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arXiv 1108.0197cond-mat.str-el
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铈化合物在零温临界点附近的非典型热力学行为

Atypical thermodynamic behavior of Ce compounds in the vicinity of zero temperature Critical Points

Julian G. Sereni

摘要:

对Ce-基示例性化合物进行的热力学性质的系统分析允许识别当系统接近量子临界区域时的不同类型的行为。它们在各自的磁相边界(T_{N,C}(x))中被识别为从经典负曲率到线性组成($x$)依赖性的变化、临界点的出现或在有限温度下在有限温度下的压力下的消逝。在第一种情况下,在x_{cr}附近观察到熵S_m相对于S_m = RLn ~ 2值(通常的Ce-磁偶极子基态所期望的)的反常减小,并利用对CeIn_{3-x} Sn_x合金的详细研究进行了分析。正如从麦克斯韦关系所预期的,在T=>0处的体积变化V_0(x)也显示出在x_{cr}附近的非单调行为。在有序相(S_{MO})的熵变的不同制度被确认。只有在前一种情况下,当T_{N,C} => 0时,S_{MO} =>0才连续,而在第二种情况下,S_{MO}(x,B)保持恒定,直到发生一阶跃迁。在第三种情况下,MO相的自由度逐渐转移到重费米子分量上,表现为C_m(T_N)跃变逐渐减小,并在有限温度下消失。

英文摘要:

A systematic analysis of thermodynamic properties performed on Ce-base exemplary compounds allows to identify different types of behaviors as the system approaches the quantum critical region. They are recognized in the respective magnetic phase boundaries (T_{N,C}(x)) as a change from the classical negative curvature to a linear composition ($x$) dependence, the occurrence of a critical point or the evanescence at finite temperature under pressure at finite temperature. In the first case, an anomalous reduction of the entropy S_m respect to the S_m = RLn2 value (expected for the usual Ce-magnetic doublet ground state) is observed around x_{cr}, and analyzed taking profit of detailed studies performed on CeIn_{3-x}Sn_x alloys. As expected from Maxwell relations, the volume variation V_0(x) at T=>0 also shows a non-monotonous behavior around x_{cr}. Different regimes in the entropy variation of the ordered phase (S_{MO}) are recognized. Only in the former case S_{MO}=> 0 continuously as T_{N,C}=>0, whereas in the second S_{MO}(x,B) remains constant till a first order transition occurs. In the third case, the degrees of freedom of the MO phase are progressively transferred to the heavy fermion component as indicated by the decreasing C_m(T_N) jump which vanishes at finite temperature.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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