Atomic clock transitions in silicon-based spin qubits
Gary Wolfowicz, Alexei M. Tyryshkin, Richard E. George, Helge Riemann, Nikolai V. Abrosimov, Peter Becker, Hans-Joachim Pohl, Mike L. W. Thewalt, Stephen A. Lyon, John J. L. Morton
A major challenge in using spins in the solid state for quantum technologies is protecting them from sources of decoherence. This can be addressed, to varying degrees, by improving material purity or isotopic composition for example, or active error correction methods such as dynamic decoupling, or even combinations of the two. However, a powerful method applied to trapped ions in the context of frequency standards and atomic clocks, is the use of particular spin transitions which are inherently robust to external perturbations. Here we show that such `clock transitions' (CTs) can be observed for electron spins in the solid state, in particular using bismuth donors in silicon. This leads to dramatic enhancements in the electron spin coherence time, exceeding seconds. We find that electron spin qubits based on CTs become less sensitive to the local magnetic environment, including the presence of 29Si nuclear spins as found in natural silicon. We expect the use of such CTs will be of additional importance for donor spins in future devices, mitigating the effects of magnetic or electric field noise arising from nearby interfaces.
Electrically detected magnetic resonance of $^{75}$As magnetic clock transitions in silicon
University of Melbourne（墨尔本大学）；University of Manchester（曼彻斯特大学）；University College London（伦敦大学学院）；RMIT University（皇家墨尔本理工大学）；Australian Research Council Centre for Quantum Computation and Communication Technology（澳大利亚研究委员会量子计算与通信技术中心）；CSIRO（联邦科学与工业研究组织）
Semiconductors offer a promising platform for physical implementation of qubits, but their broad adoption is presently hindered by limited scalability and/or very low operating temperatures. Learning from the nitrogen-vacancy centers in diamond, our goal is to find equivalent optically active point defect centers in crystalline silicon, which could be advantageous for their scalability and integration with classical devices. Transition metal (TM) impurities in silicon are common paramagnetic deep defects, but a comprehensive theoretical study of the whole 3$d$ series that considers generalized…
Cubic silicon carbide is an excellent platform for integration of defect qubits into established wafer scale device architectures for quantum information and sensing applications, where divacancy qubit, that is similar to the negatively charged nitrogen-vacancy (NV) center in diamond, has favorable coherence properties. We demonstrate by means of density functional theory calculations that divacancy in 3C SiC has superior spin-stress coupling parameters and stress sensitivity for nanoscale, quantum enhanced photonic, optoelectronic and optomechanical devices.
Two-Ievel (qubit) clock systems are often used to perform precise measurement of time. In this work, we propose a compression protocol for $n$ identically prepared states of qubit clocks. The protocol faithfully encodes the states into $(1/2)\log n$ qubits and $(1/2)\log n$ classical bits and works even in the presence of noise. If the purity of the clock states is fixed, $(1/2)\log n$ qubits are sufficient. We also prove that this protocol requires the minimum amount of total memory among all protocols with vanishing error in the large $n$ limit.
