In this paper, we propose an in-depth review of the vector and tensor polarizabilities of the two energy levels of the 87Sr clock transition whose measurement was reported in [P. G. Westergaard et al., Phys. Rev. Lett. 106, 210801 (2011)]. We conduct a theoretical calculation that reproduces the measured coefficients. In addition, we detail the experimental conditions used for their measurement in two Sr optical lattice clocks, and exhibit the quadratic behaviour of the vector and tensor shifts with the depth of the trapping potential and evaluate their impact on the accuracy of the clock.
Derivations for the higher tensor components of the quadrupole polarizabilities are given and their values for the metastable states of the Ca$^+$, Sr$^+$ and Ba$^+$ alkaline earth-metal ions are estimated. We also give the scalar quadrupole polarizabilities of the ground and metastable states of these ions to compare our results with the previously available theoretical and experimental results. Reasonably good agreement between our calculations with the previous values of scalar quadrupole polarizabilities demonstrate their correctness. The reported scalar and tensor quadrupole polarizabilit…
We address the problem of the lattice Stark shifts in the Sr clock caused by the multipolar $M1$ and $E2$ atom-field interactions and by the term nonlinear in lattice intensity and determined by the hyperpolarizability. We have developed an approach to calculate hyperpolarizabilities for atoms and ions based on a solution of the inhomogeneous equation which allows to effectively and accurately carry out complete summations over intermediate states. We applied our method to the calculation of the hyperpolarizabilities for the clock states in Sr. We also carried out an accurate calculation of th…
The progress in optical clock with uncertainty at a level of $10^{-18}$ requires unprecedented precision in estimating the contribution of multipolar and higher-order effects of atom-field interactions. Current theoretical and experimental results of dynamic multipolar polarizabilities and hyperpolarizabilities at the magic wavelength for the Sr clock differ substantially. We develop a combined approach of the Dirac-Fock plus core polarization (DFCP) and relativistic configuration interaction (RCI) methods to calculate dynamic multipolar polarizabilities and hyperpolarizabilities of the Sr ato…
Blackbody radiation shift of B$^+$ clock transition
计算B $^+$时钟跃迁的黑体辐射位移。用组态相互作用方法计算了$^+$ $^1$ S $^e$、$2s2p$ $^1$ P $^o$和$2s2p$ $^3$ P $^o$态的极化率.推荐的偶极极化率分别为9.64（3）$a_0^3$、7.78（3）$a_0^3$和16.55（5）$a_0^3$。在300 K下，$2s^2$ $^1$ S $^e$ $\to$ $2s2p$ $^3$ P $^o_0$跃迁的导出频移为0.0160（5）Hz。偶极极化率与较早的相对论计算（Safronova { \em et al.}物理修订版信函{ \bf 107} 143006（2011））至优于0.2%。四极和八极极化率和非绝热多极极化率也报告。
An atom exposed to an electric field will experience Stark shifts of its internal energy levels, proportional to their polarizabilities. In optical frequency metrology, the Stark shift due to background black-body radiation (BBR) modifies the frequency of the optical clock transition, and often represents a large contribution to a clock's uncertainty budget. For clocks based on singly-ionized ytterbium, the ion's complex structure makes this shift difficult to calculate theoretically. We present a measurement of the differential polarizabilities of two ultra-narrow optical clock transitions pr…
We present precise values of the dipole polarizabilities ($α$) of the ground $\rm [4f^{14}6s] ~ ^2S_{1/2}$ and metastable $\rm [4f^{14} 5d] ~ ^2D_{3/2}$ states of Yb$^+$, that are %vital {\bf important} in reducing systematics in the clock frequency of the $\rm[4f^{14}6s] ~ ^2S_{1/2} \rightarrow [4f^{14}5d] ~ ^2D_{3/2}$ transition. The static values of $α$ for the ground and $\rm [4f^{14} 5d] ~ ^2D_{3/2}$ states are estimated to be $9.8(1) \times 10^{-40} \,\,\rm Jm^2V^{-2}$ and $17.6(5) \times 10^{-40}\,\, \rm Jm^2V^{-2}$, respectively, while the tensor contribution to the $\rm [4f^{14} 5d] ~…
Experimental and theoretical study of dynamic polarizabilities in the $5S_{1/2}$-$5D_{5/2}$ clock transition in rubidium-87 and determination of E1 matrix elements
We experimentally investigate the lattice-induced light shift by the electric-quadrupole ($E2$) and magnetic-dipole ($M1$) polarizabilities and the hyperpolarizability in Sr optical lattice clocks. Precise control of the axial as well as the radial motion of atoms in a one-dimensional lattice allows observing the $E2$-$M1$ polarizability difference. Measured polarizabilities determine an operational lattice depth to be $72(2) E_R$, where the total light shift cancels to the $10^{-19}$ level, over a lattice-intensity variation of about 30%. This operational trap depth and its allowable intensit…
We study a wide range of neutral atoms and ions suitable for ultra-precise atomic optical clocks with naturally suppressed black body radiation shift of clock transition frequency. Calculations show that scalar polarizabilities of clock states cancel each other for at least one order of magnitude for considered systems. Results for calculations of frequencies, quadrupole moments of the states, clock transition amplitudes and natural widths of upper clock states are presented.
