Compositional diversity in the atmospheres of hot Neptunes, with application to GJ 436b
Julianne I. Moses, Michael R. Line, Channon Visscher, Molly R. Richardson, Nadine Nettelmann, Jonathan J. Fortney, Kevin B. Stevenson, Nikku Madhusudhan
Neptune-sized extrasolar planets that orbit relatively close to their host stars -- often called "hot Neptunes" -- are common within the known population of exoplanets and planetary candidates. Similar to our own Uranus and Neptune, inefficient accretion of nebular gas is expected produce hot Neptunes whose masses are dominated by elements heavier than hydrogen and helium. At high atmospheric metallicities of 10-10,000x solar, hot Neptunes will exhibit an interesting continuum of atmospheric compositions, ranging from more Neptune-like, H2-dominated atmospheres to more Venus-like, CO2-dominated atmospheres. We explore the predicted equilibrium and disequilibrium chemistry of generic hot Neptunes and find that the atmospheric composition varies strongly as a function of temperature and bulk atmospheric properties such as metallicity and the C/O ratio. Relatively exotic H2O, CO, CO2, and even O2-dominated atmospheres are possible for hot Neptunes. We apply our models to the case of GJ 436b, where we find that a CO-rich, CH4-poor atmosphere can be a natural consequence of a very high atmospheric metallicity. From comparisons of our results with Spitzer eclipse data for GJ 436b, we conclude that although the spectral fit from the high-metallicity forward models is not quite as good as the fit obtained from pure retrieval methods, the atmospheric composition predicted by these forward models is more physically and chemically plausible. High-metallicity atmospheres (orders of magnitude in excess of solar) should therefore be considered as a possibility for GJ 436b and other hot Neptunes.
Warm Neptune- and sub-Neptune-sized exoplanets in orbits smaller than Mercury's are thought to have experienced extensive atmospheric evolution. Here we propose that a potential outcome of this atmospheric evolution is the formation of helium-dominated atmospheres. The hydrodynamic escape rates of Neptune- and sub-Neptune-sized exoplanets are comparable to the diffusion-limited escape rate of hydrogen, and therefore the escape is heavily affected by diffusive separation between hydrogen and helium. A helium atmosphere can thus be formed -- from a primordial hydrogen-helium atmosphere -- via at…
Some super Earths and mini Neptunes will likely have thick atmospheres that are not H2-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths and mini Neptunes, applicable for both H2-dominated atmospheres and non-H2-dominated atmospheres. Using this model to study thick atmospheres for wide ranges of temperatures and elemental abundances, we classify them into hydrogen-rich atmospheres, water-rich atmospheres, oxygen-rich atmospheres, and hydrocarbon-rich atmospheres. We find that carbon has to …
Atmospheric observations of mini-Neptunes orbiting M-dwarfs are beginning to provide constraints on their chemical and thermal properties, while also providing clues about their interiors and potential surfaces. With their relatively large scale heights and large planet-star contrasts, mini-Neptunes are currently ideal targets towards the goal of characterising temperate low-mass exoplanets. Understanding the thermal structures and spectral appearances of mini-Neptunes is important to understand various aspects of their atmospheres, including radiative/convective energy transport, boundary con…
Planets with 2 $R_{\oplus}$ < $R$ < 3 $R_{\oplus}$ and orbital period $<$100 d are abundant; these sub-Neptune exoplanets are not well understood. For example, $Kepler$ sub-Neptunes are likely to have deep magma oceans in contact with their atmospheres, but little is known about the effect of the magma on the atmosphere. Here we study this effect using a basic model, assuming that volatiles equilibrate with magma at $T$ $\sim$ 3000 K. For our Fe-Mg-Si-O-H model system, we find that chemical reactions between the magma and the atmosphere and dissolution of volatiles into the magma are both impo…
We investigate the potential for the James Webb Space Telescope (JWST) to detect and characterize the atmospheres of the sub-Neptunian exoplanets in the TOI-270 system. Sub-Neptunes are considered more likely to be water worlds than gas dwarfs. We model their atmospheres using three atmospheric compositions - two examples of hydrogen-dominated atmospheres and a water-dominated atmosphere. We then simulate the infrared transmission spectra of these atmospheres for JWST instrument modes optimized for transit observation of exoplanet atmospheres : NIRISS, NIRSpec and MIRI. We then predict the obs…
