Analyses of primitive meteorites and cometary samples have shown that the solar nebula must have experienced a phase of large-scale outward transport of small refractory grains as well as homogenization of initially spatially heterogeneous short-lived isotopes. The stable oxygen isotopes, however, were able to remain spatially heterogenous at the $\sim$ 6% level. One promising mechanism for achieving these disparate goals is the mixing and transport associated with a marginally gravitationally unstable (MGU) disk, a likely cause of FU Orionis events in young low-mass stars. Several new sets of MGU models are presented that explore mixing and transport in disks with varied masses (0.016 to 0.13 $M_\odot$) around stars with varied masses (0.1 to 1 $M_\odot$) and varied initial $Q$ stability minima (1.8 to 3.1). The results show that MGU disks are able to rapidly (within $\sim 10^4$ yr) achieve large-scale transport and homogenization of initially spatially heterogeneous distributions of disk grains or gas. In addition, the models show that while single-shot injection heterogeneity is reduced to a relatively low level ($\sim$ 1%), as required for early solar system chronometry, continuous injection of the sort associated with the generation of stable oxygen isotope fractionations by UV photolysis leads to a sustained, relatively high level ($\sim$ 10%) of heterogeneity, in agreement with the oxygen isotope data. These models support the suggestion that the protosun may have experienced at least one FU Orionis-like outburst, which produced several of the signatures left behind in primitive chondrites and comets.
Calcium-Aluminum-rich Inclusions (CAIs), the oldest known solids of the solar system, show evidence for the past presence of short-lived radionuclide beryllium-10, which was likely produced by spallation during protosolar flares. While such $^{10}$Be production has hitherto been modeled at the inner edge of the protoplanetary disk, I calculate here that spallation at the disk surface may reproduce the measured $^{10}$Be/$^9$Be ratios at larger heliocentric distances. Beryllium-10 production in the gas prior to CAI formation would dominate that in the solid. Interestingly, provided the Sun's pr…
The refractory fraction of phosphorus in planet-forming discs
Institute for Theoretical and Computation Physics, Graz University of Technology（格拉茨工业大学理论与计算物理研究所）；Tartu Observatory, University of Tartu（塔尔图大学塔尔图天文台）；Department of Physics and Astronomy, University College London（伦敦大学学院物理与天文学系）；Space Research Institute, Austrian Academy of Sciences（奥地利科学院空间研究所）
Sulfur is one of the most abundant elements in the Universe, with important roles in astro-, geo-, and biochemistry. Its main reservoirs in planet-forming disks have previously eluded detection: gaseous molecules only account for $<1\,$\% of total elemental sulfur, with the rest likely in either ices or refractory minerals. Mechanisms such as giant planets can filter out dust from gas accreting onto disk-hosting stars. For stars above 1.4 solar masses, this leaves a chemical signature on the stellar photosphere that can be used to determine the fraction of each element that is locked in dust. …
The Earth and other rocky bodies in the inner solar system contain significantly less carbon than the primordial materials that seeded their formation. These carbon-poor objects include the parent bodies of primitive meteorites, suggesting that at least one process responsible for solid-phase carbon depletion was active prior to the early stages of planet formation. Potential mechanisms include the erosion of carbonaceous materials by photons or atomic oxygen in the surface layers of the protoplanetary disk. Under photochemically generated favorable conditions, these reactions can deplete the …
The Earth is strongly depleted in carbon compared to the dust in the ISM, implying efficient removal of refractory carbon before parent body formation. It has been argued that grains get rid of their carbon through oxidation and photolysis in the exposed upper disk layers. We assess the efficacy of these C-removal mechanisms accounting for the vertical and radial transport of grains. We obtain the carbon and carbon free mass budget of solids by solving two 1D advection-diffusion equations, accounting for the dust grain size distribution and radial transport. The carbon removal acts on the frac…
We review models of chondrite component transport in the gaseous protoplanetary disk. Refractory inclusions were likely transported by turbulent diffusion and possible early disk expansion, and required low turbulence for their subsequent preservation in the disk, possibly in a dead zone. Chondrules were produced locally but did not necessarily accrete shortly after formation. Water may have been enhanced in the inner disk because of inward drift of solids from further out, but likely not by more than a factor of a few. Incomplete condensation in chondrites may be due to slow reaction kinetics…
