We study maximal bipartite entanglement in valence-bond states and show that the average bipartite entanglement $E_v^2$, between a sub-system of two spins and the rest of the system, can be maximized through a homogenized superposition of the valence-bond states. Our derived maximal $E_v^2$ rapidly increases with system size and saturates at its maximum allowed value. We also demonstrate that our maximal $E^2_v$ states are ground states of an infinite range Heisenberg model (IRHM) and represent a new class of resonating-valence-bond (RVB) states. The entangled RVB states produced from our IRHM are robust against interaction of spins with both local and global phonons and represent a new class of decoherence free states.
We investigate the entanglement properties of resonating-valence-bond states on two and higher dimensional lattices, which play a significant role in our understanding of various many-body systems. We show that these states are genuinely multipartite entangled, while there is only a negligible amount of two-site entanglement. We comment on possible physical implications of our findings.
We investigate the behavior of bipartite as well as genuine multipartite entanglement of a resonating valence bond state on a ladder. We show that the system possesses significant amounts of bipartite entanglement in the steps of the ladder while no substantial bipartite entanglement is present in the rails. Genuine multipartite entanglement present in the system is negligible. The results are in stark contrast with the entanglement properties of the same state on isotropic lattices in two and higher dimensions, indicating that the geometry of the lattice can have important implications on the…
The nature of the kagome Heisenberg antiferromagnet (HAFM) is under ongoing debate. While recent evidence points towards a Z_2 topological spin liquid, the exact nature of the topological phase is still unclear. In this paper, we introduce semionic Resonating Valence Bond (RVB) states, this is, Resonating Valence Bond states which are in the Z_2 ordered double-semion phase, and study them using Projected Entangled Pair States (PEPS). We investigate their physics and study their suitability as an ansatz for the HAFM, as compared to a conventional RVB state which is in the Toric Code Z_2 topolog…
We study controlled generation and measurement of superfluid d-wave resonating valence bond (RVB) states of fermionic atoms in 2D optical lattices. Starting from loading spatial and spin patterns of atoms in optical superlattices as pure quantum states from a Fermi gas, we adiabatically transform this state to an RVB state by change of the lattice parameters. Results of exact time-dependent numerical studies for ladders systems are presented, suggesting generation of RVB states on timescale smaller than typical experimental decoherence times.
We study resonating valence bond (RVB) states in the Projected Entangled Pair States (PEPS) formalism. Based on symmetries in the PEPS description, we establish relations between the toric code state, the orthogonal dimer state, and the SU(2) singlet RVB state on the kagome lattice: We prove the equivalence of toric code and dimer state, and devise an interpolation between the dimer state and the RVB state. This interpolation corresponds to a continuous path in Hamiltonian space, proving that the RVB state is the four-fold degenerate ground state of a local Hamiltonian on the (finite) kagome l…
In a recent Letter [Phys. Rev. Lett. 99, 170502 (2007); quant-ph/0703227], Chandran and coworkers study the entanglement properties of valence bond (VB) states. Their main result is that VB states do not contain (or only an insignificant amount of) two-site entanglement, whereas they possess multi-body entanglement. Two examples ("RVB gas and liquid") are given to illustrate this claim, which essentially comes from a lower bound derived for spin correlators in VB states. We show in this Comment that (i) for the "RVB liquid" on the square lattice, the calculations and conclusions of Chandran et…
We investigate the entanglement properties of resonating valence bond states on a two dimensional lattice in the presence of dopants that remove electrons from the lattice creating "holes". The movement of the holes generated by the Hubbard Hamiltonian in the regime of strong Coloumb repulsion in this setting could be responsible for the phenomenon of high temperature superconductivity as hypothesised by Anderson in Science {\bf 235}, 1196, (1987). We argue that there is a particular density of dopants (holes) where the entanglement contained in the lattice attains its maximal value for the ne…
In Phys. Rev. Lett. 99, 170502 (2007) (arXiv:quant-ph/0703227), we prove that resonating-valence-bond (RVB) states on arbitrary lattices possess genuine multiparty entanglement, and provide bounds on two-particle entanglement (and correlators). We also conjecture on the entanglement in large and small portions of the whole lattice. The proof, bound, and conjecture are not considered in the Comment in Phys. Rev. Lett. 101, 248901 (2008) (arXiv:0812.1932v1 [quant-ph]). Next we take two examples: "RVB gas" and "RVB liquid". RVB liquid for arbitrary lattice size is not considered in the Comment. T…
A resonating valence bond (RVB) state of a lattice of quantum systems is a potential resource for quantum computing and communicating devices. It is a superposition of singlet, i.e., dimer, coverings - often restricted to nearest-neighbour ones - of the lattice. We develop a polynomial representation of multipartite quantum states to prove that RVB states on ladder lattices possess genuine multipartite entanglement. The multipartite entanglement of doped RVB states and RVB states that are superposed with varying weights for singlet coverings of ladder lattices can both be detected by using thi…
