High pressure structures, phase diagram and superconductivity of polonium hydrides have been systematically investigated through the first-principles calculations based on the density functional theory. With the increasing pressure, several stoichiometries (PoH, $\textrm{PoH}_\textrm{2}$, $\textrm{PoH}_4$ and $\textrm{PoH}_6$) are predicted to stabilize in the excess hydrogen environment. All of the reported hydrides, exception of PoH, exhibit intriguing structural character with the appearing $\textrm{H}_2$ units. Moreover, our electronic band structure and the projected density of states (PDOS) demonstrate that these energetically stable phases are metallic. The application of the Allen-Dynes modified McMillan equation with the calculated electron-phonon coupling parameter reveals that $\textrm{PoH}_4$ is a superconductor with a critical temperature $T_c$ of 41.2-47.2 K at 300 GPa.
We synthesized lanthanum hydride (LaHx) by laser heating of lanthanum in hydrogen atmosphere at pressure P = 170 GPa. The sample shows a superconducting step at 209 K and 170 GPa and temperature dependence of resistance. By releasing the pressure to 150 GPa, the superconducting transition temperature Tc increases to 215 K - the record Tc. This finding supports a way of achieving Tc higher than the one in H3S (203 K) in hydrides with sodalite-like structures, first proposed for CaH6 (Tc=245 K) and later for yttrium and lanthanum hydrides where higher, room temperature superconductivity is expec…
The computational and experimental exploration of the phase diagrams of binary hydrides under high pressure has uncovered phases with novel stoichiometries and structures, some which are superconducting at quite high temperatures. Herein we review the plethora of studies that have been undertaken in the last decade on the main group and transition metal hydrides, as well as a few of the rare earth hydrides at pressures attainable in diamond anvil cells. The aggregate of data shows that the propensity for superconductivity is dependent upon the species used to "dope" hydrogen, with some of the …
We report the ac magnetic susceptibility, electrical resistance, and X-ray diffraction measurements of platinum hydride (PtHx) in diamond anvil cells, which reveal its superconducting transition. At 32 GPa, when PtHx is in a P63/mmc structure, PtHx exhibits superconducting transition at 6.7 K and superconducting transition temperature (Tc) decreases with pressure to 4.8 K at 36 GPa. The observed T c is higher than that of powdered Pt by more than three orders of magnitude. It is suggested that hydrides of noble metals have higher Tc than the elements.
Over the past six years (2015-2021), many superconducting hydrides with critical temperatures $T_{C}$ up to 250 K, which are currently record highs, have been discovered. Now we can already say that a special field of superconductivity has developed. This is hydride superconductivity at ultrahigh pressures. For the most part, the properties of superhydrides are well described by the Migdal-Eliashberg theory of strong electron-phonon interaction, especially when anharmonicity of phonons is taken into account. The isotope effect, the effect of the magnetic field (up to 60-70 T) on the critical t…
Inspired by the high critical temperature in yttrium superhydride and the low stabilized pressure in superconducting cerium superhydride, we carry out four independent runs to synthesize yttrium-cerium alloy hydrides. The phases examined by the Raman scattering and x-ray diffraction measurements. The superconductivity is detected with the zero-resistance state at the critical temperature in the range of 97-140 K at pressures ranging from 114 GPa to 120$\pm$4 GPa. The maximum critical temperature of the synthesized hydrides is larger than those reported for cerium hydrides, while the correspond…
A recent experimental work on palladium hydrides suggested that metastable structures with hydrogen atoms occupying tetrahedral sites could lead to superconductivity above 50 K, a huge increase compared to the 10 K critical temperature of the stable structure with all hydrogen atoms occupying octahedral sites. By generating many structures with hydrogen atoms randomly occupying the octahedral and tetrahedral sites of the face-centered cubic lattice and calculating their energy at different theoretical levels from first principles, we determine that metastable structures with partial or full oc…
We introduce below the concept of defecton, and describe briefly the electron polaron effect, the clustering of defectons, and also the defecton mechanism of superconductivity. It is shown that in the case of high-temperature superconducting metal hydrides, which acquire superconducting properties under pressure of hundreds of gigapascals, this mechanism can make a significant contribution to the Cooper pairing.
