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arXiv 1209.1209cond-mat.supr-con
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Fe1. 13 Te磁有序相的一级结构转变

First-order structural transition in the magnetically ordered phase of Fe1.13Te

S. Rößler, Dona Cherian, W. Lorenz, M. Doerr, C. Koz, C. Curfs, Yu. Prots, U. K. Rößler, U. Schwarz, Suja Elizabeth, S. Wirth

摘要:

比热,电阻率,磁化率,线性热膨胀(LTE),和高分辨率同步X射线粉末衍射研究的单晶Fe 1 +yTe(0.06 &lt; y &lt; 0.15)揭示了分裂的一个单一的,一级跃迁y < 0.11 into two transitions for y >0.12。最引人注目的是,对相同样品Fe_(1.13)Te的所有测量一致表明,冷却时,T_N处的磁转变先于较低温度T_s处的一级结构转变。结构转变又与磁结构特征的变化相一致。沿晶体学c轴的LTE测量显示,由于磁有序导致的晶格收缩,在T_N附近出现较小的变形,而在T_s处出现更大的变化。粉末X射线衍射表明,在低于T_s时,晶格对称性发生变化。这种行为与铁磷属元素化物中发生相变的顺序形成鲜明对比。

英文摘要:

Specific heat, resistivity, magnetic susceptibility, linear thermal expansion (LTE), and high-resolution synchrotron X-ray powder diffraction investigations of single crystals Fe1+yTe (0.06 < y < 0.15) reveal a splitting of a single, first-order transition for y < 0.11 into two transitions for y > 0.12. Most strikingly, all measurements on identical samples Fe1.13Te consistently indicate that, upon cooling, the magnetic transition at T_N precedes the first-order structural transition at a lower temperature T_s. The structural transition in turn coincides with a change in the character of the magnetic structure. The LTE measurements along the crystallographic c-axis displays a small distortion close to T_N due to a lattice striction as a consequence of magnetic ordering, and a much larger change at T_s. The lattice symmetry changes, however, only below T_s as indicated by powder X-ray diffraction. This behavior is in stark contrast to the sequence in which the phase transitions occur in Fe pnictides.

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