Black-body radiation (BBR) shifts of $^3\!P_0-^1\!S_0$ clock transition in divalent atoms Cd and Zn are evaluated using accurate relativistic many-body techniques of atomic structure. Static polarizabilities of the clock levels and relevant electric-dipole matrix elements are computed. We also present a comparative overview of the BBR shifts in optical clocks based on neutral divalent atoms trapped in optical lattices.
Ionic clocks exhibit as the most promising candidates for the frequency standards. Recent investigations show the profound advantages of interrogating two laser beams with different frequencies in developing the frequency standards. Here we present a scheme of a two-photon mechanism to calculate the dynamic polarizabilities for the clock states, 6$^2$S$_{\frac{1}{2}}$ and 5$^2$D$_{\frac{3}{2}, \frac{5}{2}}$, of Ba$^+$ by employing relativistic coupled-cluster method. We illustrate the Stark-shift cancellation between these clock states at the two-photon magic wavelengths. These magic wavelengt…
Measurement of dynamic Stark polarizabilities by analyzing spectral lineshapes of forbidden transitions
我们测量了镱原子激发态3D 1的动态标量和张量极化率。通过分析在静电和磁场存在下由共振光驻波驱动的408 nm 1 S 0-> 3D 1跃迁的光谱线形来测量极化率。由于原子与驻波的相互作用，谱线的形状具有与极化率相关的特征畸变。一个理论模型被用来模拟的线形和确定的结合的极化率的基态和激发态通过拟合模型的实验数据。该组合的测量不确定度为13%，其中只有3%是由于模拟和拟合过程中的不确定性。通过比较两种不同的极化率组合，首次测量了态3D 1的标量极化率和张量极化率。我们表明，这种技术可以应用到类似的原子系统。
In the recent work [A.~Yamaguchi et. al, Phys. Rev. Lett. {\bf 123}, 113201 (2019)] Cd has been identified as an excellent candidate for a lattice clock. Here, we carried out computations needed for further clock development and made an assessment of the higher-order corrections to the light shift of the $5s^2\, ^1\!S_0$--$5s5p\, ^3\!P_0^o$ clock transition. We carried out calculations of the magnetic dipole and electric quadrupole polarizabilities and linear and circular hyperpolarizabilities of the $5s^2\, ^1\!S_0$ and $5s5p\, ^3\!P_0^o$ clock states at the magic wavelength and estimated unc…
The present work determines the precise values of magic wavelengths corresponding to the clock transitions 5$^2S$-4$^2D$ of Y$^{2+}$ ion both at the levels of fine- and hyperfine-structures due to the external light beams having linear as well as circular polarization. To calculate the dynamic polarizabilities of the associated states of the transitions, we employ the sum-over-states technique, where the dominating and correlation sensitive part of the sum is evaluated using a highly correlated relativistic coupled-cluster theory. The estimated magic wavelengths of the light beams have substan…
We study the $^1$S$_0 - ^3$D$_2$ and $^1$S$_0 - ^3$D$_3$ transitions in Cu II and the $^1$S$_0 - ^3$P$^{\rm o}_2$ transition in Yb III as possible candidates for the optical clock transitions. A recently developed version of the configuration (CI) method, designed for a large number of electrons above closed-shell core, is used to carry out the calculation. We calculate excitation energies, transition rates, lifetimes, scalar static polarizabilities of the ground and clock states, and blackbody radiation shift. We demonstrate that the considered transitions have all features of the clock trans…
We measure the dynamic differential scalar polarizabilities at 10.6 $μ$m for two candidate clock transitions in $^{176}\mathrm{Lu}^+$. The fractional black body radiation (BBR) shifts at 300 K for the $^1S_0 \leftrightarrow {^3D_1}$ and $^1S_0 \leftrightarrow {^3D_2}$ transitions are evaluated to be $-1.36\,(9) \times 10^{-18}$ and $2.70 \,(21) \times10^{-17}$, respectively. The former is the lowest of any established optical atomic clock.