The space and ground-based observations have shown a lot of activities and instabilities in the atmosphere of the giant ice planet Neptune. Using the archival data of high resolution Atacama Large Millimeter/Submillimeter Array (ALMA) with band 7 observation, we present the spectroscopic detection of the rotational emission line of sulfur dioxide (SO$_{2}$) at frequency $ν$ = 343.476 GHz with transition J=57$_{15,43}$$-$58$_{14,44}$. We also re-detect the emission line of carbon monoxide (CO) at frequency $ν$ = 345.795 GHz with transition J=3$-$2. The molecular lines of SO$_{2}$ and CO in the …
The search for signs of life through the detection of exoplanet atmosphere biosignature gases is gaining momentum. Yet, only a handful of rocky exoplanet atmospheres are suitable for observation with planned next-generation telescopes. To broaden prospects, we describe the possibilities for an aerial, liquid water cloud-based biosphere in the atmospheres of sub Neptune-sized temperate exoplanets, those receiving Earth-like irradiation from their host stars. One such planet is known (K2-18b) and other candidates are being followed up. Sub Neptunes are common and easier to study observationally …
The atmospheres of sub-Neptunes are expected to exhibit considerable chemical diversity, beyond what is anticipated for gas-giant exoplanets. In the current study, we construct self-consistent radiative transfer and equilibrium chemistry models to explore this chemical diversity. We use GJ 436 b as a case study to further study joint atmosphere-interior models. In particular, we constrain the properties of the interior and atmosphere of the planet based on the available Spitzer measurements. While it is possible to fit the emission spectrum of GJ 436 b using a high-metallicity model, we demons…
Neptune remains a mysterious world that deserves further exploration and is a high-priority objective for a future planetary mission in order to better understand the formation and evolution of ice giant planets. We have developed a coupled ion-neutral 1D photochemical model of Neptune's atmosphere to study the origin and evolution of the hydrocarbons and the oxygen species. The up-to-date chemical scheme is derived from one used for Titan's atmosphere, which led to good agreements with the Cassini-CIRS observations for oxygen species and the main hydrocarbons. The main results we obtain are t…
Super-Earths and mini-Neptunes are the most abundant types of planets among the ~3500 confirmed exoplanets, and are expected to exhibit a wide variety of atmospheric compositions. Recent transmission spectra of super-Earths and mini-Neptunes have demonstrated the possibility that exoplanets have haze/cloud layers at high altitudes in their atmospheres. However, the compositions, size distributions, and optical properties of these particles in exoplanet atmospheres are poorly understood. Here, we present the results of experimental laboratory investigations of photochemical haze formation withi…
We review the current understanding of the upper atmospheres of Uranus and Neptune, and explore the upcoming opportunities available to study these exciting planets. The ice giants are the least understood planets in the solar system, having been only visited by a single spacecraft, in 1986 and 1989, respectively. The upper atmosphere plays a critical role in connecting the atmosphere to the forces and processes contained within the magnetic field. For example, auroral current systems can drive charged particles into the atmosphere, heating it by way of Joule heating. Ground-based observations…
Mini-Neptunes orbiting M stars are a growing population of known exoplanets. Some of them are located very close to their host star, receiving large amounts of UV radiation. Many M stars emit strong chromospheric emission in the H I Lyman $α$ line (Ly$α$) at 1215.67 Å, the brightest far-UV emission line. We show that the effect of incoming Ly$α$ flux can significantly change the photochemistry of mini-Neptunes' atmospheres. We use GJ 436b as an example, considering different metallicities for its atmospheric composition. For solar composition, H$_2$O-mixing ratios show the largest change becau…
Numerous solar system atmospheres possess aerosols including the characteristic organic hazes of Titan and Pluto. Haze particles substantially impact atmospheric temperatures structures and may provide organic material to the surface of a world, thereby affecting its habitability. Observations of exoplanet atmospheres suggest the presence of aerosols, especially in cooler (<800 K), smaller (<0.3 times Jupiter's mass) exoplanets. It remains unclear if the aerosols muting the spectroscopic features of exoplanet atmospheres are condensate clouds or photochemical hazes, which is difficult to predi…
