A semiclassical approximation for the matrix elements of a quantum chaotic propagator in the scar function basis has been derived. The obtained expression is solely expressed in terms of canonical invariant objects. For our purpose, we have used, the recently developed, semiclassical matrix elements of the propagator in coherent states, together with the linearization of the flux in the neighborhood of a classically unstable periodic orbit of chaotic two dimensional systems. The expression here derived is successfully verified to be exact for a (linear) cat map, after the theory is adapted to a discrete phase space appropriate to a quantized torus.
The semiclassical formula for the quantum propagator in the coherent state representation $<\mathbf{z}'' | e^{-i\hat{H}T/\hbar} | \mathbf{z}'>$ is not free from the problem of caustics. These are singular points along the complex classical trajectories specified by $\mathbf{z}'$, $\mathbf{z}''$ and $T$ where the usual quadratic approximation fails, leading to divergences in the semiclassical formula. In this paper we derive third order approximations for this propagator that remain finite in the vicinity of caustics. We use Maslov's method and the dual representation proposed in Phys. Rev. Let…
The semiclassical approximation to the coherent state propagator requires complex classical trajectories in order to satisfy the associated boundary conditions, but finding these trajectories in practice is a difficult task that may compromise the applicability of the approximation. In this work several approximations to the coherent state propagator are derived that make use only of real trajectories, which are easier to handle and have a more direct physical interpretation. It is verified in a particular example that these real trajectories approximations may have excellent accuracy.
We construct semiclassical solutions of the symplectically covariant Schroedinger phase-space equation rigorously studied in a previous paper; we use for this purpose an adaptation of Littlejohn's nearby-orbit method. We take the opportunity to discuss in some detail the so fruitful notion of squeezed coherent state and the action of the metaplectic group on these states.
We discuss some basic tools for an analysis of one-dimensionalquantum systems defined on a cyclic coordinate space. The basic features of the generalized coherent states, the complexifier coherent states are reviewed. These states are then used to define the corresponding (quasi)densities in phase space. The properties of these generalized Husimi distributions are discussed, in particular their zeros.Furthermore, the use of the complexifier coherent states for a semiclassical analysis is demonstrated by deriving a semiclassical coherent state propagator in phase space.
Propagation of the Wigner function is studied on two levels of semiclassical propagation, one based on the van-Vleck propagator, the other on phase-space path integration. Leading quantum corrections to the classical Liouville propagator take the form of a time-dependent quantum spot. Its oscillatory structure depends on whether the underlying classical flow is elliptic or hyperbolic. It can be interpreted as the result of interference of a \emph{pair} of classical trajectories, indicating how quantum coherences are to be propagated semiclassically in phase space. The phase-space path-integral…
We derive the semiclassical limit of the coherent state propagator for systems with two degrees of freedom of which one degree of freedom is canonical and the other a spin. Systems in this category include those involving spin-orbit interactions and the Jaynes-Cummings model in which a single electromagnetic mode interacts with many independent two-level atoms. We construct a path integral representation for the propagator of such systems and derive its semiclassical limit. As special cases we consider separable systems, the limit of very large spins and the case of spin 1/2.
We use a continuous-time path integral to obtain the semiclassical propagator for minimal-spread spin coherent states. We pay particular attention to the ``extra phase'' discovered by Solari and Kochetov, and show that this correction is related to an anomaly in the fluctuation determinant. We show that, once this extra factor is included, the semiclassical propagator has the correct short time behaviour to $O(T^2)$, and demonstrate its consistency under dissection of the path
A semiclassical formula for the coherent-state propagator requires the determination of specific classical paths inhabiting a complex phase-space through a Hamiltonian flux. Such trajectories are constrained to special boundary conditions which render their determination difficult by common methods. In this paper we present a new method based on Runge-Kutta integrator for a quick, easy and accurate determination of these trajectories. Using nonlinear one dimensional systems we show that the semiclassical formula is highly accurate as compared to its exact counterpart . Further we clarify how t…
A uniform approximation for the coherent state propagator, valid in the vicinity of phase space caustics, was recently obtained using the Maslov method combined with a dual representation for coherent states. In this paper we review the derivation of this formula and apply it to two model systems: the one-dimensional quartic oscillator and a two-dimensional chaotic system.
