Observational evidence seems to indicate that the depletion of interstellar carbon into dust shows rather wide variations and that carbon undergoes rather rapid recycling in the interstellar medium (ISM). Small hydrocarbon grains are processed in photo-dissociation regions by UV photons, by ion and electron collisions in interstellar shock waves and by cosmic rays. A significant fraction of hydrocarbon dust must therefore be re-formed by accretion in the dense, molecular ISM. A new dust model (Jones et al., Astron. Astrophys., 2013, 558, A62) shows that variations in the dust observables in the diffuse interstellar medium (nH = 1000 cm^3), can be explained by systematic and environmentally-driven changes in the small hydrocarbon grain population. Here we explore the consequences of gas-phase carbon accretion onto the surfaces of grains in the transition regions between the diffuse ISM and molecular clouds (e.g., Jones, Astron. Astrophys., 2013, 555, A39). We find that significant carbonaceous dust re-processing and/or mantle accretion can occur in the outer regions of molecular clouds and that this dust will have significantly different optical properties from the dust in the adjacent diffuse ISM. We conclude that the (re-)processing and cycling of carbon into and out of dust is perhaps the key to advancing our understanding of dust evolution in the ISM.
The present study provides an investigation on the deposition of carbon-related products on different substrates using a high power dielectric barrier discharge fed with helium and saturated hydrocarbon gases. The discharge has been characterized by means of voltage-current measurements, while the neutral species and the dissociation compounds accumulated in the plasma reactor have been analyzed by Fourier-transform infrared (FTIR) spectroscopy. The properties of non-aromatic hydrogenated amorphous carbon (a-C:H) films and 'fluffy' carbon dust deposited onto various substrates are analyzed by …
We have observed a sample of 19 carbon stars in the Sculptor, Carina, Fornax, and Leo I dwarf spheroidal galaxies with the Infrared Spectrograph on the Spitzer Space Telescope. The spectra show significant quantities of dust around the carbon stars in Sculptor, Fornax, and Leo I, but little in Carina. Previous comparisons of carbon stars with similar pulsation properties in the Galaxy and the Magellanic Clouds revealed no evidence that metallicity affected the production of dust by carbon stars. However, the more metal-poor stars in the current sample appear to be generating less dust. These d…
We have carried out an investigation of the chemical evolution of gas in different carbon-rich circumstellar environments. Previous studies have tended to invoke terrestrial flame chemistries, based on acetylene (C2H2) combustion to model the formation of carbon dust, via Polycyclic Aromatic Hydrocarbons (PAHs). In this work we pay careful attention to the accurate calculation of the molecular photoreaction rate coefficients to ascertain whether there is a universal formation mechanism for carbon dust in strongly irradiated astrophysical environments. A large number of possible chemical channe…
We present infrared multi-epoch observations of the dust forming nova V1280 Sco over $\sim$2000 days from the outburst. The temporal evolution of the infrared spectral energy distributions at 1272, 1616 and 1947 days can be explained by the emissions produced by amorphous carbon dust of mass (6.6--8.7)$\times$10$^{-8}$M$_{\odot}$ with a representative grain size of 0.01$~μ$m and astronomical silicate dust of mass (3.4--4.3)$\times$10$^{-7}$M$_{\odot}$ with a representative grain size of 0.3--0.5$~μ$m. Both of these dust species travel farther away from the white dwarf without an apparent mass …
We propose an updated dust evolution model that focuses on the grain size distribution in a galaxy. We treat the galaxy as a one-zone object and include five main processes (stellar dust production, dust destruction in supernova shocks, grain growth by accretion and coagulation, and grain disruption by shattering). In this paper, we improve the predictions related to small carbonaceous grains, which are responsible for the 2175 Å bump in the extinction curve and the polycyclic aromatic hydrocarbon (PAH) emission features in the dust emission spectral energy distribution (SED), both of which we…