We investigate the emergent time scenario in quantum cosmology based on the Page-Wotters approach. Using a quantum cosmological model with a qubit clock, it is demonstrated how the entanglement between the qubit clock and the geometry derives emergence of a time parameter which defines evolution of the timeless quantum state of the universe. We show the universe wave function conditioned by a qubit clock obeys the standard Schrödinger equation and the Fisher information for the clock state, which quantifies entanglement between the universe and the clock, contributes as a negative energy densi…
High-precision manipulation of multi-qubit quantum systems requires strictly clocked and synchronized multi-channel control signals. However, practical Arbitrary Waveform Generators (AWGs) always suffer from random signal jitters and channel latencies that induces non-ignorable state or gate operation errors. In this paper, we analyze the average gate error caused by clock noises, from which an estimation formula is derived for quantifying the control robustness against clock noises. This measure is then employed for finding robust controls via a homotopic optimization algorithm. We also intro…
A good qubit must have a coherence time long enough for gate operations to be performed. Avoided level crossings allow for clock transitions in which coherence is enhanced by the insensitivity of the transition to fluctuations in external fields. Because of this insensitivity, it is not obvious how to effectively couple qubits together while retaining clock-transition behavior. Here we present a scheme for using a heterodimer of two coupled molecular nanomagnets, each with a clock transition at zero magnetic field, in which all of the gate operations needed to implement one- and two-qubit gate…
Efficient implementation of quantum algorithms requires single- or multi-qubit gates with high fidelity. In this report, we report that the fidelity of single-qubit gate operations on open quantum systems has a maximum value corresponding to an optimum value of the drive-amplitude in the presence of drive-induced decoherence. To show this, we use a previously reported fluctuation-regulated quantum master equation [Phys. Rev. A 97, 063837 (2018)]. The fidelity is found to be a function of the drive-induced dissipative terms as well as the relaxation terms arising from the qubit-environment coup…
Silicon-vacancy qubits in silicon carbide (SiC) are emerging tools in quantum technology applications due to their excellent optical and spin properties. In this paper, we explore the effect of temperature and strain on these properties by focusing on the two silicon-vacancy qubits, V1 and V2, in 4H SiC. We apply density functional theory beyond the Born-Oppenheimer approximation to describe the temperature dependent mixing of electronic excited states assisted by phonons. We obtain polaronic gap around 5 and 22~meV for V1 and V2 centers, respectively, that results in significant difference in…
Enhanced coherence in HoW$_{10}$ molecular spin qubits has been demonstrated by use of Clock Transitions (CTs). More recently it was shown that, while operating at the CTs, it was possible to use an electrical field to selectively address HoW$_{10}$ molecules pointing in a given direction, within a crystal that contains two kinds of identical but inversion-related molecules. Herein we theoretically explore the possibility of employing the electric field to effect entangling two-qubit quantum gates among two neighbouring CT-protected HoW$_{10}$ qubits within a diluted crystal. We estimate the t…
Continuous clocks, i.e. the clocks that measure time in a continuous manner, are regarded as an essential component of sensing technology. Precision and recurrence time are two basic features of continuous clocks. In this paper, in the framework of quantum estimation theory various models for continuous quantum clocks are proposed, where all tools of quantum estimation theory are employed to seek the characteristics of clocks with high precision and long recurrence time. Then, in a resource-based approach, the performance of the proposed models is compared. It is shown that quantum clocks base…
Quantum key distribution (QKD) systems provide a method for two users to exchange a provably secure key. Synchronizing the users' clocks is an essential step before a secure key can be distilled. Qubit-based synchronization protocols directly use the transmitted quantum states to achieve synchronization and thus avoid the need for additional classical synchronization hardware. Previous qubit-based synchronization protocols sacrifice secure key either directly or indirectly, and all known qubit-based synchronization protocols do not efficiently use all publicly available information published b…
Large-scale quantum computers rely on quantum error correction to protect the fragile quantum information. Among the possible candidates of quantum computing devices, silicon-based spin qubits hold a great promise due to their compatibility to mature nanofabrication technologies for scaling up. Recent advances in silicon-based qubits have enabled the implementations of high quality one and two qubit systems. However, the demonstration of quantum error correction, which requires three or more coupled qubits and often involves a three-qubit gate, remains an open challenge. Here, we demonstrate a…
