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arXiv 1311.1306cond-mat.stat-mech
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磁场中Curie-Weiss各向异性量子海森堡模型的微正则分析

Microcanonical analysis of the Curie-Weiss anisotropic quantum Heisenberg model in a magnetic field

Gerrit Olivier, Michael Kastner

摘要:

在微正则系综的几种变体中,解析地研究了具有Curie-Weiss型相互作用的各向异性量子海森堡模型。通过研究熵的性质,研究了微正则系综与正则系综的(非)等价性。在热力学极限下,微正则熵s(e,m)是能量e和磁化强度矢量m的函数。因为对于这个模型,e是由m唯一确定的,所以相同的信息可以编码为s(m)或s(e,m1,m2)。虽然这两个熵对应于相同的固定e和m的物理设置,但它们的熵性质不同。熵s_h(u)是由非凹熵s(e,m1,m2)约化得到的,它描述了在固定总能量u和任意方向的均匀外磁场h中的模型.这样做的话,就恢复了集合的等价性,从而恢复了集合的等价性。s_h(u)在(u,h)-空间中余维为1的曲面上具有非解析性.将这些表面投影到低维相图中,我们观察到所得到的相变线对于某些参数值位于正温度区域,而对于其他参数值则位于负温度区域。在正则设置的系统耦合到一个热浴的正温度,nonanalyticities在微正则负温度区不能观察到,这导致了一种情况下的有效不等价,即使当形式等价持有。

英文摘要:

The anisotropic quantum Heisenberg model with Curie-Weiss-type interactions is studied analytically in several variants of the microcanonical ensemble. (Non)equivalence of microcanonical and canonical ensembles is investigated by studying the concavity properties of entropies. The microcanonical entropy s(e,m) is obtained as a function of the energy e and the magnetization vector m in the thermodynamic limit. Since, for this model, e is uniquely determined by m, the same information can be encoded either in s(m) or s(e,m1,m2). Although these two entropies correspond to the same physical setting of fixed e and m, their concavity properties differ. The entropy s_h(u), describing the model at fixed total energy u and in a homogeneous external magnetic field h of arbitrary direction, is obtained by reduction from the nonconcave entropy s(e,m1,m2). In doing so, concavity, and therefore equivalence of ensembles, is restored. s_h(u) has nonanalyticities on surfaces of co-dimension 1 in the (u,h)-space. Projecting these surfaces into lower-dimensional phase diagrams, we observe that the resulting phase transition lines are situated in the positive-temperature region for some parameter values, and in the negative-temperature region for others. In the canonical setting of a system coupled to a heat bath of positive temperatures, the nonanalyticities in the microcanonical negative-temperature region cannot be observed, and this leads to a situation of effective nonequivalence even when formal equivalence holds.

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