The electronic properties of graphene are influenced by both geometric confinement and strain. We study the electronic structure of in-plane bent graphene nanoribbons, systems where confinement and strain are combined. To understand its electronic properties, we develop a tight-binding model that has a small computational cost and is based on exponentially decaying hopping and overlap parameters. Using this model, we show that the edge states in zigzag graphene nanoribbons are sensitive to bending and develop an effective dispersion that can be described by a one-dimensional atomic chain model. Because the velocity of the electrons at the edge is proportional to the slope of the dispersion, the edge states become gradually delocalized upon increasing the strength of bending.
We investigate the bending properties of carbon nanoribbons by combining continuum elasticity theory and tight-binding atomistic simulations. First, we develop a complete analysis of a given bended configuration through continuum mechanics. Then, we provide by tight-binding calculations the value of the bending rigidity in good agreement with recent literature. We discuss the emergence of a stretching field induced by the full atomic-scale relaxation of the nanoribbon architecture. We further prove that such an in-plane strain field can be decomposed into a first contribution due to the actual…
A WSe2 monolayer of 1T' phase is a large band gap quantum spin Hall insulator, supporting dissipationless charge and spin transports through the topologically protected edge states. In this work, we explore the nanoribbon forms of 1T' phase WSe2 by first-principles density functional calculations and the many-body perturbation GW and Bethe-Salpeter equation method. We found that the 1T' WSe2 nanoribbon can show topological edge states with a ribbon width of ~4-6 nm. Those edge bands show crossing through the Fermi level an odd number of times, with one kind of spin-polarization connecting the …
Graphene nanoribbons are prone to in-plane bending even when supported on flat substrates. However, the amount of bending that ribbons can stably withstand remains poorly known. Here, by using molecular dynamics simulations, we study the stability limits of 0.5-1.9 nm wide armchair and zigzag graphene nanoribbons subject to bending. We observe that the limits for maximum stable curvatures are below ~10 deg/nm, in case the bending is externally forced and the limit is caused by buckling instability. Furthermore, it turns out that the limits for maximum stable curvatures are also below ~10 deg/n…
A novel type of spaser with the net amplification of surface plasmons (SPs) in doped graphene nanoribbon is proposed. The plasmons in THz region can be generated in a dopped graphene nanoribbon due to nonradiative excitation by emitters like two level quantum dots located along a graphene nanoribbon. The minimal population inversion per unit area, needed for the net amplification of SPs in a doped graphene nanoribbon is obtained. The dependence of the minimal population inversion on the surface plasmon wavevector, graphene nanoribbon width, doping and damping parameters necessary for the ampli…
In contrast with carbon nanotubes, the absence of translational symmetry (or periodical boundary condition) in the restricted direction of zigzag graphene nanoribbon removes the selection rule of subband number conservation. However, zigzag graphene nanoribbons with even dimers do have the inversion symmetry. We, therefore, propose a selection rule of parity conservation for electron-phonon interactions. The electron-phonon scattering matrix in zigzag graphene nanoribbons is developed using the tight-binging model within the deformation potential approximation.
High-quality BN-Graphene-BN nanoribbon capacitors with double side-gates of graphene are experimentally realized. Graphene electronic properties can be significantly modulated by the double side-gates. The modulation effects are very obvious and followed the metallic electrode behavior of numerical simulations, while the theoretically predicted negative quantum capacitance was not observed, possibility due to the over-estimated or weakened interactions between the graphene nanoribbon and side-gate electrodes.
