We have performed an extensive analysis of a single particle stochastic heat engine constructed by manipulating a Brownian particle in a time dependent harmonic potential. The cycle consists of two isothermal steps at different temperatures and two adiabatic steps similar to that of a Carnot engine. The engine shows qualitative differences in inertial and overdamped regimes. All the thermodynamic quantities, including efficiency, exhibit strong fluctuations in a time periodic steady state. The fluctuations of stochastic efficiency dominate over the mean values even in the quasistatic regime. Interestingly, our system acts as an engine provided the temperature difference between the two reservoirs is greater than a finite critical value which in turn depends on the cycle time and other system parameters. This is supported by our analytical results carried out in the quasistatic regime. Our system works more reliably as an engine for large cycle times. By studying various model systems we observe that the operational characteristics are model dependent. Our results clearly rules out any universal relation between efficiency at maximum power and temperature of the baths. We have also verified fluctuation relations for heat engines in time periodic steady state.
Typical heat engines exhibit a kind of homotypy: The heat exchanges between a cyclic heat engine and its two heat reservoirs abide by the same function type; the forward and backward flows of an autonomous heat engine also conform to the same function type. This homotypy mathematically reflects in the existence of hidden symmetries for heat engines. The heat exchanges between the cyclic heat engine and its two reservoirs are dual under the joint transformation of parity inversion and time-reversal operation. Similarly, the forward and backward flows in the autonomous heat engine are also dual …
We retrospect three abstract models for heat engines which include a classic abstract model in textbook of thermal physics, a primary abstract model for finite-time heat engines, and a refined abstract model for finite-time heat engines. The detailed models of heat engines in literature of finite-time thermodynamics may be mapped into the refined abstract model. The future developments based on the refined abstract model are also surveyed.
The Carnot theorem, one expression of the second law of thermodynamics, places a fundamental upper bound on the efficiency of heat engines operating between two heat baths. The Carnot theorem can be stated in a more generalized form for heat engines operating with multiple heat baths, where the maximum efficiency is achieved for reversible heat engines operating quasistatically between two heat baths. In this study, we determine the irreversible efficiency of heat engines operating with multiple heat baths in a linear response regime, i.e., under small temperature differences and a slow variat…
We formulate the work output and efficiency for linear irreversible heat engines working between a finite-sized hot heat source and an infinite-sized cold heat reservoir until the total system reaches the final thermal equilibrium state with a uniform temperature. We prove that when the heat engines operate at the maximum power under the tight-coupling condition without heat leakage the work output is just half of the exergy, which is known as the maximum available work extracted from a heat source. As a consequence, the corresponding efficiency is also half of its quasistatic counterpart.
We use the general formulation of irreversible thermodynamics and study the minimally nonlinear irreversible model of heat engines operating between a time-varying hot heat source of finite size and a cold heat reservoir of infinite size. We find the criterion in which the optimized efficiency obtained by this minimally nonlinear irreversible heat engine can reach the reversible efficiency under the tight coupling condition: a condition of no heat leakage between the system and the reservoirs. We assume the rate of heat transfer from hot to cold heat reservoir obeys Fourier law and discuss phy…
The work provides an overview on some recent advances in the area of quantum thermodynamics and quantum heat engines. A particular emphasis is put on the possibility of constructing finite time quantum cycles and adiabatic shortcuts. We discuss in details the particular quantum heat engines operating with a multiferroic working substance.