Interstellar space hosts nanometre- to micron-sized dust grains. The carbonaceous-rich component of these grain populations emits in infrared bands, observed remotely for decades with telescopes and satellites. They are a key ingredient of astrochemical dust evolution. The precise carriers for most of these bands are still unknown and not well reproduced in the laboratory. In this work, we show the high-energy mechanochemical synthesis of disordered aromatic and aliphatic analogues provides interstellar relevant dust particles. The mechanochemical milling of carbon-based solids under a hydroge…
Understanding the history and evolution of small bodies, such as dust grains and comets, in planet-forming disks is very important to reveal the architectural laws responsible for the creation of planetary systems. These small bodies in cold regions of the disks are typically considered as mixtures of dust particles with molecular ices, where ices cover the surface of a dust core or are actually physically mixed with dust. Whilst the first case, ice-on-dust, has been intensively studied in the laboratory in recent decades, the second case, ice-mixed-with-dust, present uncharted territory. This…
Surface chemistry on cosmic dust grains plays an important role in the formation of molecules at low temperatures in the interstellar and circumstellar environments. For the first time, we experimentally put in evidence the catalytic role of dust surfaces using the thermal reaction CO2 + 2NH3 = NH4+NH2COO-, which is also a proxy of radical-radical reactions. Nanometre-sized amorphous silicate and carbon grains produced in our laboratory were used as grain analogues. Surface catalysis on grains accelerates the kinetics of the reaction studied at a temperature of 80 K by a factor of up to 3 comp…
There remain many open questions relating to the depletion of elements into dust, e.g., exactly how are C and O incorporated into dust in dense clouds and, in particular, what drives the disappearance of oxygen in the denser interstellar medium? This work is, in part, an attempt to explain the apparently anomalous incorporation of O atoms into dust in dense clouds. We re-visit the question of the depletion of the elements incorporated into the carbonaceous component of interstellar dust, i.e., C, H, O, N and S, in the light of recent analyses of the organics in comets, meteorites and interplan…
New infrared spectra of 33 Galactic carbon stars from FORCAST on SOFIA reveal strong connections between stellar pulsations and the dust and molecular chemistry in their circumstellar shells. A sharp boundary in overall dust content, which predominantly measures the amount of amorphous carbon, separates the semi-regular and Mira variables, with the semi-regulars showing little dust in their spectra and the Miras showing more. In semi-regulars, the contribution from SiC dust increases rapidly as the overall dust content grows, but in Miras, the SiC dust feature grows weaker as more dust is adde…
Supernova remnants (SNRs) are well-recognised dust producers, but their net dust production rate remains elusive due to uncertainties in grain properties that propagate into observed dust mass uncertainties, and determine how efficiently these grains are processed by reverse shocks. In this paper, we present a detection of polarised dust emission in the Crab pulsar wind nebula, the second SNR with confirmed polarised dust emission after Cassiopeia A. We constrain the bulk composition of the dust with new SOFIA/HAWC+ polarimetric data in band C 89 um and band D 154 um. After correcting for sync…
We present a survey for neutral atomic-carbon (CI) along gamma-ray burst (GRB) sightlines, which probes the shielded neutral gas-phase in the interstellar medium (ISM) of GRB host galaxies at high redshift. We compile a sample of 29 medium- to high-resolution GRB optical afterglow spectra spanning a redshift range through most of cosmic time from $1 < z < 6$. We find that seven ($\approx 25\%$) of the GRBs entering our statistical sample have CI detected in absorption. It is evident that there is a strong excess of cold gas in GRB hosts compared to absorbers in quasar sightlines. We investigat…
The origin of dust in the early Universe has been the subject of considerable debate. Core-collapse supernovae (ccSNe), which occur several million years after their massive progenitors form, could be a major source of that dust, as in the local universe several ccSNe have been observed to be copious dust producers. Here we report nine near-infrared (0.8 - 2.5 micron) spectra of the Type II-P SN 2017eaw in NGC 6946, spanning the time interval 22 - 205 days after discovery. The specta show the onset of CO formation and continuum emission at wavelengths greater than 2.1 micron from newly-formed …