We report ab-initio calculations of the superconducting properties of two high-Tc sodalite-like clathrate yttrium hydrides, YH6 and YH10, within the fully anisotropic ME theory, including Coulomb corrections. For both compounds we find almost isotropic superconducting gaps, resulting from a uniform distribution of the electron-phonon coupling over phonon modes and electronic states of mixed Y and H character. The Coulomb screening is rather weak, resulting in a Morel-Anderson pseudopotential mu*= 0:11, at odds with claims of unusually large Tc in lanthanum hydrides. The corresponding critical …
Lanthanum hydride is the superconductor with the highest known critical temperature. It is believed that the superconductivity is of standard BCS-type, with electrons forming Cooper pairs and opening the superconducting band gap. Here we show that the BCS electron pairing is in competition with an alternative pairing: covalent bonding. We show that the covalent pairing is favored at lower pressures, the superconducting cubic phase becomes unstable as pressure is reduced. Previous calculations based on static relaxation neglect three factors, all of which are important in stabilizing the cubic …
Disentangling electronic and phononic contributions to high-temperature superconductivity in X2MH6 hydrides
Jimei University（集美大学）；Xiamen University（厦门大学）；Iowa State University（爱荷华州立大学）；Guangdong University of Technology（广东工业大学）；Ames National Laboratory, U.S. Department of Energy（美国能源部艾姆斯国家实验室）
The Meissner effect, magnetic field expulsion, is a hallmark of superconductivity. Associated with it, superconductors exclude applied magnetic fields. Recently Minkov et al. presented experimental results reportedly showing "definitive evidence of the Meissner effect" in sulfur hydride and lanthanum hydride under high pressure [1], and more recently Eremets et al. argued that "the arguments against superconductivity (in hydrides) can be either refuted or explained" [2]. Instead, we show here that the evidence presented in those papers does not support the case for superconductivity in these m…
The discovery of high-temperature conventional superconductivity in H3S with a critical temperature of Tc=203 K was followed by the recent record of Tc ~250 K in the face-centered cubic (fcc) lanthanum hydride LaH10 compound. It was realized in a new class of hydrogen-dominated compounds having a clathrate-like crystal structure in which hydrogen atoms form a 3D framework and surround a host atom of rare earth elements. Yttrium hydrides are predicted to have even higher Tc exceeding room temperature. In this paper, we synthesized and refined the crystal structure of new hydrides: YH4, YH6, and…
The long-sought goal of room-temperature superconductivity has reportedly recently been realized in a carbonaceous sulfur hydride compound under high pressure, as reported by Snider et al. [1]. The evidence presented in that paper is stronger than in other similar recent reports of high temperature superconductivity in hydrides under high pressure [2-7], and has been received with universal acclaim [8-10]. Here we point out that features of the experimental data shown in Ref. [1] indicate that the phenomenon observed in that material is not superconductivity. This observation calls into questi…
We predicted a new ternary hydride Li$_2$SiH$_6$ at high pressures. A systematic structure search in Li$_2$SiH$_6$ compound reveals novel stable phases with intriguing electronic and phonon properties. It is found that Li$_2$SiH$_6$ is dynamically stable from ambient pressure up to 400 GPa with three novel phases: P312, P$\bar{3}$, and P$\bar{6}$2m. The calculation of electron-phonon coupling combined with Bardeen-Cooper-Schrieffer's argument indicates that this compound may be a candidate for high $T_c$ superconductors under high pressures. In particular, the maximum $T_c$ of $P\bar{6}2m$-Li$…
We report the observation of conventional superconductivity at the highest temperature yet attained without mechanical compression, around 54 kelvin in palladium-hydride and 60 kelvin in palladium-deuteride. The remarkable increase in Tc compared to the previously known value was achieved by rapidly cooling the hydride and deuteride after loading with hydrogen or deuterium at elevated temperature. Our results encourage hope that conventional superconductivity under ambient conditions will be discovered in materials with very high hydrogen density, as predicted more than a decade ago.