Graphene plasmonics is a rapidly growing field with multiple potential applications. One of the standard ways to study plasmons in graphene is by fabricating an array of graphene nanoribbons where nanoribbon edges provide the efficient photon-plasmon coupling. We systematically analyze the problem of optical plasmonic response in such systems and demonstrate the purely geometric nature of the size quantization condition for graphene plasmons. Accurate numerical calculations allowed us to tabulate the universal geometric parameters of plasmon size quantization, which is expected to become usefu…
We have experimentally investigated quantum interference corrections to the conductivity of graphene nanoribbons at temperatures down to 20 mK studying both weak localization (WL) and universal conductance fluctuations (UCF). Since in individual nanoribbons at millikelvin temperatures the UCFs strongly mask the weak localization feature we employ both gate averaging and ensemble averaging to suppress the UCFs. This allows us to extract the phase coherence length from both WL and UCF at all temperatures. Above 1 K, the phase coherence length is suppressed due to Nyquist scattering whereas at lo…
We present symmetry properties of the lattice vibrations of graphene nanoribbons with pure armchair (AGNR) and zigzag edges (ZGNR). In non-symmorphic nanoribbons the phonon modes at the edge of the Brillouin zone are twofold degenerate, whereas the phonon modes in symmorphic nanoribbons are non-degenerate. We identified the Raman-active and infrared-active modes. We predict 3N and 3(N+1) Raman-active modes for N-ZGNRs and N-AGNRs, respectively (N is the number of dimers per unit cell). These modes can be used for the experimental characterization of graphene nanoribbons. Calculations based on …
We present electronic transport measurements on etched graphene nanoribbons on silicon dioxide before and after a short hydrouoric acid (HF) treatment. We report on changes in the transport properties, in particular, in terms of a decreasing transport gap and a reduced doping level after HF dipping. Interestingly, the effective energy gap is nearly unaffected by the HF treatment. Additional measurements on a graphene nanoribbon with lateral graphene gates support strong indications that the HF significantly modifies the edges of the investigated nanoribbons leading to a significantly reduced d…
The electronic and magnetic properties of zigzag graphene nanoribbons with asymmetric notches along their edges are investigated by first principle density functional theory calculations. It is found that the electronic and magnetic properties of the asymmetrically-notched graphene nanoribbons are closely related with the depth of notches, but weekly dependent on the length of notches. As the relative depth of notch increases, the energy level of spin-up and spin-down becomes greatly shifted, associated with the gradual increase of magnetic momentum. The asymmetric band shift allows the asymme…
We study vibrational states localized at the edges of graphene nanoribbons. Such surface oscillations can be considered as a phonon analog of Tamm states well known in the electronic theory. We consider both armchair and zigzag graphene stripes and demonstrate that surface modes correspond to phonons localized at the edges of the graphene nanoribbon, and they can be classified as in-plane and out-of-plane modes. In addition, in armchair nanoribbons anharmonic edge modes can experience longitudinal localization in the form of self-localized nonlinear modes, or surface breather solitons.
We analyze the thermal fluctuations of a narrow graphene nanoribbon. Using a continuum, membrane-like model we study the height-height correlation functions and the destabilization modes corresponding to two different boundaries conditions: ribbons which are fixed or free on the edges. For the first situation, the thermal spectrum has a gap and the correlations along the ribbon decay exponentially. Thermal fluctuations produce only local perturbations of the flat situation. However, the long range crystalline order is not distorted. For free edges, the situation changes as thermal excitations …
In this paper we propose an analytical method to calculate the band structures of graphene-like nanoribbons of the armchair type with arbitrary line defects or uniaxial strains. The model is based on the tight-binding model and the standing wave assumption for the armchair nanoribbons. It gives accurate band results for large supercell systems. Within this method, we analyze different local states near the line defect in the graphene and boron-nitride nanoribbons. We also derive the analytical expression for the local states in a semi-infinite graphene nanoribbon by this method and the transfe…
In this paper, optical properties of Chiral Graphene Nanoribbons both in longitude and transverse polarization have been studied using density functional theory calculation. It has been shown that the selection rule which have been reported before for Armchair and Zigzag Graphene Nanoribbons are no longer valid due to breaking symmetry on these new categorize of graphene nanoribbons. However, still the edge states play a critical role in optical absorption. It have been illustrated that depending on the polarization of incident beam the absorption peaks are different while it is spread in the …
This paper presents electronic spectra of zigzag and armchair graphene nanoribbons calculated within the tight-binding model for pi-electrons. Zigzag and armchair nanoribbons of different edge geometries are considered, with surface perturbation taken into account. The properties of surface states are discussed on the basis of their classification into Tamm states and Shockley states. In armchair nanoribbons surface states are shown to close the energy gap at the Dirac point for certain edge geometries.