Despite being all roughly of solar composition, primitive meteorites (chondrites) present a diversity in their chemical, isotopic and petrographic properties, and in particular a first-order dichotomy between carbonaceous and non-carbonaceous chondrites. We investigate here analytically the dynamics of their components (chondrules, refractory inclusions, metal/sulfide and matrix grains) in protoplanetary disks prior to their incorporation in chondrite parent bodies. We find the dynamics of the solids, subject to gas drag, to be essentially controlled by the "gas-solid decoupling parameter" $S\…
Rocky asteroids and planets display nucleosynthetic isotope variations that are attributed to the heterogeneous distribution of stardust from different stellar sources in the solar protoplanetary disk. Here we report new high precision palladium isotope data for six iron meteorite groups, which display smaller nucleosynthetic isotope variations than the more refractory neighbouring elements. Based on this observation we present a new model in which thermal destruction of interstellar medium dust results in an enrichment of s-process dominated stardust in regions closer to the Sun. We propose t…
The Al/Si and Mg/Si ratios in non-carbonaceous chondrites are lower than the solar (i.e., CI-chondritic) values, in sharp contrast to the non-CI carbonaceous meteorites and the Earth, which are enriched in refractory elements and have Mg/Si ratios that are solar or larger. We show that the formation of a first generation of planetesimals during the condensation of refractory elements implies the subsequent formation of residual condensates with strongly sub-solar Al/Si and Mg/Si ratios. The mixing of residual condensates with different amounts of material with solar refractory/Si element ratio…
JWST Reveals Refractory-Rich Water Ice in Interstellar Comet 3I/ATLAS: Evidence for a Continuum of Grain Properties across Protoplanetary Disks
Southwest Research Institute（西南研究院）；University of Maryland, College Park（马里兰大学帕克分校）；NASA Goddard Space Flight Center（美国宇航局戈达德太空飞行中心）；Catholic University of America（美利坚天主教大学）；Auburn University（奥本大学）；Universität Bern（伯尔尼大学）
Whereas it is generally accepted that calcium-aluminum-rich inclusions (CAIs) from chondritic meteorites formed in a hot environment in the solar protoplanetary disk, the conditions of their formation remain debated. Recent laboratory studies of CAIs have provided new kind of data: their size distributions. We show that size distributions of CAIs measured in laboratory from sections of carbonaceous chondrites have a power law size distribution with cumulative size exponent between -1.7 and -1.9, which translates into cumulative size exponent between -2.5 and -2.8 after correction for sectionin…
The oxygen isotope fractionation scenario, which has been developed to explain the oxygen isotope anomaly in the solar system materials, predicts that CO gas is depleted in 18O in protoplanetary disks, where segregation between solids and gas inside disks had already occurred. Based on ALMA observations, we report the first detection of HC18O+(4-3) in a Class II protoplanetary disk (TW Hya). This detection allows us to explore the oxygen isotope fractionation of CO in the TW Hya disk from optically thin HCO+ isotopologues as a proxy of optically thicker CO isotopologues. Using the H13CO+(4-3) …
We propose the possibility of a new phenomenon affecting the settling of dust grains at the terrestrial region in early protoplanetary disks. Sinking dust grains evaporate in a hot inner region during the early stage of disk evolution, and the effects of condensation and evaporation on vertical dust settling can be significant. A 1-D dust settling model considering both physical and chemical aspects is presented in this paper. Modeling results show that dust grains evaporate as they descend into the hotter interior and form a "condensation front," above which dust-composing major elements, Mg,…
Measuring the amount of gas and dust in protoplanetary disks is a key challenge in planet formation studies. Here we provide a new set of dust depletion factors and relative mass surface densities of gas and dust for the innermost regions of a sample of protoplanetary disks. We do this by combining stellar theory with observed refractory element abundances in both disk hosts and open cluster stars. Our results are independent of, and complementary to, those obtained from spatially resolved disk observations.