The autonomous heat engine is a model system of autonomous nonequilibrium systems like biological cells, exploiting nonequilibrium flow for operations. As the Carnot engine has essentially contributed to the equilibrium thermodynamics, autonomous heat engine is expected to play a critical role in the challenge of constructing nonequilibrium thermodynamics. However, the high complexity of the engine involving an intricate coupling among heat, gas flow, and mechanics has prevented simple modeling. Here, we experimentally characterized the nonequilibrium dynamics and thermodynamics of a low-tempe…
We consider optimizations of Lenoir heat engine within a quantum dynamical field consisting of $N$ noninteracting fermions trapped in multilevel infinite potential square-well. Fermions play role as working substance of the engine with each particle nested at different level of energy. We optimized this quantum heat engine model by analysing the physical parameter and deriving the optimum properties of the engine model. The model we investigated consists of one high-energy heat bath and one low-energy sink bath. Heat leakage occurs between these two bathes as expected will degenerate the effic…
We model a microscopic heat engine as a particle hopping on a one-dimensional lattice in a periodic sawtooth potential, with or without load, assisted by the thermal kicks it gets from alternately placed hot and cold thermal baths. We find analytic expressions for current and rate of heat flow when the engine operates at steady state. Three regions are identified where the model acts either as a heat engine or as a refrigerator or as neither of the two. At quasistatic limit both efficiency of the engine and coefficient of performance of the refrigerator go to that for Carnot engine and Carnot …
A Brownian particle moving in the vicinity of a generic potential minimum under the influence of dissipation and thermal noise from two different heat baths is shown to act as a minimal heat engine, generating a systematic torque onto the physical object at the origin of the potential and an opposite torque onto the medium generating the dissipation.
A specific class of stochastic heat engines driven cyclically by time-dependent potential, which is defined in the half-line ($0<x<+\infty$), is analysed. For such engines, most of their physical quantities can be obtained explicitly, including the entropy and internal energy of the heat engine, as well as output work (power) and heat exchange with the environment during a finite time interval. The optimisation method based on the external potential to reduce {\it irreversible} work and increase energy efficiency is presented. With this optimised potential, efficiency $η^*$ and its particular …
We perform an extensive analysis of passive as well as active micro-heat engines with different single-particle stochastic models. Using stochastic thermodynamics we calculate thermodynamic work, heat, entropy production and efficiency of passive and active Brownian heat engines analytically as well as numerically and compare them. We run the heat engines with a protocol for which the average thermodynamic quantities are calculated exactly for an arbitrary cycle time. We also discuss about the group of protocols for which exact non-quasistatic calculations can be done, completely in the passiv…
We present a unified perspective on nonequilibrium heat engines by generalizing nonlinear irreversible thermodynamics. For tight-coupling heat engines, a generic constitutive relation of nonlinear response accurate up to the quadratic order is derived from the symmetry argument and the stall condition. By applying this generic nonlinear constitutive relation to finite-time thermodynamics, we obtain the necessary and sufficient condition for the universality of efficiency at maximum power, which states that a tight-coupling heat engine takes the universal efficiency at maximum power up to the q…
The efficiency at maximum power (EMP) of irreversible Carnot-like heat engines is investigated based on the weak endoreversible assumption and the phenomenologically irreversible thermodynamics. It is found that the weak endoreversible assumption can reduce to the conventional one for the heat engines working at maximum power. Carnot-like heat engines are classified into three types (linear, superlinear, and sublinear) according to different characteristics of constitutive relations between the heat transfer rate and the thermodynamic force. The EMPs of Carnot-like heat engines are proved to b…
Considering ideal paramagnetic medium, in this paper we deduced an expression for the thermal efficiency of Carnot heat engine with a paramagnetic gas as working substance. We found that the efficiency depends on the limits of maximum and minimal temperature imposed on the Carnot cycle, as in the ideal gas, photon gas and variable Chaplygin gas.
We study a class of cyclic Brownian heat engines in the framework of finite-time thermodynamics. For infinitely long cycle times, the engine works at the Carnot efficiency limit producing, however, zero power. For the efficiency at maximum power, we find a universal expression, different from the endoreversible Curzon-Ahlborn efficiency. Our results are illustrated with a simple one-dimensional engine working in and with a time-dependent harmonic potential.