We present a new approach aimed at constraining the typical size and optical properties of carbon dust grains in Circumstellar envelopes (CSEs) of carbon-rich stars (C-stars) in the Small Magellanic Cloud (SMC). To achieve this goal, we apply our recent dust growth description, coupled with a radiative transfer code to the CSEs of C-stars evolving along the TP-AGB, for which we compute spectra and colors. Then we compare our modeled colors in the near- and mid-infrared (NIR and MIR) bands with the observed ones, testing different assumptions in our dust scheme and employing several data sets o…
The Planck-HFI all-sky survey from 353 to 857GHz combined with the 100 microns IRAS show that the dust properties vary in the diffuse ISM at high Galactic latitude (1e19<NH<2.5e20 H/cm2). Our aim is to explain these variations with changes in the ISM properties and grain evolution. Our starting point is the latest core-mantle dust model. It consists of small aromatic-rich carbon grains, larger amorphous carbon grains with aliphatic-rich cores and aromatic-rich mantles, and amorphous silicates with Fe/FeS nano-inclusions covered by aromatic-rich carbon mantles. We explore whether variations in …
Radiative Torques (RATs) or Mechanical Torques (METs) acting on irregular grains can induce the alignment of dust grains in respect to the alignment axis (AA), which can be either the direction of the magnetic field, or the direction of the radiation. We show that carbonaceous grains can be aligned with their axes both parallel and perpendicular to the AA and we explore the conditions where the particular mode of alignment takes place. We identify a new process of alignment of charged carbonaceous grains in a turbulent magnetized interstellar medium with respect to an electric field. This fiel…
We probe the role of carbon in the ultraviolet (UV) extinction by examining the relations between the amount of carbon required to be locked up in dust [C/H]_dust with the 2175 Angstrom extinction bump and the far-UV extinction rise, based on an analysis of the extinction curves along 16 Galactic sightlines for which the gas-phase carbon abundance is known and the 2175 Angstrom extinction bump exhibits variable strengths and widths. We derive [C/H]_dust from the Kramers-Kronig relation which relates the wavelength-integrated extinction to the total dust volume. This approach is less model-depe…
In the interstellar medium, carbon (nano-)grains are a major component of interstellar dust. This solid phase is more vulnerable to processing and destruction than its silicate counterpart. It exhibits a complex, size-dependent evolution due to interactions within different radiative and dynamical environments. Infrared signatures of these nanocarbon grains are seen in a large number of disks around Herbig HAeBe stars. We probe the composition and evolution of carbon nano-grains at the surface of (pre-)transitional protoplanetary disks around Herbig stars. We present spatially resolved infrare…
The properties of carbon stars in the Magellanic Clouds (MCs) and their total dust production rates are predicted by fitting their spectral energy distributions (SED) over pre-computed grids of spectra reprocessed by dust. The grids are calculated as a function of the stellar parameters by consistently following the growth for several dust species in their circumstellar envelopes, coupled with a stationary wind. Dust radiative transfer is computed taking as input the results of the dust growth calculations. The optical constants for amorphous carbon are selected in order to reproduce different…
We present ALMA [CI]($1-0$) (rest frequency 492 GHz) observations for a sample of 13 strongly-lensed dusty star-forming galaxies originally discovered at 1.4mm in a blank-field survey by the South Pole Telescope. We compare these new data with available [CI] observations from the literature, allowing a study of the ISM properties of $\sim 30$ extreme dusty star-forming galaxies spanning a redshift range $2 < z < 5$. Using the [CI] line as a tracer of the molecular ISM, we find a mean molecular gas mass for SPT-DSFGs of $6.6 \times 10^{10}$ M$_{\odot}$. This is in tension with gas masses derive…
The \textit{Spitzer}/Infrared Spectrograph spectra of three spectroscopically anomalous galaxies (IRAS~F10398+1455, IRAS~F21013-0739 and SDSS~J0808+3948) are modeled in terms of a mixture of warm and cold silicate dust, and warm and cold carbon dust. Their unique infrared (IR) emission spectra are characterized by a steep $\simali$5--8$\mum$ emission continuum, strong emission bands from polycyclic aromatic hydrocarbon (PAH) molecules, and prominent silicate emission. The steep $\simali$5--8$\mum$ emission continuum and strong PAH emission features suggest the dominance of starbursts, while th…
