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arXiv 1111.1126cond-mat.mtrl-sci
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高压下石墨的普适电导率和电动力学

Universal conductivity and the electrodynamics of graphite at high pressures

A. Perucchi, L. Baldassarre, C. Marini, P. Postorino, F. Bernardini, S. Massidda, S. Lupi

摘要:

我们通过同步辐射红外光谱和从头算密度泛函理论计算研究了石墨的面内压力相关电动力学。的德鲁德长期显着增加压力应用时,作为一个结果的电子和空穴电荷密度的增强。这是由于在布里渊区的K点和H点之间沿k_z方向的带色散的增长。另一方面,在800和5000 cm-1之间的中红外光学电导率几乎是平坦的,并且非常弱的压力依赖性,至少高达7 GPa。这证明了石墨的石墨烯样通用量子电导的惊人稳健性,即使当层间距离显著减小时。

英文摘要:

We address the in-plane pressure-dependent electrodynamics of graphite through synchrotron based infrared spectroscopy and ab initio Density Functional Theory calculations. The Drude term remarkably increases upon pressure application, as a consequence of an enhancement of both electron and hole charge densities. This is due to the growth of the band dispersion along the k_z direction between the K and H points of the Brillouin zone. On the other hand, the mid-infrared optical conductivity between 800 and 5000 cm-1 is almost flat, and very weakly pressure dependent, at least up to 7 GPa. This demonstrates a surprising robustness of the graphene-like universal quantum conductance of graphite, even when the interlayer distance is significantly reduced.

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