The three-qubit Toffoli gate plays an important role in quantum error correction and complex quantum algorithms such as Shor's factoring algorithm, motivating the search for efficient implementations of this gate. Here we introduce a Toffoli gate suitable for exchange-coupled electron spin qubits in silicon quantum dot arrays. Our protocol is a natural extension of a previously demonstrated resonantly driven CNOT gate for silicon spin qubits. It is based on a single exchange pulse combined with a resonant microwave drive, with an operation time on the order of 100 ns and fidelity exceeding 99%…
Control of entanglement between qubits at distant quantum processors using a two-qubit gate is an essential function of a scalable, modular implementation of quantum computation. Among the many qubit platforms, spin qubits in silicon quantum dots are promising for large-scale integration along with their nanofabrication capability. However, linking distant silicon quantum processors is challenging as two-qubit gates in spin qubits typically utilize short-range exchange coupling, which is only effective between nearest-neighbor quantum dots. Here we demonstrate a two-qubit gate between spin qub…
As designs for superconducting qubits become more complex, 3D integration of two or more vertically bonded chips will become necessary to enable increased density and connectivity. Precise control of the spacing between these chips is required for accurate prediction of circuit performance. In this paper, we demonstrate an improvement in the planarity of bonded superconducting qubit chips while retaining device performance by utilizing hard-stop silicon spacer posts. These silicon spacers are defined by etching several microns into a silicon substrate and are compatible with 3D-integrated qubi…
Silicon spin qubits satisfy the necessary criteria for quantum information processing. However, a demonstration of high fidelity state preparation and readout combined with high fidelity single- and two-qubit gates, all of which must be present for quantum error correction, has been lacking. We use a two qubit Si/SiGe quantum processor to demonstrate state preparation and readout with fidelity over 97%, combined with both single- and two-qubit control fidelities exceeding 99%. The operation of the quantum processor is quantitatively characterized using gate set tomography and randomized benchm…
Preserving coherence long enough to perform meaningful calculations is one of the major challenges on the pathway to large scale quantum computer implementations. Noise coupled from the environment is the main contributing factor to decoherence but can be mitigated via engineering design and control solutions. However, this is only possible after acquiring a thorough understanding of the dominant noise sources and their spectrum. In this paper, we employ a silicon quantum dot spin qubit as a metrological device to study the noise environment experienced by the qubit. We compare the sensitivity…
Quantum systems must be prepared, controlled, and measured with high fidelity in order to perform complex quantum algorithms. Control fidelities have greatly improved in silicon spin qubits, but state preparation and readout fidelities have generally been poor. By operating with low electron temperatures and employing high-bandwidth cryogenic amplifiers, we demonstrate single qubit readout visibilities >99%, exceeding the threshold for quantum error correction. In the same device, we achieve average single qubit control fidelities >99.95%. Our results show that silicon spin qubits can be opera…
Silicon quantum dot spin qubits provide a promising platform for large-scale quantum computation because of their compatibility with conventional CMOS manufacturing and the long coherence times accessible using $^{28}$Si enriched material. A scalable error-corrected quantum processor, however, will require control of many qubits in parallel, while performing error detection across the constituent qubits. Spin resonance techniques are a convenient path to parallel two-axis control, while Pauli spin blockade can be used to realize local parity measurements for error detection. Despite this, sili…
Nanofabrication techniques for superconducting qubits rely on resist-based masks patterned by electron-beam or optical lithography. We have developed an alternative nanofabrication technique based on free-standing silicon shadow masks fabricated from silicon-on-insulator wafers. These silicon shadow masks not only eliminate organic residues associated with resist-based lithography, but also provide a pathway to better understand and control surface-dielectric losses in superconducting qubits by decoupling mask fabrication from substrate preparation. We have successfully fabricated aluminum 3D …
A fault-tolerant quantum processor may be configured using stationary qubits interacting only with their nearest neighbours, but at the cost of significant overheads in physical qubits per logical qubit. Such overheads could be reduced by coherently transporting qubits across the chip, allowing connectivity beyond immediate neighbours. Here we demonstrate high-fidelity coherent transport of an electron spin qubit between quantum dots in isotopically-enriched silicon. We observe qubit precession in the inter-site tunnelling regime and assess the impact of qubit transport using Ramsey interferom…