Understanding the matter cycle in the interstellar medium of galaxies from the assembly of clouds to star formation and stellar feedback remains an important and exciting field in comtemporary astrophysics. Many open questions regarding cloud and structure formation, the role of turbulence, and the relative importance of the various feedback processes can only be addressed with observations of spectrally resolved lines. We here stress the importance of two specific sets of lines: the finestructure lines of atomic carbon as a tracer of the dark molecular gas and mid-J CO lines as tracers of the…
How dust scatters and absorbs starlight in the interstellar medium (ISM) contains important clues about the size and composition of interstellar dust. While the ultraviolet (UV) and visible interstellar extinction is well studied and can be closely fitted in terms of various dust mixtures (e.g., the silicategraphite mixture), the infrared (IR) extinction is not well understood, particularly, the mid-IR extinction in the 3-8 micron wavelength range is rather flat (or "gray") and is inconsistent with the standard Mathis, Rumpl, & Nordsieck (MRN) silicate-graphite dust model. We attempt to reprod…
We formulate and calculate the evolution of dust in a galaxy focusing on the distinction among various dust components -- silicate, aromatic carbon, and non-aromatic carbon. We treat the galaxy as a one-zone object and adopt the evolution model of grain size distribution developed in our previous work. We further include aromatization and aliphatization (inverse reaction of aromatization). We regard small aromatic grains in a radius range of 3--50 Å as polycyclic aromatic hydrocarbons (PAHs). We also calculate extinction curves in a consistent manner with the abundances of silicate and aromati…
Carbon stars have been and are extensively studied, given their complex internal structure and their peculiar chemical composition, which make them living laboratories to test stellar structure and evolution theories of evolved stars. They are the most relevant dust manufacturers, thus playing a crucial role in the evolution of galaxies. We study the dust mineralogy of circumstellar envelope (CE) of C-stars in the Large Magellanic Cloud (LMC), to achieve a better understanding of the dust formation process in the outflow of these objects. We investigate the expected distribution of C-stars in …
We present Spitzer IRS spectra of four carbon stars located in the Galactic Halo and the thick disc. The spectra display typical features of carbon stars with SiC dust emission and C$_2$H$_2$ molecular absorption. Dust radiative transfer models and infrared colors enable us to determine the dust production rates for these stars whilst prior CO measurements yield expansion velocities and total mass-loss rates. The gas properties (low expansion velocities (around 7 km/s) and strong C$_2$H$_2$ molecular absorption bands) are consistent with the stars being metal-poor. However the dust content of …
Context. Excess microwave emission, commonly known as anomalous microwave emission (AME), is now routinely detected in the Milky Way. Although its link with the rotation of interstellar (carbonaceous) nano-grains seems to be relatively well established at cloud scales, large-scale observations show a lack of correlation between the different tracers of nano-carbons and AME, which has led the community to question the viability of this link. Aims. Using ancillary data and spinning dust models for nano-carbons and nano-silicates, we explore the extent to which the AME that come out of the Galact…
The low density interstellar medium (ISM) close to the Sun and inside of the heliosphere provides a unique laboratory for studying interstellar dust grains. Grain characteristics in the nearby ISM are obtained from observations of interstellar gas and dust inside of the heliosphere and the interstellar gas towards nearby stars. Comparison between the gas composition and solar abundances suggests that grains are dominated by olivines and possibly some form of iron oxide. Measurements of the interstellar Ne/O ratio by the Interstellar Boundary Explorer spacecraft indicate that a high fraction of…
We compare theoretical dust yields for stars with mass 1 Msun < mstar < 8 Msun, and metallicities 0.001 < Z < 0.008 with observed dust production rates (DPR) by carbon- rich and oxygen-rich Asymptotic Giant Branch (C-AGB and O-AGB) stars in the Large and Small Magellanic Clouds (LMC, SMC). The measured DPR of C-AGB in the LMC are reproduced only if the mass loss from AGB stars is very efficient during the carbon-star stage. The same yields over-predict the observed DPR in the SMC, suggesting a stronger metallicity dependence of the mass-loss rates during the carbon- star stage. DPR of O-AGB st…