Transmission spectroscopy to date has detected atomic and molecular absorption in Jupiter-sized exoplanets, but intense efforts to measure molecular absorption in the atmospheres of smaller (Neptune-sized) planets during transits have revealed only featureless spectra. From this it was concluded that the majority of small, warm planets evolve to sustain high mean molecular weights, opaque clouds, or scattering hazes in their atmospheres, obscuring our ability to observe the composition of these atmospheres. Here we report observations of the transmission spectrum of HAT-P-11b (~4 Earth radii) …
Uranus and Neptune share properties that are distinct from the other giant planets in the solar system, but they are also distinct from one another, particularly in their relative internal heat flux. Not only does Neptune emit about ten times the amount of heat that emitted by Uranus, the relative amount of emitted heat to the energy they absorb from the sun also differs greatly, being comparable at Uranus and the largest of all giant planets at Neptune. As a result, it is questionable whether thermal convection occurs within the interior of Uranus. However, the presence of an intrinsic magnet…
The search for signs of life on other worlds has largely focused on terrestrial planets. Recent work, however, argues that life could exist in the atmospheres of temperate sub-Neptunes. Here, we evaluate the usefulness of carbon dioxide isotopologues as evidence of aerial life. Carbon isotopes are of particular interest as metabolic processes preferentially use the lighter $^{12}$C over $^{13}$C. In principle, the upcoming James Webb Space Telescope (JWST) will be able to spectrally resolve the $^{12}$C and $^{13}$C isotopologues of CO$_{2}$, but not CO and CH$_{4}$. We simulated observations …
The upcoming James Webb Space Telescope (JWST) promises a generational shift in the study of temperate mini-Neptune atmospheres using transit spectroscopy. High-altitude clouds however threaten to impede their atmospheric characterisation by muting spectral features. In this study, we systematically investigate JWST instrument configurations for characterising cloudy mini-Neptune atmospheres, assessing the importance of instrument choice and wavelength coverage, focusing on NIRISS and NIRSpec. We consider two temperate mini-Neptunes orbiting nearby M dwarfs, K2-18 b and TOI-732 c, with equilib…
Impact of Clouds on the Atmosphere-Mantle Interface of Sub-Neptunes
School of Earth and Space Exploration, Arizona State University（亚利桑那州立大学地球与空间探索学院）；Department of Astronomy, University of Texas at Austin（德克萨斯大学奥斯汀分校天文学系）；NASA Ames Research Center（NASA艾姆斯研究中心）；SETI Institute（SETI研究所）
We present a search for helium in the upper atmospheres of three sub-Neptune size planets to investigate the origins of these ubiquitous objects. The detection of helium for a low density planet would be strong evidence for the presence of a primary atmosphere accreted from the protoplanetary nebula because large amounts of helium are not expected in the secondary atmospheres of rocky planets. We used Keck+NIRSPEC to obtain high-resolution transit spectroscopy of the planets GJ1214b, GJ9827d, and HD97658b around the 10,833 Ang He triplet feature. We did not detect helium absorption for any of …
Herschel-PACS measurements of the rotational R(0) and R(1) HD lines in the atmospheres of Uranus and Neptune are analyzed in order to derive a D/H ratio with improved precision for both planets. The derivation of the D/H ratio includes also previous measurements of the R(2) line by the Short Wavelength Spectrometer on board the Infrared Space Observatory (ISO). The available spectroscopic line information of the three rotational transitions is discussed and applied in the radiative transfer calculations. The best simultaneous fit of all three lines requires only a minor departure from the Spit…
Sub-Neptunes (planets with radii between 2 and 4 R$_{\oplus}$) are abundant around M-dwarf stars, yet the atmospheric dynamics of these planets is relatively unexplored. In this paper, we aim to provide a basic underpinning of the dry dynamics of general low mean molecular weight, temperate sub-Neptune atmospheres. We use the ExoFMS GCM with an idealised grey gas radiation scheme to simulate planetary atmospheres with different levels of instellation and rotation rates, using the atmosphere of K2-18b as our control. We find that the atmospheres of tidally-locked, temperate sub-Neptunes have we…