In this work, we derived a semiclassical approximation for the matrix elements of a quantum propagator in coherent states (CS) basis that avoids complex trajectories, it only involves real ones. For that propose, we used the, symplectically invariant, semiclassical Weyl propagator obtained by performing a stationary phase approximation (SPA) for the path integral in the Weyl representation. After what, for the transformation to CS representation SPA is avoided, instead a quadratic expansion of the complex exponent is used. This procedure also allows to express the semiclassical CS propagator u…
The semiclassical propagator in the representation of SU(n) coherent states is characterized by isolated classical trajectories subjected to boundary conditions in a doubled phase space. In this paper we recast this expression in terms of an integral over a set of initial-valued trajectories. These trajectories are monitored by a filter that collects only the appropriate contributions to the semiclassical approximation. This framework is suitable for the study of bosonic dynamics in n modes with fixed total number of particles. We exemplify the method for a Bose-Einstein condensate trapped in …
Quantized systems whose underlying classical dynamics possess an elaborate mixture of regular and chaotic motion can exhibit rather subtle long-time quantum transport phenomena. In a short wavelength regime where semiclassical theories are most relevant, such transport phenomena, being quintessentially interference based, are difficult to understand with the system's specific long-time classical dynamics. Fortunately, semiclassical methods applied to wave packet propagation can provide a natural approach to understanding the connections, even though they are known to break down progressively a…
We present a detailed derivation of the semiclassical propagator in the SU(n) coherent state representation. In order to provide support for immediate physical applications, we restrict this work to the fully symmetric irreducible representations, which are suitable for the treatment of bosonic dynamics in n modes, considering systems with conservation of total particle number. The derivation described here can be easily extended to other classes of coherent states, thus representing an alternative approach to previously published methods.
A detailed derivation of the semiclassical propagator in the generalized coherent-state representation is performed by applying the saddle-point method to a path integral over the classical phase space. With the purpose of providing greater accessibility and applicability to the developed formalism, a brief review of the generalized concept of coherent states is presented, in which three examples of coherent-state sets are examined, namely, the canonical, spin, and SU(n) bosonic coherent states.
We numerically compare the semiclassical ``frozen Gaussian'' Herman-Kluk propagator [Chem. Phys. 91, 27 (1984)] and the ``thawed Gaussian'' propagator put forward recently by Baranger et al. [J. Phys. A 34, 7227 (2001)] by studying the quantum dynamics in some nonlinear one-dimensional potentials. The reasons for the lack of long time accuracy and norm conservation in the latter method are uncovered. We amend the thawed Gaussian propagator with a global harmonic approximation for the stability of the trajectories and demonstrate that this revised propagator is a true alternative to the Herman-…
We analyze the dynamical generation of entanglement in systems of two interacting spins initially prepared in a product of spin coherent states. For arbitrary time-independent Hamiltonians, we derive a semiclassical expression for the purity of the reduced density matrix as function of time. The final formula, subsidiary to the linear entropy, shows that the short-time dynamics of entanglement depends exclusively on the stability of trajectories governed by the underlying classical Hamiltonian. Also, this semiclassical measure is shown to reproduce the general properties of its quantum counter…
For two Coulombically interacting electrons in a quantum dot with harmonic confinement and a constant magnetic field, we show that time-dependent semiclassical calculations using the Herman-Kluk initial value representation of the propagator lead to eigenvalues of the same accuracy as WKB calculations with Langer correction. The latter are restricted to integrable systems, however, whereas the time-dependent initial value approach allows for applications to high-dimensional, possibly chaotic dynamics and is extendable to arbitrary shapes of the potential.