Graphene nanoribbons provide an opportunity to integrate phase-coherent transport phenomena with nanoelectromechanical systems (NEMS). Due to the strain induced by a deflection in a graphene nanoribbon resonator, coherent electron transport and mechanical deformations couple. As the electrons in graphene have a Fermi wavelength λ~ a_0 = 1.4 Å, this coupling can be used for sensitive displacement detection in both armchair and zigzag graphene nanoribbon NEMS. Here it is shown that for ordered as well as disordered ribbon systems of length L, a strain ε~ (w/L)^2 due to a deflection w leads to a …
The magnetoconductance of graphene nanoribbons with rough zigzag and armchair edges is studied by numerical simulations. nanoribbons with sufficiently small bulk disorder show a pronounced magnetoconductance minimum at cyclotron radii close to the ribbon width, in close analogy to the wire peak observed in conventional semiconductor quantum wires. In zigzag nanoribbons, this feature becomes visible only above a threshold amplitude of the edge roughness, as a consequence of the reduced current density close to the edges.
Non-equilibrium spin-polarized transport properties of antiferromagnetic stanene nanoribbons are theoretically studied under the combining effect of a normal electric field and linearly polarized irradiation based on the tight-binding model at room temperature. Due to the existence of spin-orbit coupling in stanene lattice, applying normal electric field leads to splitting of band degeneracy of spin-resolved energy levels in conduction and valence bands. Furthermore, unequivalent absorption of the polarized photons at two valleys which is attributed to an antiferromagnetic exchange field resul…
We reveal that there exists a class of graphene structures (a sub-class of bilayer graphene nanoribbons) which has unusually strong optical response in the terahertz (THz) and far infrared (FIR) regime. The peak conductance of terahertz/FIR active bilayer ribbons is around two orders of magnitude higher than the universal conductance of $e^2/4\hbar$ observed in graphene sheets. The criterion for the terahertz/FIR active sub-class is a bilayer graphene nanoribbon with one-dimensional massless Dirac Fermion energy dispersion near the $Γ$ point. Our results overcome a significant obstacle that hi…
The geometric, electronic and magnetic properties of strained graphene nanoribbons were investigated using spin polarized calculations within the framework of density functional theory. Cases of compressive stress along the longer axis of a nanoribbon and tensile stress at the midpoint and perpendicular to the plane of the nanoribbon were considered. Significant structural changes were observed including the formation of nanoripples. The calculated electronic and magnetic properties strongly depend on the size and shape of nanoribbons. The tunable magnetic properties of strained nanoribbons ca…
We use time dependent perturbation theory to study quantum size effects on the terahertz nonlinear response of metallic graphene armchair nanoribbons of finite length under an applied electric field. Our work shows that quantization due to the finite length of the nanoribbon, the applied field profile, and the broadening of the graphene spectrum all play a significant role in the resulting nonlinear conductances. In certain cases, these effects can significantly enhance the nonlinearity over that for infinitely-long metallic armchair graphene nanoribbon.
We investigate spin conductance in zigzag graphene nanoribbons and propose a spin injection mechanism based only on graphitic nanostructures. We find that nanoribbons with atomically straight, symmetric edges show zero spin conductance, but nonzero spin Hall conductance. Only nanoribbons with asymmetrically shaped edges give rise to a finite spin conductance and can be used for spin injection into graphene. Furthermore, nanoribbons with rough edges exhibit mesoscopic spin conductance fluctuations with a universal value of $\mathrm{rms} G_\mathrm{s}\approx 0.4 e/4π$.