Integrated optics is an engineering solution proposed for exquisite control of photonic quantum information. Here we use silicon photonics and the linear combination of quantum operators scheme to realise a fully programmable two-qubit quantum processor. The device is fabricated with readily available CMOS based processing and comprises four nonlinear photon-sources, four filters, eighty-two beam splitters and fifty-eight individually addressable phase shifters. To demonstrate performance, we programmed the device to implement ninety-eight various two-qubit unitary operations (with average qua…
Beyond-Ten-Hour Coherence in a Decoherence-Free Trapped-Ion Clock Qubit
Tsinghua University（清华大学）；Beijing Academy of Quantum Information Sciences（北京量子信息科学研究院）；Hefei National Laboratory（合肥国家实验室）；Renmin University of China（中国人民大学）
We develop the theory of single-electron silicon spin qubit relaxation in the presence of a magnetic field gradient. Such field gradients are routinely generated by on-chip micromagnets to allow for electrically controlled quantum gates on spin qubits. We build on a valley-dependent envelope function theory that enables the analysis of the electron wave function in a silicon quantum dot with an arbitrary roughness at the interface. We assume the presence of single-layer atomic steps at a Si/SiGe interface and study how the presence of a gradient field modifies the spin-mixing mechanisms. We sh…
To date, the highest fidelity quantum logic gates between two qubits have been achieved with variations on the geometric-phase gate in trapped ions, with the two leading variants being the Molmer-Sorensen gate and the light-shift (LS) gate. Both of these approaches have their respective advantages and challenges. For example, the latter is technically simpler and is natively insensitive to optical phases, but it has not been made to work directly on a clock-state qubit. We present a new technique for implementing the LS gate that combines the best features of these two approaches: By using a s…
Quantum computers have the potential to efficiently solve problems in logistics, drug and material design, finance, and cybersecurity. However, millions of qubits will be necessary for correcting inevitable errors in quantum operations. In this scenario, electron spins in gate-defined silicon quantum dots are strong contenders for encoding qubits, leveraging the microelectronics industry know-how for fabricating densely populated chips with nanoscale electrodes. The sophisticated material combinations used in commercially manufactured transistors, however, will have a very different impact on …
Universal quantum computation will require qubit technology based on a scalable platform, together with quantum error correction protocols that place strict limits on the maximum infidelities for one- and two-qubit gate operations. While a variety of qubit systems have shown high fidelities at the one-qubit level, superconductor technologies have been the only solid-state qubits manufactured via standard lithographic techniques which have demonstrated two-qubit fidelities near the fault-tolerant threshold. Silicon-based quantum dot qubits are also amenable to large-scale manufacture and can ac…
Using micromagnets to enable electron spin manipulation in silicon qubits has emerged as a very popular method, enabling single-qubit gate fidelities larger than 99:9%. However, these micromagnets also apply stray magnetic field gradients onto the qubits, making the spin states susceptible to electric field noise and limiting their coherence times. We describe here a magnet design that minimizes qubit dephasing, while allowing for fast qubit control and addressability. Specifically, we design and optimize magnet dimensions and position relative to the quantum dots, minimizing dephasing from ma…
We propose a superconducting circuit-atom hybrid, where the Rabi oscillation of single excess Cooper pair in the island is stabilized via the common atomic-clock technique. The noise in the superconducting circuit is mapped onto the voltage source which biases the Cooper-pair box via an inductor and a gate capacitor. The fast fluctuations of the gate charge are significantly suppressed by an inductor-capacitor resonator, leading to a long-relaxation-time Rabi oscillation. More importantly, the residual low-frequency fluctuations are further reduced by using the general feedback-control method,…
The flip-flop qubit, encoded in the states with antiparallel donor-bound electron and donor nuclear spins in silicon, showcases long coherence times, good controllability, and, in contrast to other donor-spin-based schemes, long-distance coupling. Electron spin control near the interface, however, is likely to shorten the relaxation time by many orders of magnitude, reducing the overall qubit quality factor. Here, we theoretically study the multilevel system that is formed by the interacting electron and nuclear spins and derive analytical effective two-level Hamiltonians with and without peri…