It is shown that the semiclassical coherent state propagator takes its simplest form when the quantum mechanical Hamiltonian is replaced by its Weyl symbol in defining the classical action, in that there is then no need of a Solari-Kochetov correction. It is also shown that such a correction exists if a symbol other than the Weyl symbol is chosen, and that its form is different depending on the symbol chosen. The various forms of the propagator based on different symbols are shown to be equivalent provided the correspondingly correct Solari-Kochetov correction is included. All these results ar…
We present a complete derivation of the semiclassical limit of the coherent state propagator in one dimension, starting from path integrals in phase space. We show that the arbitrariness in the path integral representation, which follows from the overcompleteness of the coherent states, results in many different semiclassical limits. We explicitly derive two possible semiclassical formulae for the propagator, we suggest a third one, and we discuss their relationships. We also derive an initial value representation for the semiclassical propagator, based on an initial gaussian wavepacket. It tu…
We present a rigorous derivation of a semiclassical propagator for anticommuting (fermionic) degrees of freedom, starting from an exact representation in terms of Grassmann variables. As a key feature of our approach the anticommuting variables are integrated out exactly, and an exact path integral representation of the fermionic propagator in terms of commuting variables is constructed. Since our approach is not based on auxiliary (Hubbard-Stratonovich) fields, it surpasses the calculation of fermionic determinants yielding a standard form $\int {\cal D}[ψ,ψ^{*}] {\rm e}^{i R[ψ,ψ^{*}]}$ with …
The phenomenology of quantum systems in curved space-times is among the most fascinating fields of physics, allowing --often at the gedankenexperiment level-- constraints on tentative theories of quantum gravity. Determining the dynamics of fields in curved backgrounds remains however a complicated task because of the highly intricate partial differential equations involved, especially when the space metric exhibits no symmetry. In this article, we provide --in a pedagogical way-- a general formalism to determine this dynamics at the semiclassical order. To this purpose, a generic expression f…
A mixed semiclassical initial value representation expression for spectroscopic calculations is derived. The formulation takes advantage of the time-averaging filtering and the hierarchical properties of different trajectory based propagation methods. A separable approximation is then introduced that greatly reduces (about an order of magnitude) the computational cost compared with a full Herman-Kluk time-averaging semiclassical calculation for the same systems. The expression is exact for the harmonic case and it is tested numerically for a Morse potential coupled to one or two additional har…
Using phase-space complexification, an Initial Value Representation (IVR) for the semiclassical propagator in position space is obtained as a composition of inverse Segal-Bargmann (S-B) transforms of the semiclassical coherent state propagator. The result is shown to be free of caustic singularities and identical to the Herman-Kluk (H-K) propagator, found ubiquitously in physical and chemical applications. We contrast the theoretical aspects of this particular IVR with the van Vleck-Gutzwiller (vV-G) propagator and one of its IVRs, often employed in order to evade the non-linear "root-search" …
We propose a conjugate application of the Bargmann representation of quantum mechanics. Applying the Maslov method to the semiclassical connection formula between the two representations, we derive a uniform semiclassical approximation for the coherent state propagator which is finite at phase space caustics.