We present a dust spectral energy distribution (SED) and binary stellar population analysis revisiting the dust production rates (DPRs) in the winds of carbon-rich Wolf-Rayet (WC) binaries and their impact on galactic dust budgets. DustEM SED models of 19 Galactic WC ``dustars" reveal DPRs of $\dot{M}_d\sim10^{-10}-10^{-6}$ M$_\odot$ yr$^{-1}$ and carbon dust condensation fractions, $χ_C$, between $0.002 - 40\%$. A large ($0.1 - 1.0$ $μ$m) dust grain size composition is favored for efficient dustars where $χ_C\gtrsim1\%$. Results for dustars with known orbital periods verify a power-law relati…
The asymptotic giant branch (AGB) star R Sculptoris (R Scl) is one of the most extensively studied stars on the AGB. R Scl is a carbon star with a massive circumstellar shell ($M_{shell}\sim 7.3\times10^{-3}~M_{\odot}$) which is thought to have been produced during a thermal pulse event $\sim2200$ years ago. To study the thermal dust emission associated with its circumstellar material, observations were taken with the Faint Object InfraRed CAMera for the SOFIA Telescope (FORCAST) at 19.7, 25.2, 31.5, 34.8, and 37.1 $μ$m. Maps of the infrared emission at these wavelengths were used to study the…
In this work the optical properties of amorphous carbon (amC) dust condensed around carbon(C)-stars are constrained by comparing the observations for the Large Magellanic Cloud C-stars from the Two Micron All Sky Survey (2MASS) and from the Gaia data release 2 (DR2) with the synthetic photometry obtained by computing dust growth and radiative transfer in their circumstellar envelopes. The set of optical constants of amC dust considered have been pre-selected according to their ability to reproduce the infrared colour-colour diagrams in the Small Magellanic Cloud. Only two combinations of the o…
We present a numerical tool Shiva designed to simulate the dust destruction in warm neutral, warm ionized, and hot ionized media under the influence of photo-processing, sputtering, and shattering. The tool is designed primarily to study the evolution of hydrogenated amorphous carbons (HACs), but options to simulate polycyclic aromatic hydrocarbons (PAHs), silicate and graphite grains are also implemented. HAC grain photo-processing includes both dehydrogenation and carbon atom loss. Dehydrogenation leads to material transformation from aliphatic to aromatic structure. Simultaneously, some oth…
To understand the evolution of extinction curve, we calculate the dust evolution in a galaxy using smoothed particle hydrodynamics simulations incorporating stellar dust production, dust destruction in supernova shocks, grain growth by accretion and coagulation, and grain disruption by shattering. The dust species are separated into carbonaceous dust and silicate. The evolution of grain size distribution is considered by dividing grain population into large and small gains, which allows us to estimate extinction curves. We examine the dependence of extinction curves on the position, gas densit…
The quantity of NH3 produced on grain surfaces in the prestellar core is thought to be one of the determining factors regarding the chemical complexity achievable at later stages of stellar birth. In order to investigate how this quantity might be influenced by the gas-grain cycling of molecular material within the cloud, we employ a modified rates gas-grain chemical code and follow the time-dependent chemistry of NH3 as the system evolves. Our models incorporate an updated version of the most recent UDfA network of reaction rate coefficients, desorption from the grains through standard therma…
Extinction curves, especially those in the Milky Way (MW), the Large Magellanic Cloud (LMC), and the Small Magellanic Cloud (SMC), have provided us with a clue to the dust properties in the nearby Universe. We examine whether or not these extinction curves can be explained by well known dust evolution processes. We treat the dust production in stellar ejecta, destruction in supernova shocks, dust growth by accretion and coagulation, and dust disruption by shattering. To make a survey of the large parameter space possible, we simplify the treatment of the grain size distribution evolution by ad…
