arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1503.06000cond-mat.str-elcond-mat.mtrl-sci
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B位无序电子掺杂锰氧化物SrMn0.875 Mo 0.125 O3-δ中室温以上的强电荷有序

Strong charge ordering above room temperature in B-site disordered electron-doped manganite SrMn0.875Mo0.125O3-δ

Aga Shahee, N. P. Lalla

摘要:

在83 - 637 K温度范围内对无稀土B位无序电子掺杂锰氧化物SrMn_(0.875). Mo_(0.125)O_(3-δ)进行了低温和高温电子衍射和X射线衍射研究。这些研究揭示了强电荷有序(CO)在室温下发生在一个伪四方扭曲的钙钛矿相与空间群Pmmm。沿[-110]的8.95倍的非积分调制矢量表示电荷密度波型调制。具有钙钛矿结构Pmmm的CO相在355 K发生一级相变,转变为电荷无序立方相。支持温度依赖的测量电阻和磁化强度显示了金属绝缘体和反铁磁的转变跨越355 K与广泛的滞后范围从150 K到365 K。分析了c/a < 1的基本钙钛矿晶格的赝四方性以及二维调制的电荷有序区的出现是由于3dx 2/3dy 2型和3dx 2-y 2型轨道有序的两种CO相的共存。

英文摘要:

Low as well as high-temperature electron and x-ray diffraction studies have been carried out on a rare-earth free B-site disordered electron-doped manganite SrMn0.875.Mo0.125O3-δ in the temperature range of 83K to 637K. These studies reveal the occurrence of strong charge ordering (CO) at room temperature in a pseudo tetragonally distorted perovskite phase with space-group Pmmm. Non integral modulation vector of 8.95 times along [-110] indicates a charge density wave type modulation. The CO phase with basic perovskite structure Pmmm transforms to a charge disorder cubic phase through a first order phase transition at 355K. Supporting temperature dependent measurements of resistance and magnetization show a metal-insulator and antiferromagnetic transitions across 355K with a wide hysterisis ranging from 150K to 365K. The occurrence of pseudo tetragonality of the basic perovskite lattice with c/a < 1 together with charge-ordered regions with 2-dimensional modulation have been analyzed as the coexistence of two CO phases with 3dx2/3dy2 type and 3dx2-y2 type orbital ordering.

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