Graphene nanoribbons are semiconductor nanostructures with great potentials in nanoelectronics. Their realization particularly with small lateral dimensions below a few nanometers, however, remains challenging. Here we theoretically analyze zig-zag graphene nanoribbons created in a graphane substrate (a fully saturated two-dimensional hydrocarbon with formula CH) and predict that they are stable down to the limit of a single carbon chain. We exploit density functional theory with B3LYP functional that accurately treats exchange and correlation effects and demonstrate that at small widths below…
Thermal rectification in thickness asymmetric graphene nanoribbons connecting single-layer with multi-layer graphene is investigated by using classical nonequilibrium molecular dynamics. It is reported that the graphene nanoribbons with thickness-asymmetry have a good thermal rectification. The thermal rectification factor depends on temperature as well as the thickness-ratio of the two-segment. Our results provide a direct evidence that the thermal rectifier can be achieved in a nanostructure crossing two- and three-dimension.
We theoretically study graphene nanoribbons in the presence of spatially varying magnetic fields produced e.g. by nanomagnets. We show both analytically and numerically that an exceptionally large Rashba spin orbit interaction (SOI) of the order of 10 meV can be produced by the non-uniform magnetic field. As a consequence, helical modes exist in armchair nanoribbons that exhibit nearly perfect spin polarization and are robust against boundary defects. This paves the way to realizing spin filter devices in graphene nanoribbons in the temperature regime of a few Kelvins. If a nanoribbon in the h…
Graphene nanoribbons' electronic transport properties strongly depend on the type of edge, armchair, zigzag or other, and on edge functionalization that can be used for band-gap engineering. For only partly hydrogenated edges interesting magnetic properties are predicted. Electric charge accumulates at edges and corners. Scanning force microscopy has so far shown the centre of graphene nanoribbons with atomic resolution using a quartz crystal tuning fork sensor of high stiffness. Weak long-range electrostatic forces related to the charge accumulation on the edges of graphene nanoribbons could …
Based on first-principles calculations we predict that periodically repeated junctions of armchair graphene nanoribbons of different widths form superlattice structures. In these superlattice heterostructures the width and the energy gap are modulated in real space and specific states are confined in certain segments. Orientation of constituent nanoribbons, their width and length, the symmetry of the junction are the structural parameters to engineer electronic properties of these quantum structures. Not only the size modulation, but also composition modulation, such as periodically repeated, …
An odd number of zigzag edges in armchair graphene nanoribbons and their mechanical properties (e.g., Young's modulus, Poisson ratio and shear modulus) have potential interest for bandgap engineering in graphene based optoelectronic devices. In this paper, we consider armchair graphene nanoribbons passivated with hydrogen at the armchair edges and then apply the strain for tuning the bandgaps. Using density functional theory calculations, our study finds that the precise control of strain can allow tuning the bandgap from semiconductor to mettalic and then again switching back to semiconductor…
We discuss the electronic properties of graphene and graphene nanoribbons including "pseudo-Rashba" spin-orbit coupling. After summarizing the bulk properties, we first analyze the scattering behavior close to an infinite mass and zigzag boundary. For low energies, we observe strong deviations from the usual spin-conserving behavior at high energies such as reflection acting as spin polarizer or switch. This results in a spin polarization along the direction of the boundary due to the appearance of evanescent modes in the case of non-equilibrium or when there is no coherence between the two on…
We study numerically the effects of edge and bulk disorder on the conductance of graphene nanoribbons. We compute the conductance suppression due to localization induced by edge scattering. We find that even for weak edge roughness, conductance steps are suppressed and transport gaps appear. These gaps are approximately inversely proportional to the nanoribbon width. On/off conductance ratios grow exponentially with the nanoribbon length. Our results impose severe limitations to the use of graphene in ballistic nanowires.
