[This is truncated to suit the whims of the archivers ...]
Parameter studies in LVG models are used to show how the low-lying rotational transitions of common polar molecules HCO+, HCN and CS vary with number density, column density and electron fraction; with molecular properties such as the charge state and permanent dipole moment; and with observational details such as the transition that is observed. Physically-based models are used to check the parameter studies and provide a basis for relating the few extant observations. The parameter studies of LVG radiative transfer models show that lines of polar molecules are uniformly brighter for ions, for lower J-values and for higher dipole moments. Excitation by electrons is more important for J=1-0 lines and contributes rather less to the brightness of CS J=2-1 lines. If abundances are like those seen in absorption, the HCO+ J=1-0 line will be the brightest line after CO, followed by HCN (1-0) and CS (2-1). Because of the very weak rotational excitation in diffuse clouds, emission brightnesses and molecular column densities retain a nearly-linear proportionality under fixed physical conditions, even when transitions are quite optically thick; this implies that changes in relative intensities among different species can be used to infer changes in their relative abundances.
We present a theoretical calculation of the influence of ultraviolet radiative pumping on the excitation of the rotational levels of the ground vibrational state for HD molecules under conditions of the cold diffuse interstellar medium (ISM). Two main excitation mechanisms have been taken into account in our analysis: (i) collisions with atoms and molecules and (ii) radiative pumping by the interstellar ultraviolet (UV) radiation field. The calculation of the radiative pumping rate coefficients $Γ_{\rm ij}$ corresponding to Drane's model of the field of interstellar UV radiation, taking into a…
Several diffuse interstellar bands (DIBs) have profiles with resolved sub-peaks that resemble rotational bands of large molecules. Analysis of these profiles can constrain the sizes and geometries of the DIB carriers, especially if the profiles exhibit clear variations along lines of sight probing different physical conditions. Using the extensive data set from the EDIBLES survey we searched for systematic variations in the peak-to-peak separation of these sub-peaks for the $λλ$5797, 6379, and 6614 DIBs in lines of sight with a single dominant interstellar cloud. We used the spectra of twelve …
Observations of CH$^+$ are used to trace the physical properties of diffuse clouds, but this requires an accurate understanding of the underlying CH$^+$ chemistry. Until this work, the most uncertain reaction in that chemistry was dissociative recombination (DR) of CH$^+$. Using an electron-ion merged-beams experiment at the Cryogenic Storage Ring, we have determined the DR rate coefficient of the CH$^+$ electronic, vibrational, and rotational ground state applicable for different diffuse cloud conditions. Our results reduce the previously unrecognized order-of-magnitude uncertainty in the CH$…
In this paper, we present new data with interstellar C2 (Phillips bands A-X), from observations made with the Ultraviolet-Visual Echelle Spectrograph of the European Southern Observatory. We have determined the interstellar column densities and excitation temperatures of C2 for nine Galactic lines. For seven of these, C2 has never been observed before, so in this case the still small sample of interstellar clouds (26 lines of sight), where a detailed analysis of C2 excitation has been made, has increased significantly. This paper is a continuation of previous works where interstellar molecules…
We present results of analysis of physical conditions (number density, intensity of UV field, kinetic temperature) in the cold H$_2$-bearing interstellar medium of local and high redshift galaxies. Our measurements based on the fit to the observed population of H$_2$ rotational levels and CI fine-structure levels with the help of grids of numerical models calculated with the PDR Meudon code. A joint analysis of low H$_2$ rotational levels and CI fine-structure levels allows to break the degeneracy in the $I_{UV}-n_{\rm{H}}$ plane and provides significantly tighter constraints on the number den…
Utilising previous work by the authors on the spin-coupled rotational cross-sections for electron-CN collisions, data for the associated rate coefficients is presented. Data on rotational, fine-structure and hyperfine-structure transition involving rotational levels up to $N$=20 are computed for temperatures in the range 10 -- 1000~K. Rates are calculated by combining Born-corrected R-matrix calculations with the infinite-order-sudden (IOS) approximation. The dominant hyperfine transitions are those with $ΔN=Δj= ΔF=1$. For dipole-allowed transitions, electron-impact rates are shown to exceed t…
The excitation temperature T_01 derived from the relative intensities of the J = 0 (para) and J = 1 (ortho) rotational levels of H2 has been assumed to be an accurate measure of the kinetic temperature in interstellar environments. In diffuse molecular clouds, the average value of T_01 is ~70 K. However, the excitation temperature T(H3+) derived from the (J,K) = (1,1) (para) and (1,0) (ortho) rotational levels of H3+ has been observed to be ~30 K in the same types of environments. In this work, we present observations of H3+ in three additional diffuse cloud sight lines for which H2 measuremen…