Transmission spectroscopy is enabling precise measurements of atmospheric H2O abundances for numerous giant exoplanets. For hot Jupiters, relating H2O abundances to metallicities provides a powerful probe of their formation conditions. However, metallicity measurements for Neptune-mass exoplanets are only now becoming viable. Exo-Neptunes are expected to possess super-solar metallicities from accretion of H2O-rich and solid-rich planetesimals. However, initial investigations into the exo-Neptune HAT-P-26b suggested a significantly lower metallicity than predicted by the core-accretion theory o…
GJ 3470b is a warm Neptune-size planet transiting a M dwarf star. Like the handful of other small exoplanets for which transmission spectroscopy has been obtained, GJ 3470b exhibits a flat spectrum in the near- and mid-infrared. Recently, a tentative detection of Rayleigh scattering in its atmosphere has been reported. This signal manifests itself as an observed increase of the planetary radius as a function of decreasing wavelength in the visible. We set out to verify this detection and observed several transits of this planet with the LCOGT network and the Kuiper telescope in four different …
Escape of Water- and Metal-enriched Atmospheres from compact Hot mini-Neptunes with CHAIN
University of Bern（伯尔尼大学）；Space Research Institute, Austrian Academy of Sciences（奥地利科学院空间研究所）；European Space Agency (ESA), European Space Research and Technology Centre (ESTEC)（欧洲空间局（ESA）欧洲空间研究与技术中心（ESTEC））；Department of Astronomy & Astrophysics, University of Chicago（芝加哥大学天文与天体物理系）
GJ 436b is a warm-- approximately 800 K--extrasolar planet that periodically eclipses its low-mass (half the mass of the Sun) host star, and is one of the few Neptune-mass planets that is amenable to detailed characterization. Previous observations have indicated that its atmosphere has a methane-to-CO ratio that is 100,000 times smaller than predicted by models for hydrogen-dominated atmospheres at these temperatures. A recent study proposed that this unusual chemistry could be explained if the planet's atmosphere is significantly enhanced in elements heavier than H and He. In this study we p…
Raman scattering by H$_2$ in Neptune's atmosphere has significant effects on its reflectivity for $λ<$ 0.5 $μ$m, producing baseline decreases of $\sim$ 20% in a clear atmosphere and $\sim$ 10% in a hazy atmosphere. Here we present the first radiation transfer algorithm that includes both polarization and Raman scattering and facilitates computation of spatially resolved spectra. New calculations show that Cochran and Trafton's (1978, Astrophys. J. 219, 756-762) suggestion that light reflected in the deep CH$_4$ bands is mainly Raman scattered is not valid for current estimates of the CH$_4$ver…
Diversity of low-mass planet atmospheres in the C-H-O-N-S-Cl system with interior dissolution, nonideality, and condensation: Application to TRAPPIST-1e and sub-Neptunes
We report observations of the recently discovered warm Neptune TOI-674 b (5.25 \rearth{}, 23.6 \mearth{}) with the Hubble Space Telescope's Wide Field Camera 3 instrument. TOI-674 b is in the Neptune desert, an observed paucity of Neptune-size exoplanets at short orbital periods. Planets in the desert are thought to have complex evolutionary histories due to photoevaporative mass loss or orbital migration, making identifying the constituents of their atmospheres critical to understanding their origins. We obtained near-infrared transmission spectroscopy of the planet's atmosphere with the G141…
Stellar heating causes atmospheres of close-in exoplanets to expand and escape. These extended atmospheres are difficult to observe because their main spectral signature - neutral hydrogen at ultraviolet wavelengths - is strongly absorbed by interstellar medium. We report the detection of the near-infrared triplet of neutral helium in the transiting warm Neptune-mass exoplanet HAT-P-11b using ground-based, high-resolution observations. The helium feature is repeatable over two independent transits, with an average absorption depth of 1.08+/-0.05%. Interpreting absorption spectra with 3D simula…
Substantial silicate vapor is expected to be in chemical equilibrium at temperature conditions typical of the silicate-atmosphere interface of sub-Neptune planets, which can exceed 5000 K. Previous models of the atmospheric structure and evolution of these exoplanets, which have been used to constrain their atmospheric mass fractions, have neglected this compositional coupling. In this work, we show that silicate vapor in a hydrogen-dominated atmosphere acts as a condensable species, decreasing in abundance with altitude. The resultant mean molecular weight gradient inhibits convection at temp…
Observations of Neptune, made in 2018 using the new Narrow Field Adaptive Optics mode of the Multi Unit Spectroscopic Explorer (MUSE) instrument at the Very Large Telescope (VLT) from 0.48 - 0.93 micron, are analysed here to determine the latitudinal and vertical distribution of cloud opacity and methane abundance in Neptune's observable troposphere (0.1 - ~3 bar). Previous observations at these wavelengths in 2003 by HST/STIS (Karkoschka and Tomasko 2011, Icarus 205, 674-694) found that the mole fraction of methane above the cloud tops (at ~2 bar) varied from ~4% at equatorial latitudes to ~2…