We use new experiments and a theoretical analysis of the results to show that the isotopic fractionation associated with laser-heating aerodynamic levitation experiments is consistent with the velocity of flowing gas as the primary control on the fractionation. The new Fe and Mg isotope data are well explained where the gas is treated as a low-viscosity fluid that flows around the molten spheres with high Reynolds numbers and minimal drag. A relationship between the ratio of headwind velocity to thermal velocity and saturation is obtained on the basis of this analysis. The recognition that it …
Planetary systems are thought to be born in protoplanetary disks. Isotope ratios are a powerful tool for investigating the material origin and evolution from molecular clouds to planetary systems via protoplanetary disks. However, it is challenging to measure the isotope (isotopologue) ratios, especially in protoplanetary disks, because the emission lines of major species are saturated. We developed a new method to overcome these challenges by using optically thin line wings induced by thermal broadening. As a first application of the method, we analyzed two carbon monoxide isotopologue lines,…
Here we aim to explore the origin of the strong C2H lines to reimagine the chemistry of protoplanetary disks. There are a few key aspects that drive our analysis. First, C2H is detected in young and old systems, hinting at a long-lived chemistry. Second, as a radical, C2H is rapidly destroyed, within <1000 yr. These two statements hint that the chemistry responsible for C2H emission must be predominantly in the gas-phase and must be in equilibrium. Combining new and published chemical models we find that elevating the total volatile (gas and ice) C/O ratio is the only natural way to create a l…
Meteoritic chondrules were formed in the early solar system by brief heating of silicate dust to melting temperatures. Some highly refractory grains (Type B calcium-aluminum-rich inclusions, CAIs) also show signs of transient heating. A similar process may occur in other protoplanetary disks, as evidenced by observations of spectra characteristic of crystalline silicates. One possible environment for this process is the turbulent magnetohydrodynamic flow thought to drive accretion in these disks. Such flows generally form thin current sheets, which are sites of magnetic reconnection, and dissi…
We present a comprehensive evolutionary model of the Sun's protoplanetary disk, constructed to resolve the "CAI Storage" problem of meteoritics. We predict the abundances of calcium-rich, aluminum-rich inclusions (CAIs) and refractory lithophile elements under the central assumption that Jupiter's $\sim 30 \, M_{\oplus}$ core forms at about 3 AU at around 0.6 Myr and opened a gap CAIs are trapped in the pressure maximum beyond Jupiter; carbonaceous chondrites formed there. Inside Jupiter's orbit, CAIs were depleted by aerodynamic drag; ordinary and enstatite chondrites formed there. For 16 cho…
Infrared observations probe the warm gas in the inner regions of planet-forming disks around young sun-like, T Tauri stars. In these systems, H$_2$O, OH, CO, CO$_2$, C$_2$H$_2$, and HCN have been widely observed. However, the potentially abundant carbon carrier CH$_4$ remains largely unconstrained. The James Webb Space Telescope (JWST) will be able to characterize mid-infrared fluxes of CH$_4$ along with several other carriers of carbon and oxygen. In anticipation of the JWST mission, we model the physical and chemical structure of a T Tauri disk to predict the abundances and mid-infrared flux…
The presence or absence of variations in the mass-independent abundances of Si isotopes in bulk meteorites provides important clues concerning the evolution of the early solar system. No Si isotopic anomalies have been found within the level of analytical precision of 15 ppm in 29Si/28Si across a wide range of inner solar system materials, including terrestrial basalts, chondrites, and achondrites. A possible exception is the angrites, which may exhibit small excesses of 29Si. However, the general absence of anomalies suggests that primitive meteorites and differentiated planetesimals formed i…
