The coupling of internal electronic excitations to vibrational modes of the external motion of ultracold atoms in an optical lattice is studied here in using a perturbation expansion in small atomic displacements. In the Mott insulator case with one atom per site, the resonance dipole-dipole coupling between neighboring sites can induce emission and absorption of vibrational quanta. Within a cavity in the strong exciton-photon coupling regime such coupling results in polariton-vibration interactions, which create a significant thermalization mechanism for polaritons toward their minimum energy, and leading to motional heating of the lattice atoms.
Ultracold atoms uniformly filling an optical lattice can be treated like an artificial crystal. An implementation including the atomic occupation of a single excited atomic state can be represented by a two-component Bose-Hubbard model. Its phase diagram exhibits a quantum phase transition from a superfluid to a Mott insulator phase. The dynamics of electronic excitations governed by electrostatic dipole-dipole interactions in the ordered regime can be well described by wave-like collective excitations called excitons. Here we present an extensive study of such excitons for a wide range of geo…
Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity allows condensation at room temperature. The molecules act as saturable absorbers with transitions dressed by molecular vibrational modes. Motivated by this we calculate the phase diagram and spectrum of a modified Tavis-Cummings model, describing vibrationally dressed two-level systems, coupled to a cavity mode. Coupling to vibrational modes can induce re-e…
When molecular transitions strongly couple to photon modes, they form hybrid light-matter modes called polaritons. Collective vibrational strong coupling is a promising avenue for control of chemistry, but this can be deterred by the large number of quasi-degenerate dark modes. The macroscopic occupation of a single polariton mode by excitations, as observed in Bose-Einstein condensation, offers promise for overcoming this issue. Here we theoretically investigate the effect of vibrational polariton condensation on the kinetics of electron transfer processes. Compared with excitation with infra…
We consider an ensemble of ultracold bosonic atoms within a near-planar cavity, driven by a far detuned laser whose phase is modulated at a frequency comparable to the transverse cavity mode spacing. We show that a strong, dispersive atom-photon coupling can be reached for many transverse cavity modes at once. The resulting Floquet polaritons involve a superposition of a set of cavity modes with a density excitation of the atomic cloud. The mutual interactions between these modes lead to distinct avoided crossings between the polaritons. Increasing the laser drive intensity, a low-lying multim…
Advanced data analysis techniques have proved to be crucial for extracting information from noisy images. Here we show that principal component analysis can be successfully applied to ultracold gases to unveil their collective excitations. By analyzing the correlations in a series of images we are able to identify the collective modes which are excited, determine their population, image their eigenfunction, and measure their frequency. Our method allows to discriminate the relevant modes from other noise components and is robust with respect to the data sampling procedure. It can be extended t…
We show how to simulate a model of many molecules with both strong coupling to many vibrational modes and collective coupling to a single photon mode. We do this by combining process tensor matrix product operator methods with a mean-field approximation which reduces the dimension of the problem. We analyze the steady-state of the model under incoherent pumping to determine the dependence of the polariton lasing threshold on cavity detuning, light-matter coupling strength, and environmental temperature. Moreover, by measuring two-time correlations, we study quadratic fluctuations about the mea…
We perform photoassociation spectroscopy in an ultracold $^{23}$Na-$^6$Li mixture to study the $c^3Σ^+$ excited triplet molecular potential. We observe 50 vibrational states and their substructure to an accuracy of 20 MHz, and provide line strength data from photoassociation loss measurements. An analysis of the vibrational line positions using near-dissociation expansions and a full potential fit is presented. This is the first observation of the $c^3Σ^+$ potential, as well as photoassociation in the NaLi system.
Interfacing light and matter at the quantum level is at the heart of modern atomic and optical physics and enables new quantum technologies involving the manipulation of single photons and atoms. A prototypical atom-light interface is electromagnetically induced transparency, in which quantum interference gives rise to hybrid states of photons and atoms called dark-state polaritons. We have observed individual dark-state polaritons as they propagate through an ultracold atomic gas involving Rydberg states. Strong long-range interactions between Rydberg atoms give rise to an effective interacti…
Following experimental realizations of room temperature polariton lasing with organic molecules, we present a microscopic model that allows us to explore the crossover from weak to strong matter-light coupling. We consider a non-equilibrium Dicke-Holstein model, including both strong coupling to vibrational modes and strong matter-light coupling, providing the phase diagram of this model in the thermodynamic limit. We discuss the mechanism of polariton lasing, uncovering a process of self-tuning, and identify the relation and distinction between regular dye lasers and organic polariton lasers.
We report on the creation of ultracold 84Sr2 molecules in the electronic ground state. The molecules are formed from atom pairs on sites of an optical lattice using stimulated Raman adiabatic passage (STIRAP). We achieve a transfer efficiency of 30% and obtain 4x10^4 molecules with full control over the external and internal quantum state. STIRAP is performed near the narrow 1S0-3P1 intercombination transition, using a vibrational level of the 0u potential as intermediate state. In preparation of our molecule association scheme, we have determined the binding energies of the last vibrational l…
We study the combination of hyperfine and Zeeman structure in the spin-orbit coupled $A^1Σ_u^+-b^3Π_u$ complex of $^{87}\textrm{Rb}_2$. For this purpose, absorption spectroscopy at a magnetic field around $B=1000\:\textrm{G}$ is carried out. We drive optical dipole transitions from the lowest rotational state of an ultracold Feshbach molecule to various vibrational levels with $0^+$ symmetry of the $A-b$ complex. In contrast to previous measurements with rotationally excited alkali-dimers, we do not observe equal spacings of the hyperfine levels. In addition, the spectra vary substantially for…
Universal collision rate constants are calculated for ultracold collisions of two like bosonic or fermionic heteronuclear alkali-metal dimers involving the species Li, Na, K, Rb, or Cs. Universal collisions are those for which the short range probability of a reactive or quenching collision is unity such that a collision removes a pair of molecules from the sample. In this case, the collision rates are determined by universal quantum dynamics at very long range compared to the chemical bond length. We calculate the universal rate constants for reaction of the reactive dimers in their ground vi…
