We formulate and calculate the evolution of dust in a galaxy focusing on the distinction among various dust components -- silicate, aromatic carbon, and non-aromatic carbon. We treat the galaxy as a one-zone object and adopt the evolution model of grain size distribution developed in our previous work. We further include aromatization and aliphatization (inverse reaction of aromatization). We regard small aromatic grains in a radius range of 3--50 Å as polycyclic aromatic hydrocarbons (PAHs). We also calculate extinction curves in a consistent manner with the abundances of silicate and aromatic and non-aromatic carbonaceous dust. Our model nicely explains the PAH abundance as a function of metallicity in nearby galaxies. The extinction curve become similar to the Milky Way curve at age $\sim$ 10 Gyr, in terms of the carbon bump strength and the far-ultraviolet slope. We also apply our model to starburst galaxies by shortening the star formation time-scale (0.5 Gyr) and increasing the dense-gas fraction (0.9), finding that the extinction curve maintains bumpless shapes (because of low aromatic fractions), which are similar to the extinction curves observed in the Small Magellanic Cloud and high-redshift quasars. Thus, our model successfully explains the variety in extinction curve shapes at low and high redshifts.
We model the extinction profiles observed in the Small and Large Magellanic clouds with a synthetic population of dust grains consisting by core-mantle particles and a collection of free-flying polycyclic aromatic hydrocarbons. All different flavors of the extinction curves observed in the Magellanic Clouds can be described by the present model, that has been previously (successfully) applied to a large sample of diffuse and translucent lines of sight in the Milky Way. We find that in the Magellanic Clouds the extinction produced by classic grains is generally larger than absorption by polycyc…
In a series of two recent papers, the frequency and size distribution dependence of extinction spectra for astronomical silicate and graphite grains was analyzed by us in the context of MRN type interstellar dust models. These grains were taken to be homogeneous spheres following the power law $(a^{-3.5})$ size distribution which is very much in use. The analytic formulas were obtained for the graphite and silicate grains in wavelength range 1000Å- 22,500Åand their utility was demonstrated. In this paper of the series, we present analytic formulas for the scattering and absorption spectrum of …
We interpret the interstellar extinction observed towards the Galactic Center (GC) in the wavelength range $λ= 1 - 20\,\mkm$. Its main feature is the flat extinction at $3 - 8\,\mkm$ whose explanation is still a problem for the cosmic dust models. We search for structure and chemical composition of dust grains that could explain the observed extinction. In contrast to earlier works we use laboratory measured optical constants and consider particles of different structure. We show that a mixture of compact grains of aromatic carbon and of some silicate is better suited for reproducing the flat …
Observationally, the interstellar gas-phase abundance of deuterium (D) is considerably depleted and the missing D atoms are often postulated to have been locked up into carbonaceous solids and polycyclic aromatic hydrocarbon (PAH) molecules. An accurate knowledge of the fractional amount of D (relative to H) tied up in carbon dust and PAHs has important cosmological implications since D originated exclusively from the Big Bang and the present-day D abundance, after accounting for the astration it has experienced during the Galactic evolution, provides essential clues to the primordial nucleosy…
Polycyclic Aromatic Hydrocarbons (PAHs) are considered as a major constituent of interstellar dust. They have been proposed as the carriers of the Aromatic Infrared Bands (AIBs) observed in emission in the mid-IR. They likely have a significant contribution to various features of the extinction curve such as the 220 nm bump,the far-UV rise and the diffuse interstellar bands. Emission bands are also expected in the far-IR, which are better fingerprints of molecular identity than the AIBs. They will be searched for with the Herschel Space Observatory. Rotational emission is also expected in the …
The sightline toward the luminous blue hypergiant Cyg OB2-12 is widely used in studying interstellar dust on account of its large extinction ($A_V \simeq 10$ mag) and the fact that this extinction appears to be dominated by dust typical of the diffuse interstellar medium. We present a new analysis of archival ISO-SWS and Spitzer IRS observations of Cyg OB2-12 using a model of the emission from the star and its stellar wind to determine the total extinction $A_λ$ from 2.4--37 $μ$m. In addition to the prominent 9.7 and 18 $μ$m silicate features, we robustly detect absorption features associated …