H$_2^{18}$O in the terrestrial planet-forming regions of protoplanetary disks
Vassar College（瓦萨学院）；Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）；Division of Geological and Planetary Sciences, California Institute of Technology（加州理工学院地质与行星科学系）；Department of Astronomy, University of Wisconsin-Madison（威斯康星大学麦迪逊分校天文学系）；Center for Astrophysics, Harvard & Smithsonian（哈佛-史密森尼天体物理中心）；Department of Physics, Texas State University（德克萨斯州立大学物理系）；Weber State University（韦伯州立大学）；Department of Astronomy, University of Michigan（密歇根大学天文学系）；Astrophysics & Space Institute, Schmidt Sciences（施密特科学天体物理学与空间研究所）；Department of Physics and Astronomy, University of Exeter（埃克塞特大学物理与天文系）；Department of Astronomy, University of Maryland（马里兰大学天文学系）
Calcium-aluminum-rich inclusions (CAIs) are the oldest solar system solids known in primitive meteorites (chondrites). They predate the other components by 1-2 Myr, and likely condensed within a short time interval, close to the Sun in the gaseous protoplanetary disk. Their preservation must counterbalance both the sunward drift caused by gas drag and the general inward motion of the entraining gas. We propose that an efficient outward transport of CAIs can be achieved by advection as a result of the viscous expansion of the disk, provided it is initially less than 10 AU in size, which we argu…
We discuss the current state of knowledge of terrestrial planet formation from the aspects of different planet formation models and isotopic data from 182Hf-182W, U-Pb, lithophile-siderophile elements, 48Ca/44Ca isotope samples from planetary building blocks, 36Ar/38Ar, 20Ne/22Ne, 36Ar/22Ne isotope ratios in Venus' and Earth's atmospheres, the expected solar 3He abundance in Earth's deep mantle and Earth's D/H sea water ratios that shed light on the accretion time of the early protoplanets. Accretion scenarios that can explain the different isotope ratios, including a Moon-forming event after …
Chondrites are sediments of materials left over from the earliest stage of the solar system history. Based on their undifferentiated nature and less fractionated chemical compositions, chondrites are widely considered to represent the unprocessed building blocks of the terrestrial planets and their embryos. Models of chemical composition of the terrestrial planets generally find chondritic relative abundances of refractory lithophile elements (RLE) in the bulk bodies ("constant RLE ratio rule"), based on limited variations of RLE ratios among chondritic meteorites and the solar photosphere. He…
Chondrites are the likely building blocks of Earth, and identifying the group of chondrite that best represents Earth is a key to resolving the state of the early Earth. The origin of chondrites, however, remains controversial partly because of their puzzling major element compositions, some exhibiting depletion in Al, Ca, and Mg. Based on a new thermochemical evolution model of protoplanetary disks, we show that planetesimals with depletion patterns similar to ordinary and enstatite chondrites can originate at 1-2 AU just outside where enstatite evaporates. Around the "evaporation front" of e…
[Abridged] Combining a time-dependent astrochemical model with a model of planet formation and migration, we compute the carbon-to-oxygen ratio (C/O) of a range of planetary embryos starting their formation in the inner solar system (1-3 AU). The volatile and ice abundance of relevant carbon and oxygen bearing molecular species are determined through a complex chemical kinetic code which includes both gas and grain surface chemistry. This is combined with a model for the abundance of the refractory dust grains to compute the total carbon and oxygen abundance in the protoplanetary disk availabl…