The concept of valence bond resonance plays a fundamental role in the theory of the chemical bond and is believed to lie at the heart of many-body quantum physical phenomena. Here we show direct experimental evidence of a time-resolved valence bond quantum resonance with ultracold bosonic atoms in an optical lattice. By means of a superlattice structure we create a three-dimensional array of independent four-site plaquettes, which we can fully control and manipulate in parallel. Moreover, we show how small-scale plaquette resonating valence bond states with s- and d-wave symmetry can be create…
Dicke's original thought experiment with two spins coupled to a photon mode has recently been experimentally realized. We propose extending this experiment to N spins and show that it naturally gives rise to highly entangled states. In particular, it gives rise to dark states which have resonating valence bond (RVB) character. We first consider a system of N two level spins in a cavity with only one spin in the excited state. This initial state is a linear combination of a dark state and a bright state. We point out the dark state is a coherent superposition of singlets with resonating valence…
We examine in details the connections between topological and entanglement properties of short-range resonating valence bond (RVB) wave functions using Projected Entangled Pair States (PEPS) on kagome and square lattices on (quasi-)infinite cylinders with generalized boundary conditions (and perimeters with up to 20 lattice spacings). Making use of disconnected topological sectors in the space of dimer lattice coverings, we explicitly derive (orthogonal) "minimally entangled" PEPS RVB states. For the kagome lattice, we obtain, using the quantum Heisenberg antiferromagnet as a reference model, …
Emergence of Resonating Valence-Bond Correlations in Stretched Graphene
University of Manchester（曼彻斯特大学）；Center for Advanced Systems Understanding（高级系统理解中心）；Helmholtz Zentrum Dresden-Rossendorf（德累斯顿-罗斯多夫亥姆霍兹中心）；TU Dresden（德累斯顿工业大学）
Resonating valence bond (RVB) states are a class of entangled quantum many body wavefunctions with great significance in condensed matter physics. We propose a scheme to synthesize a family of RVB states using a cavity QED setup with two-level atoms (with states $\vert 0 \rangle$ and $\vert 1 \rangle$) coupled to a common photon mode. In the lossy cavity limit, starting with an initial state of $M$ atoms excited and $N$ atoms in the ground state, we show that this setup can be configured as a Stern Gerlach experiment. A measurement of photon emission collapses the wavefunction of atoms onto an…
We exploit a natural Projected Entangled-Pair State (PEPS) representation for the resonating Affleck-Kennedy-Lieb-Tasaki loop (RAL) state. By taking advantage of PEPS-based analytical and numerical methods, we characterize the RAL states on various two-dimensional lattices. On square and honeycomb lattices, these states are critical since the dimer-dimer correlations decay as a power law. On kagome lattice, the RAL state has exponentially decaying correlation functions, supporting the scenario of a gapped spin liquid. We provide further evidence that the RAL state on the kagome lattice is a $\…
We present a theory of a hybrid quantum liquid state, $\textit{quantum spin-dipole liquid}$ (QSDL), in a hydrogen-bonded electron system, by combining a quantum proton ice and Anderson's resonating valence bond spin liquid theory, motivated by the recent experimental discovery of a quantum spin liquid with proton fluctuations in $κ$-H$_3$(Cat-EDT-TTF)$_2$ (a.k.a. H-Cat). In our theory, an electron spin liquid and a proton dipole liquid are realized simultaneously in the ground state called $\textit{quantum valence bond ice}$. In this state, neither of them can be established independently of t…
We construct and study quantum trimer models and resonating SU(3)-singlet models on the kagome lattice, which generalize quantum dimer models and the Resonating Valence Bond wavefunctions to a trimer and SU(3) setting. We demonstrate that these models carry a Z_3 symmetry which originates in the structure of trimers and the SU(3) representation theory, and which becomes the only symmetry under renormalization. Based on this, we construct simple and exact parent Hamiltonians for the model which exhibit a topological 9-fold degenerate ground space. A combination of analytical reasoning and numer…
We study the entanglement properties of two-spin subsystems in spin-singlet states. The average entanglement between two spins is maximized in a single valence-bond (VB) state. On the other hand, $E_v^2$ (the average entanglement between a subsystem of two spins and the rest of the system) can be maximized through a homogenized superposition of the VB states. The maximal $E_v^2$ rapidly increases with system size and saturates at its maximum allowed value. We adopt two ways of obtaining maximal $E_v^2$ states: (1) imposing homogeneity on singlet states; and (2) generating isotropy in a general…
We introduce valence bond fluctuations, or bipartite fluctuations associated to bond-bond correlation functions, to characterize quantum spin liquids and their entanglement properties. Using analytical and numerical approaches, we find an identical scaling law between valence bond fluctuations and entanglement entropy in the two-dimensional Kitaev spin model and in one-dimensional chain analogues. We also show how these valence bond fluctuations can locate quantum phase transitions between the three gapped and the gapless Majorana semi-metal phases in the honeycomb model. We then study the eff…