Thermodynamics places a limit on the efficiency of heat engines, but not on their output power or on how the power and efficiency change with the engine's cycle time. In this manuscript, we develop a geometrical description of the power and efficiency as a function of the cycle time, applicable to an important class of heat engine models. This geometrical description is used to design engine protocols that attain both the maximal power and maximal efficiency at the fast driving limit. Furthermore, using this method we also prove that no protocol can exactly attain the Carnot efficiency at non-…
In existing linear response theories for adiabatically driven cyclic heat engines, Onsager symmetry is identified only phenomenologically, and a relation between global and local Onsager coefficients, defined over one cycle and at any instant of a cycle, respectively, is not derived. To address this limitation, we develop a linear response theory for the speed of adiabatically changing parameters and temperature differences in generic Gaussian heat engines obeying Fokker--Planck dynamics. We establish a hierarchical relationship between the global linear response relations, defined over one cy…
We study the efficiency at maximum power of non-adiabatic dissipative (internally dissipative friction in finite time adiabatic processes) Carnot-like heat engines operate in finite time under the power law dissipation regime. We find that the non-adiabatic dissipation does not influence the universal minimum and maximum bounds on the efficiency at maximum power obtained in the generalized dissipative Carnot-like heat engines which does not take in to account the non-adiabatic dissipation.
We discuss the efficiency of a heat engine operating in a nonequilibrium steady state maintained by two heat reservoirs. Within the general framework of linear irreversible thermodynamics we derive a universal upper bound on the efficiency of the engine operating at arbitrary fixed power. Furthermore, we show that a slight decrease of the power below its maximal value can lead to a significant gain in efficiency. The presented analysis yields the exact expression for this gain and the corresponding upper bound.
The second law of thermodynamics constrains that the efficiency of heat engines, classical or quantum, cannot be greater than the universal Carnot efficiency. We discover another bound for the efficiency of a quantum Otto heat engine consisting of a harmonic oscillator. Dynamics of the engine is governed by the Lindblad equation for the density matrix, which is mapped to the Fokker-Planck equation for the quasi-probability distribution. Applying stochastic thermodynamics to the Fokker-Planck equation system, we obtain the $\hbar$-dependent quantum mechanical bound for the efficiency. It turns …
We consider a simple model of a stochastic heat engine, which consists of a single Brownian particle moving in a one-dimensional periodically breathing harmonic potential. Overdamped limit is assumed. Expressions of second moments (variances and covariances ) of heat and work are obtained in the form of integrals, whose integrands contain functions satisfying certain differential equations. The results in the quasi-static limit are simple functions of temperatures of hot and cold thermal baths. The coefficient of variation of the work is suggested to give an approximate probability for the wor…
At the dawn of thermodynamics, Carnot's constraint on efficiency of heat engines stimulated the formulation of one of the most universal physical principles, the second law of thermodynamics. In recent years, the field of heat engines acquired a new twist due to enormous efforts to develop and describe microscopic machines based on systems as small as single atoms. At microscales, fluctuations are an inherent part of dynamics and thermodynamic variables such as work and heat fluctuate. Novel probabilistic formulations of the second law imply general symmetries and limitations for the fluctuati…
Low-dissipation model and the endoreversible model of heat engines are two of the most commonly studied models of machines in finite-time thermodynamics. In this paper, we compare the performance characteristics of these two models under optimal power output. We point out a basic equivalence between them, in the linear response regime.
We study the minimally nonlinear irreversible heat engines in which the time-reversal symmetry for the systems may b e broken. The expressions for the power and the efficiency are derived, in which the effects of the nonlinear terms due to dissipations are included. We show that, as within the linear responses, the minimally nonlinear irreversible heat engines enable attainment of Carnot efficiency at positive power. We also find that the Curzon-Ahlborn limit imposed on the efficiency at maximum power can be overcomed if the time-reversal symmetry is broken.
We derive the general relations between the maximum power, maximum efficiency and minimum dissipation for the irreversible heat engine in nonlinear response regime. In this context, we use the minimally nonlinear irreversible model and obtain the lower and upper bounds of the above relations for the asymmetric dissipation limits. These relations can be simplified further when the system possesses the time-reversal symmetry or anti-symmetry. We find that our results are the generalization of various such relations obtained earlier for different heat engines.