We present a semiclassical approach to many-body quantum propagation in terms of coherent sums over quantum amplitudes associated with the solutions of corresponding classical nonlinear wave equations. This approach adequately describes interference effects in the many-body space of interacting bosonic systems. The main quantity of interest, the transition amplitude between Fock states when the dynamics is driven by both single-particlecontributions and many-body interactions of similar magnitude, is non-perturbatively constructed in the spirit of Gutzwiller's derivation of the van Vleck propa…
The dynamical generation of entanglement in closed bipartite systems is investigated in the semiclassical regime. We consider a model of two particles, initially prepared in a product of coherent states, evolving in time according to a generic Hamiltonian, and derive a formula for the linear entropy of the reduced density matrix using the semiclassical propagator in the coherent-state representation. The formula is explicitly written in terms of quantities that define the stability of classical trajectories of the underlying classical system. The formalism is then applied to the problem of two…
A way of construction of semiclassical wave function (SWF) based on the Maslov - Fedoriuk approach is proposed which appears to be appropriate also for systems with chaotic classical limits. Some classical constructions called skeletons are considered. The skeletons are generalizations of Arnolds' tori able to gather chaotic dynamics. SWF's are continued by caustic singularities in the configuration space rather then in the phase space using complex time method. The skeleton formulation provides us with a new algorithm for the semiclassical approximation method which is applied to construct SW…
Based on the integral representation of the semiclassical propagator of Herman and Kluk (HK), and in the limit of high temperatures, we formulate a hybrid expression for the correlation function of infrared spectroscopy. This is achieved by performing a partial linearization inside the integral over the difference of phase space variables that occurs after a twofold application of the HK propagator. A numerical case study for a coupled anharmonic oscillator shows that already for a total number of only two degrees of freedom, one of which is treated in the simplified manner, a substantial redu…
The spin coherent state path integral describing the dynamics of a spin-1/2-system in a magnetic field of arbitrary time-dependence is considered. Defining the path integral as the limit of a Wiener regularized expression, the semiclassical approximation leads to a continuous minimal action path with jumps at the endpoints. The resulting semiclassical propagator is shown to coincide with the exact quantum mechanical propagator. A non-linear transformation of the angle variables allows for a determination of the semiclassical path and the jumps without solving a boundary-value problem. The semi…
The quantum Hamiltonian generates in time a family of evolution operators. Continuity of this family holds within any choice of representation and, in particular, for the Weyl propagator, even though its simplest semiclassical approximation may develop caustic singularities. The phase jumps of the Weyl propagator across caustics have not been previously determined. The semiclassical appproximation relies on individual classical trajectories together with their neighbouring tangent map. Based on the latter, one defines a continuous family of unitary tangent propagators, with an exact Weyl repre…
A trajectory segment in an energy shell, which combines to form a closed curve with a segment in another canonically driven energy shell, adds an oscillatory semiclassical contribution to the smooth classical background of the quantum probability density for a transition between their energies. If either segment is part of a Bohr-quantized periodic orbit of either shell, the centre of its endpoints lies on a scar disk of the spectral Wigner function for single static energy shell and the contribution to the transition is reinforced by phase coherence. The exact representation of the transition…
We study classical and quantum maps on the torus phase space, in the presence of noise. We focus on the spectral properties of the noisy evolution operator, and prove that for any amount of noise, the quantum spectrum converges to the classical one in the semiclassical limit. The small-noise behaviour of the classical spectrum highly depends on the dynamics generated by the map. For a chaotic dynamics, the outer spectrum consists in isolated eigenvalues (``resonances'') inside the unit circle, leading to an exponential damping of correlations. On the opposite, in the case of a regular map, par…
Recent experimental progress using ultracold gases in optical lattices necessitates a quantitative theoretical description for a significant number of bosons. In the present paper, we investigate if time-dependent semiclassical initial value methods, with propagators expressed as integrals over phase space using classical trajectories, is suitable to describe interacting bosons, concentrating on a single mode. Despite the nonlinear contribution from the self-interaction, the corresponding classical dynamics allows for a largely analytical treatment of the semiclassical propagator. We find that…
An initial coherent state is propagated exactly by a kicked quantum Hamiltonian and its associated classical stroboscopic map. The classical trajectories within the initial state are regular for low kicking strengths, then bifurcate and become mainly chaotic as the kicking parameter is increased. Time-evolution is tracked using classical, quantum and semiclassical Wigner functions, obtained via the Herman-Kluk propagator. Quantitative comparisons are also included and carried out from probability marginals and autocorrelation functions. Sub-Planckian classical structure such as small stability…
There is no known exact expression for the propagator of a non-relativistic particle colliding with a hard sphere. De Prunelé (2008 {\it J.~Phys.~A:~Math.~Theor.} {\bf 41} 255305) derived a partial wave expansion of the propagator and compared it against some known approximations, including the semiclassical Van Vleck-Gutzwiller (VG) propagator; the VG propagator was evaluated entirely numerically. Here we point out that the VG propagator for the particle-sphere problem admits an analytic expression in terms of elementary functions.
