrix. We evaluate the magnetic susceptibilities for the latter case and under some realistic assumptions we get results in closed form. A crossover between thermal and purely quant…
We comment on some misleading and biased statements appearing in the manuscript arXiv:1209.0298 ("Thermal fluctuations of magnetic nanoparticles") about the use of the damped Landau-Lifshitz equation and the kinetic Langer theory for the calculation of the relaxation rate of magnetic nanoclusters. We reiterate simple scientific arguments, part of which is well known to the whole community, demonstrating that the authors' criticisms are unfounded and that they overstate the issue of damping in the Landau-Lifshitz equation with no unanimous experimental evidence.
We present a theoretical investigation of magnetostatic interaction effects in geometrically frustrated arrays of anisotropic multilayer ferromagnetic nanoparticles arranged in different spatially configured systems with triangular symmetry. We show that the interlayer magnetostatic interaction significantly expands the opportunities to create magnetically frustrated systems. The effects of the magnetostatic interaction in magnetization reversal processes and the possibility to control the ferromagnetic resonance spectrum in such systems are discussed.
Thermal activation tends to destroy the magnetic stability of small magnetic nanoparticles, with crucial implications in ultra-high density recording among other applications. Here we demonstrate that low blocking temperature ferromagnetic (FM) Co nanoparticles (TB<70 K) become magnetically stable above 400 K when embedded in a high Néel temperature antiferromagnetic (AFM) NiO matrix. The origin of this remarkable TB enhancement is due to a magnetic proximity effect between a thin CoO shell (with low Néel temperature, TN; and high anisotropy, KAFM) surrounding the Co nanoparticles and the NiO …
A set of equations describing the motion of a free magnetic nanoparticle in an external magnetic field in a vacuum, or in a medium with negligibly small friction forces is postulated. The conservation of the total particle momentum, i.e. the sum of the mechanical and the total spin momentum of the nanoparticle is taken into account explicitly. It is shown that for the motion of a nanoparticle in uniform magnetic field there are three different modes of precession of the unit magnetization vector and the director that is parallel the particle easy anisotropy axis. These modes differ significant…
We investigate the consequence of the dimension reduction on the magnetic anisotropy of FePt and CoPt nanoparticles. Using an extension of the magnetic anisotropy model of Néel, we show that, due to a statistical finite size effect, chemically disordered clusters can display a magnetic anisotropy energy (MAE) as high as 0.5\times10^6 J/m3, more than one order of magnitude higher than the bulk MAE. Concerning L10 ordered clusters, we show that the surface induces a reduction of the MAE as compared to the bulk, due to the symmetry breaking at the cluster surface, which modifies the chemical orde…
: Understanding the correlations between magnetic nanoparticles is important for nanotechnologies, such as high-density magnetic recording and biomedical applications, where functionalized magnetic particles are used as contrast agents and for drug delivery. The ability to control the magnetic state of individual particles depends on the good knowledge of magnetic correlations between particles when assembled. Inaccessible via standard magnetometry techniques, nanoscale magnetic ordering in self-assemblies of Fe3O4 nanoparticles is here unveiled via x-ray resonant magnetic scattering (XRMS). M…
We study the deterministic and stochastic rotational dynamics of ferromagnetic nanoparticles in a precessing magnetic field. Our approach is based on the system of effective Langevin equations and on the corresponding Fokker-Planck equation. Two key characteristics of the rotational dynamics, the average angular frequency of precession of nanoparticles and their average magnetization, are of our interest. Using the Langevin and Fokker-Planck equations, we calculate both analytically and numerically these characteristics in the deterministic and stochastic cases, determine their dependence on t…
Magnetic nanoparticles have proven to be valuable for biomedical applications. A prerequisite for the efficiency of these applications are precisely characterized particles. Thermal Noise Magnetrometry (TNM), unlike any other magnetic characterization method, allows to characterize the particles without the application of an external excitation. We present a theoretical framework to model the experiment in order to examine the magnetic noise power properties of particle ensembles in TNM and optimize the geometry of the nanoparticle sample. An optimized sample geometry is calculated to maximize…
In this article we study magnetotransport in single nanoparticles of Ni, Py=Ni$_{0.8}$Fe$_{0.2}$, Co, and Fe, with volumes $15\pm 6$nm$^3$, using sequential electron tunneling at 4.2K temperature. We measure current versus magnetic field in the ensembles of nominally the same samples, and obtain the abundances of magnetic hysteresis. The hysteresis abundance varies among the metals as Ni:Py:Co:Fe=4\,:50\,:100\,:100(\%), in good correlation with the magnetostatic and magnetocrystalline anisotropy. The abrupt change in the hysteresis abundance among these metals suggests a concept of minimum mag…