Transmission Spectrum of the Benchmark Temperate Exo-Neptune TOI-1231 b
School of Physics and Astronomy, Cardiff University（卡迪夫大学物理与天文学学院）；Institute of Astronomy, University of Cambridge（剑桥大学天文研究所）；Space Telescope Science Institute（太空望远镜科学研究所）；Space Science Institute（空间科学研究所）
Despite the identification of a great number of Jupiter-like and Earth-like planets at close-in orbits, the number of "hot Neptunes" - the planets with 0.6-18 times of Neptune mass and orbital periods less than 3 days - turned out to be very small. The corresponding region in the mass-period distribution was assigned as the "short-period Neptunian desert". The common explanation of this fact is that the gaseous planet with few Neptune masses would not survive in the vicinity of host star due to intensive atmosphere outflow induced by heating from stellar radiation. To check this hypothesis we …
Non-rocky sub-jovian exoplanets in high irradiation environments are rare. LTT 9979b, also known as TESS Object of Interest (TOI) 193.01, is one of the few such planets discovered to date, and the first example of an ultra-hot Neptune. The planet's bulk density indicates that it has a substantial atmosphere, so to investigate its atmospheric composition and shed further light on its origin, we obtained {\it Spitzer} IRAC secondary eclipse observations of LTT 9979b at 3.6 and 4.5 $μ$m. We combined the {\it Spitzer} observations with a measurement of the secondary eclipse in the {\it TESS} bandp…
We investigate equilibrium chemistry between molten metal and silicate, and a hydrogen-rich envelope using 18 independent reactions among 25 phase components for sub-Neptune-like exoplanets. Both reactive metal and unreactive metal sequestered in an isolated core are modeled. The overarching effects of equilibration are oxidation of the envelope and reduction of the mantle and core. Hydrogen and oxygen typically comprise significant fractions of metal cores at chemical equilibrium, leading to density deficits that offer a possible alternative explanation for the low densities of the Trappist-1…
UV radiation can induce photochemical processes in exoplanet atmospheres and produce haze particles. Recent observations suggest that haze and/or cloud layers could be present in the upper atmospheres of exoplanets. Haze particles play an important role in planetary atmospheres and may provide a source of organic material to the surface which may impact the origin or evolution of life. However, very little information is known about photochemical processes in cool, high-metallicity exoplanetary atmospheres. Previously, we investigated haze formation and particle size distribution in laboratory…
Uranus and Neptune are the last unexplored planets of the Solar System. I show that they hold crucial keys to understand the atmospheric dynamics and structure of planets with hydrogen atmospheres. Their atmospheres are active and storms are believed to be fueled by methane condensation which is both extremely abundant and occurs at low optical depth. This means that mapping temperature and methane abundance as a function of position and depth will inform us on how convection organizes in an atmosphere with no surface and condensates that are heavier than the surrounding air, a general feature…
Recent analysis of Gemini-North/NIFS H-band (1.45 - 1.8 $μ$m) observations of Uranus, recorded in 2010, with recently updated line data has revealed the spectral signature of hydrogen sulphide (H$_2$S) in Uranus's atmosphere (Irwin et al., 2018). Here, we extend this analysis to Gemini-North/NIFS observations of Neptune recorded in 2009 and find a similar detection of H$_2$S spectral absorption features in the 1.57 - 1.58 $μ$m range, albeit slightly less evident, and retrieve a mole fraction of $\sim1-3$ ppm at the cloud tops. We find a much clearer detection (and much higher retrieved column …
With no analogues in the Solar System, the discovery of thousands of exoplanets with masses and radii intermediate between Earth and Neptune was one of the big surprises of exoplanet science. These super-Earths and sub-Neptunes likely represent the most common outcome of planet formation. Mass and radius measurements indicate a diversity in bulk composition much wider than for gas giants; however, direct spectroscopic detections of molecular absorption and constraints on the gas mixing ratios have largely remained limited to planets more massive than Neptune. Here, we analyze a combined Hubble…