The Heisenberg evolution of a given unitary operator corresponds classically to a fixed canonical transformation that is viewed through a moving coordinate system. The operators that form the bases of the Weyl representation and its Fourier transform, the chord representation, are, respectively, unitary reflection and translation operators. Thus, the general semiclassical study of unitary operators allows us to propagate arbitrary operators, including density operators, i.e. the Wigner function. The various propagation kernels are different representations of the superoperators which act on th…
We study the resonance (or Gamow) eigenstates of open chaotic systems in the semiclassical limit, distinguishing between left and right eigenstates of the non-unitary quantum propagator, and also between short-lived and long-lived states. The long-lived left (right) eigenstates are shown to concentrate as $\hbar\to 0$ on the forward (backward) trapped set of the classical dynamics. The limit of a sequence of eigenstates $\{ψ(\hbar)\}_{\hbar\to 0}$ is found to exhibit a remarkably rich structure in phase space that depends on the corresponding limiting decay rate. These results are illustrated …
The semiclassical approximation of coherent state path integrals is employed to study the dynamics of the Jaynes-Cummings model. Decomposing the Hilbert space into subspaces of given excitation quanta above the ground state, the semiclassical propagator is shown to describe the exact quantum dynamics of the model. We also present a semiclassical approximation that does not exploit the special properties of the Jaynes-Cummings Hamiltonian and can be extended to more general situations. In this approach the contribution of the dominant semiclassical paths and the relevant fluctuations about them…
We study the relationship of the spectral form factor with quantum as well as classical probabilities to return. Defining a quantum return probability in phase space as a trace over the propagator of the Wigner function allows us to identify and resolve manifolds in phase space that contribute to the form factor. They can be associated to classical invariant manifolds such as periodic orbits, but also to non-classical structures like sets of midpoints between periodic points. By contrast to scars in wavefunctions, these features are not subject to the uncertainty relation and therefore need no…
The semiclassical formula for the coherent-state propagator is written in terms of complex classical trajectories of an equivalent classical system. Depending on the parameters involved, more than one trajectory may contribute to the calculation. Eventually, however, two contributing trajectories coalesce, characterizing what is called phase space caustic. In this case, the usual semiclassical formula for the propagator diverges, so that a uniform approximation is required to avoid this singularity. In this paper, we present a non-trivial application illustrating this scenario, and showing the…
This paper deals with the critical issue of approximating the pre-exponential factor in semiclassical molecular dynamics. The pre-exponential factor is important because it accounts for the quantum contribution to the semiclassical propagator of the classical Feynman path fluctuations. Pre-exponential factor approximations are necessary when chaotic or complex systems are simulated. We introduced pre-exponential factor approximations based either on analytical considerations or numerical regularization. The approximations are tested for power spectrum calculations of more and more chaotic mode…
We study the phase-space representation of dynamics of bosons in the semiclassical regime where the occupation number of the modes is large. To this end, we employ the van Vleck-Gutzwiller propagator to obtain an approximation for the Green's function of the Wigner distribution. The semiclassical analysis incorporates interference of classical paths and reduces to the truncated Wigner approximation (TWA) when the interference is ignored. Furthermore, we identify the Ehrenfest time after which the TWA fails. As a case study, we consider a single-mode quantum nonlinear oscillator, which displays…
Employing the path integral approach, we calculate the semiclassical equilibrium density matrix of a particle moving in a nonlinear potential field for coordinates near the top of a potential barrier. As the temperature is decreased, near a critical temperature $T_c$ the harmonic approximation for the fluctuation path integral fails. This is due to a caustic arising at a bifurcation point of the classical paths. We provide a selfconsistent scheme to treat the large quantum fluctuations leading to a nonlinear fluctuation potential. The procedure differs from methods used near caustics of the re…