Using recent high-precision measurements of electric dipole matrix elements of atomic cesium, we make an improved determination of the scalar ($α$) and vector ($β$) polarizabilities of the cesium $6s \ ^2S_{1/2} \rightarrow 7s \ ^2S_{1/2} $ transition calculated through a sum-over-states method. We report values of $α= -268.82 \ (30) \ a_0^3$ and $β= 27.139 \ (42) \ a_0^3$ with the highest precision to date. We find a discrepancy between our value of $β$ and the past preferred value, resulting in a significant shift in the value of the weak charge $Q_w$ of the cesium nucleus. Future work to re…
Energy levels of 30 low-lying states of Lu2+ and allowed electric-dipole matrix elements between these states are evaluated using a relativistic all-order method in which all single, double and partial triple excitations of Dirac-Fock wave functions are included to all orders of perturbation theory. Matrix elements are critically evaluated for their accuracy and recommended values of the matrix elements are given together with uncertainty estimates. Line strengths, transition rates and lifetimes of the metastable 5d(3/2) and 5d(5/2) states are calculated. Recommended values are given for stati…
With direct polarizability measurements we demonstrated extremely low sensitivity of the inner-shell clock transition at $1.14\,μ$m in Tm atoms to external dc electric fields and black-body radiation (BBR). We measured differential polarizabilities of clock levels in Tm at wavelengths of 810--860\,nm and at 1064\,nm and inferred the static scalar differential polarizability of the inner-shell clock transition of $-0.047(18)$ atomic units corresponding to only $2\times10^{-18}$ fractional frequency shift from BBR at the room temperature. This is a few orders of magnitude smaller compared to the…
With the improvement of high-precision optical clock, the higher-order multipolar interaction between atoms and light needs quantitative evaluation. However for the Sr clock, the differential dynamic E2-M1 polarizability at the magic wavelength has contradictions among available theoretical and experimental results. Recently, the new experimental measurement of S. Dörscher {\em et al.} [arXiv: 2210. 14727] is consistent with measurement of Ushijima {\em et al.}, which poses new challenges to theory and urgently calls for theoretical explanations. In present work, we investigate contributions o…
The microwave clock frequency of the $|5s~^2S_{1/2}, F=0,m_F=0 \rangle \leftrightarrow |5s~^2S_{1/2}, F=1,m_F=0 \rangle$ transition in the $^{113}$Cd$^+$ ion has been reported as 15199862855.0192(10) Hz [Opt. Lett. {\bf 40}, 4249 (2015)]. Fractional systematic due to the black-body radiation (BBR) shift ($β$) arising from the Stark effect in the above clock transition was used as $-1.1 \times 10^{-16}$ from our unpublished preliminary estimation. We present here a precise value as $β=-1.815(77) \times 10^{-16}$ by carrying out rigorous calculations of third-order polarizabilities of the hyperf…
Relativistic many-body calculation of energies, oscillator strengths, transition rates, lifetimes, polarizabilities, and quadrupole moment of Fr-like Th IV ion
The dynamic dipole polarizabilities for the four lowest triplet states ($2\,^3S$, $3\,^3S$, $2\,^3P$ and $3\,^3P$) of helium are calculated using the B-spline configuration interaction method. Present values of the static dipole polarizabilities in the length, velocity and acceleration gauges are in good agreement with the best Hylleraas results. Also the tune-out wavelengths in the range from 400 nm to 4.2~$μ$m for the four lowest triplet states are identified, and the magic wavelengths in the range from 460~nm to 3.5~$μ$m for the $2\,^3S \to 3\,^3S$, $2\,^3S \to 2\,^3P$, and $2\,^3S \to 3\,^…
The efficiency of optical trapping of ultracold atoms depend on the atomic dynamic dipole polarizability governing the atom-field interaction. In this article, we have calculated the real and imaginary parts of the dynamic dipole polarizability of dysprosium in the ground and first excited level. Due to the high electronic angular momentum of those two states, the polarizabilities possess scalar, vector and tensor contributions that we have computed, on a wide range of trapping wavelengths, using the sum-over-state formula. Using the same formalism, we have also calculated the $C_6$ coefficien…
Relativistic configuration-interaction and coupled-cluster calculations of Ir$^{17+}$ transition energies and properties for optical clock applications
