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arXiv 1503.00223cond-mat.stat-mech
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非齐次空间中布朗粒子的平衡随机动力学:另一种模型的推导

Equilibrium stochastic dynamics of a Brownian particle in inhomogeneous space: derivation of an alternative model

A. Bhattacharyay

摘要:

本文导出了非齐次空间中布朗粒子的一个择一平衡随机动力学。这样的动力学可以模拟复杂分子在其构象空间中与均匀热浴平衡时的运动。推导是通过一个简单的推广的配方由于Zwanzig的布朗粒子在均匀的热浴。我们表明,如果系统耦合到不同数量的浴自由度在不同的构象,然后导出的替代模型。我们讨论的实验结果Faucheux和Libchaber这可能表明可能的限制玻尔兹曼分布的平衡分布的布朗粒子在非均匀空间,并提出实验验证本理论使用类似的方法。

英文摘要:

An alternative equilibrium stochastic dynamics for a Brownian particle in inhomogeneous space is derived. Such a dynamics can model the motion of a complex molecule in its conformation space when in equilibrium with a uniform heat bath. The derivation is done by a simple generalization of the formulation due to Zwanzig for a Brownian particle in homogeneous heat bath. We show that if the system couples to different number of bath degrees of freedom at different conformations then the alternative model is derived. We discuss results of an experiment by Faucheux and Libchaber which probably has indicated possible limitation of the Boltzmann distribution as equilibrium distribution of a Brownian particle in inhomogeneous space and propose experimental verification of the present theory using similar methods.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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