Zigzag graphene nanoribbons can have magnetic ground states with ferromagnetic, antiferromagnetic, or canted configurations, depending on carrier density. We show that an electric field directed across the ribbon alters the magnetic state, favoring antiferromagnetic configurations. This property can be used to prepare ribbons with a prescribed spin-orientation on a given edge.
Random fluctuations of the shot-noise power in disordered graphene nanoribbons are studied. In particular, we calculate the distribution of the shot noise of nanoribbons with zigzag and armchair edge terminations. We show that the shot noise statistics is different for each type of these two graphene structures, which is a consequence of presence of different electron localizations: while in zigzag nanoribbons electronic edge states are Anderson localized, in armchair nanoribbons edge states are absent, but electrons are anomalously localized. Our analytical results are verified by tight bindi…
Conductance fluctuations produced by the presence of disorder in zigzag and armchair graphene nanoribbons are studied. We show that quantum transport in zigzag nanoribbons takes place via edge states which are exponentially localized, as in the standard Anderson localization problem, whereas for armchair nanoribbons the symmetry of the graphene sublattices produces anomalous localization, or delocalization. We show that these two different electron localizations lead to significant differences of the conductance statistics between zigzag and armchair nanoribbons. In particular, armchair nanori…
Thermoelectric properties of Graphene Nanoribbons doped by magnetic impurities Fe and Co are carried out in room temperature. We report on a study of the band structure dependent properties such as electrical conductivity, charge of carriers and Seebeck coefficients. We investigate the thermoelectric properties using the Semi-classical Boltzmann method. The electronic band structure of doped nanoribbons are evaluated by using density-functional theory in which the Hubbard interaction is considered. In this work we compare the different types of the nanoribbons and their thermoelectric features…
We report scanning tunneling microscopy and spectroscopy investigation of graphene nanoribbons grown on an array of bunched steps of a 6H-SiC(0001) substrate. Our scanning tunneling microscopy images of a graphene nanoribbons on a step terrace feature a (sqrt(3)x sqrt(3))R30° pattern of aromatic rings which define our armchair nanoribbons. This is in agreement to a simulation based on density functional theory. As another signature of the one-dimensional electronic structure, in the corresponding scanning tunneling spectroscopy spectra we find well developed, sharp Van Hove singularities.
We have investigated the main scattering mechanisms affecting mobility in graphene nanoribbons using detailed atomistic simulations. We have considered carrier scattering due to acoustic and optical phonons, edge roughness, single defects, and ionized impurities, and we have defined a methodology based on simulations of statistically meaningful ensembles of nanoribbon segments. Edge disorder heavily affects mobility at room temperature in narrower nanoribbons, whereas charged impurities and phonons are hardly the limiting factors. Results are favorably compared to the few experiments available…
Using the partition-free time-dependent Landauer-B{ü}ttiker formalism for transient current correlations, we study the traversal times taken for electrons to cross graphene nanoribbon (GNR) molecular junctions. We demonstrate electron traversal signatures that vary with disorder and orientation of the GNR. These findings can be related to operational frequencies of GNR-based devices and their consequent rational design.
The characteristics of energy band spectrum of armchair graphene nanoribbons in presence of line defect are analyzed within a simple non-interacting tight-binding framework. In metallic nanoribbons an energy gap may or may not appear in the band spectrum depending on the location of the defect line, while in semiconducting ribbons the gaps are customized, yielding the potential applicabilities of graphene nanoribbons in nanoscale electronic devices. With a more general model, we also investigate two-terminal electron transport using Green's function formalism.