We demonstrate the use of the magnetic-field-dependence of highly spatially confined, GHz-frequency ferromagnetic resonances in a ferromagnetic nanostructure for the detection of adsorbed magnetic nanoparticles. This is achieved in a large area magnonic crystal consisting of a thin ferromagnetic film containing a periodic array of closely spaced, nano-scale anti-dots. Stray fields from nanoparticles within the anti-dots modify resonant dynamic magnetisation modes in the surrounding magnonic crystal, generating easily measurable resonance peak shifts. The shifts are comparable to the resonance …
Magnetic nanoparticle hyperthermia is an attractive emerging cancer treatment, but the acting microscopic energy deposition mechanisms are not well understood and optimization suffers. We describe several approximate forms for the characteristic time of Néel rotations with varying properties and external influences. We then present stochastic simulations that show agreement between the approximate expressions and the micromagnetic model. The simulations show nonlinear imaginary responses and associated relaxational hysteresis due to the field and frequency dependencies of the magnetization. Th…
A specific absorption rate of a dilute assembly of various random clusters of iron oxide nanoparticles in alternating magnetic field has been calculated using Landau- Lifshitz stochastic equation. This approach simultaneously takes into account both the presence of thermal fluctuations of the nanoparticle magnetic moments, and magneto-dipole interaction between the nanoparticles of the clusters. It is shown that for usual 3D clusters the intensity of magneto- dipole interaction is determined mainly by the cluster packing density eta = Np*V/Vcl, where Np is the average number of the particles i…
A kinetic Monte Carlo approach is developed for studying growth and evaporation of nanoparticles on/off nanotubes. This study has been motivated by recent experimental advances in using nanoparticle evaporation (sublimation) off nanoparticle-decorated nanotubes for nanoscale "thermometry." We demonstrate that the considered kinetic Monte Carlo approach can reproduce features of the process that are not included in phenomenological thermodynamic modeling, as well as provide snapshots of the growth and evaporation process morphology.
Using finite element micromagnetic simulations, we study how resonant magnetisation dynamics in thin magnetic discs with perpendicular anisotropy are influenced by magnetostatic coupling to a magnetic nanoparticle. We identify resonant modes within the disc using direct magnetic eigenmode calculations and study how their frequencies and profiles are changed by the nanoparticle's stray magnetic field. We demonstrate that particles can generate shifts in the resonant frequency of the disc's fundamental mode which exceed resonance linewidths in recently studied spin torque oscillator devices. Imp…
Iron oxide nanoparticles have tremendous scientific and technological potential in a broad range of technologies, from energy applications to biomedicine. To improve their performance, single-crystalline and defect-free nanoparticles have thus far been aspired. However, in several recent studies defect-rich nanoparticles outperform their defect-free counterparts in magnetic hyperthermia and magnetic particle imaging. Here, an overview on the state-of-the-art of design and characterization of defects and resulting spin disorder in magnetic nanoparticles is presented with a focus on iron oxide n…
The aggregation of superparamagnetic iron oxide (SPIO) nanoparticles decreases the transverse nuclear magnetic resonance (NMR) relaxation time T2 of adjacent water molecules measured by a Carr-Purcell-Meiboom-Gill (CPMG) pulse-echo sequence. This effect is commonly used to measure the concentrations of a variety of small molecules. We perform extensive Monte Carlo simulations of water diffusing around SPIO nanoparticle aggregates to determine the relationship between T2 and details of the aggregate. We find that in the motional averaging regime T2 scales as a power law with the number N of nan…
This chapter provides an introduction to the fundamental physical ideas and models relevant to the phenomenon of magnetic hysteresis in nanoparticle assemblies. The concepts of single-domain particles and superparamagnetism are discussed. The mechanisms of magnetization by coherent rotation and the role of temperature in the gradual decay of magnetization are analyzed in the framework of simple analytical models. Modern numerical techniques (Monte Carlo simulations, Magnetization Dynamics) used to study dense nanoparticle assemblies are presented. An overview of the most common experimental te…
During the last years great attention has been given to the encapsulation of magnetic nanoparticles. In this work we investigated the stability of small magnetic particles inside magnetic nanotubes. Multisegmented nanotubes were tested in order to optimize the stability of the particle inside the nanotubes. Our results evidenced that multisegmented nanotubes are more efficient to entrap the particles at temperatures up to hundreds of kelvins.
