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arXiv 1012.0693cond-mat.softcond-mat.mtrl-sci
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从简单屈服应力流体中的瞬态流化过程到Herschel-Bulkley行为

From transient fluidization processes to Herschel-Bulkley behavior in simple yield stress fluids

Thibaut Divoux, Catherine Barentin, Sébastien Manneville

摘要:

应力诱导流化的一个简单的屈服应力流体,即卡波姆微凝胶,是通过广泛的流变测量耦合到同时的时间和空间分辨测速。这些组合的测量允许我们排除流化过程中的任何大体积的类似泡沫的情况,例如在[Caton { \it et al.,Rheol Acta},2008,{ \bf 47},601-607]。相反,我们观察到的瞬态制度从solidlike到liquidlike的行为下,一个恒定的剪切应力$σ$依次涉及蠕变变形,总壁滑移,剪切带之前,达到均匀的稳定状态。有趣的是,该流化过程的总持续时间$τ_f$与$τ_f \propto 1/(σ- σ_c)^β$成比例,其中$σ_c$代表微凝胶的屈服应力,并且$β$是仅取决于微凝胶性质而不取决于间隙宽度或边界条件的指数。连同最近在施加剪切速率下的实验[Divoux { \it et al.,物理评论快报},2010,{ \bf 104},208301],该标度律提出了一种使经典地用于描述简单屈服应力流体的稳态流变学的现象学赫歇尔-巴尔克利(HB)幂律合理化的途径。特别是,我们表明,{ \it稳态} HB指数出现作为两个流化指数的比例分别从{ \it瞬态}流化过程中提取控制剪切速率和控制剪切应力下。

英文摘要:

Stress-induced fluidization of a simple yield stress fluid, namely a carbopol microgel, is addressed through extensive rheological measurements coupled to simultaneous temporally and spatially resolved velocimetry. These combined measurements allow us to rule out any bulk fracture-like scenario during the fluidization process such as that suggested in [Caton {\it et al., Rheol Acta}, 2008, {\bf 47}, 601-607]. On the contrary, we observe that the transient regime from solidlike to liquidlike behaviour under a constant shear stress $σ$ successively involves creep deformation, total wall slip, and shear banding before a homogeneous steady state is reached. Interestingly, the total duration $τ_f$ of this fluidization process scales as $τ_f \propto 1/(σ- σ_c)^β$, where $σ_c$ stands for the yield stress of the microgel, and $β$ is an exponent which only depends on the microgel properties and not on the gap width or on the boundary conditions. Together with recent experiments under imposed shear rate [Divoux {\it et al., Phys. Rev. Lett.}, 2010, {\bf 104}, 208301], this scaling law suggests a route to rationalize the phenomenological Herschel-Bulkley (HB) power-law classically used to describe the steady-state rheology of simple yield stress fluids. In particular, we show that the {\it steady-state} HB exponent appears as the ratio of the two fluidization exponents extracted separately from the {\it transient} fluidization processes respectively under controlled shear rate and under controlled shear stress.

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