We present numerical simulations of the capacitive coupling between graphene nanoribbons of various widths and gate electrodes in different configurations. We compare the influence of lateral metallic or graphene side gate structures on the overall back gate capacitive coupling. Most interestingly, we find a complex interplay between quantum capacitance effects in the graphene nanoribbon and the lateral graphene side gates, giving rise to an unconventional negative quantum capacitance. The emerging non-linear capacitive couplings are investigated in detail. The experimentally relevant relative…
The deformation and disintegration of a graphene nanoribbon under external electrostatic fields are investigated by first principle quantum mechanical calculations to establish its stability range. The zigzag edges terminated by various functional groups are considered. By analyzing the phonon spectrum, the critical fracture field for each edge structure is obtained. It is found that different terminal groups on the zigzag graphene nanoribbons lead to different fracture patterns at different fracture fields. The failure mechanism is demonstrated to rely on both the carbon bond alternation feat…
We propose that recent transport experiments revealing the existence of an energy gap in graphene nanoribbons may be understood in terms of Coulomb blockade. Electron interactions play a decisive role at the quantum dots which form due to the presence of necks arising from the roughness of the graphene edge. With the average transmission as the only fitting parameter, our theory shows good agreement with the experimental data.
We analyze numerically the thermal conductivity of carbon nanoribbons with ideal and rough edges. We demonstrate that edge disorder can lead to a suppression of thermal conductivity by several orders of magnitude. This effect is associated with the edge-induced Anderson localization and suppression of the phonon transport, and it becomes more pronounced for longer nanoribbons and low temperatures.
We investigate the electronic transport properties of a folded graphene nanoribbon with monolayer nanoribbon contacts. We consider two possible foldings: either the nanoribbon can be folded onto itself in the shape of a hairpin with the nanoribbon leads at a $0^\circ$ angle, or the monolayer contacts have different directions, forming a $60^\circ$ angle. The system is described by a single $π$-band nearest-neighbor tight-binding Hamiltonian taking into account curvature effects. We have found that for the case of a nanoribbon folded over itself the conductance oscillates from almost zero and a…
We show how hydrogenation of graphene nanoribbons at small concentrations can open new venues towards carbon-based spintronics applications regardless of any especific edge termination or passivation of the nanoribbons. Density functional theory calculations show that an adsorbed H atom induces a spin density on the surrounding $π$ orbitals whose symmetry and degree of localization depends on the distance to the edges of the nanoribbon. As expected for graphene-based systems, these induced magnetic moments interact ferromagnetically or antiferromagnetically depending on the relative adsorption…
It is shown that apart from well-known factors, like temperature, substrate, and edge reconstruction effects, also the presence of external contacts is destructive for the formation of magnetic moments at the edges of graphene nanoribbons. The edge magnetism gradually decreases when graphene/electrode interfaces become more and more transparent for electrons. In addition to the graphene/electrode coupling strength, also the aspect ratio parameter, i.e. a width/length ratio of the graphene nanoribbon, is crucial for the suppression of edge magnetism. The present theory uses a tight-binding meth…
We have studied the thermal properties of bended graphene nanoribbons (GNRs) using nonequilibrium molecular dynamics simulations. The thermal conductivity of bended GNRs shows a non-monotonous relationship with the bending angle, due to the influence of chirality and Kapitza conductance. When a constant heat flux is allowed to flow, sharp temperature jump is observed at the inside corner. On the basis of the magnitude of these jumps, we have computed the Kapitza conductance as a function of bending angles. Besides, modification of the inside corner is applied to change the ability of heat tran…
We investigate etched single-layer graphene nanoribbons with different widths ranging from 30 to 130 nm by confocal Raman spectroscopy. We show that the D-line intensity only depends on the edge-region of the nanoribbon and that consequently the fabrication process does not introduce bulk defects. In contrast, the G- and the 2D-lines scale linearly with the irradiated area and therefore with the width of the ribbons. We further give indications that the D- to G-line ratio can be used to gain information about the crystallographic orientation of the underlying graphene. Finally, we perform pola…
We study the interaction energy between two graphene nanoribbons by first principles calculations, including van der Waals interactions and spin polarization. For ultranarrow zigzag nanoribbons, the direct stacking is even more stable than Bernal, competing in energy for wider ribbons. This behavior is due to the magnetic interaction between edge states. We relate the reduction of the magnetization in zigzag nanoribbons with increasing ribbon width to the structural changes produced by the magnetic interaction, and show that when deposited on a substrate, zigzag bilayer ribbons remain magnetic…
We combine density-functional theory and the nonequilibrium Green's function method to study the thermal conductance of graphene nanoribbons with armchair and zigzag edges. Zigzag ribbons have higher thermal conductance than armchair ribbons of comparable widths due to an anisotropy in phonon dispersion for graphene nanoribbons: low-frequency bands in zigzag ribbons are more dispersive than those in armchair ribbons. The edges with and without hydrogen-passivation modify the atomic structure and ultimately influence the phonon thermal transport differently for the two ribbon types.