The classical theory of grain nucleation suffers from both theoretical and predictive deficiencies. We strive to alleviate these deficiencies in our understanding of dust formation and growth by utilizing an atomistic model of nucleation. Carbon cluster geometries are determined with a set of global minimization algorithms. Using density functional theory, the binding energies of carbon clusters from $n=2$ to $n=99$ are then calculated. These energies are used to calculate the critical size and nucleation rate of carbon clusters. We find that the critical cluster size is largely determined by …
We surveyed a sample of compact Galactic planetary nebulae (PNe) with the Space Telescope Imaging Spectrograph on the Hubble Space Telescope (HST/STIS) to determine their gas-phase carbon abundances. Carbon abundances in PNe constrain the nature of their asymptotic giant branch (AGB) progenitors, as well as cosmic recycling. We measured carbon abundances, or limits thereof, of 11 compact Galactic PNe, notably increasing the sample of Galactic PNe whose carbon abundance based on HST ultraviolet spectra is available. Dust content of most targets has been studied elsewhere from Spitzer spectrosco…
We present an infrared (IR) characterization of the born-again planetary nebulae (PNe) A30 and A78 using IR images and spectra. We demonstrate that the carbon-rich dust in A30 and A78 is spatially coincident with the H-poor ejecta and coexists with hot X-ray-emitting gas up to distances of 50$''$ from the central stars (CSPNs). Dust forms immediately after the born-again event and survives for 1000 yr in the harsh environment around the CSPN as it is destroyed and pushed away by radiation pressure and dragged by hydrodynamical effects. Spitzer IRS spectral maps showed that the broad spectral f…
Background: Most of the stars in the Universe will end their evolution by losing their envelope during the thermally pulsing asymptotic giant branch (TP-AGB) phase, enriching the interstellar medium of galaxies with heavy elements, partially condensed into dust grains formed in their extended circumstellar envelopes. Among these stars, carbon-rich TP-AGB stars (C-stars) are particularly relevant for the chemical enrichment of galaxies. We here investigated the role of the metallicity in the dust formation process from a theoretical viewpoint. Methods: We coupled an up-to-date description of du…
In the interstellar medium, carbon is distributed between the gas and solid phases. However, while about half of the expected carbon abundance can be accounted for in the gas phase, there is considerable uncertainty as to the amount incorporated in interstellar dust. The aliphatic component of the carbonaceous dust is of particular interest because it produces a significant 3.4 $μ$m absorption feature when viewed against a background radiation source. The optical depth of the 3.4 $μ$m absorption feature is related to the number of aliphatic carbon C-H bonds along the line of sight. It is possi…
An era has started in which gas and dust can be observed independently in protoplanetary disks, thanks to the recent surveys with ALMA. The first near-complete high-resolution disk survey in both dust and gas in a single star-forming region has been carried out in Lupus, finding surprisingly low gas/dust ratios. The goal of this work is to fully exploit CO isotopologues observations in Lupus, comparing them with physical-chemical model results, in order to obtain gas masses for a large number of disks. We have employed physical-chemical models to analyze continuum and CO isotopologues observat…
Interstellar carbonaceous dust is mainly formed in the innermost regions of circumstellar envelopes around carbon-rich asymptotic giant branch (AGB) stars. In these highly chemically stratified regions, atomic and diatomic carbon, along with acetylene are the most abundant species after H$_2$ and CO. In a previous study, we addressed the chemistry of carbon (C and C$_2$) with H$_2$ showing that acetylene and aliphatic species form efficiently in the dust formation region of carbon-rich AGBs whereas aromatics do not. Still, acetylene is known to be a key ingredient in the formation of linear po…
Laboratory spectra of hydrogenated amorphous carbon (HAC) particles prepared under a variety of conditions show spectral features at 7.05, 8.5, 17.4 and 18.9 μm (1418, 1176, 575 & 529 cm-1) that have been associated with emission from C60 molecules. These lines occur in the spectra even though C60 molecules as such are not present in our samples. It appears that these four spectral lines in HAC can instead be associated with precursor molecules or "proto-fullerenes" that subsequently react to yield C60. We develop a model tracing the evolution and de-hydrogenation of HAC dust and show that the…