We use a semiclassical approximation to derive the partition function for an arbitrary potential in one-dimensional Quantum Statistical Mechanics, which we view as an example of finite temperature scalar Field Theory at a point. We rely on Catastrophe Theory to analyze the pattern of extrema of the corresponding path-integral. We exhibit the propagator in the background of the different extrema and use it to compute the fluctuation determinant and to develop a (nonperturbative) semiclassical expansion which allows for the calculation of correlation functions. We discuss the examples of the sin…
We establish the difference between the propagation of semiclassical Wigner functions and classical Liouville propagation. First we re-discuss the semiclassical limit for the propagator of Wigner functions, which on its own leads to their classical propagation. Then, via stationary phase evaluation of the full integral evolution equation, using the semiclassical expressions of Wigner functions, we provide the correct geometrical prescription for their semiclassical propagation. This is determined by the classical trajectories of the tips of the chords defined by the initial semiclassical Wigne…
Conventional scattering theory is incomplete in that it does not adequately describe the behaviour of the wave function at macroscopic distances from the scattering reaction volume. In scattering experiments particles are incident from sources at macroscopic distance and measured at macroscopic distance from the microscopic reaction volume. Standard experimental procedure is to describe asymptotic particle motion by classical mechanics. However, this transition to classical mechanics is not accounted for in standard quantum scattering theory. Hence, we revisit conventional scattering theory wi…
We present a method to efficiently compute the eigenfunctions of classically chaotic systems. The key point is the definition of a modified Gram-Schmidt procedure which selects the most suitable elements from a basis set of scar functions localized along the shortest periodic orbits of the system. In this way, one benefits from the semiclassical dynamical properties of such functions. The performance of the method is assessed by presenting an application to a quartic two dimensional oscillator whose classical dynamics are highly chaotic. We have been able to compute the eigenfunctions of the s…
We present a semiclassical analysis of the quantum propagator of a particle confined on one side by a steeply, monotonically rising potential. The models studied in detail have potentials proportional to $x^α$ for $x>0$; the limit $α\to\infty$ would reproduce a perfectly reflecting boundary, but at present we concentrate on the cases $α=1$ and 2, for which exact solutions in terms of well known functions are available for comparison. We classify the classical paths in this system by their qualitative nature and calculate the contributions of the various classes to the leading-order semiclassic…
We construct, using simple geometrical arguments, a Wigner function defined on a discrete phase space of arbitrary integer Hilbert-space dimension that is free of redundancies. ``Ghost images'' plaguing other Wigner functions for discrete phase spaces are thus revealed as artifacts. It allows to devise a corresponding phase-space propagator in an unambiguous manner. We apply our definitions to eigenstates and propagator of the quantum baker map. Scars on unstable periodic points of the corresponding classical map become visible with unprecedented resolution.
By using the overcompleteness of coherent states we find an alternative form of the unit operator for which the ket and the bra appearing under the integration sign do not refer to the same phase-space point. This defines a new quantum representation in terms of Bargmann functions, whose basic features are presented. A continuous family of secondary reproducing kernels for the Bargmann functions is obtained, showing that this quantity is not necessarily unique for representations based on overcomplete sets. We illustrate the applicability of the presented results by deriving a semiclassical ex…
A semiclassical approximation for an evolving density operator, driven by a "closed" hamiltonian operator and "open" markovian Lindblad operators, is obtained. The theory is based on the chord function, i.e. the Fourier transform of the Wigner function. It reduces to an exact solution of the Lindblad master equation if the hamiltonian operator is a quadratic function and the Lindblad operators are linear functions of positions and momenta. Initially, the semiclassical formulae for the case of hermitian Lindblad operators are reinterpreted in terms of a (real) double phase space, generated by a…