It has been a hot issue to search for hydrides at high pressure with high superconducting transition temperature (Tc). In this work, ternary hydrogen-rich compounds KYHn (n = 1-16) were studied and calculated using the density function theory (DFT) method and he results showed that the KYH8 demonstrates good stability and superconductivity. And keep thermodynamically stable in the pressure range of 50-300 GPa. The research found that the Tc of KYH8-C2/m was predicted to be 111.3K, 122.0K, and 142.3K at 200, 250 and 300 GPa, respectively. Our current study provides a possibility for searching n…
Hydrides offer an opportunity to study high-temperature (Tc) superconductivity at experimentally achievable pressures. However, they remained extremely high. Using density functional theory calculations, herein we demonstrated that a newly rare earth hydride, namely bulk ErH2, could be superconducting with a Tc around 80 K at 14.5 GPa. To date, the drived pressure is the lowest reported value for compressed hydrides. Besides superconductivity, Fermi Surface nesting and Kondo effect were manifested at this pressure. Intriguingly, due to Kondo destruction, superconductivity was prone to exist at…
Over the past decade, a combination of crystal structure prediction techniques and experimental synthetic work has thoroughly explored the phase diagrams of binary hydrides under pressure. The fruitfulness of this dual approach is demonstrated in the recent identification of several superconducting hydrides with $T_c$s approaching room temperature. We start with an overview of the computational procedures for predicting stable structures and estimating their propensity for superconductivity. A survey of phases with high $T_c$ reveals some common structural features that appear conducive to the…
Here we report targeted high-pressure synthesis of two novel high-$T_C$ hydride superconductors, $P6_3/mmc$-$ThH_9$ and $Fm\bar{3}m$-$ThH_{10}$, with the experimental critical temperatures ($T_C$) of 146 K and 159-161 K and upper critical magnetic fields ($μ$$H_C$) 38 and 45 Tesla at pressures 170-175 Gigapascals, respectively. Superconductivity was evidenced by the observation of zero resistance and a decrease of $T_C$ under external magnetic field up to 16 Tesla. This is one of the highest critical temperatures that has been achieved experimentally in any compounds, along with such materials…
The discovery of high-$T_c$ conventional superconductivity in high-pressure hydrides has helped establish computational methods as a formidable tool to guide material discoveries in a field traditionally dominated by serendipitous experimental search. This paves the way to an ever-increasing use of data-driven approaches to the study and design of superconductors. In this work, we propose a new method to generate meaningful datasets of superconductors, based on element substitution into a small set of representative structural templates, generated by crystal structure prediction methods (Multi…
The 2014-2015 prediction, discovery, and confirmation of record high temperature superconductivity above 200K in H$_3$S, followed by the 2018 extension to superconductivity in the 250-280K range in lanthanum hydride, marks a new era in the longstanding quest for room temperature superconductivity: quest achieved, at the cost of supplying 1.5-2 megabars of pressure. Predictions of numerous high temperature superconducting metal hydrides $XH_n$ ($X$=metal) have appeared, but are providing limited understanding of what drives the high transition temperature T$_c$, or what limits T$_c$. We apply a…
Evidence against superconductivity in flux trapping experiments on hydrides under high pressure & On magnetic field screening and expulsion in hydride superconductors
Since the discovery of superconductivity at 200 K in H3S [1] similar or higher transition temperatures, Tcs, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved by different methods, including electrical resistance, magnetic susceptibility, optical infrared, and nuclear resonant scattering measurements. The crystal structures of superconducting phases were determined by X-ray diffraction. Numerous electrical transport measurements demonstrate the typical behaviour of a conventional phonon-mediated superconductor: ze…
It is generally believed that magnetization measurements on sulfur hydride under high pressure performed in 2015 [1] provided "final convincing evidence of superconductivity" [2] in that material, in agreement with theoretical predictions [3,4]. Supported by this precedent, drops in resistance that were later observed in several other hydrides under high pressure [2,5] have been generally accepted as evidence of superconductivity without corroborating evidence from magnetic measurements. In this paper we challenge the original interpretation that the magnetic measurements on sulfur hydride per…