The energy levels and electric dipole ($E1$) matrix elements of the ground state and low-lying excited states of Be atoms are calculated using the relativistic configuration interaction plus core polarization (RCICP) method. The static and dynamic $E1$, magnetic dipole ($M1$) and electric quadrupole ($E2$) polarizabilities as well as the hyperpolarizabilities of the $2s^2~^1S_0$ and $2s2p~^3P_0$ states are determined. Two magic wavelengths, 300.03 and 252.28 nm, of $2s^2~^1S_0 \rightarrow 2s2p~^3P_0$ clock transition are found. Then, the multipolar and nonlinear Stark shifts of the clock trans…
We demonstrate that several metastable excited states in Hf$~$II, Hf$~$IV and W$~$VI ions may be good clock states since they are sufficiently long-living and are not sensitive to the perturbations. Cooling E1 transitions are available. Energy levels, Landé $g$-factors, transition amplitudes for electric dipole (E1), electric quadrupole (E2), and magnetic dipole (M1) transitions, lifetimes, and electric quadrupole moments for Hf$~$II, Hf$~$IV, and W$~$VI ions are investigated using a combination of several methods of relativistic many-body calculations including the configuration interaction (…
We have investigated energies, magnetic dipole hyperfine structure constants ($A_{hyf}$) and electric dipole (E1) matrix elements of a number of low-lying states of the triply ionized tin (Sn$^{3+}$) by employing relativistic coupled-cluster theory. Contributions from the Breit interaction and lower-order quantum electrodynamics (QED) effects in determination of above quantities are also given explicitly. These higher-order relativistic effects are found to be important for accurate evaluation of energies, while QED contributions are seen to be contributing significantly to the determination o…
We present revised measurements of the static electric dipole polarizabilities of K, Rb, and Cs based on atom interferometer experiments presented in [Phys. Rev. A 2015, 92, 052513] but now re-analyzed with new calibrations for the magnitude and geometry of the applied electric field gradient. The resulting polarizability values did not change, but the uncertainties were significantly reduced. Then we interpret several measurements of alkali metal atomic polarizabilities in terms of atomic oscillator strengths $f_{ik}$, Einstein coefficients $A_{ik}$, state lifetimes $τ_{k}$, transition dipole…
We report measurements of the $^{115}$In $7p_{1/2}$ and $7p_{3/2}$ scalar and tensor polarizabilities using two-step diode laser spectroscopy in an atomic beam. The scalar polarizabilities are one to two orders of magnitude larger than for lower lying indium states due to the close proximity of the $7p$ and $6d$ states. For the scalar polarizabilities, we find values (in atomic units) of $1.811(4) \times 10^5$ $a_0^3$ and $2.876(6) \times 10^5$ $a_0^3$ for the $7p_{1/2}$ and $7p_{3/2}$ states respectively. We estimate the smaller tensor polarizability component of the $7p_{3/2}$ state to be $-…
We present additional magic wavelengths ($λ_{\rm{magic}}$) for the clock transitions in the alkaline-earth metal ions considering circular polarized light aside from our previously reported values in [J. Kaur et al., Phys. Rev. A {\bf 92}, 031402(R) (2015)] for the linearly polarized light. Contributions from the vector component to the dynamic dipole polarizabilities ($α_d(ω)$) of the atomic states associated with the clock transitions play major roles in the evaluation of these $λ_{\rm{magic}}$, hence facilitating in choosing circular polarization of lasers in the experiments. Moreover, the …
We study the prospects of using transitions from the ytterbium ground state to metastable states $^3{\rm P}^{\rm o}_2$ at $E=19\,710.388~$cm$^{-1}$ and $4f^{13}5d6s^2\,(J=2)$ at $E=23\,188.518~$cm$^{-1}$ as clock transitions in an optical lattice clock. Having more than one clock transition in Yb could benefit the search for new physics beyond the Standard Model via studying the non-linearity of King's plot or the time-variation of the ratio of the frequencies of two clock transitions. We calculate the lifetime of the states, relevant transition amplitudes, systematic shifts, and the sensitivi…
We performed an absolute frequency measurement of the $^1S_{0}$-$^3P_{0}$ transition in $^{87}$Sr with a fractional uncertainty of $1.2 \times 10^{-15}$, which is less than one third that of our previous measurement. A caesium fountain atomic clock was used as a transfer oscillator to reduce the uncertainty of the link between a strontium optical lattice clock and the SI second. The absolute value of the transition frequency is 429 228 004 229 873.56(49) Hz.