A basic model for the formation of non-equilibrium rotational energy distributions is described for reactive, homo-polar diatomic molecules and ions in the interstellar medium. Kinetic models were constructed to calculate the rotational populations of C2+ under the conditions it would experience in the diffuse interstellar medium. As the non-polar ion reacts with molecular hydrogen, but not atomic hydrogen, the thermalization of a hot nascent rotational population will be arrested by chemical reaction when the H2 density begins to be significant. Populations that deviate strongly from the loca…
We present the first kinematic study of extraplanar diffuse ionized gas (eDIG) in the nearby, face-on disk galaxy M83 using optical emission-line spectroscopy from the Robert Stobie Spectrograph on the Southern African Large Telescope. We use a Markov Chain Monte Carlo method to decompose the [NII]$λλ$6548, 6583, H$α$, and [SII]$λλ$6717, 6731 emission lines into HII region and diffuse ionized gas emission. Extraplanar, diffuse gas is distinguished by its emission-line ratios ([NII]$λ$6583/H$α\gtrsim 1.0$) and its rotational velocity lag with respect to the disk ($Δv = -24$ km/s in projection).…
We present a study of the magnetic field of the Large Magellanic Cloud (LMC), carried out using diffuse polarized synchrotron emission data at 1.4 GHz acquired at the Parkes Radio Telescope and the Australia Telescope Compact Array. The observed diffuse polarized emission is likely to originate above the LMC disk on the near side of the galaxy. Consistent negative rotation measures (RMs) derived from the diffuse emission indicate that the line-of-sight magnetic field in the LMC's near-side halo is directed coherently away from us. In combination with RMs of extragalactic sources that lie behin…
Magnetism is one of the most important forces on the interstellar medium (ISM), anisotropically regulating the structure and star formation that drive galactic evolution. Recent high dynamic range observations of diffuse gas and molecular clouds have revealed new links between interstellar structures and the ambient magnetic field. ISM morphology encodes rich physical information, but deciphering it requires high-resolution measurements of the magnetic field: linear polarization of starlight and dust emission, and Zeeman splitting. These measure different components of the magnetic field, and …
Absorption spectra toward Herschel 36 for the A^1Pi <-- X^1Sigma transitions of CH+ in the J=1 excited rotational level and the A^2Delta <-- X^2Pi transition of CH in the J=3/2 excited fine structure level have been analyzed. These excited levels are above their ground levels by 40.1 K and ~25.7 K and indicate high radiative temperatures of the environment, 14.6 K and 6.7 K, respectively. The effect of the high radiative temperature is more spectacular in some diffuse interstellar bands (DIBs) observed toward Her 36; remarkable extended tails toward red (ETR) were observed. We interpret these …
The availability of large datasets with stellar distance and polarization information will enable a tomographic reconstruction of the (plane-of-the-sky-projected) interstellar magnetic field in the near future. We demonstrate the feasibility of such a decomposition within a small region of the diffuse ISM. We combine measurements of starlight (R-band) linear polarization obtained using the RoboPol polarimeter with stellar distances from the second Gaia data release. The stellar sample is brighter than 17 mag in the R band and reaches out to several kpc from the Sun. HI emission spectra reveal …
We present measurements of circular polarization from rotational spectral lines of molecular species in Orion KL, most notably 12CO (J=2 - 1), obtained at the Caltech Submillimeter Observatory with the Four-Stokes-Parameter Spectra Line Polarimeter. We find levels of polarization of up to 1 to 2% in general, for 12CO (J=2 - 1) this level is comparable to that of linear polarization also measured for that line. We present a physical model based on resonant scattering in an attempt to explain our observations. We discuss how slight differences in scattering amplitudes for radiation polarized par…
We explore via spectroscopic modeling whether the highly correlated diffuse interstellar bands at 6613.6 and 6196.0 Å might originate from a single molecule. Efforts were made to simulate the band contours of the DIBs along the three lines-of-sight, which have been observed by others at high resolution: HD179406, HD174165, and Her 36. Reasonable simultaneous fits were obtained using a prolate symmetric top molecule that exhibits transitions of two different band types, type-a parallel and type-b perpendicular bands. Two different excited states of a long- or heavy-chain, forked molecule are pr…
Context: An unexpectedly complex polyatomic chemistry exists in diffuse clouds, allowing detection of species such as C2H, C3H2, H2CO and NH3 which have relative abundances that are strikingly similar to those inferred toward the dark cloud TMC-1 Aims: We probe the limits of complexity of diffuse cloud polyatomic chemistry. Methods: We used the IRAM Plateau de Bure Interferometer to search for galactic absorption from low-lying J=2-1 rotational transitions of A- and E-CH3OH near 96.740 GHz and used the VLA to search for the J=8-7 transition of HC5N at 21.3 GHz. Results: Neither CH3OH nor HC5N …