We present a study on the prospects of observing carbon, sulfur, and other lower abundance elements (namely Al, Ca, Ti and Ni) present in the interstellar medium using future X-ray instruments. We focus in particular on the detection and characterization of interstellar dust along the lines of sight. We compare the simulated data with different sets of dust aggregates, either obtained from past literature or measured by us using the SOLEIL-LUCIA synchrotron beamline. Extinction by interstellar grains induces modulations of a given photolelectric edge, which can be in principle traced back to t…
The Infrared Spectrograph on the Spitzer Space Telescope observed 184 carbon stars in the Magellanic Clouds. This sample reveals that the dust-production rate (DPR) from carbon stars generally increases with the pulsation period of the star. The composition of the dust grains follows two condensation sequences, with more SiC condensing before amorphous carbon in metal-rich stars, and the order reversed in metal-poor stars. MgS dust condenses in optically thicker dust shells, and its condensation is delayed in more metal-poor stars. Metal-poor carbon stars also tend to have stronger absorption …
We present Spitzer/IRAC observations of dust formation from six extragalactic carbon-rich Wolf-Rayet (WC) binary candidates in low-metallicity (Z $\lesssim0.65$ Z$_\odot$) environments using multi-epoch mid-infrared (IR) imaging data from the SPitzer InfraRed Intensive Transients Survey (SPIRITS). Optical follow-up spectroscopy of SPIRITS~16ln, 19q, 16df, 18hb, and 14apu reveals emission features from C IV $\lambda5801\text{-}12$~and/or the C III-IV $\lambda4650$ He II $\lambda4686$~blend that are consistent with early-type WC stars. We identify SPIRITS~16ln as the variable mid-IR counterpart …
The life-cycle of cosmic dust grains is far from being understood and the origin and evolution of interstellar medium (ISM) grains is still under debate. In the ISM, the cosmic dust destruction rate is faster than the production rate by stellar sources. However, observations of ISM refractory matter suggest that to maintain a steady amount of cosmic grains, some supplementary production mechanism takes place. In this context, we aimed to study possible re-formation mechanisms of cosmic grains taking place at low temperature directly in the ISM. The low temperature condensation of carbonaceous …
It had been understood that astronomically observed infrared spectrum of carbon rich planetary nebula as like Tc 1 and Lin 49 comes from fullerene (C60). Also, it is well known that graphene is a raw material for synthesizing fullerene. This study seeks some capability of graphene based on the quantum-chemical DFT calculation. It was demonstrated that graphene plays major role rather than fullerene. We applied two astrophysical conditions, which are void creation by high speed proton and photo-ionization by the central star. Model molecule was ionized void-graphene (C23) having one carbon pent…
Gas giants accrete their envelopes from the gas and dust of proto-planetary disks, so it is important to determine the composition of the inner few AU, where most giant planets are expected to form. We aim to constrain the elemental carbon and oxygen abundance in the inner disk ($R<$2.3 AU) of TW Hya and compare with the outer disk ($R>2.3$ AU) where carbon and oxygen appear underabundant by a factor of $\sim$50. Archival infrared observations of TW Hya are compared with a detailed thermo-chemical model, DALI. The inner disk gas mass and elemental C and O abundances are varied to fit the infra…
We present a new analysis of the infrared (IR) emission from the ejecta of SN1987A covering days 615, 775, 1144, 8515, and 9090 after the explosion. We show that the observations are consistent with the rapid formation of about 0.4 Msun of dust, consisting of mostly silicates, near day 615, and evolving to about 0.45 Msun of composite dust grains consisting of ~0.4 Msun of silicates and ~ 0.05 Msun of amorphous carbon after day ~8500. The proposed scenario challenges previous claims that dust in SN ejecta is predominantly carbon, and that it grew from an initial mass of ~1e-3 Msun, to over 0.5…
In the interstellar medium, the cosmic elemental carbon abundance includes the total carbon in both gas and solid phases. The aim of the study was to trial a new method for measuring the amount and distribution of aliphatic carbon within interstellar dust over wide fields of view of our Galaxy. This method is based on measurement of the 3.4 $μ$m absorption feature from aliphatic carbonaceous matter. This can readily be achieved for single sources using IR spectrometers. However, making such measurements over wide fields requires an imaging IR camera, equipped with narrow-band filters that are …