The mid-infrared spectrum contains rich diagnostics to probe the physical properties of galaxies, among which the pervasive emission features from polycyclic aromatic hydrocarbons (PAHs) offer a promising means of estimating the star formation rate (SFR) relatively immune from dust extinction. This paper investigates the effectiveness of PAH emission as a SFR indicator on sub-kpc scales by studying the Spitzer/IRS mapping-mode observations of the nearby grand-design spiral galaxy M51. We present a new approach of analyzing the spatial elements of the spectral datacube that simultaneously maxim…
We present a study for a sample of galaxies with active nuclei to characterize the main type of PAH molecules present in these objects and the local physical conditions of their irradiating sources, as well as the characteristics of the residing ionized gas, by combining optical and infrared data. Photoionization models were built with the {\sc CLOUDY} code to reproduce optical emission line ratios in combination with PAH intensity ratios. We find that the species containing 10 $-$ 82 carbon atoms are the most abundant in the sample. We suggest that family of species with only two or three fus…
We analyze extragalactic extinction profiles derived through gamma-ray burst afterglows, using a dust model specifically constructed on the assumption that dust grains are not immutable but respond time-dependently to the local physics. Such a model includes core-mantle spherical particles of mixed chemical composition (silicate core, sp2 and sp3 carbonaceous layers), and an additional molecular component, in the form of free-flying polycyclic aromatic hydrocarbons. We fit most of the observed extinction profiles. Failures occur for lines of sight presenting remarkable rises blueward the bump.…
A previous article argued that the antagonism between sight-lines with and without a bump at 2200 Å disappears, and that the observed properties of interstellar extinction can be globally understood, if it is accepted that scattered starlight contaminates the observed spectrum of reddened stars. The present paper develops this new paradigm by providing a better understanding of the characteristics of this scattered light. It further examines the consequences of this revision of interstellar extinction theory for interpreting the 2200 Å bump and the diffuse interstellar bands (DIBs). Two implic…
The life cycle of the population of interstellar polycyclic aromatic hydrocarbon (PAH) molecules depends partly on the photostability of the individual species. We have studied the dissociative photoionization of two ethynyl-substituted PAH species, namely, 9-ethynylphenanthrene and 1-ethynylpyrene. Their adiabatic ionization energy and the appearance energy of fragment ions have been measured with the photoelectron photoion coincidence (PEPICO) spectroscopy technique. The adiabatic ionization energy has been found at 7.84 +/- 0.02 eV for 9-ethynylphenanthrene and at 7.41 +/- 0.02 eV for 1-eth…
We modelled dust grain-size distributions for carbonaceous and silicates dust, as well as for free-flying iron nanoparticles in the environment of a $γ$-ray burst (GRB) afterglow, GRB 180325A. This GRB, at $z=2.2486$, has an unambiguous detection of the 2175 Å extinction feature with $R_V=4.58$ and $A_V=1.58$. In addition to silicates, polycyclic aromatic hydrocarbons (PAH), and graphite, we used iron nanoparticles grain-size distributions for the first time to model the observed extinction curve of GRB 180325A. We fit the observed extinction for four model permutations, using 232 sets of sili…
We present the results of a computational study to investigate the infrared spectroscopic properties of a large number of polycyclic aromatic hydrocarbon (PAH) molecules and their fully dehydrogenated counterparts. We constructed a database of fully optimized geometries for PAHs that is complete for eight or fewer fused benzene rings, thus containing 1550 PAHs and 805 fully dehydrogenated aromatics. A large fraction of the species in our database have clearly non-planar or curved geometries. For each species, we determined the frequencies and intensities of their normal modes using density fun…
We propose an updated dust evolution model that focuses on the grain size distribution in a galaxy. We treat the galaxy as a one-zone object and include five main processes (stellar dust production, dust destruction in supernova shocks, grain growth by accretion and coagulation, and grain disruption by shattering). In this paper, we improve the predictions related to small carbonaceous grains, which are responsible for the 2175 Å bump in the extinction curve and the polycyclic aromatic hydrocarbon (PAH) emission features in the dust emission spectral energy distribution (SED), both of which we…
The distinctive set of infrared (IR) emission bands at 3.3, 6.2, 7.7, 8.6, and 11.3μm are ubiquitously seen in a wide variety of astrophysical environments. They are generally attributed to polycyclic aromatic hydrocarbon (PAH) molecules. However, not a single PAH species has yet been identified in space, as the mid-IR vibrational bands are mostly representative of functional groups and thus do not allow one to fingerprint individual PAH molecules. In contrast, the far-IR (FIR) bands are sensitive to the skeletal characteristics of a molecule, hence they are important for chemical identificati…