The magnetic behavior of truncated conical nanoparticles in patterned thin films is investigated as a function of their size and shape. Using a scaling technique, phase diagrams giving the relative stability of characteristic internal magnetic structures of the particles are obtained. The role of the uniaxial anisotropy in determining the magnetic properties of such systems is discussed, and a simple method for stablishing its strength is proposed.
Homogeneous single phase GdCrO3 nanoparticles are synthesized by a modified-hydrothermal synthesis. The sample shows a compensation temperature at 128 K, below which the DC magnetization becomes negative and positive at low temperatures due to the competition between the two sublattice magnetization. At Néel temperature (168K), the line width and the intensity show an abrupt transition, revealed from electron paramagnetic resonance spectroscopy.
To evaluate the self-heating effects of FeCo magnetic nanoparticles, the surface oxidized FeCo nanoparticles were synthesized by co-precipitation method with the reduction reaction without any post treatments. As-synthesized FeCo nanoparticles exhibited the mean diameter of about 39 nm with the oxidized shell thickness of about 4-5 nm. The saturation magnetization and coercivity were obtained 172 emu/g and 268 Oe at 300 K, respectively. The heat elevation of the FeCo magnetic colloid was measured under alternating magnetic fields of 76, 102, and 127 Oe with selectable frequencies of 190, 250 a…
Magnetic and NMR relaxivity properties of γ-Fe2O3 nanoparticles embedded into the walls of polyelectrolyte multilayer capsules and freely dispersed in a sodium borate buffer solution have been investigated. The different geometric distribution of both configurations provides the opportunity to study the relationship of water accessibility and magnetic properties of particles on the NMR relaxivity. Changes in their blocking temperature and average dipolar field were modeled as a function of packing fraction in the ensemble of free and entrapped nanoparticles. For free nanoparticles with relativ…
We report about a combined structural and magnetometric characterization of self-assembled magnetic nanoparticle arrays. Monodisperse iron oxide nanoparticles with a diameter of 20 nm were synthesized by thermal decomposition. The nanoparticle suspension was spin-coated on Si substrates to achieve self-organized arrays of particles and subsequently annealed at various conditions. The samples were characterized by x-ray diffraction, bright and dark field high resolution transmission electron microscopy (HRTEM). The structural analysis is compared to the magnetic behavior investigated by superco…
Using a new microSQUID set-up, we investigate magnetic anisotropy in a single 1000-atoms cobalt cluster. This system opens new fields in the characterization and the understanding of the origin of magnetic anisotropy in such nanoparticles. For this purpose, we report three-dimensional switching field measurements performed on a 3 nm cobalt cluster embedded in a niobium matrix. We are able to separate the different magnetic anisotropy contributions and evidence the dominating role of the cluster surface.
Near room temperature, thin films of MnAs spontaneously align into two phases, one ferromagnetic and the other paramagnetic. These two phases take the intriguing form of nanoscale "wires." In this experiment, we investigate the spontaneous formation of ordered linear arrays of magnetite nanoparticles on MnAs thin films using scanning probe microscopy.
The deterministic Landau-Lifshitz-Gilbert equation has been used to investigate the nonlinear dynamics of magnetization and the specific loss power in magnetic nanoparticles with uniaxial anisotropy driven by a rotating magnetic field. We propose a new type of applied field, which is "simultaneously rotating and alternating", i.e. the direction of the rotating external field changes periodically. We show that a more efficient heat generation by magnetic nanoparticles is possible with this new type of applied field and we suggest its possible experimental realization in cancer therapy which req…
This paper reports the effect of Fe doping on the structure and room temperature ferromagnetism of CeO2 nanoparticles. X-ray diffraction and selective area electron diffraction measurement reflects that Ce1-xFexO2 (x = 0.0 - 0.07) nanoparticles exhibit single phase nature with cubic structure and none of the sample showed the presence of any secondary phase. The mean particle size calculated by using a transmission electron microscopy measurement was found to increase with increase in Fe content. DC magnetization measurements performed at room temperature indicates that all the samples exhibit…
We theoretically investigate the creation of a magnetic moment in gold nanoparticles by circularly polarized laser light. To this end, we describe the collective electron dynamics in gold nanoparticles using a semiclassical approach based on a quantum hydrodynamic model that incorporates the prin- cipal quantum many-body and nonlocal effects, such as the electron spill-out, the Hartree potential, and the exchange and correlation effects. We use a variational approach to investigate the breathing and the dipole dynamics induced by an external electric field. We show that gold nanoparticles can …