We present a model for the diffuse interstellar dust that explains the observed wavelength-dependence of extinction, emission, linear and circular polarisation of light. The model is set-up with a small number of parameters. It consists of a mixture of amorphous carbon and silicate grains with sizes from the molecular domain of 0.5 up to about 500nm. Dust grains with radii larger than 6nm are spheroids. Spheroidal dust particles have a factor 1.5 - 3 larger absorption cross section in the far IR than spherical grains of the same volume. Mass estimates derived from submillimeter observations th…
Context. The identification of the carriers of diffuse interstellar bands (DIBs) remains one of the long-standing mysteries in astronomy. The detection of a polarisation signal in a DIB profile can be used to distinguish between a dust or gas-phase carrier. The polarisation profile can give additional information on the grain or molecular properties of the absorber. In order to detect and measure the linear and circular polarisation of the DIBs we observed reddened lines of sight showing continuum polarisation. For this study we selected two stars HD 197770 and HD 194279. We used high-resoluti…
It is well known that the dust properties of the diffuse interstellar medium exhibit variations towards different sight-lines on a large scale. We have investigated the variability of the dust characteristics on a small scale, and from cloud-to-cloud. We use low-resolution spectro-polarimetric data obtained in the context of the Large Interstellar Polarisation Survey (LIPS) towards 59 sight-lines in the Southern Hemisphere, and we fit these data using a dust model composed of silicate and carbon particles with sizes from the molecular to the sub-micrometre domain. Large (> 6 nm) silicates of p…
Context: We investigate non-Zeeman circular polarization and linear polarization levels of up to 1% of $^{12}$CO spectral line emission detected in a shocked molecular clump around the supernova remnant (SNR) IC 443, with the goal of understanding the magnetic field structure in this source. Aims: We examine our polarization results to confirm that the circular polarization signal in CO lines is caused by a conversion of linear to circular polarization, consistent with anisotropic resonant scattering. In this process background linearly polarized CO emission interacts with similar foreground m…
We present very high signal-to-noise ratio absorption-line observations of CN and CH+ along 13 lines of sight through diffuse molecular clouds. The data are examined to extract precise isotopologic ratios of 12CN/13CN and 12CH+/13CH+ in order to assess predictions of diffuse cloud chemistry. Our results on 12CH+/13CH+ confirm that this ratio does not deviate from the ambient 12C/13C ratio in local interstellar clouds, as expected if the formation of CH+ involves nonthermal processes. We find that 12CN/13CN, however, can be significantly fractionated away from the ambient value. The dispersion …
Molecules in diffuse and translucent clouds experience cooling as a result of radiation and less excitation from collisions. However, a rotation around a molecular axis of acetonitrile, CH3CN, cannot be cooled by radiation, causing rotational populations to concentrate at the J = K levels. We aim to search for absorption lines of CH3CN having J = K level concentrations in diffuse and translucent clouds. The JK = 43-33 transition at 73.6 GHz was investigated toward Sgr B2(M) in the Galactic Center region and other sources, using the Nobeyama 45 m telescope. Based on the detected absorption line…
Complex Organic Molecules (COMs) are believed to form in the ice mantle of dust grains and are released to the gas by thermal sublimation when grain mantles are heated to temperatures of $T_{\rm d}\gtrsim 100\,\rm K$. However, some COMs are detected in regions with temperatures below 100 K. Recently, a new mechanism of rotational desorption due to centrifugal stress induced by radiative torques (RATs) is proposed by Hoang & Tram 2020 that can desorb COMs at low temperatures. In this paper, we report observational evidence for rotational desorption of COMs toward the nearest massive star-formin…
Measuring the temperature and abundance patterns of clouds in the interstellar medium (ISM) provides an observational basis for models of the physical conditions within the clouds, which play an important role in studies of star and planet formation. The Colorado High-resolution Echelle Stellar Spectrograph (CHESS) is a far ultraviolet rocket-borne instrument designed to study the atomic-to-molecular transitions within diffuse molecular and translucent cloud regions. The final two flights of the instrument observed $β^{1}$ Scorpii ($β$ Sco) and $γ$ Arae. We present flight results of interstell…
Diffuse and translucent molecular clouds fill a vast majority of the interstellar space in the galactic disk being thus the most typical objects of the Interstellar Medium (ISM). Recent advances in observational techniques of modern optical and ultraviolet spectroscopy led to detection of many features of atomic and molecular origin in spectra of such clouds. Molecular spectra of heteronuclear diatomic molecules, ie. OH, OH+, CH CH+, CN, NH, CO play an important role in understanding chemistry and physical conditions in environments they do populate. A historical review of astronomical observa…