Graphene nanoribbons are the flimsiest material systems in the world, and they get readily distorted. Distortion by twisting, for one, is important because it couples to ribbon's electronic properties. In this Letter, using simulations with density-functional tight-binding and revised periodic boundary conditions, I show that twisting appears almost equivalent to stretching; electronic structures in a given nanoribbon either upon twisting or upon certain stretching are quantitatively similar. This simple equivalence will provide a valuable guideline for interpreting and designing experiments w…
The effects of substrate on the electronic properties of Graphene remains unclear. Many theoretical and experimental efforts have been done to clarify this discrepancy. In this work, we studied the electronic transport in armchair Graphene nanoribbons (AGNR) in the presence of substrate's disorder. The three main substrate's disorders -- surface roughness, charged impurity and surface optical phonon -- are investigated. Non-Equilibrium Green's function along with the tight-binding model is employed to investigate the electronic properties of Graphene Nanoribbons. The effects of these disorders…
The conductivity of armchair graphene nanoribbons in the presence of short-range impurities and edge roughness is studied theoretically using the Boltzmann transport equation for quasi-one-dimensional systems. As the number of occupied subbands increases, the conductivity due to short-range impurities converges towards the two-dimensional case. Calculations of the magnetoconductivity confirm the edge-roughness-induced dips at cyclotron radii close to the ribbon width suggested by the recent quantum simulations.
A pseudo-magnetic field kink can be realized along a graphene nanoribbon using strain engineering. Electron transport along this kink is governed by snake states that are characterized by a single propagation direction. Those pseudo-magnetic fields point towards opposite directions in the K and K' valleys, leading to valley polarized snake states. In a graphene nanoribbon with armchair edges this effect results in a valley filter that is based only on strain engineering. We discuss how to maximize this valley filtering by adjusting the parameters that define the stress distribution along the g…
One of the ways to use graphene in field effect transistors is to introduce a band gap by quantum confinement effect [1]. That is why narrow graphene nanoribbons (GNRs) with width less than 50nm are considered to be essential components in future graphene electronics. The growth of graphene on sidewalls of SiC(0001) mesa structures using scalable photolithography was shown to produce high quality GNR with excellent transport properties [2-7]. Such epitaxial graphene nanoribbons are very important in fundamental science but if GNR are supposed to be used in advanced nanoelectronics, high qualit…
We investigate the transport properties of double-gated bilayer graphene nanoribbons at room temperature. The devices were fabricated using conventional CMOS-compatible processes. By analyzing the dependence of the resistance at the charge neutrality point as a function of the electric field applied perpendicular to the graphene surface, we show that a band gap in the density of states opens, reaching an effective value of ~sim50 meV. This demonstrates the potential of bilayer graphene as FET channel material in a conventional CMOS environment.
Electron spin resonance (ESR) investigation of graphene nanoribbons (GNRs) prepared through longitudinal unzipping of multiwalled carbon nanotubes (MWCNTs) indicates the presence of C-related dangling bond centers, exhibiting paramagnetic features. ESR signal broadening from pristine or oxidized graphene nanoribbons (OGNRs) is explained in terms of unresolved hyperfine structure, and in the case of reduced GNRs (RGNRs), the broadening of ESR signal can be due to enhancement in conductivity upon reduction. The spin dynamics observed from ESR linewidth-temperature data reflect a variable range h…
