arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1102.2177cond-mat.softcond-mat.dis-nn
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高粘流动机理的探讨

On the mechanism of the highly viscous flow

U. Buchenau

摘要:

高粘性流的不对称模型假设热激活跳跃从一个几乎不扭曲的基态强烈扭曲,但稳定的结构,从扭曲的环境中具有显着的Eshelby背应力。粘性归因于那些稳定的扭曲结构,这些结构不跳回,而是通过周围粘弹性基质的松弛而松弛。它示出,这种机制意味着在剪切顺应性方面的描述,与粘度,可以从延迟谱的截止计算。一致性要求这个截止时间接近麦克斯韦时间。改进后的非对称模型与实验结果吻合较好。

英文摘要:

The asymmetry model for the highly viscous flow postulates thermally activated jumps from a practically undistorted ground state to strongly distorted, but stable structures, with a pronounced Eshelby backstress from the distorted surroundings. The viscosity is ascribed to those stable distorted structures which do not jump back, but relax by the relaxation of the surrounding viscoelastic matrix. It is shown that this mechanism implies a description in terms of the shear compliance, with a viscosity which can be calculated from the cutoff of the retardation spectrum. Consistency requires that this cutoff lies close to the Maxwell time. The improved asymmetry model compares well with experiment.

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