A large number of interstellar absorption features at ~ 4000Å -- 1.8 μm, known as the "diffuse interstellar bands" (DIBs), remains unidentified. Most recent works relate them to large polycyclic aromatic hydrocarbon (PAH) molecules or ultrasmall carbonaceous grains which are also thought to be responsible for the 2175 Å extinction bump and/or the far ultraviolet (UV) extinction rise at $λ^{-1} > 5.9\ μm^{-1}$. Therefore, one might expect some relation between the UV extinction and DIBs. Such a relationship, if established, could put important constraints on the carrier of DIBs. Over the past f…
Deuterium (D) is one of the light elements created in the big bang. As the Galaxy evolves, the D/H abundance in the interstellar medium (ISM) decreases from its primordial value due to "astration". However, the observed gas-phase D/H abundances of some interstellar sightlines are substantially lower than the expected reduction by astration alone. The missing D could have been depleted onto polycyclic aromatic hydrocarbon (PAH) molecules which are ubiquitous and abundant in interstellar regions. To quantitatively explore the hypothesis of PAHs as a possible reservoir of interstellar D, we compu…
We present new H$α$ photometry for the Star-Formation Reference Survey (SFRS), a representative sample of star-forming galaxies in the local Universe. Combining these data with the panchromatic coverage of the SFRS, we provide calibrations of H$α$-based star-formation rates (SFRs) with and without correction for the contribution of [$\rm N_{^{II}}$] emission. We consider the effect of extinction corrections based on the Balmer decrement, infrared excess (IRX), and spectral energy distribution (SED) fits. We compare the SFR estimates derived from SED fits, polycyclic aromatic hydrocarbons, hybr…
We present polarisation spectra of seven stars in the lines-of-sight towards the Sco OB1 association. Our spectra were obtained within the framework of the Large Interstellar Polarization Survey carried out with the FORS instrument of the ESO VLT. We have modelled the wavelength-dependence of extinction and linear polarisation with a dust model for the diffuse interstellar medium which consists of a mixture of particles with size ranging from the molecular domain of 0.5 nm up to 350 nm. We have included stochastically heated small dust grains with radii between 0.5 and 6 nm made of graphite an…
Almost 20 % of the ~ 200 different species detected in the interstellar and circumstellar media present a carbon atom linked to nitrogen by a triple bond. Of these 37 molecules, 30 are nitrile R-CN compounds, the remaining 7 belonging to the isonitrile R-NC family. How these species behave in their interactions with the grain surfaces is still an open question. In a previous work, we have investigated whether the difference between nitrile and isonitrile functional groups may induce differences in the adsorption energies of the related isomers at the surfaces of interstellar grains of various …
Interstellar carbonaceous dust is mainly formed in the innermost regions of circumstellar envelopes around carbon-rich asymptotic giant branch (AGB) stars. In these highly chemically stratified regions, atomic and diatomic carbon, along with acetylene are the most abundant species after H$_2$ and CO. In a previous study, we addressed the chemistry of carbon (C and C$_2$) with H$_2$ showing that acetylene and aliphatic species form efficiently in the dust formation region of carbon-rich AGBs whereas aromatics do not. Still, acetylene is known to be a key ingredient in the formation of linear po…
We probe the role of carbon in the ultraviolet (UV) extinction by examining the relations between the amount of carbon required to be locked up in dust [C/H]_dust with the 2175 Angstrom extinction bump and the far-UV extinction rise, based on an analysis of the extinction curves along 16 Galactic sightlines for which the gas-phase carbon abundance is known and the 2175 Angstrom extinction bump exhibits variable strengths and widths. We derive [C/H]_dust from the Kramers-Kronig relation which relates the wavelength-integrated extinction to the total dust volume. This approach is less model-depe…
Context. As revealed by high-resolution spectral investigations in the wavelength range between 300 and 400 nm, the interstellar extinction curve does not display any of the sharp electronic absorption bands that are characteristic for large polyatomic molecules, such as polycyclic aromatic hydrocarbons (PAHs), which belong to the most abundant interstellar molecules. Aims. We aim to verify whether the absorption curves of mixtures of medium-sized PAHs produced in the laboratory can explain the astronomical observations. Methods. The PAH mixtures were synthesized by infrared laser pyrolysis an…