A unified $χ$-criterion for heat devices (including heat engines and refrigerators) which is defined as the product of the energy conversion efficiency and the heat absorbed per unit time by the working substance [de Tomás \emph{et al} 2012 \textit{Phys. Rev. E} \textbf{85} 010104(R)] is optimized for tight-coupling heat engines and refrigerators operating between two heat baths at temperatures $T_c$ and $T_h(>T_c)$. By taking a new convention on the thermodynamic flux related to the heat transfer between two baths, we find that for a refrigerator tightly and symmetrically coupled with two hea…
A microscopic heat engine is modeled as a Brownian particle in a sawtooh potential (with load) moving through a highly viscous medium driven by the thermal kick it gets from alternately placed hot and cold heat reservoirs. We found closed form expression for the current as a function of the parameters characterizing the model. Depending on the values these model parameters take, the engine is also found to function as a refrigerator. Expressions for the efficiency as well as for the refrigerator performance are also reported. Study of how these quantities depend on the model parameters enabled…
We propose the minimally nonlinear irreversible heat engine as a new general theoretical model to study the efficiency at the maximum power $η^*$ of heat engines operating between the hot heat reservoir at the temperature $T_h$ and the cold one at $T_c$ ($T_c \le T_h $). Our model is based on the extended Onsager relations with a new nonlinear term meaning the power dissipation. In this model, we show that $η^*$ is bounded from the upper side by a function of the Carnot efficiency $η_C\equiv 1-T_c/T_h$ as $η^*\le η_C/(2-η_C)$. We demonstrate the validity of our theory by showing that the low-d…
We model a tiny heat engine as a Brownian particle that moves in a viscous medium in a sawtooth potential (with or without load) assisted by $\it {alternately}$ placed hot and cold heat baths along its path. We find closed form expression for the steady state current as a function of the model parameters. This enables us to deal with the energetics of the model and evaluate either its efficiency or its coefficient of performance depending upon whether the model functions either as a heat engine or as a refrigerator, respectively. We also study the way current changes with changes in parameters…
The Carnot-like heat engines are classified into three types (normal-, sub- and super-dissipative) according to relations between the minimum irreversible entropy production in the "isothermal" processes and the time for completing those processes. The efficiencies at maximum power of normal-, sub- and super-dissipative Carnot-like heat engines are proved to be bounded between $η_C/2$ and $η_C/(2-η_C)$, $η_C /2$ and $η_C$, 0 and $η_C/(2-η_C)$, respectively. These bounds are also shared by linear, sub- and super-linear irreversible Carnot-like engines [Tu and Wang, Europhys. Lett. 98, 40001 (20…
Heat engines should ideally have large power output, operate close to Carnot efficiency and show constancy, i.e., exhibit only small fluctuations in this output. For steady-state heat engines, driven by a constant temperature difference between the two heat baths, we prove that out of these three requirements only two are compatible. Constancy enters quantitatively the conventional trade-off between power and efficiency. Thus, we rationalize and unify recent suggestions for overcoming this simple trade-off. Our universal bound is illustrated for a paradigmatic model of a quantum dot solar cell…
Based on the notion of quantum trajectory, we present a stochastic theoretical framework for Floquet quantum heat engines. As an application, the large deviation functions of two types of stochastic efficiencies for a two-level Floquet quantum heat engine are investigated. We find that the statistics of one efficiency agree well with the predictions of the universal theory of efficiency fluctuations developed by Verley et al. [Phys. Rev. E {\bf 90}, 052145 (2014)], whereas the statistics of the other efficiency do not. The reason for this discrepancy is attributed to the lack of fluctuation th…
We study the ratio between the variances of work output and heat input, $η^{(2)}$, for a class of four-stroke heat engines which covers various typical cycles. Recent studies on the upper and lower bounds of $η^{(2)}$ are based on the quasistatic limit and the linear response regime, respectively. We extend these relations to the finite-time regime within the endoreversible approximation. We consider the ratio $η_{\text{MP}}^{(2)}$ at maximum power and find that the square of the Curzon-Ahlborn efficiency, $η_{\text{CA}}^2$, gives a good estimate of $η_{\text{MP}}^{(2)}$ for the class of heat …
The energetics of the stochastic process has shown the balance of energy on the mesoscopic level. The heat and the energy defined there are, however, generally different from their macroscopic counterpart. We show that this discrepancy can be removed by adding to these quantities the reversible heat associated with the mesoscopic free energy.