Binary hydrides formed by the pnictogens of phosphorus, arsenic and antimony are studied at high pressures using first principles methods. Stable structures are predicted and their electronic, vibrational and superconducting properties are investigated. We predict that SbH$_{4}$ and AsH$_{8}$ will be high-temperature superconductors at megabar pressures, with critical temperatures in excess of 100 K. The highly symmetric hexagonal SbH$_{4}$ phase is predicted to be stabilized above about 150 GPa, which is readily achievable in diamond anvil cell experiments. We find that all phosphorus hydride…
Motivated by the recent claim of hot superconductivity with critical temperatures up to 550 K in La + x hydrides (arXiv:2006.03004), we investigate the high-pressure phase diagram of possible compounds that may have formed in the experiment, using first-principles calculations for evolutionary crystal structure prediction and superconductivity. Starting from the hypothesis that the observed T$_c$ may be realized by successive heating upon a pre-formed LaH$_{10}$ phase, we examine plausible ternaries of lanthanum, hydrogen and other elements present in the diamond anvil cell: boron, nitrogen, c…
The recent report of superconductivity under high pressure at the record transition temperature of Tc=203K in sulfur hydride has been identified as conventional in view of the observation of an isotope effect upon deuteration. Here it is demonstrated that conventional theories of superconductivity in the sense of BCS or Eliashberg formalisms can neither account for the observed values of Tc nor the pressure dependence of the isotope coefficient. The only way out of the dilemma is a multi-band approach of superconductivity where already small interband coupling suffices to achieve the high valu…
Over the past six years, superconductivity at high temperatures has been reported in a variety of hydrogen-rich compounds under high pressure. That high-temperature superconductivity should exist in these materials is expected according to the conventional theory of superconductivity, as shown by detailed calculations. However here we argue that experimental observations rule out conventional superconductivity in these materials. Our results indicate that either these materials are unconventional superconductors of a novel kind, which we term `nonstandard superconductors', or alternatively tha…
Capitani and coworkers [1] reported that infrared optical reflectance measurements provided evidence for a superconducting transition in sulfur hydride [2] under 150 GPa pressure, and that the transition is driven by the electron-phonon interaction. Here we argue that the measured data did not provide evidence that the system undergoes a transition to a superconducting state, nor do the data support any role of phonons in driving a transition. Rather, the data are consistent with the system remaining in the normal state down to temperature 50K, the lowest temperature measured in the experiment…
Recent discovery of superconductive rare earth/actinide superhydrides has ushered in a new era of superconductivity research at high pressures. This distinct type of clathrate metal hydrides was first proposed for alkaline-earth-metal hydride CaH6 that, however, has long eluded experimental synthesis, impeding an understanding of pertinent physics. Here, we report successful synthesis of CaH6 and its measured superconducting critical temperature Tc of 215 K at 172 GPa, which is evidenced by a sharp drop of resistivity to zero and a characteristic decrease of Tc under a magnetic field up to 9 T…
Ambient and Pressure Dependent Superconductivity with Hydrogen Storage Potential in Quaternary Hydride LiMgZr2H12: A Comprehensive First-principles Insights
Department of Physics, University of Rajshahi（拉杰沙希大学物理系）
Using the data on the superconducting critical temperature ($T_{C}$) for a number of metal hydrides, we found a rule that makes it possible to predict the maximum $T_{C}$ based only on the information about the electronic structure of metal atoms. Using this guiding principle, we explored the hydride systems for which no reliable information existed, predicted new higher hydrides in the K-H, Zr-H, Hf-H, Ti-H, Mg-H, Sr-H, Ba-H, Cs-H, and Rb-H systems at high pressures, and calculated their $T_{C}$. Results of the study of actinides and lanthanides show that they form highly symmetric superhydri…
Searching for superconductivity with Tc near room temperature is of great interest both for fundamental science & many potential applications. Here we report the experimental discovery of superconductivity with maximum critical temperature (Tc) above 210 K in calcium superhydrides, the new alkali earth hydrides experimentally showing superconductivity above 200 K in addition to sulfur hydride & rare-earth hydride system. The materials are synthesized at the synergetic conditions of 160~190 GPa and ~2000 K using diamond anvil cell combined with in-situ laser heating technique. The superconducti…
