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arXiv 1012.2408cond-mat.str-el
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Co $_{1/3}$ NbS $_2$输运性质的高压研究

High pressure study of transport properties in Co$_{1/3}$NbS$_2$

N. Barišić, I. Smiljanić, P. Popčević, A. Bilušić, E. Tutiš, A. Smontara, H. Berger, J. Jaćimović, O. Yuli, L. Forró

摘要:

这是首次研究压力对磁性有序原子嵌入过渡金属二硫属化合物的影响。Co $_{1/3}$ NbS $_2$是一种层状体系,其中Co原子在室温下T $_N$ = 26 K时反铁磁有序排列。我们已经进行了详细的研究直流电阻率($ρ$),热电功率(S)和热导率($κ$)。我们发现,在环境压力下的磁转变对应于一个很明显的峰值dS/dT,以及在直流电阻率的扭结。有序化对热导率的影响相当小,但令人惊讶的是,在晶格贡献中比在电子对$κ$的贡献中更明显。在压力下,在高温范围内的电阻率增加,相反,在其他层状过渡金属二硫属化物(TMD)的所有以前的测量。在低温范围内,观察到热电势和电阻率对压力的强烈依赖性低于TN,这反过来,也取决于在速率为dT $_N$ /dp $\approx$-1 K/kbar的压力。几个可能的微观解释的有序温度的降低和随压力的输运性质的演变进行了讨论。

英文摘要:

This is the first study of the effect of pressure on transition metal dichalcogenides intercalated by atoms that order magnetically. Co$_{1/3}$NbS$_2$ is a layered system where the intercalated Co atoms order antiferromagnetically at T$_N$ = 26 K at ambient pressure. We have conducted a detailed study of dc-resistivity ($ρ$), thermoelectric power (S) and thermal conductivity ($κ$). We found that at ambient pressure the magnetic transition corresponds to a well pronounced peak in dS/dT, as well as to a kink in the dc-resistivity. The effect of ordering on the thermal conductivity is rather small but, surprisingly, more pronounced in the lattice contribution than in the electronic contribution to $κ$. Under pressure, the resistivity increases in the high temperature range, contrary to all previous measurements in other layered transition metal dichalcogenides (TMD). In the low temperature range, the strong dependences of thermopower and resistivity on pressure are observed below TN, which, in turn, also depends on pressure at rate of dT$_N$/dp $\approx$ -1 K/kbar. Several possible microscopic explanations of the reduction of the ordering temperature and the evolution of the transport properties with pressure are discussed.

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