In this paper, we consider a model of two-level quantum heat engine to investigate the explicit analytic expression for the thermodynamics quantities in different condition under the finite-time operation. In this engine, the working substance is composed of a spin-half particles immersed in a magnetic field. The finite-time thermodynamic processes consisting of two quantum adiabatic and two quantum isothermal processes. This processes working between two heat reservoirs with an inverse temperatures $β_{1}$ and $β_{2}$ ($<β_{1}$). In this processes, we obtain the work, heat, power and efficien…
Low-temperature-differential (LTD) Stirling heat engines are able to operate with a small temperature difference between low-temperature heat reservoirs that exist in our daily lives, and thus they are considered to be an important sustainable energy technology. The author recently proposed a nonlinear dynamics model of an LTD kinematic Stirling heat engine to study the rotational mechanism of the engine [Y. Izumida, EPL \textbf{121}, 50004 (2018)]. This paper presents our study of the nonequilibrium thermodynamics analysis of this engine model, where a load torque against which the engine doe…
Differences between the thermodynamic behavior of the three-level amplifier (a quantum heat engine based on a thermally pumped laser) and the classical Carnot cycle are usually attributed to the essentially quantum or discrete nature of the former. Here we provide examples of a number of classical and semiclassical heat engines, such as thermionic, thermoelectric and photovoltaic devices, which all utilize the same thermodynamic mechanism for achieving reversibility as the three-level amplifier, namely isentropic (but non-isothermal) particle transfer between hot and cold reservoirs. This mech…
We derive the exact equality, referred to as the fluctuation relation for heat engines (FRHE), that relates statistics of heat extracted from one of the two heat baths and the work per one cycle of a heat engine operation. Carnot's inequality of classical thermodynamics follows as a direct consequence of the FRHE.
Heat engines are fundamental physical objects to develop nonequilibrium thermodynamics. The thermodynamic performance of the heat engine is determined by the choice of cycle and time-dependence of parameters. Here, we propose a systematic numerical method to find a heat engine cycle to optimize some target functions. We apply the method to heat engines with slowly varying parameters and show that the method works well. Our numerical method is based on the genetic algorithm which is widely applied to various optimization problems.
The aim of this paper is to determine lost works in a molecular engine and compare results with macro (classical) heat engines. Firstly, irreversible thermodynamics are reviewed for macro and molecular cycles. Secondly, irreversible thermodynamics approaches are applied for a quantum heat engine with -1/2 spin system. Finally, lost works are determined for considered system and results show that macro and molecular heat engines obey same limitations. Moreover, a quantum thermodynamic approach is suggested in order to explain the results previously obtained from an atomic viewpoint.
We discuss the reversibility of Brownian heat engine. We perform asymptotic analysis of Kramers equation on Büttiker-Landauer system and show quantitatively that Carnot efficiency is inattainable even in a fully overdamping limit. The inattainability is attributed to the inevitable irreversible heat flow over the temperature boundary.
The efficiency of macroscopic heat engines is restricted by the second law of thermodynamics. They can reach at most the efficiency of a Carnot engine. In contrast, heat currents in mesoscopic heat engines show fluctuations. Thus, there is a small probability that a mesoscopic heat engine exceeds Carnot's maximum value during a short measurement time. We illustrate this effect using a quantum point contact as a heat engine. When a temperature difference is applied to a quantum point contact, the system may be utilized as a source of electrical power under steady state conditions. We first disc…
We propose a quantum-enhanced heat engine with entanglement. The key feature of our scheme is superabsorption, which facilitates enhanced energy absorption by entangled qubits. Whereas a conventional engine with $N$ separable qubits provides power with a scaling of $P = Θ(N)$, our engine uses superabsorption to provide power with a quantum scaling of $P = Θ(N^2)$. This quantum heat engine also exhibits a scaling advantage over classical ones composed of $N$-particle Langevin systems. Our work elucidates the quantum properties allowing for the enhancement of performance.