Current models of (exo)planet formation often rely on a large influx of so-called `pebbles' from the outer disk into the planet formation region. In this paper, we investigate how the formation of pebbles in the cold outer regions of protoplanetary disks and their subsequent migration to the inner disk can alter the gas-phase CO distribution both interior and exterior to the midplane CO snowline. By simulating the resulting CO abundances in the midplane as well as the warm surface layer, we identify observable signatures of large-scale pebble formation and migration that can be used as `smokin…
Observations of different molecular lines in protoplanetary disks provide valuable information on the gas kinematics, as well as constraints on the radial density and temperature structure of the gas. With ALMA we have detected H13CO+ (J=4-3) and HC15N (J=4-3) in the HD97048 protoplanetary disk for the first time. We compare these new detections to the ringed continuum mm-dust emission and the spatially resolved CO (J=3-2) and HCO+ (J=4-3) emission. The radial distributions of the H13CO+ and HC15N emission show hints of ringed sub-structure whereas, the optically thick tracers, CO and HCO+, do…
An understanding of the abundance and distribution of water vapor in the innermost region of protoplanetary disks is key to understanding the origin of habitable worlds and planetary systems. Past observations have shown H2O to be abundant and a major carrier of elemental oxygen in disk surface layers that lie within the inner few au of the disk. The combination of high abundance and strong radiative transitions leads to emission lines that are optically thick across the infrared spectral range. Its rarer isotopologue H2-18O traces deeper into this layer and will trace the full content of the …
A fundamental puzzle of our solar system's formation is understanding why the terrestrial bodies including the planets,comets,and asteroids are depleted in $^{16}$O compared to the Sun. The most favored mechanism,the selective photodissociation of CO gas to produce $^{16}$O depleted water,requires finely tuned mixing timescales to transport $^{16}$O depleted water from the cold outer solar system to exchange isotopically with dust grains to produce the $^{16}$O depleted planetary bodies observed today. Here we show that energetic particle irradiation of SiO$_2$ (and Al$_2$O$_3$) makes them sus…
Oxygen Isotopic Compositions of Chondrules as Probes of Solar Protoplanetary Disk Formation
Japan Agency for Marine-Earth Science and Technology（日本海洋地球科学技术局）；Kochi Institute for Core Sample Research, EMS, Japan Agency for Marine-Earth Science and Technology（日本海洋地球科学技术局高知岩心研究所以及EMS）；Marine Core Research Institute, Kochi University（高知大学海洋岩心研究所）；Department of Earth and Planetary Sciences, Institute of Science Tokyo（东京科学大学地球与行星科学系）
Meteorites contain relict decay products of short-lived radionuclides that were present in the protoplanetary disk when asteroids and planets formed. Several studies reported a high abundance of 60Fe (t1/2=2.62+/-0.04 Myr) in chondrites (60Fe/56Fe~6*10-7), suggesting that planetary materials incorporated fresh products of stellar nucleosynthesis ejected by one or several massive stars that exploded in the vicinity of the newborn Sun. We measured 58Fe/54Fe and 60Ni/58Ni isotope ratios in whole rocks and constituents of differentiated achondrites (ureilites, aubrites, HEDs, and angrites), unequi…
Ortho-Para Chemistry of H2CO in the Protoplanetary Disk TW Hya
Université Grenoble Alpes（格勒诺布尔阿尔卑斯大学）；CNRS（法国国家科学研究中心）；Korea Astronomy and Space Science Institute（韩国天文学与空间科学研究院）；National Astronomical Observatory of Japan（日本国立天文台）；RIKEN Pioneering Research Institute（理化学研究所前沿研究机构）
Injection of material from a core-collapse supernova into the solar system's already-formed disk is one proposed mechanism for producing the short-lived radionuclides, such as 26Al and 41Ca, inferred from isotopic studies of meteorites to have existed in the solar nebula. This hypothesis has recently been challenged on the basis that the injection of enough supernova material to match the meteoritic abundances of 26Al and 41Ca would produce large, measureable, and unobserved collateral effects on oxygen isotopes. Here we calculate again the shifts in oxygen isotopes due to injection of superno…