In this paper, we study the role and relevance of the cost for an invariant-based shortcut to adiabaticity enabled qubit heat engine operates in a quantum Otto cycle. We consider a qubit heat engine with Landau-Zener Hamiltonian and improve its performance using the Lewis-Riesenfeld invariant-based shortcut to adiabaticity method. Addressing the importance of cost for better performance, the paper explores its relationship with the work and efficiency of the heat engine. We analyze the cost variation with the time duration of non-adiabatic unitary processes involved in the heat engine cycle. T…
An analysis of efficiency and its bounds at maximum work output for Carnot-like heat engines is conducted. The heat transfer processes are described by the linear law with time-dependent heat conductance. The upper bound of efficiency is found to be the CA efficiency,and is independent of the time duration completing each process and the time-dependent conductance. We prove that even the working medium exchanges heat sufficiently with the heat reservoirs, the work which could be extracted is finite and limited. The optimal temperature profiles in the heat exchanging processes are also analyzed…
We propose a generalized model of a heat engine and calculate the minimum and maximum bounds on the efficiency at maximum power. We obtain a universal form of generalized extreme bounds on the efficiency at maximum power. Our model unifies the bounds on the efficiency and the universality features are observed for various heat engine models. Even though our model is a direct generalization of low-dissipation heat engines, the bounds on the efficiency obtained at a single target function capture those observed in the actual power plants working at different dissipation levels.
Brownian heat engines use local temperature gradients in asymmetric potentials to move particles against an external force. The energy efficiency of such machines is generally limited by irreversible heat flow carried by particles that make contact with different heat baths. Here we show that, by using a suitably chosen energy filter, electrons can be transferred reversibly between reservoirs that have different temperatures and electrochemical potentials. We apply this result to propose heat engines based on mesoscopic semiconductor ratchets, which can quasistatically operate arbitrarily clos…
Macroscopic cyclic heat engines have been a major motivation for the emergence of thermodynamics. In the last decade, cyclic heat engines that have large fluctuations and operate at finite time were studied within the more modern framework of stochastic thermodynamics. The second law for such heat engines states that the efficiency cannot be larger than the Carnot efficiency. The concept of cyclic active heat engines for a system in the presence of hidden dissipative degrees of freedom, also known as a nonequilibrium or active reservoir, has also been studied in theory and experiment. Such act…
We propose and analyze the theoretical model for a two-stroke quantum heat engine with one of the heat baths replaced by a non-selective quantum measurement. We show that the engine's invariant reference state depends on whether the cycle is monitored or unmonitored via diagnostic measurements to determine the engine's work output. We explore in detail the average work output and fluctuations of the proposed heat engine for the monitored and unmonitored cases. We also identify unitary work strokes for which the invariant states can support coherences in the energy basis leading to differing pr…
A heat engine operating on the basis of the Carnot cycle is considered, where the mechanical work performed is dissipated within the engine at the temperature of the warmer isotherm and the resulting heat is added to the engine together with an external heat input. The resulting work performed by the engine per cycle is increased at the expense of dissipated work produced in the previous cycle. It is shown that such a dissipative heat engine is thermodynamically inconsistent violating the first and second laws of thermodynamics. The existing physical models employing the dissipative heat engin…
The impacts of quantum coherence on nonequilibrium thermodynamics become observable by dividing the heat and work into the conventional diagonal part and the other part relaying on the superpositions and the time derivative of Hamiltonian. Specializing to exactly-solvable dynamics of Larmor precession, we build a quantum Otto heat engine employing magnetic-driven atomic rotations. The coherence induced by the population transition guarantees the positive work output when the control protocol is time dependent. The time-dependent control of a quantum heat engine implements the correspondence be…
Stochastic heat engines are devices that generate work from random thermal motion using a small number of highly fluctuating degrees of freedom. Proposals for such devices have existed for more than a century and include the Maxwell demon and the Feynman ratchet. Only recently have they been demonstrated experimentally, using e.g., thermal cycles implemented in optical traps. However, the recent demonstrations of stochastic heat engines are nonautonomous, since they require an external control system that prescribes a heating and cooling cycle, and consume more energy than they produce. This R…
